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  • Lembar Perhitungan HMJ

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    Lya Wulandari
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    This document provides calculations for a chemical reaction experiment. It includes: 1) Calculations of reagent volumes and masses, including sodium hydroxide, hydrochloric acid, and oil densities. 2) Calculations of free fatty acid content before and after hydrolysis at different temperatures. 3) Calculations of conversion rates and reaction rate constants based on changes in free fatty acid content over time and temperature. The document thoroughly outlines the calculations and variables considered in analyzing a hydrolysis reaction at various temperatures.

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    Lembar perhitungan Minyak Jarak

    Original Title

    LEMBAR PERHITUNGAN HMJ

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    This document provides calculations for a chemical reaction experiment. It includes: 1) Calculations of reagent volumes and masses, including sodium hydroxide, hydrochloric acid, and oil densities. 2) Calculations of free fatty acid content before and after hydrolysis at different temperatures. 3) Calculations of conversion rates and reaction rate constants based on changes in free fatty acid content over time and temperature. The document thoroughly outlines the calculations and variables considered in analyzing a hydrolysis reaction at various temperatures.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    13 views7 pages

    Lembar Perhitungan HMJ

    Uploaded by

    Lya Wulandari
    This document provides calculations for a chemical reaction experiment. It includes: 1) Calculations of reagent volumes and masses, including sodium hydroxide, hydrochloric acid, and oil densities. 2) Calculations of free fatty acid content before and after hydrolysis at different temperatures. 3) Calculations of conversion rates and reaction rate constants based on changes in free fatty acid content over time and temperature. The document thoroughly outlines the calculations and variables considered in analyzing a hydrolysis reaction at various temperatures.

    Copyright:

    © All Rights Reserved
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    of 7

    LEMBAR PERHITUNGAN REAGEN

    Variable tetap
    Volume total = 300 ml
    Volume emulsifier = 15 ml
    N NaOH = 0,17 N @350 ml
    Perbandingan Vmj dan Vaq = 1:8
    Suhu titrasi = 60C
    N HCl = 0,17 N
    Variable bebas
    Suhu Hidrolisa = 40oC; 55oC; 65oC

    A. Perhitungan Reagen
    Reagen NaOH 0,17 N 350 ml
    gram 1000
    x x1
    N= Mr Volume total
    gram 1000
    x
    0,17 = 40 350

    gram = 2,38 gram

    B. Perhitungan Massa Jenis


    Massa jenis minyak jarak
    Berat picnometer kosong (m1) = 21,489 gram
    Berat picnometer+minyak jarak (m2) = 46,350 gram
    V picnometer = 26,05 ml
    46,35021,489 gr
    =0,95
    Minyak Jarak = 26,05 ml

    Massa jenis katalis (HCl)


    Berat Picnometer kosong (m1) = 21,489 gram
    Berat picnometer+ HCl (m2) = 51,041 gram
    V picnometer = 26,05 ml
    51,04121,489 gr
    =1,13
    HCl = 26,05 ml

    Volume picnometer
    Berat Picnometer kosong (m1) = 21,489 gram
    Berat picnometer+ Air (m2) = 47,489 gram
    picnometer = 0,998
    47,48921,489
    =26,05 ml
    V picnometer = 0,998

    C. Perhitungan Volume HCl


    N . BM . Vtotal
    VHCl = . %HCL.1000.grek

    0,17 x 36,5 x 300


    =6,59 ml
    VHCL = 1,13 x 0,25 x 1000 x 1

    D. Perbandingan mol minyak jarak dan mol aquadest (1:8)


    V total = Vmj + Vaq + Vemulsifier + V HCl
    300 ml = Vmj + Vaq + 15 ml+ 6,59 ml
    278,41 ml = Vmj + Vaq . . . . . (1)

    mj x V mj
    Mol Minyak Jarak = BM mj
    0,95 x Vmj
    = 1067

    = 8,9 x 10-4 V mj
    aq x V aq
    Mol Aquadest = BM aq
    0,998 x Vaq
    = 18

    = 0,055 V aquadest

    Mol Aquadest 8
    ( Mol Minyak Jarak ) = 1
    mol aquadest = 8 mol minyak jarak
    0,055 V aq = 8 ( 8,9 x 10-4 V minyak jarak )
    V minyak jarak = 7,72V aq

    Dari persamaan (1) 278,41 ml = Vmj + Vaq


    Vmj = 246,38 ml
    Vaq = (300 15 6,59 246,38) ml = 32,03 ml

    LEMBAR PERHITUNGAN

    A. Analisa Kadar Asam Lemak dalam Minyak Jarak


    ( V x N ) NaOH x BMmj
    % Kadar = ( x V ) mj x 10

    ( 1,5 x 0,17 ) x 1067


    % Kadar = ( 0,95 x 10 ) x 10 = 2,86 %

    Kadar Gliserida = Bahan Baku Asam lemak bebas awal dalam bahan baku
    Kadar Gliserida = 100% - 2,86 % = 97,14 %

    B. Perhitungan Asam Lemak Bebas Awal


    (V x N ) NaOH 1,5 x 0,17
    Asam lemak bebas awal = ( x V ) mj = 0,95 x 10 = 0,027

    mgrek/grmj
    97,14
    x 0,027
    Mol gliserida Awal = 2,86 = 0,92

    C. Perhitungan Asam Lemak Bebas Setelah Hidrolisa (Ca)


    (V x N ) NaOH V x 0,17
    Asam lemak bebas (Ca) setelah hidrolisa = ( x V ) mj = 0,95 x 10

    Variabel I (T : 40oC)
    t = 0 menit
    10,2 x 0,17
    Ca= =0,18
    0,95 x 10

    t = 5 menit
    14,3 x 0,17
    Ca= = 0,26
    0,95 x 10

    t = 10 menit
    16 x 0,17
    Ca= = 0,29
    0,95 x 10

    t = 15 menit
    20,9 x 0,17
    Ca= = 0,37
    0,95 x 10

    Variabel II (T : 55oC)
    t = 0 menit
    12,2 x 0,17
    Ca= =0,22
    0,95 x 10

    t = 5 menit
    18,5 x 0,17
    Ca= =0,33
    0,95 x 10
    t = 10 menit
    20,8 x 0,17
    Ca= =0,37
    0,95 x 10

    t = 15 menit
    22,4 x 0,17
    Ca= =0,40
    0,95 x 10

    Variabel III (T : 65oC)


    t = 0 menit
    14,4 x 0,17
    Ca= =0,26
    0,95 x 10

    t = 5 menit
    19,1 x 0,17
    Ca= =0,34
    0,95 x 10

    t = 10 menit
    21,9 x 0,17
    Ca= =0,39
    0,95 x 10

    t = 15 menit
    23,7 x 0,17
    Ca= =0,42
    0,95 x 10

    D. Perhitungan CA yang terbentuk


    CA terbentuk = Ca setelah hidrolisa Ca Awal
    Ca terbentuk = Ca setelah hidrolisa 0,027

    Variabel I (T : 40oC)
    t = 0 menit CA terbentuk = 0,18-0,027= 0,153
    t = 5 menit CA terbentuk = 0,26-0,027= 0,233
    t = 10 menit CA terbentuk = 0,29-0,027= 0,263
    t = 15 menit CA terbentuk = 0,37-0,027= 0,343

    Variabel II (T : 55oC)
    t = 0 menit CA terbentuk = 0,22-0,027= 0,193
    t = 5 menit CA terbentuk = 0,33-0,027= 0,303
    t = 10 menit CA terbentuk = 0,37-0,027= 0,343
    t = 15 menit CA terbentuk = 0,40-0,027= 0,373
    Variabel III (T : 65oC)
    t = 0 menit CA terbentuk = 0,26-0,027= 0,233
    t = 5 menit CA terbentuk = 0,34-0,027= 0,313
    t = 10 menit CA terbentuk = 0,39-0,027= 0,363
    t = 15 menit CA terbentuk = 0,42-0,027= 0,393

    E. Perhitungan nilai konversi (XA)


    C B Terbentuk CB Terbentuk
    XA = Mol gliserida awal = 0,92

    Variabel I (T : 40oC)
    t=0 menit 0
    0,233
    t=5 menit XA= 0,92 =0,25

    0,263
    t=10 menit XA= 0,92 =0,29

    0,343
    t=15 menit XA= 0,92 =0,37

    Variabel II (T : 55oC)
    t=0 menit XA=0
    0,303
    t=5 menit XA= 0,92 =0,33

    0,343
    t=10 menit XA= 0,92 =0,37

    0,373
    XA= =0,41
    t=15 menit 0,92

    Variabel III (T : 65oC)


    t=0 menit XA=0
    0,313
    t=5 menit XA= 0,92 =0,34

    0,363
    t=10 menit XA= 0,92 =0,39
    0,393
    XA= =0,43
    t=15 menit 0,92

    F. Perhitungan Nilai Konstanta Laju Reaksi


    dC A
    =k . CA
    - dt
    CA t

    dC
    - CAO
    A
    CA
    =k . dt
    0

    CA
    =kt
    -ln CAO

    CAO (1 X A)
    -ln =kt
    CAO

    -ln(1-XA) = kt

    y = mx

    G. Perhitungan nilai kesetimbangan reaksi


    nxy xy
    k=m= 2
    n x ( x )
    2

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