I GATE - 20011

CHEMICAL ENGINEERING
d ma)' exhibit either positive or negative
SEcnON·A deviatiQn from RaOtdt's law.
ONE MARKS QUESTION8 C1· 2i) 5 A$St>me thai benzene is insoluble in water
for M(h of the fol.lowing questions (I to 29) 1lte normal boiling points of bcmcue aJJd
four allemativts A, ll, C >md Dare provided. ｾ＾｡ｴ･ｲ＠ arc 80.1•c and 1oo•c. resuecti1 ely
AI a pressure of 1-atm, dtc boiling point of

om
lttdicate the con u t answe.o· by writing A, B, C
or D, as -uppo·opoiule, against the too-responding a ｭｌ ｾ ｴｵ ｲ･＠ of ｢ ･ｮｺｾ｣＠ and wntor is
question number in the box in the answer a ｾＰ Ｎ Ｑ＠ •c
book. b less lhan su.1•c
(Ma•·ks: I x. 29 = 19) c. wo•c
d, greater ihml 80 t•c but less than
tou•c

.c
1\ paor oil';11r dice is rolled Simultaneously
1lte probabllity that the sum of lhe
numbers from ｾ Ｑ･＠ dice equals ｾｬｸ＠ is
On a P - V diagram of nn ideal ｾ［ｮｳＮ＠
suppose a rc1·ersible adiabatic line
uner,;ects a reversible tsotherm<d line at

ce
I
a pomi A Then at pontl A. 01e. slope of the
6
b
7 re\'ersible adiabatic .Line ( ap ),.
c.r and the.
ra 36
5 slope of lhe reversfble isolhenual line
c.
36 iJP)
(i'V are related as (where J =!2_)
1 r C ,.
d
Ｈ ［ｾＺ ＩＬ＠ ］Ｈ ［ｾ ＩＮ＠
m
12
2. For an e1•en function ｦＨｾｬ＠ • a,
•
f f(x)dx'=ll
Ｈ ｾ Ｉｾ＠ ］ ｛ Ｈ ｾ ＠ｵ
a
xa

b
J' ((-x)d( =!I
＠ｾ (ＺＬｾ＠ 1. = r(ｾ＠ ).
b.
'
c. J (.+ =-J (- x)
.e

d j (x) = f (- x) d. Ｈ ｾ ｌ］ ｦＨｾ Ｚ ｾ Ｉｲ＠

3 l'he lmegraung facror for d1e differential 7 The mol.ar compos• loon of a gas IS IV1!-l, H).
w

equation. (ces' Ｎ ｾＩ･ｬｹ＠ -t J' = tan x. IS 10% 0 1. 30% C01 and balance IJlO If
dx 50% Ｑﾷ ｾ Ｐ＠ condenses, the frnnl mote
a. ｾｬ ｬＧ＠ percent of ｾ ｨ＠ in the gas on a dry basis "111
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b. cos2.1: be
ｾ＠ c> ""' & 1(1%
d s'" 2x b. 5%
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In n binary liquid solution of cornponeniS c. 18 IS%

A and B. of component-A et<hibiiS positive d 20".-t.
de1·iation lrom Rnoult's la11'. lhen 8. For u sphere fiilling in the constant drug
component B coefficient regime, its terminal velodi)
a. e.x:h[bits poStbve de1•inlion from depends on Its diameter (d) as
Raoult's la11. a. d
b. e.-.:.hibits n<:gab1•e del'mioon frr m b. ,fJ
Raoull's Lm1 , c. ｣Ｏ ｾ＠
c. obeys Raoult's law I
d. d
 In o lull) lurbulenl flo11 (Rt: 1031 in n d. LG
pipe of cJiamcler ｾ Ｍ for a constam pressun. m
grndicnL Ulc <k:pcndonce of vulumclri"
Ocmt t'Aic of an i11compressiblc Ouid is
where I. = t.quid ·llow rnle, a = flow s••
rnle ｾｮ､＠ m = slope of lhe equilibrium line,
Ｚｴ ｾ＠
d L5. At 750 K llnd I ;tlliL lhc ｵｰ ｲｯｸＮｩｴｵＡｾ＠ value
b. ,fl of the Sabnudt number for air is
"· d1J •. 0.01
d. d' b. ll. t
1(). In the laminar ｬ＾ｩｵｮ＼ｾ ｴ ｴＩ＠ lay.W now ｯｶ･ ｲ ｾ＠ c. 1
d. 10

om
lhl plate, the t'!l1t() (•i )t) vorics 3$;
J , R""
16. ror the n111 lrny (counted !Tom the b<Jilom
of ;a distillociun column\. the Mnrphree
b. .JRc
.
lJ'l'V tfliCicnt'-· is !!ivcn bv
ｾ＠ - .

.c
where ,; •• the boandniJ' layer tht10knes•
and x is Ute distance fronl the leading edge

ce
in the dirc:ctlun. of 11ow.
11. Por laminnr flow of n shcnr-lbfnning liquid Y•• , - _v,,
in a pipe. if lhe volumetric ilo" rnte ｩｾ＠
tl. ｹ ｾ＠ J'!t-1
doubled. the pressure gradient will
)'. v.,._t
in.,.e.sc by Q f•cto.r or
ra
a. 2 17, 'lne ｴＭｬ ｃ ｾ｢･＠ 61.. la11 ｾｬ｡＠ that lite
b. < 2 a. mobr Jtcnts of Vaporization of
c. > 2 components ore ncnrly equa l.
b. linear 01'ysllll growth rate depends on
m
d. 112
The Gtushof number i.l defined as che r.cio lite degree of ｡＠ｾ pet' salunrtJon :
I) I
c, lUtt.-tttr crystn l _growth rnlc does ool
:c buO)'OI\ey IH inertial rurcc:s, dep01td on lhe Cl)'$1als®.
xa

h. buoynt\O) lu vi>Wu• ｬｩｮＧｃ｣ ｾＮ＠ d. llnear erysla I gt'Owlh role depe!>d• on

c:.. lneni:.lt<• v iRCOUS Ｇ ｏｲｾ Ｎ＠ tile cryshtl size.
d. ｨｵ ｱ ｹ｡ｮ｣ｾ＠ In ｳ ｵｦｬＧｮｾ＠ to:n,<ion forces. 18. 'lbc "'P"timcnllllly dctenninod ovemll
13. A splll'fc of ｲ｡ ｣ｊ ｩｵｾ＠ R, is ottCIO$Gd in a order tOr t1Ha re:u!tion A ｾ＠ B _. C t- D l!;
.e

$Jlh.-re of r.tdi11,1. R:. 1l1e ''iCII (or lill•llC) lwo.11•en the

fnccor for rndiative heal trollSfer of the a. rca<tion is clcm<=nlfiJ1 11 IIll a
oulc'T ｾｰｨ･Ｚｲ＠ 11 ilh ｲ｣Ｚｳｰｾｬ＠ lO Ihe innt:T ullllcculority clf2.
spbcro ｩｾ＠ h. mnlecul•rit_v of the re:tctinn ｩｾ＠ 2. but
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n. ll Ihe reacfion tnay n111 he elt:tnenbry,

e. [tllction '"") ba elotltcnl•r> "iUt a
b. ｭ ｯ ｬ ･ ｣ｵｬｾｲｩｴ Ｎ ｬ Ｇ＠ of 2.
R, 4 R,
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d f'CIIction lJ elemenCJJry ｾｵ Ｑ＠ lho

I!. 1 molecularit)' nit} nul"" 2.

[tJ Ill. Th• "'action i\ -+ B L• cl)nducced in ｾｮ＠

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d. isoUumual bateh J'enctor, 1f th.: ｣ｯｭ ｾ ｵｲＮ［ｩｯｮ＠

of A j ncooase.• linearly with holding time,
14.
lhen the orderof tl1e reacclon is
lL 11
mG b. 1
h G c. 1.5
mi. d. 2
mL 20. For ｾＱ ･＠ ｬ ｬ｣ ｴｵ ｬｾ＠ pbasc por.tUclreol!ltOos
cJ
 3UJ ,l;
E, ｾ＠ 80 /JI MOl a. bus u mm-<1erv slope at lhc ori&in
b. has n dnmrcd ＼ ｬｾ ｇｦｩｮｴｯｹ＠ churucterislie.
r1 c q C, : F.t ｾ＠ 110 k.J(,o(
c. is ovcrdampeJ.
d. is unslahle,
tho dcslf\.-d pt1JJucl Ｑｾ＠ R A high"r 27 Select the COrt<.'Ct slatemeol l'rUm Ute
:>declivity or R will be l1Cn1CVL'<l tf lhc rnllo\1 ing.
rencuon ｾ＠ cCinducted al a, The ft>:tju<.:ncy re!q><>nsc nf n rtttc
:1. low tempemtw>: tn a CSTR cnpacit}' process ｩｾ＠ uohouoded
b lugh temperature m a CS'J'R b. ｨｾ＠ｔ J'ltUse hi[! of A pure time ｣ｬ･｡ｾ ＠
c. lo11 lcmp\lraturc In a PFR. ｾ ﾷＡ［ ｴｯｭ＠ 1kcrcn""s wll11 ｩｮＢｲｌＧｦｾ ｩ ｮｧ＠

om
d. hi gb temperature m n PJ7R fi'C<tllcnc.)'
21 ln solid cawtysed reac.ltW1S tlte dtl'Fusmnal c> ｔｩｬｾ＠ llllltJlitude raliu ui a pme cnpacil)'
･ｊｔｾ｣ｴｳ＠ nre more llkelv 10 affect the O\'emll proc:e:<:l I> ｭｶｾＱＧｬ＼Ａ ＮｬＧ＠ prupurtionu.l (n the
mtc of reacuoo l'o r • frcqu"ncy
IL fast reactions '" catolysL• of smal l f'lWC d llle umplitude rnuo of u ｰ ｮ ｾ＠ lim"
diameter del a) S) ｾｴ･ｲｮ＠ incrca!l<!s 11 ith frequ<'ncy

.c
b fnsl reDctitlns 111 ｣ｴ ｬ ｴｾｬｹｳＮ＠ of IDrg« pore lti. 1'\ >r n ll:t>.1l' nek c<1ntml sy>tem I<) he stuhl.:.,
､ｩ｡ｭ･ｴｾ ＮＭ lh"
c. <low reucllons in cnllllysts of small a. rQots of the ｣ ｨ ｵｲ｡､･ｬｳｴｾ＠ equotiQtl

ce
p<>tt uiilmtrer. •huuld l>e rent.
d ｾｬｮｷ＠ ｲｾｮ｣ｴｩｯ ｮ ｳ＠ m ｣｡ ｴ ｡ｬｹｳｴｾ＠ nf ｴｮｲｧｾ＠
b pol<" or
th" ci•JSed loop trunsfor
IX'"' WUI\ICicr. l'wtcllon should bt:. m Lh<' ldt lroU' uf
I" pctlvll!wu refining. 01c J>IOCUSS u.<<tlli:1r the complex plane.
｣ｾ＾ｮ ｶ｣ｲｳ ｩｯｮ＠ uf ｬｷ､ｲｵｮｨｯＮ ｾ＠ tu uromillius is
ra
:1. ｬｵｴ｡ｹｈｾ＠ Cl'uckin[!
11 cutnlytia retlnminjl
c. Bode plutS of the correspondmg open
loop transter function should
mooutontcaUv d.:creu.,;c.
e hvdnJin:lll mg U. pl)les of lh"c clos<tl loop IJ'tlflSfer
m
U. nit.:vlouon rmiCIIOn ｾｨｯｵ ｬ ｴｦ＠ lte m the njlht hillt' ol'
ｃｯｭｵＡｾｲ｣ｩ｡ ｬ ｹＬ＠ ethylene is produced trow the complex plnn«.
rwphthu by 29 For a Lypiaal 11roje<."', the cumulative cash
a, calalylic crucking. now ls zen> at th<l
xa

h cutal)1ic dehydrog.cnntion. o. end uf tbe pro;ect w·e

.:. pyrolysis b. ｢ ｴ Ｇ･ｬｫＭｩｾｕ＠ ｾｩｮｌ＠
d. hyclrocmckrn!Jo c. ｾｴｵｮＭ ｵ ｰ ｟＠
J4. Triple sup.;.-r pbool'butc is monut'&cturcd hy d end ｴ ｬｩ ｨ ｣､ｾｧｮ＠ stugo.
.e

ren.:ung
"· phosphate rock'' ith pbospbodc actU.
h ph(!Spbate ruck 11 1lh sulpltw1c acid , TWO MARKS QUESTIONS (30-$3)
c, pho:splrote wck with muic acid For each (If t he follo11i ng questions (30 10 53).
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d. ummomum ph(lsphntc wub plto:;ph<lnC t'our ｡ｬ ｣ ｭＺｾｴｨ ﾷ｣ＮＬ＠ - A, B, C.:, und !)are
nctd> JII'Oiidrd. lndktlle the correct lllt.<wcr b.' '
25. The or
tlJI! trausrcr writing A, B, c. or D, as ｉ Ｈｊｉｲ ｰｯ ｲ ｩｮｴ･ ｾ＠ tlgainsf
w

Wlll :.1 djJ l'CSj)l)lls.l-

25-1 "' ' the ｣ｯ ｲ･ ｾｰｶ ｮ､ｬ ｧ＠ qul'.•liun number In lhe
fun<!lll\n reAches fls lmtll an.nwr ｨｾｫＮ＠
ｬ Ｇ ｾｬＩＨＴＮｲＫ ｬ Ｉ＠
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ｾ ｴ｣ ｵ Ｈｬｹ＠ stale ll>.)mpiOIICUII\ Mtcr

u, n mooolonic incrense. 10.
b. u muuUIUtUC ile<:reuJ;e. Tl{'" v lfnc x in}t.:gralnf
c. ｩｮｴ ｬ ｾ＠ incrc'lli<iug nuJ ll11l0 f• ,.-,.....;r, ､ｾ＠ ｾＫ
ｾ＠
ｹ
- dt , II here C IS tho.
Ｍ
､ｾｲ･｡Ａｯｬｩ ｮ ｧ＠
•1. 1nibbUy det.TeOaing und then .unit clt"lc.urmmd the. <nigm truver:;c;;l tmcc
11\Cfi!:.Sing. in thu ｣ｴｬｭ ｴ ｃｲ Ｍ｣ ｬｾｫ｜ｳｃ＠ llirl!l.!liun. is
J'ht IJml Sl<!p rc>'fl<msc ul' lh..: trunsft:r a. -2x
• . l h ｾＱ＠
j umliJQn
.t
1
+2s+3 c, 2Jt
 I <ll 8
d rr K (ｾ［ ﾷ Ｌｋ ｴ Ｉ＠
3l rhe inverse of the IJlatrJ., ' [I -I]
- I-I
Cr. '·' -

d K; =(K,A.1 )j
2

a. Doe1; not exist 36. The spbericrty of a solid particle of cubical

b LS [: ｾ ｾ｝＠ $lwpo is
a. 1t
c. . [ o 5
IS --{).5
-o.s]
-0.5 b (:)t
d ｛ｾ 05]

om
Ｎ Ｕ＠
05 05 e. Ｈ ｾ ｩ＠
Tbe complex con; llgale of' - 1- ts
I •I d
3
1

.c
a, 37 A 30% (b.y voltune) ｳｵｰｾ ｮ ｳｬｯｮ＠ of
1-1 spherical sand particles in a ｶｩｾｯｵｳ＠ oil has
b. (I 1) hindered seuhnJ! velo<uty of 4 4-l ｾｵｮＡｳ Ｎ＠ If
e 0.5(1 - 1) the RlclJardso2-Zakl hindered setti!lg

ce
d. Ul \lie Ursl quadrant or ｾ Ｑ･＠ complex tndex ts4.5. thcn the tenninal ｾ｣ｬｴｵｩｹ＠ of a
plane saod gram •s
lite general so.lut1on of a 0,<JO ｾｵｮ Ｏ ｳ＠
tl' v 1
dy
- ·- +2 -+J'=
ra O IS h I mm/s
<!-<' dx1 c. 22 J ｾｵｮ ｬ ｳ＠
a. (t',,r-C.,)e' 1 (r'1 T ( ,.r)e • d. 0.02 funis

..
b. C, cosx+C, stnx+C;e• ｾ＠
. c,e.·• 38 A I m high bed ｭ｡､ｾ＠ up of a mm parucles
ｾｳ＠ to be nUidlsed by an oil (density 900
m
a. (' ,e. T ,.
\ 1e 1 glm3 ; viscosity 0.0 1 Pa s), Jf'at 01e pomt
d (l', + C,.r)aos .H(t ·, ＫＨ ｾｸ Ｉｳｭ＠ ｾ＠ or incipient fluidiwion. the bed voltage is
39"1c> and the pressure drop across the bed
xa

whL-rc C1,(',,C, unt! C:, are t(lns!ants, ts I0 kPa, tl1en tbe density o.f panicles 1s
The Lhennal emc.ency or a reven\tble beai !L 2.5 74 kg/tn I
engme operatmg between two gaven b. J5 14 kg/m3
thermal reservou-s ts 0.4. The dev1ce IS c. 4000 kg/rn
3
used Ctther as a refngcralor or as a boar
.e

d 4350 kgtm'
pump between the ｳｾｭ･＠ Teservtrs Then 39 A free jei of waicr of cross-secuooaJ aren
the coefllc1ent of lJerforruance as a 0.02 m1 and velocity of 20 m/s stnkes d
r<•fri!l.erator (COP)R and the coefficient of plate and d1en tlm>JS in ｾＱ･＠ plane parallel to
w

perfmmnncc as a heat pmnp (C'OI'hw Bte U1e plate as shown 10 the figure below. 1l1e
a (COT')R = (COP)tlfl ｾ＠ 0.6 hQtizontal cumpqni!O\ of the force: on U1e
b. (COP)• - 2..5, (COP)w· • 1..5 suppoti 1s
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c (COP)R = I 5; (COP)np = :t5

d (COJ>)• = (COP),, = 2 5
35 1\t a &1Veo temperature. K1. K1 and K, are
w

ｴｨｾ＠ equOibriLtm consuuus for 1hc following

reactioll!l I. :?., 3 respectively:
rH, (g) ｾｦｬＬＨｊ＠ f 'O(g)+JHjg) (I)
CO( g)• H,O(g)C C'O,(g) I H1 (g) (Z) ll 200 ｾ＠
C'H,(g) t2H;i)(g)fl C01 (g) 14H ,(g) (3) b -lOON
c, :woo N
Then K,. Kzaod K_, are rel!tted as
d 4000 N
a K, =K1K1 -!() A s1eel sphere of rndtus () I m at 400 K rs
b, K ,=(K1K, )"'' unmersed tn an oil Qt 39Q K. If the centre
 5 olll
of the sphere rcoche« 350 K in 20 ｮｵｾｬ
how long will it take for a 0.05 m rndin•
･ｳＮ＠
••
b; 4000
2000

s feel sphere to teach the sante tempet'oture ｾ Ｎ＠ 5()0()

(at Ute coult" ) under identical coodilioru? d. 6000
ｴ｜ＮＢｾｊｯｭ･＠ lltat lh,. u.)nv..owc hl!llt tran5fer 45. The ounvet'bion for ｾ＠ firsl·torder liquid-
cl1ell'icient iR in finitely lllrgt. phase f\.'JICti(m t \ ""> 13 in u ("S'I'R i• ｾＱﾰ｜ Ｌ Ｌ＠
s. 5 min If 11110lher t'STR 11f lht some volume is
h. LO tttin oonn...,t.od ln ｓｴＺｲｩｑｾＮ＠ tho>n Ull>"• Ull.nWrsion
c. 10Jttlo al the <xit af the .•<oond I'Cllctor wiU bd
d, 40 111 in a. GO

om
41 , A uompo5Jte J'Wt waU ofu ona<Je is onade of b. 75
hvo ｭ｡ｬ ｣ ｴ ｩ ｡ｾ＠ A dod B. Titc tbclinlll .:. 90
oonduolivil)• of A Is twice of' tluol of d. LOO
mm.erinl B, \lhlle the thickne.• oF lnyer of 41>. Tbe following hair-life dllla ｾｲ･＠ .,••; lnblc
A t• ha)fol'llHol nfB. U' tlte tempt:r:OlUn:s :ot for the irreversible I[quid phnse reaction.
tltc two Ｓｩｬ･Ｎｾ＠ •of lito wollafc 401lollll 1200 A ｾ＠ products:

.c
K. !hen lhu u:mpcrnturo drop (in K ) across Tnitial conccntralioa, Half-life
the layer of' male,·ral ,\ :S
•• 125 {.blooll•') (lllht)

ce
b. 133 2 2
" · 150
d 1611 8 I
For turbulent llow in a tube ｨｾ＠ｬ
42. ra heat
The ｯｶ ｾｬ＠ order oflho reaotillJI is '
trlln$1C!t ｾｯｴ ･ｬＮＧｩ ｾｩ ｣ｮｴ＠ is OI)Lailtru ftilnt (he
u. 0.5
Dittu.•·Boeltor ｾｯｲ ｣ ｬ ｯ ｴ ｩｯ ｮ Ｎ＠ U' Uta tube
b. I
､ｩ｡ ﾷ ｭ ｯｴｾＺ ｲ＠ i• halved and lllll n,w rate ｴｾ＠ c. 1.5
•loubled. lloen Ute iteat transfw coeffictent d. ?
m
will ｣ ｨ｡ｮｧ ｾ＠ IYy a ｦ｡ ｣ ｴ ｯｾ＠ of
47, Tiu: .fir.fll order ｣ｲｳ ｩ ･ｾ＠ reaction
n. 1
b. 1,7.1 ＬｲＮｩｂｾ ｃ＠ is oondueicd in •
batoh toootor. l'he initial oollQeotntions of
xa

c. (i,J
tL 37 A, 13, 11111) C (<"AO. C'oo, ('"'" respeelively)
43. ·nte indlviduul III008b ｴｲｾｭｦ･＠ >loefficienl• a"' ..11 non-z"ro. The \'..ristion of Cu willo
(molrml $) ror ahsO'lllion of U ｾｯ ｬｵｴ ･＠ lronl roaolil!n time will not sbQw a .ma.xitn.um if
a gas moxture into a liquid solvent otre k1, = •. t,c,. ... k,c,.
.e

ｾ Ｍ Ｕ＠ and !..a 1..5. 1]": .sloJ"' of llo< b. k,c ,., kp;;,)

equilibrium line i. 3. Which of Uo« c. ｾ＠ .!"Q ,. c_
following rcsistance(s) i5 (are) ｣ ｯｮｬ ｲ ｯｬｩｴｾｧＧＩ＠
d. c•• >c,.
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:o. liquid - side

b. golf- side 48. Titc ronotion A ｾ＠ 1J •• <><>nduowtl in ｾｮ＠
a. interfacial ｡､ｩ｢ｴｯ ｬ ｩｾ＠
plug Oow re3ctor (PFR). Pure A
at a concentr•li<.m or 2 ｫｴｰｶｾｭＧ＠
w

d. both liquid - and gas - ｾｩ ､ ｯ Ｎ＠ is fed lu

J4. In ｾ＠ laboratory test non. Ute mte of drying tho: reuotor at Ute rate ofi).OI m'Is and at a
\1 us fuwld to be 0.5 10·• kglm' s whet\ lemp«atUJ'() of 500 K. lf the c:xtl
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tlnl motslure content otdu<Wd from 0.4 to conversion is 20%. than lhe exit
0.1 on a dry basis. 'l11e· c ritical moisture temperature (inK ) is
comtent of the mfllt:{inl i,. O,Oil Qn a dry a. .j()O
｢ｾｩ Ｎ＠ t\ ttP) drier ｩ ｾ＠ u.<oil to dr) I00 ｾ＠ b. 500
(dry bu$is) of lite same lt1llt<t'illl under c. 600
1<1entical u.)ndilions. 11te <urtilce 1Tf'C8 or d. 1000
the moterial is 1!.04 m11J;g of dry solid. l'he Data: ｈ･［ｾ＠ I of l'eactiooo nt298 K ｾ＠ -50.000
lime ｲｵｾ･､＠ (in s<l\loootb) to ｲ･､ｯｾ＠ the kJI!uuol af A rcoelad
moi..tur.: uonlc.:nt of Ute solids .from 0.3 to
1},2 (.dry ba1.i .) ｾ＠
 1.) ors
Heat eapacities, CI'A = Cn = l 00 kJ/kmo1 long prpo to pump ihe oil at tltc same.
K (may be assmned to be independent of volnmeiric .flow rate as in Ute prevtous
tempernture.) case. Estintate thc pressutEf drop f01 llte O.i
49 'T'he t"<i.te ｯＨｩｊｴｲｾｬ ｩｲ ｾﾥ＠ slep f11r ｾｴ ･＠ m diamet·er pipe. Asawne hotiJ pipejt to be
ｨ･ｦｴＺｏｧｾｮｯｵｳ＠ irreversible oatalytic ltydtodynmnicaJJy smoofll and in tlte range
reactio1TI of opet'iding eonffirians, l.he Fanning
ａ Ｈ ｧ Ｉｾ＠ ＱＨｧＩｾｃ＠ Diction factor is ｧｩｶ･ｮｾ Ｍ

is the. surfwe ｲ･｡ｾｴｩｯ

ｮ＠ of adsorbed A wi tll / = Q.079Re-OJ'
adsorbed B to give adsorbed C. The mte
ｾｲ･＼ｓｩＧｴ＠ for lft.is t't!liCticm can lhert be 55 A rree Jet of water ls produced usi ng a 75

om
written as mm diarrtet,er u ,1ZZJe ui.mehed to >L 200 fllm
diameter pipe, m; -.b.owu .in the .figure.. If
the average vclooi ty of'water at plane B is
3.8 mJ., calculate tlw velocity ｯ ｦ ｷｾ ｴ ･ｲ＠ at
SI!C11DN · a
point A i.it tlte froo jet Neglect friction
i Jh'•J '' ,,I;. J.\ili.,,t.::r ｬｦＡＵｩ ｾ ｬ＠ l.:,gses in llte 1lll:(21E' and pipe•

.c
.'!.nswer Any fo'lf\e11n Questions
(Mark$ 5 x 15 = 75)

ce
50 :Vutd the directional derivative of u = >.)'£
"I lhe point (1, 2, 3) I t1 ｴｬｲ ｾ＠ ltirecHon llom
(1 , 2, 3)to(l,-l, -3)
ra •T
5 1. Futd whether or not tht> vcct"rs (1,1,2), Obtain the eqnalion 1pr fltc. qclinc givc11
(1. 2, J) ru1d (0, 3, -3) are linearly thaL lhe. OJJt'f>ll:htg limsare.
independent
/. D • ., , . cfi
m
52 [ndnstrial sra•ie metlumol ClU1 he E£00UOed y - - -.<-- -X.v tenJJ.,.•Uig ｾ･＠ 011)
according to tlte reacdon L+ .D L + .D

CO(g)+2H1 (g)C C$pR(g) ｶ ］ Ｍ

L ｲＭＺＢｾＮｂ＠ 8 I I
(l;lr.ippmg ｾ･｣ｴｩｯ｟ｮＩ＠
• '

' J;-.1) C-JJ

xa

For Uti9 fffiction .c.o•4uu = - U484 kl. 1f

WilEn" Lruul I are i.he lfqui:cl llow tale!! tn
-rut equi.toolril .mi..'dllJ·e Df 00 !llld liz is fed
the eruiching and strippmg.secbons, D and
l<> a retct.or rr•rurJtlnne4 at.. 400. K a11d 10
bar, detemune, tlte fraction of CO lhat is B are the top aad bottom product flow
.e

conv.erted into CHPH a1 egui.b'brium. rates. and Xo and XI< are lhe mole fraclions
of top and bottom producls, rcspecbvcly.
Ao."Ulne iltat ilte reactio11 mixture .behaves
like 9:11 ideal gas. 56. A ｣ｾｭｴｬ ｮｵ ｯ｜ ｴ ｾ＠ w ntact ex:lractlon cc>lllJTm
w

ls used to extract a solute from rut aqtteous

53. b• a binruy mixture the aotiVll;y coefficienl
stream (F) t!Sing an o.q;anic .<olvenl (S)
rt of compon011t I, in the cutirc range of Tlte distribution coefficient (y/x) is 1.0,
ronrpo>11ion, is g1 ven by
w

whet-e x Md y ate dte mass fraction;; of

.R ln r1 =!lr]+&; sl)ltlle in mffinnte nnJ extmet phaiies,
ri!S]l<!ctively. 11te height of trar!Slllr- unil
w

wltere R. A 1llld B are constants. Denve b<IJled o.n ·flle eJctrttct phase is 1.0rn, The
lhe ･Ｎ＾Ｌｰ Ｎｲ･ｳ ｾｯｮ＠ for Ute activity coefficient rest of lhe data are ｳｊｖｾ ｮ＠ m the figure,
ofCOJtlponenl 2. Assurui.og that ｬｨｾ＠ phase flow ｭ ｴ ｾ＠ are
54 A Jtydrocarbou oil (visce>slly 0.025 Pa s cunsianl, find the heig;lll o.f lhe Lt>Wer.
and density 900 l<glm') is trnnsJlOt!ed
using a 0.6 m diameter, 10 km .long pipe
n.e ·max:inmm allowable pressw-e drop
ｾ Ｎ｣ｲｯｳ＠ the ｰｩｾ＠ length i..- I MPa. D\te to p
n tainlemmce schedule om thiS.JliJ>eline, it ｩｾ＠
Ｎｲ･ｱｵｩ､ｾ＠ use a Q,4 m diameter, 10 km
 7on
environment. If such a thcnnocouple '31
25"C is inuuersed suddenly in a fluid at
80°C ana held tht'l'C. it Is fOlDld that Otec
thcnn!lCOuple reading (in °C) re:whc:>
63.2%of the final steady state value in 41l
seoo11ds. Find the time coostaut of tlte
Olimll()COUille:

60 A tcedi,Hck control loop with n

propottional controller has an open loop

om
trlU!$ler fuuctiou
57, 1\ir at 1 ｡ ｾ ｮ＠
is blown past the bulb of a
mercuty ｴ ｨ･ｲ ｭ ｯｭｾ
ｴ ･ｲ＠ 111e butb is covered
with a wick. l11e wick is Immersed in rut
orgamc liqwd (molecular wcight = 58).
'The reading of tho them10meter is 7.6 "C. where rime i$ ill miuuteS; Obtain Ute
At Otis temperature, the vapour pressure of crussover liequency wtd Uce ultinmlc

.c
01e liquld c; 5 kPa. fiud O•c air controlh:r gail).
t.emperttture; given that the raht> of the ｨ ･ｾ ﾷ＠ 61 Given the (QIIowing bloc!. tll!lgrnm,
tru.qsfer c.oet1'ic•ents to the o>ass ITansfer

ce
ｾ＠
coeflicient (psychromeuic mtio) ts 2 kJlll!!
K and the latent heat of vapourisation of
the liquid is 360 kJikg. Assume ihm the
arr, which ts blown. is free from the
ra
organic vapour. a. EAl llllSS the trnnsii:r Jimcoon (Y/X \ ns

A piau! 1s designed to produce. 1.2 IＰ ｾ＠ a ratio ur polynoultals in s.

58.
ki!lvte of an agro<:hemtc<\1. The csnmntcd b. Calculare tlte off.o;er '" C due io o unit
ｩＧ［Ｎｾ､＠ ｓ ｴ ｾｰ＠ ｾＺｨ｟｡ｮｧ･＠
m
capttnlmvesrment is Rs 1.5' 10?, 'The. in lhc rcrcrence Slg_nal
working capital tS Rs ｚ ｬｏ ｾ＠ and the sult1'- \Set-point) R.
up cost (ouly iu the lirst yelll' o t:
61. 1'he elementary. second-order. ltqutd
c:omnnssloni.ng and to be ｾＮＺ｣ｯ ｵｮ ｴ･ ､＠ fbr m
phase r"nction ｩ｜ Ｋ ｾｃ Ｋ ｄ＠ is conducccd .n
xa

the first year) is Rs I 5>< 10•. The followitlf\

oost datn are available;
an. tSI,ltherma1 plug flow ｲ･ｾ｣ｴｯ＠ or I m1
capacity. The inlet ''ol umetrfc flllW rate is
Raw matcnals: ｒＮ ｾ＠ 0.!!9/Kg product 10 m' tb and C.-.1 = C1111 "' 2 lunolltu' At
these ｣ｯｮ､ ｩ ｴｩｯｮｳ ｾ＠ conversion o f A is ＵＰｾＭｯ Ｎ＠
.e

Labour and uulinos. c.tc.: Rs 0.27/iql:

product Now. if a stirred tank reactor of 2 rn3
capacity is installed in series, upstream of
ｓ｣ ｬ ｾ ｮｧ＠ prlce ufproducf: Rs 10/Kg lhe plug 0Qw reactor, lbcu wilaL
w

Oil•cr costs (On pet• ycur ｡ｳ｢ ｴ ｾＩ＠ includinH, conversion tmu bt:" expected_ h1 the nd:w
mamlertance. tnsura»ce. etc, @W% or system Qf reactors?
lixed capital. 63. The ｦｯｬｷ ｩ ｵ ｾ＠ liquid pbnse t<eactions are
w

Indirect costs of ､ｭｩ ｵ ｴｓｕＧｭｩｯｾ＠ R&D. ｃｾ ｕ ｮ ｴ､＠ OUJ Ill n f>PR..

marketing. c(c. @20% <>f sale pnx;ceds. .A H .'-;. 28 +P ; r, =k,Cp,.
w

'n 1e plant will be titll) depreciated ovet• u ａｾｬＺ＠ r., = lt.,L 1

period of 5 years us ing the stmlslu• line
tueOtod.. llte rate of titcmue tax is ·10%.
Cukulat"
a, rl1e net pro tit at the end of first yenr
ll, dte payout period.
59, l he re;-ponse of a tlicnuoeouplc can be.
modelled as u first order process to
changes tn the temperarure of the
Wl1at ls ｴｨ ｾ＠ mtio of moles of l' formed fo
moles oro formed ru 01e reaotor e.(ft if 01e
CQm•ersion uf C is 50%'1 No product ts
present in the feed
Data!
( ',. =( ',., =21imoll m'.A = lm l (lm11/ s);
k, = b -1
 K ot k
64, Each of tlto!. products menuoned 111 the left- W/m1 K.. To reduce tltc rate of heat loss,
hand column requires one or Jnore of the lbe pipe is 1nsulated by a 50mm thick ｊ ｡ｹＡｾ＠
reactants mel\fioned In the right-hand ofnsbestos (k = 0.5 Wlm K). Calculate Ut<>
column, March the products wi1h the percentage reduction m the rnte of heat
approprinte ｲ･｡｣ｭｮｴｻｳｾ＠ loss.
68. In a 1-1 counter flow shell and tube hear
(I) Phthalic anhydride exchanger, a process stream (Cr = 4.2
kJ!kg K) is cooloo limn 450 to J5(l K
(U 1 Cu111ene using '""ter (c,. = 4. 2 kJ/kg J.:) a1 JOO K

om
The proCes$ .stream flows on the shell-side
ar a rare of I kg/s and the warer on the
tAl Benzene tuhe·s1de at a, rJte of 5 4;/s, If heatlmnsfer
(!l) N.aphthale}le coefficients on the shel l nnd rube s1des are
1000 Wtm• K and 1500 Wtm" K,
(C) Carbon monoXIde respectively, d<1lll'mlne

.c
(D) Phenol a. the requJre<l heat transfer area.
(E) Propylene b. by What facror wt ll the required area
(F) Atr changu ｩｦｲｨｾ＠ flo,v is ｾｯ｣ ｵ ｲ･ｮｴ ＿＠

ce
(G) EtltyJ benzene Neglect rube \Vlill resiStance and ｦｯｵｬｩ ｾ ｧ＠

(H) Hydrogen resistances.

(>C) An ｡ｱｵ･ｯＮｾ＠ solullou of a solute is
65. SyttU,.lSis gas rs 11 n#iurc of
ra
n. CO and H,
Cdncentrated from5% to :10% (mass bas1S)
in a sing le-effecl short-tube eyaptmitor
b. ｎ ｾ ｡ｮ､＠ H, The J.:cd ･ｾｷｳ＠ !he evaporator at a rare of
LO kgls and at a ｴ･ｭｰＧ＼ｾｵｲ＠ of 300 K
m
n II_, ｃｈｾ＠ and CO Stearn tS available at a saturation pressure
d COt and H, of I 3 bar Tbe pressure 1n the vapour
space of the C\f!lporator IS 0.13 bru and ilie
The tt••ction A ｾ＠ ZB + C takes place ru. a
xa

66. corresponding saturation temperature of

caw lytic reuttor (see diagnun below), The
reactor effluent IS sent to u separator The
overall conversiOn of A is 95% 11te
product stream from the separator consists
.e
steam 1s 32() K rf the overall heat transfer
coefficientrs 5000 W/m2 K, c;alculatc the
a. 'le;lm economy

Qf B. (' and 0.5o/o of A enterrng the b heatl!Dnsfcr surface area.

separator, w hile rhe recycle Sll'eam 'Olio:

-- .
consistS of lbc rema1nder of the unrcactcd
w

A aud 1% of B entcriug tl!t! separaJor.

Calculate !he
ＨｊＮ ｊｩｲＬＭｾ＠
a, swgle P¥8 couvorsooo of A ill tl1e
w

reactor ｻ｡ｬｲＬｾ＠

b molar ratoo of recycle to feed

.....,_
-
ｾＨＵ＠
c

-
II;- «l.
ｾ＠ ........
ｾ＠
w

.........
OII"'J:IS.ll

:. I ｌｬ｟ＭＮＬﾷ ｾ ｟ Ｎ ＭＧ＠
--.. lfl
,
.. , .(

67 "l'he 0111S1de surface temperature of a pipe

(radms = 0. I m) IS 400 K The ptpe ts
los tog hear to atmosphere, wbJch IS at 300
K The ftllll .beat transfer CQefficieut IS 10