I GATE - 1992 I U( (I

CHEMICAL ENGINEERING
SECTION A cent excess reactant supplied is

(SO Marks) c. A gaseous reaction A - t 28 + C takes.

place isothennnll) in a constant
Fill in the.blnaks . pressure reactor, Starling With u
a. '!'he steps 101oiled in the manufacture gaseous ｭｩｾｴｵｲ･＠ containing S<l% •A

om
of pbenol by chlorobenzene caustic (res1 onens), the 111ll0 of final to 111ttial
ｊｬｔ＼ Ｉｃｾ＠ are chlorination or bon7.Cile. volume is round to he 1,6 The
and pcrcentagecorwersoon of A is
:T:::-he_ p_ro_ce
_ss-:-is- -compe-.ti'"'ti"',.e- "-:1,-en
-.
. -,l;o--11· (A) .30
cost cltloMe Is avrulable, T1us means (B) 50

.c
!hal the process must be coupled lo a ((') (i\)
ｾＭ｟Ｌ ｰｬ ｡ｮｴ＠ (D) 74
b. For manufacture of slyrene the maJOr d. A multiple effect <.waporator bas a
rs11 mstcnals are and capacny to process 400tl kg of solrd

ce
-;:---- One rmportant copoly mer caustic soda per day " hen it is
of styrene IS Which IS ｣ ｯ ｮ ｣ｵ ｮｴｲ ｾｴｩ ｮｧ＠ Iron ltl'}o tQ 2.5% solods.
111ddy us<.\d in the manufacture or The water el'nporated in l.g per day is
nut!)mobile tyres \A) 600
raec Select the appropriate name from the
rigbl hi111d colunm. against the
(B)
\C)
24.000
60,tl0()
processes memiorted : (D) 48.Wil
(1) H, from light ｾ･ｴ ｲｯｬ･ｵｭ＠ stock 3. Choose the correct alternate •
m
(II) Hrgh oetanegnsoline from nnptha il. The ml!l:hanicnl energy equaOun
(lU ) ｇ｡ｳｯｨｮｾ＠ frtlrn g11s oil
(TV) Petroleum Cl)ke from resodue (-(.2'-t•f.i- •-'''l' ); ('''
- +w +p)
2
- - tlrl'. - ,,,,
::o
P , c.lm <lm
xa

(A) Pyr'Olysis hns peen obtained under 1vhich of tM

( l:l) Catnly tic ctacking follo11ing assur'nptions
(C) Platfonning. (A) the llaw is stead)
(0) Steam rcfonnin.g of napiba (B) the ll ow rs incompressoble
.e

d. An electrostatic prec1prtator ts (C} no viscous work is being done

normally used lor separating particles (D) (Joints 2 and I are on the same
from gases \\hoo streamline.
(A) PartlCie s1ze IS greater than Lmm
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b_ A spherical partide 1S ｦｩｬｵｾｧ＠ slowl)· Ul

\B) Particle SIZC IS less UUIO I micron a viscous liqwd such ｾＧ ｾ＠ Revnolds
(0 Gases contain ｾｵ ｧ ｨ＠ c<mcenlmtlon nwnber Is less than 1. Wh1ch s1aiemenr
of carbon monoxide
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is correc1 for this SJhlahon'!

( D) Gases contaon 'erv hrgh (A) Inertial and drag rorces are
concentration of solids, • 1mponant
Fill in the blunks
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(B) Drag, ｧ ｲｮ ｜ｲｬｾ ｴｲ ｯ ｮ｡ｬ＠ Md ｢ｵｯｹ｡ｾ＠

:1. It is desired 10 rnnke I (lO kg or u forces are important
solution containing ＭＱＰ ｾ＠ salt b)' mixing (C) Drng ｦｯｲ･＼ｾ＠ and gra1 ltat1onal forres
solution A ｣ｯｮｾ｡ｩｧ＠ 25% salt and ana imporlant
ｳｯｬｵｴｩｾ［＾ ｮ＠ B cool!llni'ng 50° % salt. The
(D) one of ibe abore
mass In Lg of solution A rcquored IS c. As the veloc1l\ V nnd Utus the
Re)'l10ids ｮｵ ｭ｢ ｾ ｲ＠ of u Oow past o
b, 1.2 g 1\toms of carbon and 1,5 g moles sphere increases from very lo11 'ruues.
or ｾｸ ＩＧ ｧ･ｮ＠ are reacted to gil'e I g mole the dras, force for Re << I
or carbon dioxide. The limitin& (A) increases linenrl) 11 iib\1
reactant is . The per
 J Ut i)
ffi} ､ｾ｣ｳｬｦｮ･ｲｶ＠ with V tltc lemperoture of the exit liquid will
(Cl decre;,se. as v > · bl>
CD) none ofUtooc. (A) l<:s• thon 45°('
tl. Titc W"bcr numlx" CAn be usell I!! (B) ｣ｾｵｯｬ＠ •WC
<l111imate (C"l greater rh•n 4S•C
(.\) mliQ ｯｦｩｮ｣Ｚｲｴｾ ｬ＠ ｾｮｩｬ＠ surfac<>tensinn {0) ｬＱｩｴｾｹ＠ dctrl:!k'C$ and rtmain•
forces conswut ll•cJttJ/lc,r.
(B) rntio of in<:rlin and ＮＺ｣＾ｯｮｰｾﾷｩｬｴｹ＠ b. Indirect 1.'>:11ltnc1 hcot excltongc't" 01-c
forces preferrtd over ､ｩｾｬ＠ heal e.>«:.ftangers
(('I rAtio uf' mortial and ccnltifugal bCC.1USC

om
｢ｩｴ･ｾ＠ (I\ ) heat ｴｭｮｾｦ｣ｲ＠ ｣＼＾･ｦｬｪｩｮｴｾ＠ are high
(C") t:ttin 1•f ｾＢＧ＠ ..""" and \'iurfacc (B) ｴｬｾ･ｲ｣＠ i• no risk ()f cmttnm in•liQn
ten$ion fnn..'ef;. {(') then: i• n11 mist l'nrmntil)n
+. ChtJQsc tile correct J Item ate ; (lJ) ｣ Ｑ ｾｴ＠ of "'JUipmen t i; lowc:r
n. A partl<!lo A of tlinmoter 10 micro&. <:. To JniliAtco boiling of n liquid. ｉｬｾ＠
setllos 111 an oil llf spedlic grnvity 0.!1 tcmpornl\111! of tho heoled surface. if

.c
nnd \iscoshy 10 poise under Stokes smooth will be
Law. A pat tide B will• diameter 20 ( higher/lqwer) lhan for • commercial
truc.rom •ottling in the ｾ ｭ ･＠ oil will or a roughened s ucfaco.

ce
have a settling Yelocity d. 'l'he ndvanl.lRe of backwMd-foed
tA) s;une n• that of A multiple-etl'ecl ･ｶ｡ｰｯｲ ｾｴ ｯｲｳ＠ oYer
(B) ｯｾ ｦ ｯｵ､ｊ＠ as that orA forwnt'd· foed unit; ls tbnl
(C)
ra twic<: •• th.1i of,\ (A) heal scnsltiyc matcrinls can bc
(0) four-times o.• tltai of;\, h•ndled
b. \Vrile ･ｱｵ ｾｴｩ ｯｾ＠ J'or : IBJ there is no additional cost of
lA) Bnud's lllw ofsi:a: t·oductiou
1B) Filtration under constant pressure ｾ ｃ Ｉ＠
P"'"l''"!!
mo•t ｾｯｮ ｯ｣ ｮｬｲ｡ｴ ･､＠ lic1uor is nl
m
c. M•tclt the following : bighestlemperattlro
II) Cut diameter (D) equnJ be.'lt trnnsf.:r oo<:fficients
(ll) Spccl!io ｾＺ｡ｬ＼･＠ r.:;s-ist:mee ｾｸｬｳ ｴ＠ iu ••nrious effects.
(ill) Sfzc Reduction ｬｾｴｩｯ＠ G. rnthe blanks :
xa

Fill
(1\' ) Angh: offntemni Friction a, In •trying ·a ｾｯｬ ｩ､＠ conhlinin.g moi•ture
(A ) Filtrnti<m uoov< the eritii!ul mol,w.rc cOntent, the
(131 Cyclone separllli!O• number of Jee.rec:s C)f f,-.,edom IJ
(C\ Stomgc ofgolids
.e

(IJ) Ｑ｜ｩ ､ ［ Ｇ ｾ＠ ｉｾＢ＠ b. In the 1\ ｉｾ ｃ ｮ｢･ＮＭ l'hlclc tliagram fvr

<I During ｜ＺｬＮｾｨｩｮｧ＠ 11f ｬｩｴﾫｾ＠ the end uf blnacy dis tillation. \'t:l1lcal feed line
ｾｮＭｬ＾ ｮｬ＠ ｰｯＺＮ＼ｾ］＠ nltroiiiJU, the rot.c of ｮＺｰｲ｣ｴＮｾ＠ teed und
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wn•hing t.'<lttals lhc huri2onlnl feed ｬｩｮｾ＠ ttprel!ellb

(I\) rltte offillr.Hi<m ｾｉ＠ ｴｩｭｾ＠ zem teed.
(Bl rate qf llllr•tion at the end c)r c. - - - - number in mass transfer
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Liltrllllon eom:spon!L• to Nt1!15elt number iu ｢ｯｾｬ＠

lt l tote of fiHrotion whc:n half ｴｨｾ＠ lt311sfer and numllCr I()
ｬｩｴｲｮｾ＠ ｨｾｳ＠ be."' ｵ ｾｴＮｩｮ｣Ｚ､＠ l'randt hlltm b<:r.
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CO) rule of Glttali<m at the end of d. Ill small cblumn.1- local elfodtncy i•
Liltrntion. but d<Jc"""""" 1vitl• time Murphree ･ｦｬｩ｣ｾ ｮ ｣ｹ ｪ＠ tn
subse<(lltntJy, '"
lo-rg_e_ --;
<Xl1-um
- ns lcoe•l elfioieJ><Y is
Choose tlte correct ｾ ｬｴ･ｲｮ｡ ･＠ I 1\ lurplu·ee efficiency,
a. In • heal cxch3ngcr Will>•L:3m out>lde 7. Cbo-o-$o....,.
th_e_co
_ r:rccl
_ :.ltcrnnl• •
the tubes. • Liquid gel• bcnluct to ｾｳ ﾷ ｣＠ a. Write "''P"'•••ons.for
when ill! now Yelocity 111 the tub ... IS 2 (A) Van·, Hon· oquahon
mls. ·tftlJe. now velocity is •educed to I (.B) Vander Waals "'ruat iou S tole or
mls. otl1cr tJ1ings remaiuiH!!, t.lu: same. b. Durmg Joulo-Tiwm e:xpon3io11 of
ｾＡＨＤＮ＠
 3 ei' 6
ｾ ＢＮＩ＠ Entlllllpy remains consiBnt (Aj Fnst;er ruid osci.ll MOJY
()3) Llnll'OP¥ ｲｾＧｬｴ｡ｩｮｳ＠ COJI!itartl (B) Fmller and no.n-QScillitlory
(c;) Temperature Temalns c'Qn$tant (C) Slower and osdlhllory
(D) None of the above (p) Slowennd non-oscillatory,
c. Tba necessllty and sufhcient c<lttditiott b. ReiU:rllllgc i.ttto an ¢qllivalant llllity
for equ.ilibrill111 between two plll1Ses is fet!dtiadt di ｾｯｭ＠ :
(A.) concentrdtion Qf each contponenl
should be same in tlte two phases
(ll) ｴｨｾ＠ lt'tllperature of <>ach phase
ｾｨ＼ｬｴ ｬ ､＠ bes•me

om
(C) the 11re!;Wre should be S<une in 1he
two phases
(D) tlte clumlical potential of eaclt c. An integrating ｰｲｯｴ＼･ｳｾ＠ [lfl',sj -ill
ｃｩｭｬｰ｜ｖｊ･ｮ ｾ＠ s'l\ou)d be S<mll! in Llte conlroU"'i by a llr<lflor\ional .:inttroller
tlyo phases [K.;} The ｭ･ｮｳｾ＠ instrument and
d. For a single. component, two-phase tho. futal control olentent resp<md

.c
ｭｩｸｬｾ＠ l}w nunlbat <lf itlih:penJent it\stanmtteo\lllly_ Firld li\e o ffset
ｶ｡ｲｩｈ｢ｬｾ＠ properties ate tollowing a unit sler) ohange in load,
{.b,.) two d. Slate. whether tlte fol.lowing systems

ce
(B) ｰｩｴｾ＠ IJJ'e stable orunsmlile :
(C) ?.ero (i) t G{im) = -110" when .IGCiMI= I
(D) three (i0 1. G()<O) =-180° wben IG (io:>)I=0.588,
Choose Ute c'Qrrectalll"l1lule :
ra 10. (]ive HteMSwers ofihe.followi.ng •
a. 'Tite conversion
.reaf.)tllnt;,of n a. ｬ｡､ｩｾｴｯ＠ tlte lllOSt apprQPriste material
undergoing a JID.-1-order -reaction, at a for tlte hanJling of (he ｣ｬｴ･ｭｩｾ｡＠ as
lima equal to rlwe- DJUCS .half life me given below ·
ofUte reudioJil is ｏ ｴ ｣ｭｩ｡ｬｾ＠
m
(A) 0,875 (!)' Dilute Sulplmric
(B) 0.5 (ll) Cvrlcentrated FlydrochloricAdd
(C) 0.425 (Ill) Wet chlonne
xa

(D) not possibl<> lo c'ilctll.at.e hooanse of (f\!) Com::entrated Caustic Soda

ｭｾｵｦｩ｣･ｮｴ＠ data, Mattlri.'ils
U. The llluts af frequency fuctoc in (A) ｋｾ ｲ ｢｡ｴ･＠
Ac:heniLJS equati<111 Ol) Nkkel
{A) are l'he sru.ne ·as th(ll;e e>f.tlte rare· (C) Lead
.e

conslrutt (D) Ti taniwn

(B) depend em the·order "ffbe l'l'Sction 'b. FO!: pi]>" lines ihmdling fluid under
((.' ) depenft <trl tempe.r'J.lllre, rm•ssure presstlle, t:irctUnferential ｳｴｩｦ･ｲｵｮｾ＠
w

etc of the reaction ring> are used for witltstandi.ng higher

ｾＩ＠ arc eyolcs per unit rune. intel1bl1Jlre<..J<IU'e, { l'nte or Fills e).
l!. Fill ill the blanks:
c. In 1he. layout plan; lor, a vacuum
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l'ramition state 'theozy npproaclm ｏｴｾ＠ dlstillabQlL 111UI:, operating at @ .tum

problem of calculating reaction rates Ilg, suppott<!d by a blilt>metrie
by concentrating on, tlte ldeaof._ __ N ttdenser, ｦｾ･＠ \IJ)iJTCipriul.e vJuce for
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d. rill1ll the blanks: the location of VllCUUlll drum fpr

h1 a ru'St-Qmer reactio,., coUecliiJg tlte cHsMI1<Jtewl11 be
ａｾｐｲｯｵ｣ｴｳ＠ (A) at grnund Jevel
the reaction bECOmes ｳｬＮｯｷｾｲ＠ >1s it (B) 2111 111><1\\t> gt'Oun'll
l)r<t<:eeds, because Ute concentration of (C) .5 m abQve ground
A artd tlttnltle is (D) I0 m above gml'md.
9 Choose th<>right answer; d. ｍ｡ｴｾｬ＠ Ute. following :
a Vllten a bare titcnnocouple is cowered (I) ｃ｡ｰｩｴｬｺｾ＠ cc'st
by a protective sh<!atiL t11e- response- (ll) \Jnnmortized vulua
bec<>me:.; (nl) Payout pmod
 I of6
(lV) Coet index 0.15 lT''tsec ihrouglt pipe A, wJtile oil
(A) Comparing alternative1nveslnwnl of specific gravity ().8 for,-ed in ill the
chuit.!es rate of O.OS m1/sec through lripe B. If
(B) Uprt1tmg CtlSI dnln of eq1UJlll1enl ｾｨ･＠ liqnid• .are ITIC<lmprem'ble and
(C) Profttabilily ev-aluation lom1 a IJ.omogeneous mixmre of oil
(b) CQsl ncootmbitg gl<•bules in ·wale,, wh>.tl i;· llie liVernge
(F) Rep)acemenL ､ＢｬＮｾｩｯｵ ｬｲ＠ ｶｾｯｱ ｪ ｊｹ＠ and densi ty of [he m.biture
leaving throll!!l• pipe C havmg a
(F} Working capital di;uneter of " 7 / 22 J11
ﾷｾ Ｍ For Oow over a llal plttle where'JJ, a

om
SECTIONB laminar bP!lJld.'JJY layer 1• present for
ＨＱＲＰｾＩ＠
th,. ｣ｾ･＠ nh :tero presS1.1fl> gradien1; the
fllli"Jbotic llfOfile lbr \teloci ty U;,. given
I I. 'J1u•' ooncentration of SO, in the lltUHillle!< by
ｵ ］ ｡Ｎ Ｑ ｹ Ｍ ｡ Ｒ ｹ ｾ＠ for y s 8
from a 'boiler tV'SS fowd to be 0.2 kg!';;\' at

.c
u =Vu ｦｯｾ＠ ;y 1!0
N.T.P. Detern;i.Jle the concert1J)IJ:i:On.ofSO:.
in paris per millicm by ｶｯ ｬｮｴｾＬ＠
Ass•Jme ｴｨｾ＠ the gil.•es are perfe<;t..
at ＱＧ Ｎ ｾ ﾷ＠ P.
--
r ind a; artd ,.,.

ce
12. .Answer Uie fllllowing ｉｽｔｨＡｓＱｯｲ｣ｾ＠ :

ﾷ Ｇｌ Ｚ ｾ＠
a. The Qnalysill C 1f ｬｩｴｾ＠ J!.aS entering- the
sec'Ondaf)' C1Jnver1<!r in 9 CQfllact
snlphur.ic ncirl pl811t .is 4% S02. J3%
＼ＩＮｾＬ＠ ｴ ｕ ｜ｾ＠ 1:'3% · , (l•olume %). In the
ra <:Onvet1er ｳｯ ｾ＠ is ,ucidised to so,. 'l'lie
gases l eavmg !he converter contaln ]<I i\llliWSr
& . ..
; ｾｳＮ＠
lttefoll<>"in£:
_ ...
. ..-:..,..

0,45% SOa on au SOt free basis a. Prutit:lcs o.f sve1'age .feed size Ｒ ｾ＠
4
m
{volume %). Calcnlate 1he percent 1 0 m are crushed to an average
w nversion <:>fS01 prnilu{'t sizt- of) •<. J0'"' 1T1 nl the ml,e of
b. D.ry methane is bii.Oled with. dry air. l5 t.ons per hoOT. AI Ihilt rnl.e the
Both are at 2s•c initially. 'rhe llame crusher consun1es 32 kW ofpower of
xa

tempe.ranue 1s 1300 C, 1( complete w.hic;h 7 kW me fllil'lired for 11111ning

combustion. Is assumed how Jnuch tlte mill empty. what wollld be 01e
axcess air is being used? 'lite reaction power & wn;mmption if 40 tolL!' _per
ｩｾ＠ hllut of this. product is .further oru£ltcd
.e

ｃｴｌＡ Ｋ ｚｏ ｾ＠ 4 ｾ Ｋ＠ Ｒ ｈ ｾｏ Ｌ＠ to I ' 10_. ru ｳｩｺｾ＠ .iu ｬｨｾ＠ Slllne mill1

Standard heat of ｴｾ｣ｩＰＱ＠ "' -8.028 ｾ＠ Assrune llllll Rittinaer·s law is
I 05 J/g mole of OH. :reacted. Mean applicable. -
b. A tillerl)ress oonlai.ns- 2() frames, each
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molal specific heats of gases betWeen

25°C and 1300•c &'!' .in J/(g. mole) of 0.6 m. by 0.6 m f11Slde duneJtSion
("K) : '111e- .6'llll.1es ate 1'>.02.5 m !luck. 'rltu
press l• equiwed wiLI1 l il!ld Ｓ Ｍ ｾｵｬｴｯｮ＠
w

COa- 51.88
I·h0 - 40.45 plates for wliSh.ing. The ｶｾ ｬｵｷ･＠ of
ｾ］ ＳＴＮｑｬ＠ wrt$h water nsecl is l 0% of lhe filtrate
per cycle, The time required fur
w

N2= J2.2 1
13. Aru;.w er th<t followiltg : filtering, nt ,'On.stlmt. pressrn:e, is 2
tt. Wallrr Is forced h;to 1he device showrt hOUJJi oy wJiich time !he IDUtle.< ·are
mｦｩ ｧｬｴｲ･｢ ｯ ｗｾｴ ｬ ｨ･ｲｯ ｬ ･ＮＬｦ＠ fuU, Washing .is done ·at dte same
ｰｲｩｯＡｾｉｕＧ･＠ as filtering and tile viso;osity
of wash water .is nearly ＨＺ｜Ｑｾ＠ same as
tru!t of the Jj.Jbute. Wltat l.s the time for
washing? Thc:re is 0.05 m' of ｾ＠
cake per m 3 of illlrate, Neglect the
rc.-islmtce of the 1ilter medium.
15. ａｵＮｾ｜ｶ･ｲ＠ tlte following questions !.

ot. Comider ｴｨｲ ｾ＠
infinite pmllel ｰｬ ｾ ｬ ﾢＱＮ＠
Plate I is m:nnL1.ned • I 1227"C and
plate 3 il mtuntained ot Ｍ ＱＷｾＢ
Euti.8ivilics ure equ• l to thM <Jl" a hlack
hlldy. PI ole 2 ｩ ｾ＠ pl•ced between plnre,
I :mel 3; :md receive,; t"' hent li'CJm
ｾｴ｣ｲｵ ｬ＠ ｾ ｯｵｴ Ｇｃｏｩｬ Ｎ＠ Wllttl is Ute
ltmtpCI'aiUrc of pinto 2 'I
ll A nickel steel rod S ｾ ｭ＠ OJ) ongjnnlly
al n b:mJlomirun; ｾｯ ｲ＠ 31)0"(' i> ｾ ｵＬｗ Ｎ ｴ ｮｬ ｹ＠
, ur ll
{ii) the composition of-v:apor ･ ｮｴ ｴＭ ｲｩｮｾ＠ thai
pla1e from 11hich liquid Ｈｗ ｾ Ｖｗ＠
ｃ＠ cOr\tuin$ 0. 7 mnlo l'raotiun Qf the mbl'o
' ul•lile ｃｏ ｴｰ ｯｮ ｵｾ＠
c. ｾ ｨ ･ ｬｭ ｾ ｬ ｣ ｲｩ ｯｬ＠Ｚ (),S ｾ ｭ＠ Chick CQnl:tining
SOt) ｬ ｱｾ＠ ol' dry ｾ ｬ ｯ｣ｫ＠ m·1 of original Wtt.
ｾｬｏｴ ｾ＠ ii to be dried al CQnownt dtying
w nditiOnM. Th<' initiJ>l drying mte is ｾ＠
kgl(hr) (m1 ) at dtc initio! ｭ ｯｬｾ ｴｵｲ･＠
ｾ ＼ ｬｮ ｣ｮ ｬ＠ <l l' 33°0. The lin" I dl)'ilig rotc ill

om
imoocr.<cd iu • li4uid ol ｈ ｬ ｯｾ ｣＠ ror I kgl(ltr) Ｈ ｭ ｾ Ｉ＠ JJl Ｖｾ＠ final mvislw e
wlticb lh<> L'OliVtdivc heat transfer contanL The CtjUilibrium moisture
coallici;;nt is 10\J \\11m2 K. Dele111tin« content is negligible. If drying is from
Ute timc-l'e(IUired for Ihe rod to teach 3 - ｴ｢ ｾ＠ two htrge surl'a= ｏ ｉｌ ｾＮ＠ iltld if cbe
Ａ ｣ ｭｰｯｵｴｲ ｾ＠ of 150"C. (Hint: C•kulote dryin,g ｲｮｬ ｾ＠ in ｴｨｾ＠ filling rntc p<riud t.
the Bioi number nnd nuke tho prnportionnl to the lh:c moisture

.c
necessary assumption). ｾ ｯ ｮｴ ･ｮｬＬ＠ o lcnlate the lolnl drying time,
ｐ ｲｯ ｴ ｾ･ｴ ｬ ｬ＼ＺＤ＠ of nid,"el steel A.IJ mois luo'e conlenls ore OJI the dry
K SOW/ru. K : ｾＮ Ｎ Ｎ＠ .

ce
t> - 81100 kglm1 :
I ' p = 0.5 J/kg. K. Two, e ... & sax MAJUtS
16. Answer the rollowing questjons :
<L Equilibrium re.lllliCJI\$hir f()t' Lbe ｳｾ
ra ｴｯｭ＠ QUDTIONa (17-20)
lt"J)t.one-oil· •ir iS givcu by Y : 2.'( (Y
and X nre kg-hepume!kg.nir ｡ｮｾ＠ kg- 11. All.\<wcnl!c following :
heptaneik&"Qil re• pectivcly). f'HI •· 106 Joules of ｨ ｣ ｾｬ＠ ate ｬ ｲ｡ｵｾ ｬ ｩＺ ｭＺ､＠ ti·om
ｯｾ ｮｴＮｯｩ ｮｧ＠ 0.005 ｫｧ Ｍｨ ｯ ｰ｢ｮ ｾﾷｵ ｩｬ＠ ｾ ｾ＠ • "'-"t:niOir al ＳＢＲ ＷＧ ｣ ｾ＠ to ll1l .,gffie lh;,t
m
being U!led as ｾｯ ｬ ｶ･ ｮｬ＠ ll>r reducing tht: ｯ ｲ ｸ Ｚｲｯｴ ｾ＠ on lhc C'a mol cyd o. Th .;.
hep!Ani! content or ｾ ｩｲ＠ from \),10 to cop oc rejects hQnl to • r(.-,urvuit ol
().021.:g-heplnnclkg-sir in • cooltlnuo\1$ 27"C. Determine d•e tbetJn"l
effiaiency of the cycle ｾｮ､＠ the worli;
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counter-current ｰｾ ｣ ｫｬ､＠ hed ｾｬＮＡ ｯｲ｢｣ ｲ Ｎ＠

ｗｨ ｾ ｬ＠ column ｨ ･ｩｧ ｨｴ ｾ＠ n:quired to trcot don" by Oce cnglM. 13 nwrks)
1400 kW(hr) (m1 tol' "'"PLY luwer cross b. An tnvo::nto r clnims 10 how duvoloJ"'<<
ｾ ･｣ｴ ｩｴｬ Ｉ＠ of pure nir «mlilining iO<:(>tn.nc o rofnserntion unit whcch mnint:>in• lhe
if Uoc tl"cull !!"" nln.!l• transll:r rd h genned spa.:<> at - 3"(" while
.e

cnefficienl is ｾＲＰ＠ kgl(hr) lm'1) p<:r unit opor3tinj! in • room "'lu:rc tlce
ｾＱ ､ ｩ ｴＺｮ＠ of Y 'rhc: oil raa.: ｃｊｔＡｉ Ｉ ｉ ｯｾ ＼ｬ＠ l• tcmpct:alun: it 21°C. nnd wloi.::h has •
3 100 \4!i(br ) {m1) . ooefficient of perl'oml3nce of 9,5, How
do you evaluate-his claim? {3 marks)
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Solve ｾ ｮ Ｂ ｬ ｹ ｴｩ･｡ ｬ ｹ Ｎ＠
h. 'l'he following iltformntion l• av:ulublo .:. Consider the compt'tssion of ail' from
lrum Ute record, of a binlll') UY Pa ;\( 27'C Ill 3 106 ｐｾ＠ In •n iuo•l
｣ｯ ｮｴｰｭ ｾｯｲ＠
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Jracliouatiug <:Olumo: twll-•lt{ge with

Fwd 180 kg-molelltt and ＶＰｾ＠ inl.:t'C!Wiing, ｯ｜ＮＬｾ ｵｭ ･＠ U1lll th"
yaporosed; ｴ ｣ ｭ ｪｬ ｯｲＺｾｬｵ ｲ ｴ＠ .. r lht: uit lcnvinJ! the
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DlstiiJ,,te = 100 kg-mole!br wlUt 0.9!C intctCAlulor is aiM> '27"C. •nd thnt lloc
mole froctioo of tho moro ｶｯ ｬ ｬｩ ｾ＠ op1imu111 ｩ ｮｴ ｭ ｣ ｾｧ･＠ ﾷ ｰ ｮＺＮｾ ｵｲ＼Ｚ＠ is used,
component Tbc; ｣ｯｴｮ ｰｲ ｣ｾ［ ｲ＠ i.< ｷ ｡ ｴＮ［ ｲ ｾ ｾ ､［･ ｴ ･ ､＠ 3nd
Reboiler st...,m demand = 420 kgtlu-; Ult I>Oiyltt)l)iO CXfl()lleni ii is [ ,31) fhr
U.tent b«ot of column liquid = 3 10' both ｳ ｵｴ ｧ ｯｾ Ｎ＠ ｄ･ｴｯｲｭ
ｩ ｮ ｾ＠ the \\ Ork of
Jig nlOic! lloHI ｾ ｭｰ ｲ･ｳｩｯ ｮ＠
per kg of air, (tl mnrks)
U.lent ｨ ｾ ｮｴ＠ or.,teauo u•o<l in rohuili:r - IK Answer tho ll>lluwing -
22(!0 J/j!. a. & plsin in nne or t"o li<nlcncc.,. why
('nlcuiUie Ute ｦｯ ｬ ｭｶｴ ｮ ｧｾ ｴｯ ｣Ｚｲｮ･ ｮｴｬｯ＠ .,.., ｩｵ ｣ｯ ｲ｣ ｣ ｬ ｾ＠
(I) IJ)e Qpotatin£, Ｑ ＧＰ Ｌ Ｐ ｾ＠ r.uin :tnd ( i) 'f]le ｾ ｾ ･ ｾ､ ｹ Ｍｳｴ｡ ･＠ •pproxim;tlinn iq"
 6oC6
rodtcal c)twq mcchanunt illvolv"" (i) I = OJ mm
ｴｨｾ＠ ll$SWnption that since tlte (ii) I = OA min. (6 marks)
roncentrnli oll of any particular b. ｄ･ｴｾｮｩ＠ :
all1mic or radical ｾｰ･｣ｩ＼ｬＡ＠ is oo (i) The ma."mum 1\IDII for l111lb1e
im!all 111at tl can be taken to be operntiC'Il.
ｾ･ｲｯ Ｎ＠ (2 tnad:s) (ii) 11te COrre!!JlOPding frequency Qf
(i:i) Coal f\)nJI$ !lfl inLoxpl<:lsive mixture ｾ･ｩｕｵ ｴｩ ｯｮ Ｎ＠

ｾｲ＠
witlt air at ordimuy ternperatntes
whenlt li 111 finely diVtdcd form.
(2 marl:s)

om
(ill) lnltibition JB the Jli'OCCfS where the
rate-of reaction 11 ､ｾＧｒＮ｡ｓ｣＠ by
( (> 1TlJ!1b)
lowt'riug tho tcmJX:nuuro.
20 Amwer tlte fullowmg •
(3 marks)
b. A llomogeneooEliquid phasd reaction a Give the e;>.."]J.t'l$8tC'Jtt ｦ ｾ＠ the two
principal stresses for a ｾｹｮ､｣｡ｬ＠
ａｾ＠ R; ,.. .. kc ..=

.c
ｰｲ･ｳｾｵｶｬ＠ closed at boUt ends.
Iukes place witl1 SO% conven;ion Ul a
(2 marks)
weU ｭｾＢｴ･､＠ reactor ｏｊｬｦＧｾ＠
b. For a sas cylinder, dcStsncd 011 the
isolhermally. Whul will be r.he

ce
•'fhin Cylinder Principle'·, calculate
conv<mm:m it Ute reuctN ts replacYd by the- tlticl:ness of o acnmless cylinder
n v!ug flow lyl'e of <'<\lUll size all else
under the f<lilowhl8 condition.! :
remairung the same1 (3 rnas:ks) ｐｲ･ｳｮｴｾ＠ of N. gas in dte eylutde. =
o Cmstdel: tbe l'el ·\lf elemental)•
ra 100 105 ｎ ｬ ｭ ｾ＠
reactiow:
Telliile stre!'S ｰ･ｯｮｬＤＱ｢ ｯ ｾ＠ 1200 105
A -'4 JJ N/m.:.
.-1 - n......:.......c !ilternal diameter of cylulder = 25 em
ａ ｾ ｄ ｾ ＧＲｅ＠
m
('I marks)
At time I = 0, n batch reactor IS filled c. 11te pl!lllt of o ｣ｬｾｊｕｩｮ＠ coruprury 'has
with a mixture of A and 0 What is ilie 1111 initial wo1ili of Rli SO l:lkbs, and au
relstim bctwCCII th<' oonccntratio!IS of l'!lrimaled ｳ｡ｬｖ＾ｴｧｾ＠ value ofR.B. 2 lukhl!
xa

B andD after n time I? (3 marks) itt a s-ervice life of8 yenrr.

A.n.-wer tbe f<ilowllll! qu..'Stions (i) Given 8 ｣ｬｴ ｯ ｩ ｾ ｣＠ bel wee11 the
a, A thCilliOmcter foDov.-s tim-order sirnight-llne and declining-balance
dynamics with a time oonl!1anl 0.2 min. utethods of depreciation. \Vluclt
.e

lt is ｰｩ｡ｾ＠ i11 11 teJnpernrure ballt at method would you recommend to

Joo•c and is aUowl'll tn reach ste-ad)' •-ave tall w1d why? (3 marl:s)
stale. lt is suddenly b·uusfencd to (ti) '&ttmate U1e l>ook value of the plant
unoll1er ba.lh ul 150"C n.l time I = 0 and at the end.of •I yenn f<'r each. of Ute
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is leJ1 tht)J:'e f11r 0 2 min II ｩｾ＠ two methodP. of doproclnticn.

ｩｮｭｴ･､｡ｾ ｬ ｹ＠ returned to Ute original (3rnarks)
bath at 1oo•c.
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C'alculate ｩｾ＠ rending' at

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