1

JEE MAIN 2021

ONLINE
24th February
2nd Shift

PHYSICS (a) Statement I is true but Statement II is false.

(b) Statement I is false but Statement II is true.
SECTION-A (MULTIPLE CHOICE QUESTIONS) (c) Both Statement I and Statement II are false.
1. The de Broglie wavelength of a proton and a-particle (d) Both Statement I and Statement II are true.
are equal. The ratio of their velocities is 7. If one mole of an ideal gas at (P1, V1) is allowed to
(a) 4 : 3 (b) 4 : 2 (c) 4 : 1 (d) 1 : 4 expand reversibly and isothermally (A to B) its pressure
2. The period of oscillation of a simple pendulum is is reduced to one-half of the original pressure (see
figure). This is followed by a constant volume cooling
L till its pressure is reduced to one-fourth of the initial
T = 2π . Measured value of ‘L’ is 1.0 m from meter
g value (B → C). Then it is restored to its initial state by
scale having a minimum division of 1 mm and time a reversible adiabatic compression (C to A). The net
of one complete oscillation is 1.95 s measured from workdone by the gas is equal to
stopwatch of 0.01 s resolution. The percentage error in (a) 0 P A
the determination of ‘g’ will be P1
RT P B
(a) 1.03% (b) 1.30% (c) 1.13% (d) 1.33% (b) − 1
2( γ − 1) 2
3. Figure shows a circuit that contains four identical P1
(c) RT ln2 4
C
resistors with resistance R = 2.0 W, two identical
inductors with inductance L = 2.0 mH and an ideal  1 
(d) RT  ln 2 − 2( γ− 1)  V1 2V1
V
battery with emf E = 9 V. The current ‘i’ just after the  
switch ‘S’ is closed will be 8. In the given figure, a body of mass M is held between
two massless springs, on a smooth inclined plane. The
A
S free ends of the springs are attached to firm supports.
R
+ R L If each spring has spring constant k, the frequency of
i oscillation of given body is
E=9V L
R k

k M
R
(a) 3.37 A (b) 3.0 A (c) 2.25 A (d) 9 A
a
4. An X-ray tube is operated at 1.24 million volt. The
shortest wavelength of the produced photon will be 1 k 1 k
(a) 10–1 nm (b) 10–4 nm (c) 10–2 nm (d) 10–3 nm (a) (b)
2π 2 M 2π Mg sin α
5. When a particle executes SHM, nature of graphical
1 2k
representation of velocity as a function of displacement (c) 1 2k (d)
is 2π M 2 π Mg sin α
(a) elliptical (b) circular 9. According to Bohr atom model, in which of the
(c) straight line (d) parabolic following transitions will the frequency be maximum?
6. Given below are two statements : (a) n = 4 to n = 3 (b) n = 3 to n = 2
Statement I : PN junction diodes can be used to (c) n = 2 to n = 1 (d) n = 5 to n = 4
function as transistor, simply by connecting two diodes,
back to back, which acts as the base terminal. 10. If the source of light used in a Young’s double slit
Statement II : In the study of transistor, the experiment is changed from red to violet
amplification factor b indicates ratio of the collector (a) the intensity of minima will increase.
current to the base current. (b) the central bright fringe will become a dark fringe.
In the light of the above statements, choose the correct (c) the fringes will become brighter.
answer from the options given below. (d) consecutive fringe lines will come closer.
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11. A circular hole of 1/2 1/2

 3  2q2 
a Y-axis (a)  πε0 md  (b)

radius   is cut out 3
2  2q2   πε0 md 
1/2 1/2
of a circular disc of  q2   2 πε md 3 
radius ‘a’ as shown in a/2 (c)  (d) 0
O
a 3  2 
figure. The centroid of X-axis  2πε0 md   q 
the remaining circular 17. Which of the following equations represents a travelling
portion with respect to wave?
point ‘O’ will be (a) y = Aexcos(wt – q) (b) y = Asin(15x – 2t)
10 2 5 2
(a) 1 a (b) a (c) a (d) a (c) y = Asinx coswt (d) y = Ae–x (vt + q)
6 11 3 6 18. Match List-I with List-II.
A
12. C List-I List-II
B (A) Source of microwave (i) Radioactive decay
The logic circuit shown above is equivalent to frequency of nucleus
A (B) Source of infrared (ii) Magnetron
(a) C
B frequency
A (C) Source of Gamma (iii) Inner shell
(b) C Rays electrons
B
(D) Source of X-rays (iv) Vibration of atoms
A and molecules
(c) C
B (v) LASER
(d) A (vi) RC circuit
C
B Choose the correct answer from the options given
13. On the basis of kinetic theory of gases, the gas exerts below
pressure because its molecules (a) (A)-(vi), (B)-(v), (C)-(i), (D)-(iv)
(a) suffer change in momentum when impinge on the (b) (A)-(ii), (B)-(iv), (C)-(vi), (D)-(iii)
walls of container. (c) (A)-(ii), (B)-(iv), (C)-(i), (D)-(iii)
(b) continuously stick to the walls of container. (d) (A)-(vi), (B)-(iv), (C)-(i), (D)-(v)
(c) continuously lose their energy till it reaches wall. 19. Zener breakdown occurs in a p-n junction having p and
(d) are attracted by the walls of container. n both
14. A soft ferromagnetic material is placed in an external (a) heavily doped and have narrow depletion layer.
magnetic field. The magnetic domains (b) heavily doped and have wide depletion layer.
(c) lightly doped and have wide depletion layer.
(a) decrease in size and changes orientation.
(d) lightly doped and have narrow depletion layer.
(b) increase in size but no change in orientation.
(c) may increase or decrease in size and change its 20. A particle is projected with velocity v0 along x-axis.
A damping force is acting on the particle which is
orientation.
proportional to the square of the distance from the
(d) have no relation with external magnetic field.
origin i.e., ma = – ax2. The distance at which the
15. A body weighs 49 N on a spring balance at the north particle stops
pole. What will be its weight recorded on the same 1/2 1/2
 3v 2 
weighing machine, if it is shifted to the equator? (a)  2v02  (b) 0
   
GM −2 3α  2α 
[Use g = 2 = 9.8 ms and radius of earth, R = 6400 km] 1/3 1/3
 3v 2 
R (c)  2v0  (d) 0
   
(a) 49.83 N (b) 48.83 N 3α  2α 
(c) 49.17 N (d) 49 N
SECTION-B (NUMERICAL VALUE TYPE)
16. Two electrons each are fixed at a distance ‘2d’. A third Attempt any 5 questions out of 10.
charge proton placed at the midpoint is displaced
21. Two solids A and B of mass 1 kg and 2 kg respectively
slightly by a distance x(x < < d) perpendicular to the
are moving with equal linear momentum. The ratio of
line joining the two fixed charges. Proton will execute
simple harmonic motion having angular frequency their kinetic energies (K.E.)A : (K.E.)B will be A , so the
(m = mass of charged particle) 1
value of A will be _______.
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22. A series LCR circuit is designed to resonate at an NO2 Br

angular frequency w0 = 105 rad/s. The circuit draws
16 W power from 120 V source at resonance. The value
of resistance ‘R’ in the circuit is _______ W. Br
23. A signal of 0.1 kW is transmitted in a cable. The (a) Sn/HCl KBr Br2 H+
attenuation of cable is –5 dB per km and cable length
Br2/Fe NaNO2/HCl CuBr/HBr
is 20 km. The power received at receiver is 10–x W. The (b) Sn/HCl
value of x is _______. NaNO2 HCl KBr H+
 (c)
 Po  
Gain in dB = 10 log10    (d) Sn/HCl Br2 NaNO2 NaBr
  Pi  
24. A uniform metallic wire is elongated by 0.04 m when 32. Given below are two statements :
subjected to a linear force F. The elongation, if its Statement I : The value of the parameter “Biochemical
length and diameter is doubled and subjected to the Oxygen Demand (BOD)” is important for survival of
same force will be _______ cm. aquatic life.
25. The root mean square speed of molecules of a given Statement II : The optimum value of BOD is 6.5 ppm.
mass of a gas at 27°C and 1 atmosphere pressure is In the light of the above statements, choose the most
200 ms–1. The root mean square speed of molecules appropriate answer from the options given below.
of the gas at 127°C and 2 atmosphere pressure is
(a) Both statement I and statement II are false.
x
m s −1 . The value of x will be _______. (b) Both statement I and statement II are true.
3 (c) Statement I is false but statement II is true.
26. A uniform thin bar of mass 6 kg and length 2.4 meter (d) Statement I is true but statement II is false.
is bent to make an equilateral hexagon. The moment of
33. Which one of the following carbonyl compounds
inertia about an axis passing through the centre of mass cannot be prepared by addition of water on an alkyne
and perpendicular to the plane of hexagon is _______ in the presence of HgSO4 and H2SO4?
× 10–1 kg m2. O O
27. A point charge of +12 mC is at a +q (a) CH3 C CH2CH3 (b) CH3 CH2 C H
distance 6 cm vertically above the O O
centre of a square of side 12 cm as 6 cm (c) C CH3 (d)
CH3 C H
shown in figure. The magnitude of
34. The calculated magnetic moments (spin only value)
the electric flux through the square
12

for species [FeCl4]2–, [Co(C2O4)3]3– and MnO42–

will be _______ × 103 N m2/C. cm
cm

12 respectively are
28. An electromagnetic wave of frequency 3 GHz enters (a) 4.90, 0 and 1.73 BM (b) 5.82, 0 and 0 BM
a dielectric medium of relative electric permittivity (c) 4.90, 0 and 2.83 BM (d) 5.92, 4.90 and 0 BM.
2.25 from vacuum. The wavelength of this wave in that 35. The diazonium salt of which of the following
medium will be _______ × 10–2 cm. compounds will form a coloured dye on reaction with
b-naphthol in NaOH?
29. Two cars are approaching each other at an equal speed CH3
of 7.2 km/hr. When they see each other, both blow
NH2 N—CH3
horns having frequency of 676 Hz. The beat frequency (a) (b)
heard by each driver will be _______ Hz. [Velocity of
sound in air is 340 m/s.] CH2NH2 NH—CH3
30. A cylindrical wire of radius 0.5 mm and conductivity (c) (d)
5 × 107 S/m is subjected to an electric field of 10 mV/m.
The expected value of current in the wire will be 36. Match List-I and List-II.
x3p mA. The value of x is _______ List-I List-II
CHEMISTRY (A) Valium (i) Antifertility drug
SECTION - A (MULTIPLE CHOICE QUESTIONS) (B) Morphine (ii) Pernicious anaemia
(C) Norethindrone (iii) Analgesic
31. What is the correct sequence of reagents used for
(D) Vitamin B12 (iv) Tranquilizer
converting nitrobenzene into m-dibromobenzene?
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(a) (A)-(iv), (B)-(iii), (C)-(ii), (D)-(i) 40. Match List-I and List-II.
(b) (A)-(ii), (B)-(iv), (C)-(iii), (D)-(i) List-I (Metal) List-II (Ores)
(c) (A)-(i), (B)-(iii), (C)-(iv), (D)-(ii) (A) Aluminium (i) Siderite
(d) (A)-(iv), (B)-(iii), (C)-(i), (D)-(ii)
(B) Iron (ii) Calamine
37. Match List-I and List-II.
(C) Copper (iii) Kaolinite
List-I List-II (D) Zinc (iv) Malachite
(A) O (i) Br2/NaOH Choose the correct answer from the options given
R C Cl R CHO below.
(a) (A)-(iv), (B)-(iii), (C)-(ii), (D)-(i)
(B) R CH2 COOH (ii) H2/Pd (b) (A)-(iii), (B)-(i), (C)-(iv), (D)-(ii)
BaSO4 (c) (A)-(ii), (B)-(iv), (C)-(i), (D)-(iii)
R CH COOH
(d) (A)-(i), (B)-(ii), (C)-(iii), (D)-(iv)
Cl 41. Most suitable salt which can be used for efficient
(C) O (iii) Z n ( H g ) / clotting of blood will be
R C NH2 R NH2 Conc. HCl (a) FeCl3 (b) NaHCO3
(c) FeSO4 (d) Mg(HCO3)2
(D) O (iv) Cl2/Red P, 42. The correct order of the following compounds showing
R C CH3 H2O increasing tendency towards nucleophilic substitution
reaction is
R CH2 CH3 Cl Cl Cl Cl
NO2 O2N NO2
Choose the correct answer from the options given
below.
(a) (A)-(iii), (B)-(iv), (C)-(i), (D)-(ii) NO2 NO2 NO2
(b) (A)-(iii), (B)-(i), (C)-(iv), (D)-(ii) (i) (ii) (iii) (iv)
(c) (A)-(ii), (B)-(iv), (C)-(i), (D)-(iii) (a) (iv) < (iii) < (ii) < (i) (b) (iv) < (i) < (ii) < (iii)
(d) (A)-(ii), (B)-(i), (C)-(iv), (D)-(iii) (c) (i) < (ii) < (iii) < (iv) (d) (iv) < (i) < (iii) < (ii)
43. The correct set from the following in which both pairs
38. The correct shape and I I I bond angles respectively
are in correct order of melting point is
in I–3 ion are (a) LiCl > LiF; MgO > NaCl
(a) linear; 180° (b) LiF > LiCl; NaCl > MgO
(b) T-shaped; 180° and 90° (c) LiF > LiCl; MgO > NaCl
(c) trigonal planar; 120° (d) LiCl > LiF; NaCl > MgO
(d) distorted trigonal planar; 135° and 90° 44. Which one of the following compounds is non-
aromatic?
39. According to Bohr’s atomic theory ⊕
(a) (b)
Z2
(A) Kinetic energy of electron is ∝ . ⊕
n2
(B) The product of velocity (v) of electron and principal (c) (d)
O
quantum number (n), ‘vn’ ∝ Z2.
(C) Frequency of revolution of electron in an orbit is 45. Given below are two statements : One is labelled as
Assertion (A) and the other is labelled as Reason (R).
Z3
∝ . Assertion (A) : Hydrogen is the most abundant element
n3 in the universe, but it is not the most abundant gas in
(D) Coulombic force of attraction on the electron is
the troposphere.
Z3 Reason (R) : Hydrogen is the lightest element.
∝ .
n4 In the light of the above statements, choose the correct
Choose the most appropriate answer from the options answer from the options given below.
given below. (a) Both (A) and (R) are true and (R) is the correct
(a) (A) and (D) only (b) (A) only explanation of (A).
(c) (C) only (d) (A), (C) and (D) only (b) (A) is false but (R) is true.
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(c) Both (A) and (R) are true but (R) is not the correct 53. The magnitude of the change in oxidising power
explanation of (A). of the MnO4–/Mn2+ couple is x × 10–4 V, if the H+
(d) (A) is true but (R) is false. concentration is decreased from 1 M to 10–4 M at
–
46. What is the correct order of the following elements 25°C. (Assume concentration of MnO4 and Mn2+ to be
with respect to their density? same on change in H+ concentration). The value of x is
(a) Cr < Fe < Co < Cu < Zn . (Rounded off to the nearest integer)
(b) Zn < Cr < Fe < Co < Cu  2.303RT 
Given : = 0.059
(c) Cr < Zn < Co < Cu < Fe F 
(d) Zn < Cu < Co < Fe < Cr
54. The total number of amines among the following which
47. Match List-I and List-II.
can be synthesized by Gabriel synthesis is .
List-I List-II
CH3
(Salt) (Flame colour wavelength) (A) CH CH2 NH2
(A) LiCl (i) 455.5 nm CH3

(B) NaCl (ii) 670.8 nm (B) CH3CH2NH2

(C) RbCl (iii) 780.0 nm
(D) CsCl (iv) 589.2 nm
Choose the correct answer from the options given below.
(a) (A)-(i), (B)-(iv), (C)-(ii), (D)-(iii)
(b) (A)-(ii), (B)-(iv), (C)-(iii), (D)-(i)
(c) (A)-(ii), (B)-(i), (C)-(iv), (D)-(iii)
(d) (A)-(iv), (B)-(ii), (C)-(iii), (D)-(i)
48. ?
O (C) S2-form
Which of the following reagent is suitable for the
preparation of the product in the above reaction?
(a) Ni/H2 (b) NaBH4
(c) Red P + Cl2
(d) NH2 NH2 /C2H5ONa
49. The incorrect statement among the following is
(a) red colour of ruby is due to the presence of Co3+
(b) RuO4 is an oxidizing agent
(c) Cr2O3 is an amphoteric oxide
(d) VOSO4 is a reducing agent.
50. In polymer Buna-S, ‘S’ stands for
(a) strength (b) sulphonation
(c) styrene (d) sulphur.
SECTION - B (NUMERICAL VALUE TYPE)
Attempt any 5 questions out of 10.
51. The volume occupied by 4.75 g of acetylene gas at 50°C
and 740 mmHg pressure is L. (Rounded off to
the nearest integer)
[Given R = 0.0826 L atm K–1 mol–1]
52. The solubility product of PbI2 is 8.0 × 10–9. The
solubility of lead iodide in 0.1 molar solution of lead
nitrate is x × 10–6 mol/L. The value of x is
(Rounded off to the nearest integer)
[Given 2 = 1.41 ]
CH2 NH2
(C)
NH2
(D)
55. Among the following allotropic forms of sulphur,
the number of allotropic forms, which will show
paramagnetism is .
(A) a-sulphur b-sulphur
(B)
56. Assuming ideal behaviour, the magnitude of log K for
the following reaction at 25°C is x × 10–1. The value of x
is . (Integer answer)
3HC ≡ CH(g) C6H6(l)
[Given : Df G° (HC ≡ CH) = –2.04 × 105 J mol–1;
Df G° (C6H6) = –1.24 × 105 J mol–1; R = 8.314 J K–1 mol–1]
57. C6H6 freezes at 5.5°C. The temperature at which a
solution of 10 g of C4H10 in 200 g of C6H6 freeze is
°C. (The molal freezing point depression
constant of C6H6 is 5.12°C/m.)
58. Sucrose hydrolyses in acid solution into glucose and
fructose following first order rate law with a half-life
of 3.33 h at 25°C. After 9 h, the fraction of sucrose
1
remaining is f. The value of log10   is × 10–2.
f
(Rounded off to the nearest integer)
[Assume : ln 10 = 2.303, ln 2 = 0.693]
59. The formula of a gaseous hydrocarbon which requires
6 times of its own volume of O2 for complete oxidation
and produces 4 times its own volume of CO2 is CxHy.
The value of y is .
60. 1.86 g of aniline completely reacts to form acetanilide.
.
10% of the product is lost during purification. Amount
of acetanilide obtained after purification (in g) is
× 10–2.
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MATHEMATICS
SECTION - A (MULTIPLE CHOICE QUESTIONS)
61. If a curve y = f(x) passes through the point (1, 2) and
dy
satisfies x + y = bx 4 , then for what value of b,
dx
2
62
∫ f (x)dx = 5 ?
1 69. The vector equation of the plane passing through
62 31
(a) (b) (c) 5 (d) 10
5 5
62. For the system of linear equations :
x – 2y = 1, x – y + kz = –2, ky + 4z = 6, k ∈R,
consider the following statements :
(A) The system has unique solution if k ≠ 2, k ≠ –2.
(B) The system has unique solution if k = –2.
(C) The system has unique solution if k = 2.
(D) The system has no solution if k = 2.
(E) The system has infinite number of solutions if k ≠ –2.
Which of the following statements are correct?
(a) (B) and (E) only (b) (A) and (D) only
(c) (C) and (D) only (d) (A) and (E) only
1 63 
63. A possible value of tan  sin −1  is
4 8 
1 1
(a) (b) 2 2 − 1 (c) 7 − 1 (d) (a) (b) (c) (d)
2 2 7 28
64. Let f(x) be a differentiable function defined on [0, 2]
such that f ′(x) = f ′(2 – x) for all x ∈(0, 2), f(0) = 1 and
2 73. For which of the following curves, the line
f(2) = e2. Then the value of ∫ f (x) dx is
0
2
(a) 2(1 + e ) (b) 1 + e2
(c) 2(1 – e2) (d) 1 – e2
65. The angle of elevation of a jet plane from a point A on
the ground is 60°. After a flight of 20 seconds at the
speed of 432 km/hour, the angle of elevation changes to
30°. If the jet plane is flying at a constant height, then its
height is
(a) 3600 3 m (b)
2400 3 m
(c) 1200 3 m (d)
1800 3 m
66. Let f be a twice differentiable function defined on R
such that f(0) = 1, f ′(0) = 2 and f ′(x) ≠ 0 for all x ∈R. If
f ( x ) f ′( x )
= 0, for all x ∈R, then the value of f(1)
f ′(x ) f ′′(x )
lies in the interval
(a) (3, 6) (b) (0, 3) (c) (9, 12) (d) (6, 9)
67. Let A and B be 3 × 3 real matrices such that A is
symmetric matrix and B is skew-symmetric matrix.
Then the system of linear equations (A2B2 – B2A2)X = O,
where X is a 3 × 1 column matrix of unknown variables
and O is a 3 × 1 null matrix, has
(a) a unique solution
(b) exactly two solutions
(c) no solution
(d) infinitely many solutions
68. If P is a point on the parabola y = x2 + 4 which is closest
to the straight line y = 4x – 1, then the co-ordinates of P
are
(a) (3, 13) (b) (–2, 8) (c) (2, 8) (d) (1, 5)
 ^ ^ ^
the intersection of the planes r ⋅ ( i + j + k ) = 1 and
 ^ ^
r ⋅ ( i − 2 j) = − 2, and the point (1, 0, 2) is
 ^ ^ ^  ^ ^ ^
(a) r ⋅ ( i + 7 j + 3 k ) = 7 (b) r ⋅ (3 i + 7 j + 3 k ) = 7
 ^ 7  ^ ^ ^ 7
(c) r ⋅ ( i^ + 7 ^j + 3 k ) = (d) r ⋅ (i − 7 j + 3 k) =
3 3
70. If the curve y = ax2 + bx + c, x ∈R, passes through the
point (1, 2) and the tangent line to this curve at origin
is y = x, then the possible values of a, b, c are
(a) a = –1, b = 1, c = 1 (b) a = 1, b = 0, c = 1
1 1
(c) a = 1, b = 1, c = 0 (d) a = , b = , c = 1
2 2
71. The probability that two randomly selected subsets of
the set {1, 2, 3, 4, 5} have exactly two elements in their
intersection, is
65 35 135 65
2 7
29 27
72. The negation of the statement ~ p ∧ (p ∨ q) is
(a) ~ p ∨ q (b) p ∧ ~ q (c) p ∨ ~ q (d) ~p ∧ q
 
x + 3 y = 2 3 is the tangent at the point  3 3 , 1  ?
 2 2
(a) x2 + 9y2 = 9 (b) 2x2 – 18y2 = 9
1
(c) x2 + y2 = 7 (d) y 2 = x
6 3
74. The area of the region : R = {(x, y) : 5x2 ≤ y ≤ 2x2 + 9} is
(a) 9 3 square units (b) 6 3 square units
(c) 11 3 square units (d) 12 3 square units
75. For the statements p and q, consider the following
compound statements :
(A) (~q ∧ (p → q)) → ~ p
(B) ((p ∨ q) ∧ ~ p) → q
Then which of the following statements is correct?
(a) (A) and (B) both are tautologies.
(b) (A) is a tautology but not (B).
(c) (B) is a tautology but not (A).
(d) (A) and (B) both are not tautologies.
76. Let a, b, c be in arithmetic progression. Let the
centroid of the triangle with vertices (a, c), (2, b) and
(a, b) be  10 , 7  . If a, b are the roots of the equation
 3 3
ax2 + bx + 1 = 0, then the value of a2 + b2 – ab is
 7

71 71 69 69 83. The sum of first four terms of a geometric progression

(a) − (b) (c)
− (d) 65
256 256 256 256 (G.P.) is and the sum of their respective reciprocals
12
77. If n ≥ 2 is a positive integer, then the sum of the series
n+1 65
C2 + 2(2C2 + 3C2 + 4C2 + ..... + nC2) is is . If the product of first three terms of the G.P. is 1,
18
n(n − 1)(2n + 1) n(n + 1)2 (n + 2)
(a) (b) and the third term is a, then 2a is .
6 12
n(2n + 1)(3n + 1) 84. If the area of the triangle formed by the positive
n(n + 1)(2n + 1)
(c) (d) x-axis, the normal and the tangent to the circle
6 6
(x – 2)2 + (y – 3)2 = 25 at the point (5, 7) is A, then 24A
78. Let f : R → R be defined as
is equal to .
−55x , if x < − 5
 3 85. The students S1, S2, ......, S10 are to be divided into 3
f (x ) = 2 x − 3x 2 − 120 x , if − 5 ≤ x ≤ 4 . groups A, B and C such that each group has at least one
 3 2 student and the group C has at most 3 students. Then
2 x − 3x − 36 x − 336, if x > 4
the total number of possibilities of forming such groups
Let A = {x ∈R : f is increasing}. Then A is equal to is .
(a) (–5, ∞) (b) (–∞, –5) ∪ (–4, ∞)
86. The number of the real roots of the equation
(c) (–5, –4) ∪ (4, ∞) (d) (–∞, –5) ∪ (4, ∞)
27
79. Let a, b ∈ R. If the mirror image of the point P(a, 6, 9) (x + 1)2 + | x − 5 | = is .
4
x − 3 y − 2 z −1
with respect to the line = = is 1 β
7 5 −9 87. If a + a = 1, b + b = 2 and af (x ) + αf   = bx + , x ≠ 0,
x x
(20, b, –a –9), then |a + b| is equal to
(a) 88 (b) 86 (c) 90 (d) 84 1
f (x ) + f  
x
3 then the value of the expression is
80. The value of the integral, ∫ [x 2 − 2 x − 2]dx , where [x] . 1
x+
1 x
denotes the greatest integer less than or equal to x, is 88. Let a point P be such that its distance from the point
(a) –5 (b) –4 (5, 0) is thrice the distance of P from the point (–5, 0).
If the locus of the point P is a circle of radius r, then 4r2
− 2 − 3 −1
(c) − 2 − 3 + 1 (d) is equal to .
SECTION-B (NUMERICAL VALUE TYPE)  n   n C , if n ≥ r ≥ 0
89. For integers n and r, let   =  r
Attempt any 5 questions out of 10.  r   0, otherwise
(−1 + i 3 )21 (1 + i 3 )21 The maximum value of k for which the sum
81. Let i = −1. If + = k, k 10   15  k +1
12   13 
(1 − i)24 (1 + i)24 ∑  i   k − i  ∑  i   k + 1 − i 
+
and n = [|k|] be the greatest integral part of |k|. i=0 i=0
n+5 n+5
exists, is equal to .
Then ∑ ( j + 5)2 − ∑ ( j + 5) is equal to .
j=0 j=0 90. Let l be an integer. If the shortest distance between the
82. If the variance of 10 natural numbers 1, 1, 1, ...., 1, k is 7
lines x – l = 2y – 1 = –2z and x = y + 2l = z – l is ,
less than 10, then the maximum possible value of k is 2 2
. then the value of |l| is .

1. (c) : de Broglie wavelength of a particle is given by h

h λp =
λ= mpv p
mv
where, m = mass of the particle de Broglie wavelength of a-particle
v = speed of the particle h
h = Planck’s constant λα =
\ de Broglie wavelength of proton mα vα
8

λp m v where, x = displacement
h m v 
∴ = × α α =  α  α  A = amplitude
λα mpv p h  mp   v p  w = angular frequency
Q mα = 4m p
 x2  v2 x2
⇒ v 2 = ω2 A2 1 −  ⇒ + =1
λp v   A2  ω 2 A2 A2
∴ = 4 α 
λα  vp  This represents an ellipse.
Given, lp = la 6. (b) : PN junction diodes cannot be used a transistor
vp 4 by simply connecting two diodes back to back. Because the
⇒ = = 4 :1 base is very thin as compared to emitter and collector.
vα 1
The amplification factor is given by
2. (c) : Time period of oscillation of a simple pendulum is
I Collector current
given by β= c =
L Ib Base current
T = 2π Therefore, statement I is false and statement II is true.
g

7. (d) : Work done by the gas is given by
2 L 4 π2 L
2 ∆g ∆L 2∆T W = WAB + WBC + WCA
⇒ T = 4π × ⇒ g= ⇒ = +
g 2 g L T It is given that, AB is isothermal process
T
−3 V   2V 
∆L 1 × 10 ∆T 0.01 1 ∴ WAB = nRT ln  B  = 1 × R × T × ln  1 
Given, = a = =
L 1 T 1.95 195  VA   V1 
= RTln(2)
∆g  1 
∴ = 10−3 + 2 ×  = 11.25 × 10–3 Also, the process BC is isochoric
g  195 
\ WBC = 0
∆g The process CA is adiabatic
⇒ × 100% = 11.25 × 10−3 × 100%
g PV − P V P V − PAVA
∴ WCA = 1 1 2 2 = C C
= 1.125% = 1.13% γ −1 γ −1
3. (c) : Given, P1
× 2V1 − P1 × V1 − P V / 2 −nRT
R = 2.0 W, L = 2.0 mH = 2 × 10–3 H RT
= 4 = 1 1 = =
E=9V γ −1 γ −1 2( γ − 1) 2(1 − γ )

When the switch is closed at t = 0, the inductors will offer
RT
infinite resistance (behaves as open circuit). Therefore, the ∴ W = RT ln(2) + 0 +
circuit can be redrawn as follows : 2(1 − γ )

RT  1 
A = RT ln(2) − = RT  ln(2) −
2( γ − 1) 
R
+ R 2( γ − 1) 
i
E=9V – 8. (c) : Given two springs are connected in parallel.
R
R Therefore, equivalent spring constant is given by
keq = k1 + k2 = k + k = 2k
Current through the circuit is Time period oscillation of the body is
E E 9 9 9 M M
i= = = = = = 2.25 A T = 2π = 2π
Rtotal R+R 2R 2 × 2 4 keq 2k

4. (d) : Given, 1 1 2k
Voltage of X-ray tube V0 = 1.24 million volt = 1.24 × 106 V ∴ Frequency of oscillation, f = =
T 2π M
Shortest wavelength produced is
9. (c) : Energy for transition from n1 to n2 is
hc 1240 1240
λ min = = nm = nm = 10−3 nm 1 1 
eV V 6
0 0 1 . 24 × 10 ∆E = E2 − E1 = 13.6 − eV
 n2 n2 
 1 2
5. (a) : Velocity of particle executing SHM is given by
DE = hu ⇒ DE ∝ u
x2 Therefore, more is DE more will be frequency (u) of
v = ωA 1 −
A2 transition.
 9

It is clear that DE is maximum for The output is same, therefore this circuit is equivalent to the
n1 = 1 and n2 = 2 given circuit.
Thus frequency will be maximum for this transition. 13. (a) : According to the assumption of kinetic theory of
10. (d) : The fringe width in YDSE is given by gases, the gas molecules do not exert any force either on
each other or on the walls of the container. The pressure of
D
β =  λ the gas results from the force developed due to change in
d
momentum molecules, colliding elastically with the walls.
Where D = distance of screen from slits.
14. (c) : Soft ferromagnetic materials can easily magnetised
d = separation between the slits.
and demagnetised. These materials, when placed in an
Cleary b ∝ l
external magnetic field, experiences net torque which can
Also, lR > lV change the orientation. Also, when the domains are aligned
\ bR > bV along the magnetic field, the size will increase and when
they are aligned opposite to the field the size will decrease.
Therefore, if light source is changed from red to violet
15. (b) : We know that,
consecutive fringe lines will come closer.
Weight of a body, W = mg
11. (d) : The given disc can be assumed as a combination At pole, gp = g
of a complete disc of positive mass and a negative mass as At equator, ge = g – w2R < gp
shown below Here, R = radius of the earth
+M
–m w = angular velocity
+ We mg e g e
a/2 ∴ = = <1
Wp mg p g p
a
Let us assume that mass per unit area is ⇒ We < Wp = 49 N
M From the given option We = 48.83 N
σ=
π(a)2 16. (c) : Let magnitude of charge on electron and proton be
2 q. Now, consider the arrangement of charges shown in the
a σπa2 M
∴ m = σ × π  = = figure.
2 4 4 Fecosq Proton
+q
\ Centre of mass of the remaining portion q q Fecosq
M  3a 
MX1 − mX2 M × a − 4 ×  2 
Fe Fe
Xcm = = x
M −m M q q
M−
4 –q d d –q
 3a  Electron Electron
M a − 
 8  5a / 8 5a 2d
∴ Xcm = = =
 1  3/4 6 Let force exerted by each electron on proton is Fe.
M 1 − 
 4 Net force on the proton along a-direction
12. (c) : Given logic circuit with outputs is Fx = Fecosq – Fecosq = 0
Net force on the proton along Y-direction
A A A+B A+B
C Fy = Fesinq + Fesinq
B B
NOT x
NOT OR gate = 2Fe sinθ = 2Fe
x2 + d2
Therefore, from above circuit, net output
C = A + B = A ⋅ B (De Morgan’s theorem) Kq2 Kq2
Also, Fe = =
⇒ C = A⋅B ( x2 + d2 ) x2 + d2

Now consider output of the circuit given in option (c). Since, x < < d
NOT A \ x2 + d2 ≈ d2
A
B C = A ⋅B Kq2 x 2Kq2
B ∴ Fe = and Fy ≈ 2Fe = x
AND d2 d d3
10

2 1 q2 1
⇒ Fy = × q2 x = x 3mv02  3mv 2  3
d 3 4 πε0 2πε0 d 3 ⇒ x03 = ⇒ x0 =  0
2α  2α 
As Fy and x are in opposite directions
The closest option is (d).
q2 21. (2) : Given that
∴ Fy = (− x ) ⇒ Fy ∝ (–x)
2πε0 d 3 Momentum of A = Momentum of B
Here, proportionality constant ⇒ PA = PB
q2 ⇒ 2mA K A = 2mB K B
 p2 
K= Q K = 2m 
2πε0 d 3
⇒ 2mAKA = 2mBKB
q2 (K .E )A mB 2 A
∴ Net force F = Fy = (− x ) ⇒ = = =
2πε0 d 3 ( K . E ) B mA 1 1
⇒ F = –Kx ⇒ A = 2
q2 22. (900) : At resonance, Z = R
where constant K =
2πε0 d 3 V2 V2
Power = P = =
Also, F ∝ (–x) Z R
Therefore, the motion will be SHM. 120 × 120
⇒ 16 =
Angular frequency of SHM will be R
K q 2 12 × 12 × 100
ω= = ⇒ R= = 900 W
m 2 πε0 md 3 16

23. (8) : Given,
17. (b) : We know that, a travelling wave can be represented Input power = Pi = 0.1 kW
as Y = F(x, t) Q Attenuation per km = –5 dB
Here the function F, should be such that Y is a linear \ Attenuation in 10 km = –20 × 5 = –100 dB
function of x and t. According to the question
From the given options the linear function of x and t is P 
Y = Asin(15x – 2t) −100 = 10 log10  o 
 Pi 
Other equations are not linear function of x and t.
18. (c) : Magnetron is the source of microwave frequency. P  Po
⇒ − 10 = log10  o  ⇒ = 10−10
Vibration of atoms and molecules produces infrared waves.  Pi  Pi
Due to transition of inner shell electrons X-ray (Ka and Kb)
are produced. ⇒ Po = Pi × 10–10 = 0.1 × 1000 × 10–10
Radioactive decay of a nucleus produces a, b and g rays. = 100 × 10–10 = 10–8 W
According to the question
19. (a) : In zener diode the P-type and N-type materials
Po = 10–x = 10–8
are heavily doped. When a high electric field is applied
across the junction, the zener breakdown occurs. Also the ⇒ x = 8
depletion layer will be narrow. 24. (2) : Consider the metallic wire on which a force F is
20. (d) : For acting on the particle is applied
F = –ax2 Now, we can write
Let the particle stops at a distance x0. Stress F /A F l
Y= = = ×
Work done by the force, during the movement of the particle Strain ∆l /l A ∆l
from x = 0 to x = x0 is Now,
x0 x0 x F1 l F l
2
 x3 
0
αx03 × 1 = 2 × 2 b
W = ∫ Fdx = ∫ −αx dx =  −α  = − A1 ∆l1 A2 ∆l2
 3 0 3
0 0
From Work-Energy theorem ∆l2  A1  F2 l2
⇒ = × ×
DW = DK ⇒ W = Kf – Ki ∆l1  A2  F1 l1

−αx03 1 2αx03  r 2   F   2l   r  2 1 1
⇒ = 0 − mv02 ⇒ v02 = =  1  ×   ×  1  =  1  ×1× 2 = × 2 =
3 2 3m 2
 r2   F   l   2r  4 2
1 1
 11

∆l1 0.04 28. (667) : Given, frequency of the EM wave

⇒ ∆l2 = = = 0.02 m = 2 cm D = 3 GHZ = 3 × 109 Hz
2 2
25. (400) : The rms of a gas is Relative permittivity, er = 2.25
3RT Now, refractive index of the medium
vrms = ⇒ vrms ∝ T
M n = µr εr = 1 × 2.25 = 1.5
(vrms )2 T 273 + 127 400 2 Here relative permeability, mr = 1
⇒ = 2 = = =
(vrms )1 T1 273 + 27 300 3 \ Wavelength of the wave in the medium,
According to the question λ c/υ
λm = vacuum =
(vrms )2 2 n 1. 5
=
(vrms )1 3 (3 × 108 /3 × 109 ) 0. 1 1
= = = m ≈ 667 × 10−2 cm
2 400 x 1. 5 1.5 15
⇒ (vrms )2 = × 200 = = (Given)
3 3 3 29. (8) : Consider the situation shown below
⇒ x = 400 v1 v2
26. (8) : Let length of each side be a. 1 2
According to the question vs
6a = 2.4 ⇒ a = 0.4 m
A
Consider the triangle OAB. a
x 7.2 × 1000
x O Speed of each car = = 2 m/s
sin60° = 60° 60 × 60
a B a
3 Apparent frequency heared by the driver in car-1
⇒ x = asin60° =
2  v + v1 
Moment of inertia of the hexagon about an axis passing f1 =  s  f2
 v s − v2 
through the centre is
 340 + 2  342
I0 = 6(ID + mx2)(m = 1 kg) = × 676 = × 676 = 684 Hz

 2  340 − 2  338
 3  
2
ma  1 3
= 6 + m  a   = 6ma2  +  The driver in car-1 will receive two frequencies one is f1 and
 12  2   12 4  other the original frequency of horn of car-1, f0 = 676 Hz
 1 3 1 + 9 
= 6m × (0.4)2  +  = 6 × 1 × (0.4)2   \ Beat frequency = Df = f1 – f0 = 684 – 676 = 8 Hz
12 4   12  Same beat frequency will be heared by the driver of car-2.
10
= 16 × 10−2 × 6 × 30. (5) : Current density is given by
12 I
= 80 × 10 = 8 × 10–1 kg m2
–2 J = = σE
A
27. (226) : To find the electric flux +q Here, E = Electric field = 10 × 10–3 V/m
through the square, let us assume a s = Conductivity = 5 × 107 S/m
⇒ I = A(sE)
symmetric situation, in which the charge a/2 a
= pr2 (5 × 107 × 10 × 10–3)
+q is placed at the centre of a cube made = p(0.5 ×10–3)2 (50 × 104)
by such surfaces. a = p × 25 ×10–8 × 5 × 105
From Gauss’s law flux through the cube = p × 125 × 10–3 A
q ⇒ I = 125p mA = x3 pm A
φc = ⇒ x = (125)1/3 = 5
ε0
NO2 NO2 NH2
Let flux through each surface be f.
q 31. (b) : Br2/Fe Sn/HCl
∴ 6φ = a D
ε0 q Br Br
−6
1 q  1 12 × 10 Br
+
⇒ φ=   = × N2Cl
6  ε0  6 8.85 × 10−12 a
CuBr/HBr NaNO2/HCl
3 2
= 225.988 × 10 Nm /C
Br Br
= 226 × 103 Nm2/C m-dibromobenzene
12

32. (d) : Clean water would have BOD value less than 36. (d) : Valium is used to treat anxiety hence it is a
5 ppm whereas highly polluted water could have a BOD tranquilizer. (A-iv)
Morphine is an example of narcotic analgesics. (B-iii)
value of 17 ppm or more.
Norethindrone is used to prevent pregnancy i.e., antifertility
HgSO4/H2SO4
33. (b) : CH3 C C CH3 drug. (C-i)
Vitamin B12 is used to cure pernicious anaemia. (D-ii)
Tautomerises
CH3 C CH CH3 CH3 C CH2 CH3 O O
37. (c) : R C Cl H2/Pd-BaSO4 R C H (A-ii)
OH O
HgSO4/H2SO4 (Rosenmund reduction)
CH3 C CH CH3 C CH2 Cl2/Red P, H2O
R CH2 COOH R CH COOH (B-iv)
OH
Tautomerism Cl
CH3 C CH3 (Hell-Volhard-Zelinsky reaction)
O
 O Br2/NaOH
R C NH2 R NH2 (C-i)
HgSO4/H2SO4
C CH C CH2 (Hoffmann bromamide
degradation reaction)
OH O
Zn(Hg)/Conc. HCl
Tautomerism R C CH3 RCH2CH3 (D-iii)
C CH3 (Clemmensen reduction)
 O –
38. (a) : I3 ion is linear in shape with sp3d hybridisation
HgSO4/H2SO4
HC CH CH2 CH OH and 180° bond angle.
Tautomerism I
CH3 C H
 I
Hence, CH3CH2CHO can not be prepared. O
34. (a) : [FeCl4]2– represent Fe2+. Z2 I
39. (a) : K.E. ∝ (here A is correct)
Cl– is a weak field ligand. n2
2+
\ Fe : [Ar]3d : 6 KZ
v= ⇒ nv ∝ Z (here B is incorrect)
Hence, 4 unpaired electrons. n
v
µ = n(n + 2) = 4(6) = 4.90 Frequency of revolution = n
2πrn
Z
[Co(C2O4)3]3– represents Co3+ vn ∝
n
C2O42– is a strong field ligand.
n2
rn ∝
\ Co3+ : [Ar] 3d 6 : Z
Number of unpaired electrons = 0 ⇒ m = 0 Z Z2
Frequency ∝ ∝ (here C is incorrect)
MnO42– represents Mn6+. n(n2 /Z ) n3
Mn6+ : [Ar]3d1 :
Z Z3
Number of unpaired electrons = 1 Force ∝ ∝ (here D is correct)
rn2 n4
⇒ µ = 1(1 + 2) = 3 = 1.73
40. (b) : Kaolinite is Al2O3(SiO2)2⋅2H2O (A-iii)
35. (a) : Benzene diazonium salt, when coupled with Siderite is FeCO3 (B-i)
b-naphthol gives an azodye of red colour. Malachite is CuCO3⋅Cu(OH)2 (C-iv)
+ Calamine is ZnCO3 (D-ii)
N2Cl OH
NH2 41. (a) : According to Hardy Schulze’s rule, the cation
NaNO2/HCl
with high charge has high coagulation power. FeCl3 is an
NaOH
electrolyte which gives Fe3+ and blood contain negatively
colloid. So, FeCl3 coagulates blood.
42. (c) : Electron withdrawing groups such as —NO2,
N N —CN etc. at ortho and para positions increase the reactivity
OH of haloarene towards nucleophilic substitution reactions.
 red coloured dye Hence, the correct order is
 13

Cl Cl Cl Cl 52. (141) : Ksp = 8.0 × 10–9

NO2 NO2 NO2 s = x × 10–6 mol/L
> > > PbI2 Pb2+ + 2I–
(s + 0.1) (2s)
NO2 NO2 NO2 (s + 0.1)(2s)2 = 8.0 × 10–9
(iv) (iii) (ii) (i) as 0.1 > > > s Hence, s + 0.1 = 0.1
43. (c) : Compound M.P. (0.1) 4s2 = 8 × 10–9
LiCl 605°C 8 × 10−9
s2 = = 2 × 10−8
LiF 848.2°C 0. 4
MgO 2852°C s = (2 × 10–8)1/2
NaCl 801°C = 1.41 × 10–4 mol/L or 141 × 10–6 mol/L
Hence, correct order is LiF > LiCl ; MgO > NaCl
53. (3776) : Balanced equation is
44. (b) : Cycloheptatriene is non-aromatic as it is a non- MnO4– + 8H+ + 5e– Mn2+ + 4H2O
conjugated system.
Hence, according to Nernst equation,
45. (a) : Hydrogen is the most abundant element in the
0.0591 [Mn2+ ]
universe since it is the lightest element. Nitrogen is the most E = E° − log
abundant gas in troposphere. 5 [MnO−4 ][H + ]8
46. (b) : The decrease in metallic radius coupled with Case-I, When [H+] = 1 M
increase in atomic mass results in a general increase in the 0.0591 [Mn2+ ]
E1 = E ° − log = E° − 0 = E°
density of transition elements from titanium to copper. 5 [MnO−4 ]
Hence, the correct order is
Zn < Cr < Fe < Co < Cu Case-II, When H+ = 10–4 M
7.1 7.19 7.8 8.7 8.9 (Density in g/cm3) 0.0591 [Mn2+ ] 0.0591
E2 = E ° − log = E° − × 32
5 − −4 8 5
47. (b) : Li Na K Rb Cs [MnO4 ][10 ]
Colour Crimson Red Yellow Violet Red violet Blue Change in electrode potential
l/nm 670.8 589.2 766.5 780.0 455.5
0.0591 × 32
48. (d) : This is an example of Wolff-Kishner reduction. E2 − E1 = − = 0.3776
5
Hence x is 3776.
NH2 — NH2 54. (3) : Gabriel pthalamide synthesis is used to prepare
C2H5ONa+ 1° aliphatic amines.
O Hence,
This reduction does not affect double-bond, only reduces CH3
CH2NH2 , CH CH2NH2 and CH3CH2NH2
C O to CH2 group.
CH3
49. (a) : Ruby is the mineral also called as red corundum can be prepared but aniline cannot be prepared by this
which has the traces of chromium element which causes the method because arylhalides do not undergo nucleophilic
red colour in the ruby. substitution with the phthalimide formed anion.
50. (c) : Buna-S is a polymer of styrene-butadiene. 55. (1) : Sulphur exists in S2 form in vapour phase which
Hence, S stand for styrene. has two unpaired electrons while a-sulphur and b-sulphur
51. (5) : T = 50 + 273 = 323 K are diamagnetic.
740 56. (855) : 3CH ≡ CH(g) C6H6(l)
P = 740 mm Hg = atm
760 DG° = (DG°)P – (DG°)R
R = 0.0826 L atm K–1 mol–1 = (–1.24 × 105)J/mol – (3 × –2.04 × 105) J/mol
4.75 = –1.24 × 105 + 6.12 × 105 J/mol
n=  (Molar mass of acetylene (C2H2) = 26 g/mol)
26 = 4.88 × 105 J/mol
= 0.1826 DG° = –RT lnK or –2.303RT log K
nRT 4.88 × 105 = –2.303 × 8.314 × 298 log K
PV = nRT ⇒ V =
P
4.88 × 105
0.1826 mol × 0.0826 L atm K −1
mol −1
× 323 K log K = −
V= =5L 2.303 × 8.314 × 298
(740 / 760) atm |log K| = 85.5 or 855 × 10–1
14

57. (1) : Tf (C6H6) = 5.5°C 1

C4H10 = 10 g C6H6 = 200 g Here, I.F. = e
∫ x dx = e log x = x
Kf = 5.12°C/m \ Solution is given by
DTf = iKf m i = 1 for C4H10
bx 5 bx 4 C
Moles of solute y ⋅ x = ∫ bx 4 dx = +C ⇒ y = +
m= × 1000 5 5 x
Mass of solvent (g ) Since y = f(x) passes through (1, 2), therefore
10/58 b
m= × 1000 = 0.86 2= +C ...(i)
200 5
DTf = 1 × 5.12 × 0.86 = 4.403 2 2 4
bx C 62
DTf = Tf° – T ′f
T ′f = Tf° – DTf = 5.5 – 4.40 = 1.1 ≈ 1°C
Now, ∫ f (x ) dx = ∫ 
 5
+  dx =
x 5
1 1
0.693 2
58. (81) : For first order reaction, t1/2 =  bx 5  62
k ⇒  + C log x  =
0.693 0.693 −1  25 1 5
So, k = = h (As t1/2 = 3.33 h)
t1/2 3.33 32b b 62
⇒ + C log 2 − = ...(ii)
2.303 a 25 25 5
k= log
t a−x Solving (i) and (ii), we get C = 0, b = 10
Given, a – x = f a=1 1 −2 0
2.303 1  1  0.693 9 62. (b) : D = 1 −1 k
k= log   ⇒ log   = ×
t f  f  3.33 2.303 0 k 4
1 = 1(–4 – k2) + 2(4) = 4 – k2
log   = 0.8132 = 81 × 10−2
f If D ≠ 0 i.e., 4 – k2 ≠ 0 ⇒ k2 ≠ 4
59. (8) : Combustion reaction is given as, ⇒ k ≠ 2, k ≠ –2, then the system has unique solution.
 y y At k = 2,
C x Hy ( g ) +  x +  O2( g ) 
→ xCO2( g ) + H2O(l ) 1 −2 0
 4  2
D1 = −2 −1 2 = − 48 ≠ 0
According to question,
Volume of CxHy = V 6 2 4
 y \ The system has no solution if k = 2.
Volume of O2 = 6 V =  x +  ...(i)
 4 63 63
Volume of CO2 = 4 V = x...(ii) 63. (d) : Let sin −1 = x ⇒ sin x =
8 8
y
From (i) and (ii) we can say that = 2 V 1 8
4 ∴ cos x = and tan x = 63 63
y=8V 8 x
Ratio of x : y = 4 : 8 x 1 9 1
Hence, formula of CxHy is C4H8 Now, 2 cos2 = 1 + cos x = 1 + =
2 8 8
C4H8(g) + 6O2 4CO2 + 4H2O x 3
⇒ cos =
2 4
60. (243) : NH2 NH C CH3 x x 3 7
Also, 2 cos2 = 1 + cos = 1 + =
2

O 4 2 4 4 1
2

1.86 x/4
Moles of aniline = = 0.02
93 x 7 7
⇒ cos =
Mass of acetalinilde = 0.02 moles = 0.02 × 135 g = 2.7 g 4 2 2
10% lost during purification i.e., efficiency of reaction = 90% 1 63  x 1
90 Now, tan  sin −1  = tan   =
Hence, obtained amount of product = 2.7 × = 2.43 4 8 4 7
100 64. (b) : Given, f ′(x) = f ′(2 – x)
= 243 × 10–2 g Integrating both sides, we get
dy y f(x) = –f(2 – x) + C
61. (d) : The given differential equation is + = bx 3 .
dx x At x = 0, f(0) + f(2) = C
 15

⇒ C = 1 + e2 \ P is skew-symmetric matrix
\ f(x) + f(2 – x) = 1 + e2 \ |P| = 0 [Q Determinant of skew symmetic
2 2  matrix of odd order is zero]
Now , let I = ∫ f (x ) dx ⇒ I = ∫ f (2 − x )dx Hence, PX = O have infinite solutions.
0 0
2 68. (c) : Let P(x1, y1) be the required point.
∴ 2 I = ∫ [ f (x ) + f (2 − x )] dx \ y1 = x12 + 4 ...(i)
y y = x2 + 4
0 Given, equation of line is y = 4x – 1
2
⇒ y – 4x + 1 = 0
⇒ 2 I = (1 + e 2 )∫ dx ⇒ 2 I = (1 + e 2 )(2 − 0) P
\ Shortest distance from P

–1
0
⇒ I = 1 + e2 y1 − 4 x1 + 1

y = 4x
C D
=
17 x
O
x12 + 4 − 4 x1 + 1
65. (c) : h h = [Using (i)]
17
60° 30°
A B E (x1 − 2)2 + 1
= , which will be minimum when x1 = 2.
1000 17
Speed of jet plane = 432 × m/ sec = 120 m/ sec
60 × 60 So, y1 = 22 + 4 = 8
Distance CD = Speed × Time = 120 × 20 = 2400 m Hence, required point is (2, 8).
h h 69. (a) : Equation of plane passing through the intersection
In DACB, tan60° = ⇒ AB =
AB 3  ^ ^ ^  ^ ^
of planes is [r ⋅ ( i + j + k ) − 1] + λ[r ⋅ ( i − 2 j) + 2] = 0
h h  ^ ^ ^
In DADE, tan30° = ⇒ AE = 3h ⇒ + BE = 3h ⇒ r ⋅[ i (1 + λ) + j(1 − 2 λ) + k] − 1 + 2 λ = 0
AE 3
h It passes through the point ^i + 0 ^j + 2 k^ .
⇒ 3h − = 2400 [Q BE = CD]
3 ^ ^ ^ ^ ^
∴ ( i + 2 k ) ⋅[ i (1 + λ) + j(1 − 2 λ) + k] − 1 + 2 λ = 0
⇒ 2h = 2400 3 ⇒ h = 1200 3 m 2
⇒ 1 + l + 2 – 1 + 2l = 0 ⇒ 3λ + 2 = 0 ⇒ λ = −
3
f (x ) f ′( x )  ^  2  ^ 4  ^ 4
66. (d) : We have, =0 ∴ r ⋅  i 1 −  + j 1 +  + k  = 1 +
f ′( x ) f ′′(x )   3  3  3
 ^ ^ ^
⇒ f(x) f ′′(x) – (f ′(x))2 = 0 ⇒ r ⋅ [ i + 7 j + 3 k] = 7
d  f ′( x )  70. (c) : Since curve y = ax2 + bx + c is passing through
⇒ = 0  [Q f ′(x) ≠ 0 ∀ x ∈ R ⇒ f (x) ≠ 0 ∀ ∈ R]
dx  f (x )  (1, 2).
f ′( x ) \ 2 = a + b + c ...(i)
⇒ =c dy
f (x ) Also, = 2ax + b
dx
At x = 0, f ′(0) = cf(0) ⇒ 2 = c
f ′( x )  dy 
∴ =2 Since,   = 1 (given)
f (x )  dx (0, 0)
f ′( x ) ∴ [2ax + b](0, 0) = 1
Integrating both sides, we get ∫ dx = ∫ 2 dx
f (x ) \ b = 1
⇒ log |f(x)| = 2x + c1
Also, curve passes through origin. \ c = 0
At x = 0, log |f(0)| = 2(0) + c1 ⇒ c1 = 0
Hence, a = 1 [From (i)]
\ log| f(x)| = 2x ⇒ f(x) = e2x
71. (c) : Let A and B be any two subsets of given set.
\ f(1) = e2 ∈(6, 9)
Total number of possible outcomes = 4 × 4 × 4 × 4 × 4 = 45
67. (d) : We have, AT = A and BT = –B
[Q Each element of given set has only four options only A,
Let A2B2 – B2A2 = P, then
only B, Both A and B, None of A and B]
PT = (A2B2 – B2A2)T = (A2B2)T – (B2A2)T
= (B2)T(A2)T – (A2)T(B2)T = (BT)2(AT)2 – (AT)2(BT)2 Number of favourable outcomes = 5C2 × 33

= B2A2 – A2B2 [Q Each of rest three numbers has only three options only
\ PT = –P A, only B, None of A and B]
16

5
C2 × 33 10 × 27 135 11 1
\ Required probability = = = ∴ α+β=− and αβ =
16 4
45 210 29
72. (c) : ~ (~ p ∧ (p ∨ q)) Now, a2 + b2 – ab = (a + b)2 – 3ab
≡ ~ ((~ p ∧ p) ∨ (~ p ∧ q)) 2
 −11   1  121 3 71
≡ ~ (~ p ∧ q) = − 3  = − =−
 16   4  256 4 256
≡p∨~q
  77. (c) : Clearly, n+1C2 + 2(2C2 + 3C2 + 4C2 + ...... + nC2)
73. (a) : Tangent to x2 + 9y2 = 9 at point  3 3 , 1  is
 2 2 = n+1C2 + 2(3C3 + 3C2 + 4C2 + ...... + nC2)
3 3  1
x + 9y   = 9
 2  2 = n+1C2 + 2(4C3 + 4C2 + 5C2 + ...... + nC2)

i.e., x + 3 y = 2 3 (Q nCr+1 + nCr = n+1Cr+1)

3 = n+1 5 5
C2 + 2( C3 + C2 + ...... + C2) n
74. (d) : Required area = 2 ∫ (2 x 2 + 9 − 5x 2 )dx n+1
= C2 + 2(n+1C3) = n+1C2 + n+1C3 + n+1C3
0
y 2
3 y=
5x 9 = n+2C3 + n+1C3
= 2 9 x − x 3  x +
2

0 y =2 (n + 2)! (n + 1)!
= +
3! (n − 1)! 3! (n − 2)!
= 2 9 3 − 3 3 
x (n + 2)(n + 1)(n) (n + 1)(n)(n − 1)
–3 0 3 = +
6 6
= 12 3 sq. units
n(n + 1)
75. (a) : (A) = [2n + 1]
6
p q ~q p → q ~p ~q ∧ (p → q) (~q ∧ (p → q))  −55 ; if x < − 5
→ ~p  2
78. (c) : f ′(x ) = 6(x − x − 20) ; if − 5 < x < 4
T T F T F F T
 2
T F T F F F T  6(x − x − 6) ; if x > 4
F T F T T F T  −55 ; if x < − 5

F F T T T T T = 6(x − 5)(x + 4) ; if − 5 < x < 4
6(x − 3)(x + 2) ; if x > 4
(B) 
Sign of f ′(x)
p q p∨q ~p (p ∨ q) ∧ ~ p ((p ∨ q) ∧ ~ p) → q
–ve +ve –ve +ve +ve
T T T F F T –∞ –5 –4 4 5 ∞
T F T F F T \ f(x) is increasing in x ∈ (–5, –4) ∪ (4, ∞)
F T T T T T
79. (a) : Here, P ≡ (a, 6, 9) and Q ≡ (20, b, – a – 9)
F F F T F T  a + 20 6 + b 9 − a − 9 
\ Mid point of PQ is  , , 
Both (A) and (B) are tautologies.  2 2 2
a+a+2 10 x − 3 y − 2 z −1
76. (a) : Given, = ⇒ 2a + 2 = 10 ⇒ a = 4 It must lie on the line = = .
3 3 7 5 −9
c +b+b 7 a + 20 6+b −a
and = ⇒ c + 2b = 7 ⇒ 2b = 7 − c −3 −2 −1
3 3 i.e., 2 = 2 = 2
7 5 −9
Also, we have 2b = a + c ⇒ 2b = 4 + c
3 a + 14 b+2 a+2
∴ 7−c = 4+c ⇒ c = i.e., = =
2 14 10 18
3 \ a = –56 and b = –32
7−
⇒ b= 2 = 11 Hence, |a + b| = 88.
2 4
11 3
\ Given quadratic equation is 4 x 2 + x +1= 0
80. (d) : We have, [ x 2 − 2 x − 2]dx
4 ∫
Since a, b are roots of above equation. 1
 17

3  1 − r4 
1 
= ∫ ([(x − 1)2 ] − 3) dx − 1  4 
1  r 4  65 1  = 65
1 Also, = ⇒  r
2 3 Using x − 1 = t ⇒ dx = dt  a 1 18 a  1− r  18
 Also, at x = 1, t = 0  −1  
2 r
= ∫ [t ]dt − 3∫ dx  
r
0 1 at x = 3, t = 2 
1  1 − r  65
4

⇒  = ...(ii)
1 2 3 2 ar 3  1 − r  18
= ∫ 0dt + ∫ 1dt + ∫ 2dt + ∫ 3dt − 6 2 3 3
0 1 2 3
Dividing (i) by (ii), we get a r = ...(iii)
2
Also, we have a3r3 = 1, i.e., ar = 1
= ( 2 − 1) + 2 3 − 2 2 + 6 − 3 3 − 6
Now, from (iii), we get
= −1 − 2 − 3 3 3
(a2r 2 )r = ⇒ r=
81. (310) : We know that 2 2
−1 + 3i −1 − 3i 3 2
ω= and ω2 = , ω3 = 1 ∴ a  =1 ⇒ a =
2 2 2 3

2
2 3 3
Also (1 + i)2 = 1 + i2 + 2i = 2i and (1 – i)2 = 1 + i2 – 2i = –2i Now, third term, ar 2 =   = = α (Given)

3 2  2
(−1 + i 3 )21 (1 + i 3 )21 ⇒ 2a = 3.
∴ k= +
(1 − i)24 (1 + i)24 84. (1225) : Equation of normal at P is
7−3
(2ω)21 (−2ω2 )21 221 ω21 221 ω 42 y −7= (x − 5) y
= + = − =0 5−2
(−2i)12 (2i)12 212 i12 212 i12

⇒ 3y – 21 = 4x – 20 , 7)
[Q w21 = (w3)7 = 1 and w42 = (w3)14 = 1] P (5
⇒ 4x – 3y + 1 = 0 ...(i)
\ n = [|k|] = 0 3)
 1  (2, x
n+5 n+5 5 ∴ C ≡ − , 0 O B
 4  C
Now, ∑ ( j + 5) 2
− ∑ ( j + 5) = ∑ ( j 2
+ 25 + 10 j − j − 5)
Equation of tangent at P is
j=0 j=0 j=0
3
5 5 5 5 y − 7 = − (x − 5)
= ∑ ( j2 + 9 j + 20) = ∑ j2 + 9 ∑ j + 20 ∑1 4
j=0 j=0 j=0 j=0 ⇒ 4y – 28 = – 3x + 15
⇒ 3x + 4y = 43 ...(ii)
5 × 6 × 11 5 × 6
= + 9 + 20 × 6
6  2   43 
∴ B ≡  , 0
3 
= 55 + 135 + 120 = 310
2 2
2  43 1 175
82. (11) : Given, σ 2 = Σx −  Σx  < 10 So, BC =  +
3  =
n  n  4 12
2 1
9 + k2 9 + k  Hence, area of DPBC = × BC × 7
⇒ − < 10 2
10  10 
1 175 1225
⇒ 90 + 10k2 – 81 – k2 – 18k < 1000 = × ×7= = A (Given)
2 12 24
⇒ 9k2 – 18k + 9 < 1000 ⇒ 9(k – 1)2 < 1000
\ 24 A = 1225
1000 10 10
⇒ (k − 1)2 < ⇒ k< + 1 ≈ 11.54 85. (31650) :
9 3
A B C
\ Maximum integral value of k is 11.
1 8 1
83. (3) : Let the terms are a, ar, ar2, ar3. 2 7 1
 r 4 − 1  65 . . .
. . .
∴ a  = ...(i) . . .
 r − 1  12 6 1 3
18

Number of ways to form groups

(25)2 − 400 225
= (10C1)(9C1 + 9C2 + .... + 9C8) + 10C2(8C1 + 8C2 + .... + 8C7) ⇒ 4r 2 = = = 56.25
4 4
+ 10C3(7C1 + 7C2 + .... + 7C6) k k +1
10   15  12   13 
9 8
= 10(2 – 2) + 45(2 – 2) + 120(2 – 2) 7 89. (24) : ∑  i   k − i  ∑  i   k + 1 − i 
+
i=0 i=0
= 10 × 510 + 45 × 254 + 120 × 126
= 5100 + 11430 + 15120 = 31650 10  15  10   15  10  15 
=    +    + ..... +    
86. (2) : Case-I : When x ≤ 5 0 k
     1 k − 1   k  0 
27
In this case, we have (x + 1)2 − (x − 5) = 12   13  12  13   12  13 
4 +   +     + .... + 
0
  k + 1  1
    k  k + 1  0 
3
⇒ (x + 1)2 − (x + 1) − =0 
4 = Coeff. of xk in (1 + x)10 (1 + x)15
3 1 1 −3 + Coeff. of xk+1 in (1 + x)12 (1 + x)13
⇒ x +1= , − ⇒ x= , which are real
2 2 2 2 = Coeff. of x in (1 + x)25 + Coeff. of xk+1 in (1 + x)25
k

Case-II : When x ≥ 5 = 25Ck + 25Ck+1

27 Now, for sum to be exists 0 ≤ k ≤ 25 and 0 ≤ k + 1 ≤ 25.
In this case, we have, (x + 1)2 + (x − 5) =
4 ⇒ 0 ≤ k ≤ 24
2 51
⇒ (x + 1) + (x + 1) − = 0 Thus, maximum value of k is 24.
4
1
−1 ± 52 x−λ y−
⇒ x +1= , which are not possible as x ≥ 5 90. (1) : The given lines are = 2 = z − 0 and
2 1 1 1
−
\ The equation has 2 real roots. x −0 y + 2λ z−λ 2 2
87. (2) : We have, a + a = 1 and b + b = 2 = =
1 1 1
1 β
Also, we have af (x ) + α f   = bx + ...(i) The shortest distance between the lines is given by
x x
1
1 0 − λ −2 λ − λ−0
Interchanging x by , we get 2
x 1 1
1 −
1 1 2 2
af   + αf (x ) = b   + βx ...(ii)
x x 1 1 1 7
=
Adding (i) and (ii), we get 2 2 2 2 2
1 1  1   1
  1   1   1  1  +  +  − − 1 + 1 − 
a  f (x ) + f    + α  f   + f (x )  = b  x +  + β  x +  2 2 2 2
 x   x  x x
2
1 1 1  1 1  1
f (x ) + f   b + β − λ  +  +  2 λ +  1 +  + λ 1 − 
x 2 2 2  2   2   2 7
⇒ = = =2 ⇒ =
1 a+α 1 14 2 2
x+
x 2
88. (56.25) : Let the coordinates of point P be (h, k). Then, 3 λ 7 5λ 3 7 5λ 3 7
2 2 2 2
⇒ − λ + 3λ + + = ⇒ + = ⇒ + =±
(h − 5) + k = 3 (h + 5) + k 4 2 4 2 4 4 2 4 4

⇒ h2 + k2 + 25 – 10h = 9(h2 + k2 + 25 + 10h) 5λ 7 3 5λ 7 3

⇒ Either = − or =− −
2 2 25 2 4 4 2 4 4
⇒ 8h2 + 8k2 + 100h + 200 = 0 ⇒ h + k + h + 25 = 0
2 5λ 5λ −10
⇒ = 1 or =
25 2 2 4
Thus, the locus is x 2 + y 2 + x + 25 = 0, which is a circle
2 2
2 ⇒ λ= or λ = − 1 ⇒ λ = − 1 [Q λ is an integer]
 −25  5
whose centre is  − 25 , 0  and radius, r =  + (0)2 − 25
 4   4  \ |l| = 1