SUSTAINABLE

CLEANTECH
SOLUTIONS

ECOSOLUT 24 ®

Technical Guideline

APPLICATION USAGE AREAS

Cleaning of Noxious Liquid Substances (NLS) Cargo Tanks

CHARACTERISTICS

ECOSOLUT 24 is a specialized detergent formulation, particularly effective for the cleaning of

• Vegetable Oil residues (all grades)

• Clean Petroleum Products (CPP)

• Ultra Low Sulphur Diesel (ULSD)

• Gasoline

• Benzene, Toluene, Ethylbenzene, Xylenes (BTEX)

• Hydrocracker Bottoms (HCB)

• Linear Alpha Olefines (LAO)

• Fatty Acids Methyl Ester (from soya-bean oil) (FAME)

• Pitch Tall Oil (PTO)

from cargo tanks by using fixed and portable tank cleaning machines and for manual cleaning through high pressure portable
barrel pumps with spray gun attachments. It can also be used for general cleaning of machinery, tools, bilge spaces, galley etc.

ECOSOLUT 24 is a proven product for the cleaning of all aforementioned products and similar materials.

ECOSOLUT 24 is used at very low dilutions from 1:200 (or 0.5%) to 1:100 (or 0.1%), and is effective from ambient temperature
to 60ºC or in steam cleaning systems, with increased efficacy at higher temperatures.

ECOSOLUT 24 is equally effective in seawater and freshwater.

In its concentrated form, the pH of ECOSOLUT 24 is approximately 7, and is safe to use on all types of coatings and stainless
steel.
ECOSOLUT 24 does not contain aggressive cleaning additives (caustic, acids etc.) and is safe to transport by land, sea and air.
ECOSOLUT 24 does not contain solvents.

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 SUSTAINABLE
CLEANTECH
SOLUTIONS

ECOSOLUT 24 ®

TYPICAL APPLICATION

Before the use of any cleaning chemical, it is important to remove as much of the previous cargo as possible from the cargo
tanks and transfer lines using water, to prevent the excess use of cleaning chemicals with the obvious environmental and
financial implications. ECOSOLUT 24 has been specifically designed for use at very low concentrations and every effort should
be taken to take advantage of its performance.

Typically, cargo tanks should be cleaned as following:

Pre-wash with ambient or heated seawater, depending on the chemical characteristics and IMO classification of the
previous cargo.

Notes: For chemical cargoes that polymerize or contain drying / semi drying oils, the pre-wash should always be carried
out with copious amounts of ambient temperature water in order to prevent the formation of a “polymerized” film on
the surface of the cargo tanks.

For all oil based cargoes, if cleaning cannot start immediately after the cargo tanks are certified as empty, keep the tanks
moist / wet by flushing with water and keeping the tanks closed, until cleaning can start. Non-drying oils may be steamed
at this time.

Continue with seawater washing, using increased temperature (where appropriate), until all previous cargo residues are
removed.

Continue with ECOSOLUT 24 diluted to 0.5–1% in sea or fresh water for a minimum of 2 hours or 4 washing cycles. Using
elevated washing water temperatures increases the efficacy of the cleaning process.

Note: ECOSOLUT 24 is a neutral pH cleaning chemical that will work equally well on organic or more porous inorganic
zinc silicate cargo tank coatings as well as stainless steel. Approvals of ECOSOLUT 24 by coating manufacturers are
available on request

DOSAGE AND APPLICATION PROCEDURE

The following suggestions should only be used as a guide, but are based on first- hand experience of cargo tank cleaning. The
product requirement for specific cleaning operations could vary depending on the nature of the previous cargo, the degree of
contamination and the temperature of the washing water to name the three most common variables.

For the removal of vegetable oils from the internal surfaces of cargo tanks using tank-cleaning machines, ECOSOLUT 24 may
be used as follows:

By recirculation at a dilution rate from 1:200 to 1:100 (0.5–1% by concentration)

By injection directly into the tank cleaning line, typically at a rate of 2 – 5L per MT of washing water

For the manual removal of traces of surface contamination use scrubbing or brushing to produce oil free surfaces, ECOSOLUT
24 is particularly effective at concentrations of between 1 and 10% in fresh water (2 – 20L in freshwater) depending on the
extent of the contamination. After cleaning, the cargo tanks should be washed out with hot water.

In extraordinary circumstances, ECOSOLUT 24 may be used for spot cleaning in its undiluted form. The product can be applied
to contaminated areas by manual spraying or brushing, left for 15 – 30 minutes (but never allowed to dry out) and then washed
away with high pressure either through a barrel pump or tank cleaning machines.

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 SUSTAINABLE
CLEANTECH
SOLUTIONS

ECOSOLUT 24 ®

REQUIRED EQUIPMENT

For manual removal of surface contamination: High pressure cleaner with heating feature (pressure 30–180 bar), hand-brushes.

RECOMMENDED DILUTION

Typically very low concentrations can be used. ECOSOLUT 24 concentrate is effective at dilutions of 1 part concentrate to
200–100 parts water (i.e. 5–10 litres of concentrate in 1000 litres of water) depending on the degree of contamination.

REQUIRED WATER QUALITY

Sweet water (regular, river or lake water) or salt water.

TEMPERATURE RANGE OF TREATMENT SOLUTION

In general the performance of ECOSOLUT 24 increases with temperature. An application temperature of at least 60ºC or in a
steam cleaning system is recommended.

HAZARD CLASSIFICATION (EC)

Refer to the ECOSOLUT 24 Safety Data Sheet.

PRODUCT STORAGE

ECOSOLUT 24 concentrate has a shelf life of 12 months. The diluted, wash solution should be made immediately prior to
application.

WASTE MANAGEMENT

Materials should be disposed of according to local regulations.

APPROVALS

ECOSOLUT 24 has been accepted as a cleaning chemical by the International Maritime Organisation and is listed in annex 10
of the MEPC.2/Circular.

HSE

OTI have carefully developed their products to minimise the safety risks and environmental impact of using their products.
However, OTI advises that, prior to using its products, users should read in detail the accompanying MSDS and ensure that its
products are applied within the required HSE regulations of the country in which the user operates. Best practice and safety
requirements should be followed which will likely include method statements and risk assessments, together with any specific
requirements of the user’s own company HSE requirements.

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ECOSOLUT 24 E24MSDS201409

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Version 3.0 Revision date / valid from 14.05.2014

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name : ECOSOLUT 24

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the : Cleaning agent
Substance / Mixture
Uses advised against : At this moment we have not identified any uses advised against

1.3. Details of the supplier of the safety data sheet

Company : Uniservice Unisafe S.r.l.
via Al S.N.S. della Guardia 58a, Genova 16163 Italy
Telephone : +39 (0)10.711.395
Telefax : +39 (0)10.713.120
E-mail address : info@uniservicemarine.com
Responsible/issuing : Matteo Niego
person

1.4. Emergency telephone number

Emergency telephone : +39 (0)2.6610.1029 Centro Antiveleni Milano - Niguarda

ECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Regulation (EC) No. 1272/2008

Regulation (EC) No. 1272/2008

Hazard class Hazard category Target Organs Hazard statements

Serious eye damage Category 2 --- H318

For the full text of H-Statement mentioned in this Section, see Section 16.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Regulation (EC) No. 1272/2008

Hazard symbol / Category danger Risk phrase

Irritatnt (Xi) R41

For the full text of R-phrases mentioned in this Section, see Section 16.

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Most important adverse effects

Human Health : See section 11 for toxicological information.
Physical and chemical : See section 9 for physicochemical information.
hazards
Potential environmental : See section 12 for environmental information.
effects

2.2. Label elements

Labeling according to Regulation (EC) No 1272/2008

Hazard symbols :

Signal word : Danger

Hazards statements : H318 causes serious eye damage

Precautionary statements
Prevention : P280 Water protective gloves / eye protection / face
protection.

Response : P305 + P351+ IF IN EYES: Rise cautiously with water for several
P338 minutes. Remove contact lenses, if present and easy
to do. Continue rinsing
P310 Immediately call a POSION CENTER or doctor /
physician.

Hazardous components which must be listed on the label:

• Poly(oxy-1,2-ethanediyl), α-(2-propylheptyl)-ω-hydroxy-
• Sodium dodecyl sulphate

Regulation (EC) No 648/2004 on detergents

The surfactant(s) contained in this mixture complies (comply) with the biodegradability criteria as laid down
in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the
competent authorities of the Member States and will be made available to them, at their direct request or at
the request of a detergent manufacturer.
non-ionic surfactants Concentration : >= 30,00%
anionic surfactants Concentration : >= 5,00 % - < 15,00 %

2.3. Other hazards

For Results of PBT and vPvB assessment see section 12.5.

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SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical nature : Cleaning agent

Classification
Regulation (EC) No 1272/2008 Classification
Hazardous components Amount [%]
Hazard class / Hazard statements (67/548/EEG)
Hazard category
Poly(oxy-1,2-ethanediyl), α-(2-propylheptyl)-ω-hydroxy-

CAS-No. : 160875-66-1 12,5 – 25 Eye Dam. 1 H318 Irritant, Xi R41

Sodium dedecyl sulphate

CAS-No. : 151-21-3 Acute Tox.4 H302 Harmful; Xn; R22

EC- No. : 205-788-1 Skin Irrit.2 H315 Irritant; Xi R38
5 -10 Eye Dam. 1 H318 Irritant, Xi R41
Aquatic Chronic3 H412

For full text of the r-phrases mentioned in this Section, see Section 16.
For full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice : Take off all contaminated clothing immediately.
If inhaled : Move to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. If unconscious place in recovery position and seek
medical advice.
In case of skin contact : Wash off with soap and plenty of water. If symptoms call a physician.
In case of eye contact : Rinse thoroughly with plenty of water, also under the eyelids.
Consult an eye specialist immediately. Go to ophthalmic hospital if
possible.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting. If a person vomits when lying on his
back, place him in the recovery position. Call a physician
immediately.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms : Severe eye irritation.
Effects : Risk of serious damage to eyes

4.3. Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically

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SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing : Using extinguishing measures that are appropriate to local
media circumstances and the surrounding environment. The product itself
does not burn
Unsuitable extinguishing : None know
media
5.2. Special hazards arising from the substance or mixture
Specific hazards during : Fire may cause evolution of: Carbon oxides, It cannot be excluded that
firefighting spreading fir may case formation of toxic substances from neighboring
material
5.3. Advice for firefighters
Special protective equipment : In case of insufficient ventilation, wear suitable respiratory equipment.
for firefighters Wear personal protective equipment.
Further information : Collect contaminated fire extinguishing water separately.
This must not be discharged into drains.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions :
Ensure adequate ventilation. Wear personal protective equipment.
Handle in accordance with good industrial hygiene and safety praxis.
6.2. Environmental precautions
Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration. Local authorities should be advised if
significant spillages cannot be contained
6.3. Methods and materials for containment and cleaning up
Methods and materials for : Absorb with liquid-binding material (sand, binders, universal binders).
containment and cleaning up
Further information : Treat recovered material as described in the section “Disposal
considerations”
6.4. Reference to other sections
For personal protection see section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling
sufficient air exchange
Hygiene measures
: Keep only in the original container. Keep container tightly closed. Provide
Handle and open container with care. Provide sufficient air exchange
and/or exhaust in work room. Emergency eye wash fountains and
emergency showers should be available in the immediate vicinity
: Keep away from food, drink and animal feedingstuffs. Smoking, eating
and drinking should be prohibited in the application area. Provide
adequate ventilation. Wash hands before breaks and at the end of
workday

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7.2. Conditions for safe storage, including any incompatibilities

Advice on protection
against fire and explosion
Further information on
storage conditions
Advice on common storage
German storage class
: The product is not flammable. Normal measures for preventive fire
protection.
: Keep tightly closed in a dry and cool place.
: Keep away from oxidizing agents.
: 12 Non Combustible Liquids.

7.3. Specific end use(s)

Specific use(s) : No information available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Other Occupational Exposure Limit Values

(Additional) Information : Contains no substances with occupational exposure limit values.

8.2. Exposure controls

Appropriate engineering controls
Refer to protective measures listed section 7 and 8.

Personal protective equipment

Respiratory protection
Advice : No personal respiratory protective equipment normally required. In case
of insufficient ventilation, wear suitable respiratory equipment.
Particle filter: P2
Hand protection
Advice : Wear suitable gloves. Please observe the instructions regarding
permeability and breakthrough time which are provided by the supplier
of the gloves. Also take into consideration the specific local conditions
under which the product is used, such as the danger of cuts, abrasion,
and the contact time.
Protective gloves should be replaced at first signs of wear.
The following materials are suitable:
Butyl-rubber
Nitrile rubber
Eye protection
Advice : Tightly fitting safety goggles
Skin and body protection
Advice : Protective work clothing
Environmental exposure controls
General advice : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration. Local authorities if significant spillages
cannot be contained.

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SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form
Colour
Odour
Odour Threshold
pH
Melting point/range
Boiling point/boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper explosion limit
Lower explosion limit
Vapour pressure
Relative vapour density
Density
Water solubility
Partition coefficient:
n-octanol/water
Auto-ignition temperature
Thermal decomposition
Viscosity, dynamic
Explosive properties
Oxidizing properties
9.2. Other information
Refractive index
: liquid
: colorless to yellowish
: characteristic
: no data available
: 7
: no data available
: > 100 °C
: > 100 °C
: no data available
: not applicable
: no data available
: no data available
: no data available
: no data available
: 1,02 g/cm3 (20 °C)
: miscible
: no data available
: no data available
: no data available
: no data available
: Product is not explosive
: none
: 1,4371

SECTION 10: Stability and reactivity

10.1. Reactivity
Advice : No decomposition if stored and applied as directed.

10.2. Chemical stability

Advice : Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions : None known.

10.4. Conditions to avoid

Conditions to avoid : Protect from frost, heat and sunlight.
Thermal decomposition : no data available

10.5. Incompatible materials

Materials to avoid : Oxidizing agents

10.6. Hazardous decomposition products

Hazardous decomposition : fire may cause evolution of: Carbon oxides, Under certain fire
Products conditions, traces of other toxic products cannot be excluded.

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SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
Oral
Acute toxicity estimate : >2000mg/kg) ( Calculation method)
Inhalation
For this mixture is no data available.
Please find this information in the listing of the component /
components below the MSDS.
Dermal
For this mixture is no data available.
Please find this information in the listing of the component /
components below the MSDS.
Irritation
Skin
Result : Based on available data, the classification criteria are not met.
Eyes
Result : Causes serious eye damage.
Sensitisation
Result : Based on available data, the classification criteria are not met.
CMR effects
CMR Properties
Carcinogenicity : For this product currently is no data available
Based on available data, the classification criteria are not met.
Mutagenicity : For this product currently is no data available.
Based on available data, the classification criteria are not met.
Reproductive toxicity : For this product currently is no data available.
Based on available data, the classification criteria are not met.
Specific Target Organ Toxicity

Single exposure
Remark : The substance or mixture is not classified as specific target
organ toxicant, single exposure.
Repeated exposure

Remark : The substance or mixture is not classified as specific target

organ toxicant, repeated exposure.

Other toxic properties

Repeated dose toxicity

: no data available
Aspiration hazard

: Based on available data, the classification criteria are not met.

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Further information
Other relevant : Health injures are not know or expected under normal toxicity
information use. Handle in accordance with good industrial hygiene and
safety practice.
Poly(oxy-1,2-ethanediyl), CAS-No.
Component:
α-(2-propylheptyl)-ω-hydroxy- 160875-66-1 α-(2-propylh
Acute toxicity
Inhalation
LC50 : > 20 mg/kg
Dermal
LC50 : > 2000mg/kg)
Other toxic properties
CAS-No.
Component: Sodium dodecyl sulphate α-(2-propylh
151-21-3
Acute toxicity
Inhalation
no data available
Dermal
no data available

SECTION 12: Ecological information

12.1. Toxicity

Poly(oxy-1,2-ethanediyl), CAS-No.
Component:
α-(2-propylheptyl)-ω-hydroxy- 160875-66-1 α-(2-propylh
Acute toxicity
Fish
LC50 : 10 – 100 mg/l (Fish; 96 h)
Toxicity to daphnia and other aquatic invertebrates
EC50 : 10 – 100 mg/l (Daphnia manga (Water flea); 48 h)
Algae
EC50 : 10 – 100 mg/l (algae; 72 h)

Sodium dodecyl sulphate CAS-No. α-(2-propylh

Component:
151-21-3

Acute toxicity
Fish

LC50 : 13,5 mg/l (Poecilia reticulate (guppy); 96 h)

LC50 : 4,06 mg/l (Lepomis macrochirus (Bluegill sunfish); 96 h)
LC50 : 22,5 mg/l (Pimephales promelas (fathead minnow); 96 h)
LC50 : 4,6 mg/l (Oncorhynchus my kiss(rainbow trout); 96 h)

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Toxicity to daphnia and other aquatic invertebrates

EC50 : 1,8 mg/l (Daphnia manga (Water flea); 48 h)
Algae

EC50 : 53 mg/l (Scenedesmus; subspicatus; 72 h)

EC50 : 30 mg/l (Scenedesmus; subspicatus; 96 h)
EC50 : 117 mg/l (Scenedesmus; capricornutum (fresh water algae); 96 h)

12.2. Persistence and degradability

Persistence and degradability

Persistence

Result : no data available

Poly(oxy-1,2-ethanediyl), CAS-No.
Component:
α-(2-propylheptyl)-ω-hydroxy- 160875-66-1 α-(2-propylh

Persistence and degradability

Biodegradability

Result : > 60% (related to: Biochemical oxygen demand;

Exposure Time: 28d)(OECD 301 D)
Readily biodegradable.

Sodium dodecyl sulphate CAS-No. α-(2-propylh

Component:
151-21-3

Persistence and degradability

Persistence

Result : no data available

Biodegradability

Result : > 98% (Exposure Time: 28d)(DOC (Dissolved Organic Carbon)

Test; EC 92/69)
Readily biodegradable.
Result : > 60% (OECD 301 B)
Readily biodegradable.
12.3. Bioaccumulative potential

Bioaccumulation

Result : Bioaccumulation is not expected

Sodium dodecyl sulphate CAS-No. α-(2-propylh

Component:
151-21-3

Bioaccumulation

Result : no data available

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12.4. Mobility in soil

Mobility

Result : The product is partly soluble in water.

Sodium dodecyl sulphate CAS-No. α-(2-propylh

Component:
151-21-3
Mobility

Result : no data available

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB assessment

Result : This mixture contains no substance considered to be

persistent, bioaccumulating nor toxic (PTB)., This mixture
contains no substance considered to be very persistent nor
very bioaccumulating (pvPvB)

Sodium dodecyl sulphate CAS-No. α-(2-propylh

Component:
151-21-3

Results of PBT and vPvB assessment

Result : no data available

12.6. Other adverse effects

Additional ecological information

Result : Do not flush into surface water or sanitary sewer water.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product : Disposal together with normal waste is not allowed. Special disposal
required according to local regulations. Do not let product enter drains.
Dispose of in accordance with local regulations.
Contaminated packaging : Empty contaminated packagings thoroughly. They can be recycled
after thorough and proper cleaning. Packagings that cannot be
cleaned are to be disposed of in the same manner as the product.

European Waste : No waste code according to the European Waste Catalogue can
Catalogue Number be assigned for this product, as the intended use dictates the
assignment. The waste code is established in consultation with
the regional waste disposer.

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SECTION 14: Transport information

Not dangerous goods for ADR, RID and IMDG.

14.1. UN number : Not applicable.
14.2. UN proper shipping name : Not applicable.
14.3. Transport hazard class(es) : Not applicable.
14.4. Packaging group : Not applicable.
14.5. Environmental hazards : Not applicable.
14.6. Special precautions for user : Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
IMDG : Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
WGK (DE) : WGK:2; water endangering; WGK (DE); Self- classification
according VwVwS of 17 May 1999, Annex 4
Major Accident Hazard : Does not fall under the German StörfallV. –
Legislation
Other regulations : Occupational restrictions: Take note of Dir 92/85/EEC on the
safety and health of pregnant workers at work and of Dir 94/33/EC
on the protection of young people at work.
15.2. Chemical Safety Assessment
There is no data available for this product.

SECTION 16: Other information

Full text of R-phrases referred to under sections 2 and 3.

R22 Harmful if swallowed.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
Full text of R-phrases referred to under sections 2 and 3.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage
H412 Harmful to aquatic life with long lasting effects.
Further information
Key literature references : Supplier information and data from the "Database of registered
and sources for data substances" of the European Chemicals Agency (ECHA) were
used to create this safety data sheet.
Other information : The information provided in this Safety Data Sheet is correct to
the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for
safety handling, use, processing, storage, transportation, disposal
and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material
designated and may not be valid for such material use or in any process,
unless specified in the text. Restricted to professional users.
Attention - Avoid exposure – obtain special instructions before use
|| Indicates updated section.

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