1-

GUJARAT POLLUTION CONTROL BOARD

PARYAVARAN BHAVAN
Sector 10-A. Gandhinagar 382 010
Phone (079) 23226295
Fax . (079) 23232156
Website WI'\YIItI1l,llob.govin
In exercise ufthe power conferred under section-25 of the Water (Prevention and Control of Polhltiun)
Act-\974, under SCCtiOD-21ufthe Air (Prevention and Control ofPol1ution)·1981 and Authorization under rule
5(4) urthe Hazardous Waste (Management, Handling & Transboundary Movement) Rules-ZOOS, framed under
the Environmental (Protection) Act-1986,

And whereas Board has received CC& A application dated 20/112014 tor the Consolidated Consent
and Authorization (CC & A) of this Board under the provisions/rules of the aforesaid Acts. Consents &
Authorization are hereby granted as under:

CONSENTS AND AUTHORISATION:

(Under the provisions !rules of the aforesaid environmental acts)

~UNITED PHOSPHOROUS LTD,

Plot No. 3-11, A-2/1, A-2/Z, A-2/6 & A-Ill, PHASE-I,
GIDC Estate, Vapi~396195,
Dist.Valsad.

I. Consent Order No.: AWH-60886, Date of issue: 3/312014.

2. The consents shall be valid up to 51l12019 for usc of outlet for the discharge of trade cenuent &
emission due lo ooeration of industrial lant for manufacture of the following items/products:
Sr.No. Prodnct Quantity (MTlMontb)
1. Aluminum Phosphide (Fumi ant) 200
2. Zinc Phosphide (Rodenticide) 40
3. Cypermethrin (Insecticide) 330
4. Alpha Cypermethrin (Insecticide) OR 30
Beta Cypermethrin OR
Imidacloprid Tech.
5. Pennethrln (Insecticide) 100
--
6. Desmedipham (DMP) (Herbicide) OR 90
Phenmooipham (PMP) Either OR
Metamitron OR
Metribuzin
7. Bifenthrin (BF 20) (Insecticide) OR 32
Clodinofop Propargyl(UPII-20J) OR
Thiomethaxam (STAR) OR
Lambda Cyhalothrin
8. Safner (UPH-203 S) (Herbicide) 5.0
--
9. Magnesium Phosphide (Fumi ant) 8.0
10. ASAM 2.0
11. Pronanil (Herbicide) 108.00
12. Pesticide Formulation Product JOO
13. Dichloro Vinvl Acid Chloride (DVACL) JOO
14. Meta henoxy 8""Dzaldehvde (MPBAD) 275
15. Hydrazide 20
16. Red Phosphorus (Non Pesticide) 80
17. Denatonium Benzoate 1
By-Product
1. Phosnhoric Acid (100 %basis 40
2. Hydrochloric Add (30 % 2048
3. SpentSulfuricAcj,d(46-68%) OR --lO25~
Ammonium Sulnhatc 600
4. Phosnhorous OXYchloride 640
Ammonium Chloride (Solid) 34.8
. • Tljo
m, ., '. _"';lOA.' OA."

:..ff ~
ISO - 9001 - 2008 & ISO - 14001 ,2004 Certified Organisation
/,
 7. Sodium Bromide solution 720
8. Sodium Sultite (20 %) 930
9. KC1Salt oc 160 oc
KCI Solution 91~O__
10. Copner HydroxiddCoDpcr Sui hate
11. Sodium Sulohate (20%) 160
12. MPBAD Distillation Cut 20
13. Aluminium Chloride (20 %) QB. 1130
Poly Aluminium Chloride (PAC)

r-~ ~7dcapacitv)
• Sodium Sulphite Solution and! OR
Solid Sodium Sulphite
QR Sodium Bi Sulphite Solution
Sodium Hi Sulphite Solids --l
and I OR
1130
930/
190

930
1JI
~binedcapacity) 190
-- --------

SPECIFIC CONDITION:
As Board has granted merger of two units, uDit-llocated at plot no. 3-11 & Unit-2 located at A-
211, A·212, A-2/6 & A-If2 Applicant shall surrender CC&A No: WH 56192 dated 09108/2013 to
the board along with GPCB ID No.: 24356 issued by GPCB.

3 CONDITIONS UNDER THE WATER ACT:

3.\ The quantity of trade emuent from the industry shall not exceed 2,312.542 MJIDA Y.
3.2 The quantity of Sewage etlluent from the industry shaH not eXI.'eed93.4 MJIDA Y.

3.3 TRADE EFFLUENT:

3.3.1 fbt: effluent from the industrial unit shall conform to the CEll' inlet norms mentioned in column No.1
helow (in ca:;e of CETP mt:mbt:r). The final discharge from CETP shall adhere to tht: prt:seribed
standards tor CUT?
3.3.2 In the evt:nt. if the effluent from indUstrial unit not routed through CETP. the applicant shall prm ide
adequate efnuent treatment system in order to achieve the quality of the treated efflucnl as per GPCB
norms mentioned in column No 3
PARAMETERS CETP INLET NORMS GPCBNORMS
pH 6.51D8.5 6.5 TO g.5
femnerature 40 C 40C
Color (ot.co.scale) in units 100 units
f--.--.--.
Suspended Solids 300m /1 lOO~
Oil and Urease 10m 11 10 mel
Phenolic Compounds Imgll Img.1
C 'anidcs D.2m 1 O.2m 1
~.~es 2mgll 2mgl,'
~hides 2mQ/1 2m¥-1
I\mmonicalNitrogcn 5Dm0\ 5Om.l
Arsenic O.2mgll 0211Ul-I
Total Chromium 2mgll 2 ••• 1
Hexavelent Chromium O.lmg/l O.11D2.1
3mgll :; DJ21
~-~--_._-
O·l~ O.11J121
~- O.Olmgll o.Ol1D2.1
Nickel
Zinc 5m,
3mll 3iM-l
5m2.~
Cadmium 2m ' ••• 1
Iron 3m 1 :; mg.l
400m 30111£1
Yob(5da~~ __ f--
lOOOrn "'50mgl
 Chlorides 600m£!l 600 mg/l
Sulphates 100Omg/l 1000mg/l
Total dissolved Solids 2100m II 2100mg/1
Insecticides/Pesticides Absent Absent
Sodium absor tion ratio 26
-~
Sodium Percent 60 60
Bio·assaytest ---_..- 90% Survj,,'al offish after 96
hour in 100% effluent.
All efforts shall be made to remove color & unpleasant odor as far as practicable.
3.3.3 The final treated effluent confirming to the above standards shan be discharged into GlDe
underground drainage system & shall ultimately be conveyed into tidal zone of river Damanganga
through CETP.
3.3.4 High TDS & low COD effluent shall be segregated & sent to Multiple Effect Evaporator. High COD &
low TDS effluent shall be sent to Incinerator of BElL, Ankleshwar-following manifest system.
3.3.5 Cyanide bearing effluent shall be detoxified by adequate system & then sent to ETP after cheddng
cyanide & p<..-'Sticidelevels. Only treated effluent shan be sent to ETP for further treatment to achieve
norms.
3.3.6 Unit to provide magnetic tlow meter & online TOCITN at final outlet of ETP with provisiun of
recording.
3.3.7 Domestic effluent shall be disposed off through septic tankJsoak pit system or it shall be treated along
with indUstrial effluent or it shall be treated separately to conform to the following standards and shall
discharge into GIOC under ground drainage system.
BOD (5 days at 20 IC) Less than 20 mgll
Suspended solids Less than 30 mgll
Residual Chlorine Minimum 0.5 mgll

4 CONDITIONS UNDER THE AIR ACT:

4.1 The following shall be used as fuel in boiler, furnace, and heater res ectivc1y.
Sr.No. Fuel uanti
l. Natura} Gas 1,200 sm3/hr
2. HSD 340litfhr
3. FO 909litlhr
4. LDO I Other 43 k
4.2 fhe applicant shall install & operate air pollution control system in order to achieve norms prescribed
below:
4.3 The flue gas emission throu h stack shall conform to the followin standards:
Stack
"
l.
.. Stack attached to

Boiler#l(lO
Stack height in
Meter
11 with
Air Pollution
Control System
NA
Parameter

Particulate matter
Permissible
Limit
150 mgfNM
TPH) condensing SOl 100 ppm
economizer or NO, 50 ppm
30.5 meter when
usim!F.O.
2. Boiler #2 (8 TPH) II with NA
condensing
economizer or
30.5 meter when
I
using F.O.
3. Boiler #3 (5 TPH) 30.5 NA
4. Thennic Fluid 30.5 NA
Heater
(MPBAD Plant)
5. Thermic Fluid 30.5 NA
Heater
(Pesticide Plant)
6. Thermic Fluid 30.5 NA
 Heater (Propanil
Plant)
7. DO Set -} (1250 15.5 NA
KVA)
(Stand by fad lit )
R. DO Set Il 15.5 NA
( 500 KVA)
(Stand by facility)
9. DO Set III 15.5 NA
(500KVA)
(Stand bvtilcility)

4.4 Thc Process emission through various stacks/vent of reactors, proccss, vessel shall conform to the
followinl!: standar d s:
Stack Stack attached to Stack height Air Pollution Parameter Permissible
No. in Meter Control svstem Limit

!I Pesticide Plant (Permethrin

Reactor)
12 Water scrubber
followed by
Hel
CI,
20mg/NM
5 mgfNl\..l'
Caustic Scrubber PM 20mgiNM.1
2. Alp Plant Firing Chamber 30 Misteliminator & PM 20 mgiNM
Water Scrubber p]OS a~ HJP04 5mgINM1
3. MPBAD Plant Reaction 22 Sodium Hel 20 mgINM
Vessel & Bromine Thiosulphate CI, 5 mgINM3
recovery system absorber for Br2 HB, 5mgINM'
reooveryand
Caustic Scrubber
4. DVACI plant (TCBACI 22 Alkali Scrubber HCI 20 mg,fNM
Reactor) PCI] 9mg/NMJ
5. DVACI Plant (DVACI 22 Alkali Scrubber HCI 20 mgINM
Reactor) PCI) 9mg/NM1
6. DVACI Plant 22 Alkali Scrubber S02 40mg/NM)
(PCl3 storage
tankiPOCL2& PCL3
recovery system/distillation
svstem)
7. DVACI Plant 22 Alkali Scrubber HCI 20mgiNM
(Fugitive Emission) el, 5 mg/NM3
SO, 40 mgINM\
8. ASAM 22 Alkali Scrubber ~CI 20mgINM
Cb 5m~M)
9. 7npPlantReactor 12 Mistcliminator PM 20mgiNM
I P205 asHJPO. 5m~M.1
10. Lambda CYHALOTHRIN 12 Alkali Scrubber IICI 20 mgINM
S02 40mgmMJ
II. Metribuzine 12 Water and Alkali IIBr 5 mg/NM
scrubber (Sodium
Thiosulphate
absorber)

4.7 The concentration of the following substances in the ambient air within the premises of the industry and
at a distance of 10 meters from the source (other than the stack/vent with height of more than 9 meters
from the ground level) shall not exceed the following levels:

====+~08~0~M~:~~oRMi!J,[~~S
P.~~~~i~~"~~~~S~~E~,pR~h'=' p~s:Iii~~i:i;~biLi:i, ~~,:~::q,
Oxides of Nitro en 080 Microgram Per cubic meter
 PMIO 100 Microgram Per cubic meter
PM 2.5 60 Micro ram P(.,"fcubic meter
C[, 100 MicrOi!ram Per cubic meter
HC[ 200 Micro ram Per cubic meter
PCh 100 Microgram Per cubic meter
Phos horous Pentoxide 30 Micro ram Pcr cubic meter
Bromine 20 Micro ram Per cubic metcr
11 droR,en Bromide 300 Microgram Per cubic m(.,1.er

4.& The applicant shall provide portholes, ladder, platform etc at chimney(s) for monitoring the air
emissions and the same shall be open for inspection to/and for usc of Board's statf. The chimney(s)
vents attached to various sources of emission shall be designed by numbers such as S- L S-2, etc. and
thesc shall be painted! displayed to facilitate identification.

4.9 The industry shall take adequate measures for control of noise levels from its own sources within the
premises so as to maintain ambient air quality standards in respect of noise to less than 75 d13 (a)
during day time and 70 dB (A) during night time. Daytime is reckoned in between 6 a.m. and 10 p.m.
and nighttime is reckoned between 10 p.m. and 6 a.m.

5 GENERAL CONDITlONS:-
5.1. Any change in personnel, equipment or working conditions as mcntioned in the consents torm/order
should immediately be intimated to this Board.
5.2 Applicant shall also comply with the general conditions given in annexure I

6. AUTHORISATION FOR THE MANAGEMENT & HANDLING OF HAZARDOUS WASTES

Form·2 (5 (4))
6.1 Number of authorization: A WH-60886, Date of issue: 3/3/2014.

MIs. UNITED PHOSPHOROUS LTD is hereby granted an authorization to operate facility for
tollO\ving hazardous wastes on the premises situated at Plot No. 3-11, A·211, A-2f2, A-216 & A-tl2,
PHASE-I GlDC Estate, Yaoi- 396195, Dist.Valsad.
S,. Waste Quantity Schedule-l Facility
No Process No,
[ ETPwaste 544.417 34.3 Collection, storage, transportation, disposal at
MT/Month TSDF· VWEMCLlREIL-Ankleshwar.
2 Used Oil 4.197 5.[ Collection, Storage, Transportation,
KLiMonth Disposal by selling to regislercd re roccssors.
3 Discarded 42052 33.3 Collection, Storage, Decontamination &
ContainerlBall.s Nos/Month recycle or sold to scrap operators. ~,_
4 Oil/Grease from 0.468 34.4 Collection, storage, transportation, disposal by
ETP MT/Month incineration ,t rSDF-VWEMCLlBEIL-
Ankleshwar.
5 Spent filter 3.00 35.1 Collection, storage, transportation, disposal by
material MTlMonth incineration TSDF-VWEMCLlBElI.-
Ankleshwar. " . _-;----
6 Salt from 760 34.4 Collection, stor •.ge, transportation, disposal at
evaporation MT/Month TSDF- VWEMCLIBEIL-Ankleshwar.
system
7 Sludge f'Om wet 4.197 36.1 Collection, storage, transportation, disposal by
scrubber KLlMonth incineration at TSDF-VWEMCLiBEIL-
Ankleshwar.
Collection, Storage. Transportation,
--
8 Used batteries 3 "4
NosIMonth Disposal by selling to re!!;istered reprocessors.
9 Process Inorganic 30.8 34.3 Collection, storage, transportation, disposal at
Waste MTlMonth TSDF- VWEMCLlBEIL-Ankleshwar.
10 AI, M, Zoo 2.608 Sch-II Collection, storage, trans ortation, dis osal at
 Hydroxide (Dust MTiMonth TSDF- V\oVEMCI ./BELL-Ankleshwar.
collection)
II Distillation 681.343 28.1 Collection, storage, transportation. disposal b)
TSDF-VWEMCLiBEIL-
Residue MTrM:onth incineration
Ankleshwar. "
12 Spent Solvent 22.917 20.2 Collection, storage. transportation, disposal by
incineration TSDF-VWEMCLiBEIL-
MT/Month
Ankleshwar. "
13 Waste/Residue 0.795 29.1 Collection, storage. transportation, disposal b)'
incineration TSDF-VWEMCLiBEIL-
containing
esticide
MTlMonth
Ankleshwar. "
14 Date expired/off 2.4 29.3 Collection, storage, transportation, disposal hy
specification MT/Month incineration TSDF-VWEMCLiBEIL-
I nroducts Ankleshwar. "
6.2 The authorization is granted to operate a facility for collection, storage within factory premisl."S
transportation and ultimate disposal of Hazardous wastes at TSDF developed hy the Vapi Waste &
Effiucnt Management Co. Ltd -Vapi.
6.3 The authorization shall be valid up to 5/212019.
6.4 The authorization is subject to the conditions stated below and such other conditions as rna" be
specified in the ruJcs fro~ time to time under the Environment (Protection) Aet-1986. -
6.5 TERMS AND CONDITIONS OF AUTHORISATION:
a) The applicant shall comply with the provisions of the Environment (Protection) Act - 1986 and the
rules made there under.
b) The authorizJltion shall be produced tOr inspection at the request of an officer authorized b)' the
Gujarat Pollution Control Board.
c) The persons authorized shaH not rl.'1lt, land, sell, and transfer of otherwise transport the ha7.ardous
wastes without obtaining prior pennission ofthe Gujarat Pollution Control Board.
d) Any unauthorized change in personnel. equipment or working conditions as mentioned in the
authorization order by the persons authorized shall constitute a breach of thb authorization.
e) It is the duty of the authorized person to take prior permission of the Gujarat Pollution Control
Board to close down the facility.
f) An application for the renewal of an authorization shall be made as laid dO\V11in rule-7.

6.6 In addition to above terms and conditions Industry shall also comply following dire",ives issued by the
Supreme Court of India dated.l4.l0.2003.

a) Industry shan have to display the relevant information with regard to hazardous waste as indicated
in the Court's order in W,P. No.657 of 1995 dated 14th October 2003.
b) lndustry sball have to display on-line data outside the main factory gate with regard to quantity and
nature of hazardous chemicals being bandied in the plant, including wastewater and air em issions
and solid hazardous wastes generated within the factory premises.
For and on behalf of
Gujarat Pollution Control Board

_ ..
NO: GPCBlCCA-VSD-218(2)/1D:

MIs. UNITED PHOSPHOROUS

24711{ f2..D '6"

LTD,
'2b
~~}~
(T. B.SHAH)

End;hme~~o~Dle~r4

-.V_
•••• fIifa 3-11. PHASE-I,
e-:••.••.
Vapi- 396195,
 _ '-4
GUJARAT POLLUTION CONTROL BOARb
PARYAVARAN BHAVAN
Sector 10-A, Gandhinagaf38tO'&
Phone : (079) ~295
Fax: (079) 23232156
Website : www.gpcb.gov.in
BYR.P.A.D.

NO: GPCB/CCA-VSD-218(2) /10: 24711/

~. UNITED PHOSPHOROUS LTO,

Plot No. 3-11, PHASE-I,
GIDC ESTATE, VAPI-396 195,
Dist: Valsad.

SUB: Amendment to CC&A No (AWH-77786) Consolidated Consent & Authorization (CC & A) under
various Environmental Acts/ Rules.

REF: 1) Your Application inward no 103048 dated: 08/0212016.

2) CTE issued vide this office letter dated: 20/11/2014.

Sir,
This has reference to the CCA order nO.AWH-60886 dated: 03/03/2014 issued vide letter No.
GPCB/CCA-VSD-218(2)/ID:24711/208120 the dated:25103/2014 having validity up to 5/0212019
provisions of the various Environmental AcU Rules, which stands amended as under, for the conditions
under rule act

CONDITIONS UNDER AIR ACT 1981:

1. The following shall be used as fuel in the Boiler. _

~ Fuel I Quantity
CI:J Coal 5000 Kg/Hr

1.1 The applicant shall install & operate air pollution control system in order to achieve norms
prescribed below
16

1.2 The flue Qas emission throuqh stack shall conform to the followinq standards:
20

Stack Stack attached Stack Air Pollution Parameter PermIsSible

No. to height in Control Limit
4/

Meter svstem
/0

1. Coal fired Boiler 55 ESP PM 100mgINM'

(23 TPH) SO, 100 ppm
•
18

NO, 50 ppm
9,

Note: After installation of new 23 TPH Boiler, unit shall use other boilers as stand by.
69

• All other conditions of CCA order nO.AWH-60886 dated:03/03/2014 issued vide letter No.
52

GPCB/CCA-VSD-218(2)/ID: 24711/208120 the dated:25/03/2014 shall remain unchanged.

:3

For and on behalf of

No

Gujarat Pollution control Board

DP~
d
ar

(Smt.~.P.StWt)
Environmental Engineer
tw
Ou

Clean Gujarat Green Gujarat

150-9001-2008 & 150-14001 - 2004 Certified Organisation
 GUJARAT POLLUTION CONTROL BOARD
PARYAVARA.N BHAVAN
~ Sector 10-A, Gandhinagar 382 010
~ Phone : (079) 23226295
"llQI'"
Fax: (079) 23232156
GPCB Website : www.gpcb.gov.in
~
NO: GPCB/CCA-VSO-21B(3)/10: 24711/

TO,
~. UNITEO PHOSPHOROUS L TO,
PLOT NO. 3-11, PHASE-I,
GIOC ESTATE, VAPI-396195,
TAL: PAROl, OIST: VALSAO.

SUB: Amendment (AWH- 84270) to Consolidated Consent & Authorization (CC & A) under various
Environmental Acts! Rules

REF: 1) Your Application inward No.115563 dated: 19111/2016

17
2) CTE issued vide this office letter dated: 29/10/2016

Sir, 20
The Gujarat Pollution Control Board had granted Consolidated Consents & Authorization
Order No. AWH- 60886 dated 03/0312014. Which is valid up to 05/0212019. This order is served vide
2/
letter No. GPCB/CCA-VSD-218{2)/ID-24711/208120 dated:25/0312014 is further amended with
resped of following CQnditions
3 /0
,2

AlphaCypermethrin 30
77

OR OR OR
51

1.
BetaCypermethrin BetaCypermethrin 30
~-- _lOR I OR OR
,
0

Imidaclopria i 30 ~dacloprid 30
:4

OR
~ ~OXystrobin I 30
I·
No

Denatonlum I' 1 Denatonium 1

Benzoate. Benzoate
2. i I (OB) I I
ASAM I 2 ' ASAM 2
rd

OR OR
Denatonium 2
a

Benzoate
tw

Total I 33 Total 33
Ou

Clean Gujarat Green Gujarat

ISO-9001-2008 & ISO-14001 - 2004 Certified Organisation
 SUBJECT TO THE FOLLOWING CONDITIONS:-

SPECIFIC CONDITIONS:

1. There shall be no increase in pollution load after change in above mentioned product mix.
2. There shall be no increase in waste water quantity for disposal
3. There shall be no addition of any new plant machineries fOf proposed product mix change.
4. There shall be no increase in hazardous waste generation quantity.
5 Unit shall explore possibility for co-processing of Hazardous Waste at Cement Industries
6. No increasein existingpollutionload.
7. Unit shall comply the guideline made by GPCB for spent solvent management and handling.
8. Unit shall not dispose domestic waste water through soak pit, instead of it overflow of septic
shall be diverted to ETP of unit.

• All other conditions of eCA order AWH- 60886 dated 03/03/2014. issued vide No. GPCBlCCA·
VSD-218(2)/ID-24711/208120 dated:25/0312014 shall remain unchanged.

For and on behalf of

Gujarat Pollution Control Board

17
ol'~
(Smt. D. P. Shah)

20 Environmental Engineer
2/
3 /0
,2
77
0 51
:4
No
a rd
tw

Signature Not Verified

Ou

Digitally signed by SHAH

DIPTI PRAKASH
Date: 2017.07.25 11:01:34 IST
Reason: Secure Document
Location: India