IIt-jee chemistry by n.j.

sir Organic chemistry

DAILY PROBLEM PRACTICE SHEET

Q.1 Name reactions

OH O O

(I) CH3–CH2–C–CH–C–H CH3–CH=CH–CH–C–H

H CH3 CH3

IR
(A) (B)
O
OH OH O

(II) (III) C6H5–C–CH–C–H

H C 6H 5
(C)
.S (D)
O
OH O OH O O

(IV) (V) C6H5–C–CH2–C–CH3 C6H5–C=CH–C–CH3

H3C C6H5 H3C C6H5
(E) (F)
(G)
.J
OH HO
CH2 CH2 CH3
CH3
Q.2 (I) CH3–C (II) C–CH3
CH2 C
O
O
O
(A) (B)
N

HO
C CH3 OH
(III) (IV)

O O O
(E) (F)
(D)
HO
C CH3
(V) C–CH3 C–CH3
O O

(G) (H)

1
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 OH O OH O
Q.3 *
(I) CH3–C–CH *
2–C–H CH3–CH2–CH–CH–C–H
1 2 *
H R/S (2 ) (2 ) CH3
OH O OH OH
*
CH3–CH–CH–CH–C–H CH3–CH2–CH–CH2–C–H
*
CH3
2 1
2 2
= 12
OH O OH O
(II) C6H5–CH–CH2–C–H CH3–CH–CH2–C–H

IR
* *
21 21
=4
OH O OH O
(III) CH3–CH–CH2–CH3 CH3–CH–CH2–C–H
* *
.S 21 21
OH O OH O
CH3–C–CH2–C–H CH3–C–CH2–C–CH3
CH3 CH3
0 0
2 2
= 10
OH O OH O
.J
(IV) CH3–C–CH2–C–H * *
CH3–C–CH–C–CH 3
*
H H CH3
1 2
2 2
OH O OH O
CH3–CH2–C–CH2–C–H CH3–CH2–C–CH–CH–CH3
N

CH3 H3C CH3

1 1
2 2
= 10
OH O OH O
(V) C6H5–CH–CH–C–CH3 * *
CH3–CH2–C–CH–C–CH 3
*
CH3 H3C CH3
1 2
2 2
=6

2
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ETOOS Education Pvt. Ltd.
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Kota, Rajasthan - 324005
 O O
Q.4 (I) dil. NaOH
O 5ºC
HO

(A) (B)
O O O OH
dil. NaOH
(II) CH3–C–CH3 + CH3–C–CH3 CH3–C–CH2–C–CH3
5ºC
CH3
O OH

(i) O3 C–H OH–

IR
Q.5 (a)
(ii) Zn/H2O 
CH2–CH2–C–H C–H C–H
O O O
(A) (B)
HO
O
.S •• C–C6H5 CH–C6H5
C6H5C–H 
(b)
H
O O O
O O O HO
(c) CH3 ••
+ CH3C–H C–H
CH3
O
O O
.J
OH–
(d) CH3–C–CH2–CH2–C–OH3
OH
O
O O
(e) CH3–C–CH2–CH2–CH2–C–H OH–

N

3
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ETOOS Education Pvt. Ltd.
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Kota, Rajasthan - 324005