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This Safety Data Sheet has been prepared in accordance with the Preparation of Safety Data Sheets for Hazardous Chemicals
Code of Practice (Safe Work Australia, December 2011)
SECTION 1: Identification
1.1. Product identifier
3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
Recommended use
Polish and wax for marine applications., Marine polish and wax
Refer to Section 14 of this Safety Data Sheets for product Dangerous Goods Classification.
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
label.
Signal word
DANGER!
Symbols
Health Hazard |
Pictograms
Hazard statements
H227 Combustible liquid.
Precautionary statements
General:
P102 Keep out of reach of children.
P103 Read label before use.
P101 If medical advice is needed, have product container or label at hand.
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280B Wear protective gloves and eye/face protection.
P281 Use personal protective equipment as required.
P270 Do not eat, drink or smoke when using this product.
P264 Wash thoroughly after handling.
Response:
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P370 + P378G In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry
chemical or carbon dioxide to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with applicable
local/regional/national/international regulations.
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
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Closed containers exposed to heat from fire may build pressure and explode.
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
ppm)
Tripoli (Crystalline Silica) 1317-95-9 ACGIH TWA(respirable A2: Suspected human
fraction):0.025 mg/m3 carcin.
Tripoli (Crystalline Silica) 1317-95-9 Australia OELs Limit value not established:
Quartz 14808-60-7 ACGIH TWA(respirable A2: Suspected human
fraction):0.025 mg/m3 carcin.
Quartz 14808-60-7 Australia OELs TWA(8 hours):0.1
mg/m3;Limit value not
established:
Formaldehyde 50-00-0 CMRG TWA:0.5 ppm
Formaldehyde 50-00-0 ACGIH CEIL:0.3 ppm Sensitizer, A2:
Suspected human carcin.
Formaldehyde 50-00-0
Australia OELs TWA(8 hours):1.2 mg/m3(1
ppm);STEL(15 minutes):2.5
mg/m3(2 ppm)
Paraffin oil 64741-88-4 Australia OELs TWA(as mist)(8 hours):5
mg/m3
Solvent-Refined Heavy Paraffinic 64741-88-4 CMRG TWA:5 mg/m3
Petroleum Distillates
MINERAL OILS, HIGHLY- 64741-88-4 ACGIH TWA(inhalable fraction):5 A4: Not class. as human
REFINED OILS mg/m3 carcin
Paraffin oil 64741-89-5 Australia OELs TWA(as mist)(8 hours):5
mg/m3
MINERAL OILS, HIGHLY- 64741-89-5 ACGIH TWA(inhalable fraction):5 A4: Not class. as human
REFINED OILS mg/m3 carcin
Hydrotreated Light Petroleum 64742-47-8 CMRG TWA:165 ppm
Distillates
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
Australia OELs : Australia. Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment
CMRG : Chemical Manufacturer's Recommended Guidelines
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
Sen: Sensitiser
Sk: Absorption through the skin may be a significant source of exposure.
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.
Select and use eye protection in accordance with AS/NZS 1336. Eye protection should comply with the performance
specifications of AS/NZS 1337.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Neoprene.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
Select and use respirators according to AS/NZS 1715. Respirators should comply with AS/NZS 1716 performance
specifications. For information about respirators, call 3M on 1800 024 464.
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain. May cause additional health effects (see below).
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye contact
Dust created by cutting, grinding, sanding, or machining may cause eye irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000
mg/kg
Overall product Ingestion No data available; calculated ATE >5,000
mg/kg
Tripoli (Crystalline Silica) Dermal LD50 estimated to be > 5,000 mg/kg
Tripoli (Crystalline Silica) Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Hydrotreated Light Petroleum Dermal Rabbit LD50 > 3,160 mg/kg
Distillates
Hydrotreated Light Petroleum Inhalation-Dust/Mist Rat LC50 > 3 mg/l
Distillates (4 hours)
Hydrotreated Light Petroleum Ingestion Rat LD50 > 5,000 mg/kg
Distillates
Aluminum Silicate Dermal LD50 estimated to be > 5,000 mg/kg
Aluminum Silicate Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Montan-Wax Fatty Acids Ingestion Rat LD50 > 15,000 mg/kg
Carnuba Wax Dermal LD50 estimated to be > 5,000 mg/kg
Carnuba Wax Ingestion Rat LD50 > 8,800 mg/kg
Solvent-Refined Heavy Paraffinic Dermal Rabbit LD50 > 2,000 mg/kg
Petroleum Distillates
Solvent-Refined Heavy Paraffinic Ingestion Rat LD50 > 5,000
Petroleum Distillates
Morpholine Dermal Rabbit LD50 310 mg/kg
Morpholine Inhalation-Vapour Rat LC50 estimated to be 10 - 20 mg/l
Morpholine Ingestion Rat LD50 1,050 mg/kg
Distillates (petroleum), solvent- Dermal Rabbit LD50 > 5,000 mg/kg
refined light paraffinic
Distillates (petroleum), solvent- Inhalation-Dust/Mist Rat LC50 > 4 mg/l
refined light paraffinic (4 hours)
Distillates (petroleum), solvent- Ingestion Rat LD50 > 5,000 mg/kg
refined light paraffinic
Quartz Dermal LD50 estimated to be > 5,000 mg/kg
Quartz Ingestion LD50 estimated to be > 5,000 mg/kg
Formaldehyde Dermal Rabbit LD50 270 mg/kg
Formaldehyde Inhalation-Gas (4 Rat LC50 470 ppm
hours)
Formaldehyde Ingestion Rat LD50 800 mg/kg
2-Methoxyethanol Inhalation-Vapour (4 Mouse LC50 6.1 mg/l
hours)
2-Methoxyethanol Dermal Rabbit LD50 1,290 mg/kg
2-Methoxyethanol Ingestion Rat LD50 2,460 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
Skin Sensitisation
Name Species Value
Respiratory Sensitisation
Name Species Value
Formaldehyde Human Some positive data exist, but the data are not
sufficient for classification
Tripoli (Crystalline Silica) In Vitro Some positive data exist, but the data are not
sufficient for classification
Tripoli (Crystalline Silica) In vivo Some positive data exist, but the data are not
sufficient for classification
Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic
Aluminum Silicate In Vitro Some positive data exist, but the data are not
sufficient for classification
Solvent-Refined Heavy Paraffinic Petroleum In Vitro Some positive data exist, but the data are not
Distillates sufficient for classification
Morpholine In Vitro Some positive data exist, but the data are not
sufficient for classification
Morpholine In vivo Some positive data exist, but the data are not
sufficient for classification
Distillates (petroleum), solvent-refined light In vivo Not mutagenic
paraffinic
Distillates (petroleum), solvent-refined light In Vitro Some positive data exist, but the data are not
paraffinic sufficient for classification
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
Quartz In Vitro Some positive data exist, but the data are not
sufficient for classification
Quartz In vivo Some positive data exist, but the data are not
sufficient for classification
Formaldehyde In Vitro Some positive data exist, but the data are not
sufficient for classification
Formaldehyde In vivo Mutagenic
2-Methoxyethanol In Vitro Not mutagenic
2-Methoxyethanol In vivo Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Tripoli (Crystalline Silica) Inhalation Human and animal Carcinogenic.
Hydrotreated Light Petroleum Dermal Mouse Some positive data exist, but the data
Distillates are not sufficient for classification
Aluminum Silicate Inhalation Multiple animal Some positive data exist, but the data
species are not sufficient for classification
Solvent-Refined Heavy Paraffinic Dermal Mouse Some positive data exist, but the data
Petroleum Distillates are not sufficient for classification
Morpholine Ingestion Multiple animal Not carcinogenic
species
Morpholine Inhalation Rat Not carcinogenic
Distillates (petroleum), solvent- Dermal Mouse Some positive data exist, but the data
refined light paraffinic are not sufficient for classification
Quartz Inhalation Human and animal Carcinogenic.
Formaldehyde Not specified. Human and animal Carcinogenic.
Reproductive Toxicity
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2-Methoxyethanol Inhalation Toxic to development Multiple animal NOAEL 0.03 during organogenesis
species mg/l
Target Organ(s)
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
respiratory
system |
vascular system
Formaldehyde Ingestion skin | muscles | All data are Rat NOAEL 109 2 years
eyes negative mg/kg/day
2- Inhalation blood Causes damage to Human NOAEL Not occupational
Methoxyethan organs through available exposure
ol prolonged or
repeated exposure
2- Inhalation immune system May cause Multiple NOAEL 0.31 13 weeks
Methoxyethan damage to organs animal species mg/l
ol though prolonged
or repeated
exposure
2- Inhalation liver Some positive Multiple NOAEL 0.9 13 weeks
Methoxyethan data exist, but the animal species mg/l
ol data are not
sufficient for
classification
2- Inhalation kidney and/or All data are Rat NOAEL 0.9 13 weeks
Methoxyethan bladder negative mg/l
ol
2- Ingestion immune system Some positive Rat NOAEL 85 13 weeks
Methoxyethan data exist, but the mg/kg/day
ol data are not
sufficient for
classification
2- Ingestion blood Some positive Rat NOAEL 340 13 weeks
Methoxyethan data exist, but the mg/kg/day
ol data are not
sufficient for
classification
2- Ingestion liver All data are Rat NOAEL 800 13 weeks
Methoxyethan negative mg/kg/day
ol
Aspiration Hazard
Name Value
Hydrotreated Light Petroleum Distillates Aspiration hazard
Solvent-Refined Heavy Paraffinic Petroleum Distillates Aspiration hazard
Distillates (petroleum), solvent-refined light paraffinic Aspiration hazard
Exposure Levels
Refer Section 8.1 Control Parameters of this Safety Data Sheet.
Interactive Effects
Not determined.
12.1. Toxicity
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
Material CAS Number Organism Type Exposure Test endpoint Test result
2- 109-86-4 Bluegill Experimental 96 hours LC50 >9,650 mg/l
Methoxyethano
l
2- 109-86-4 Water flea Experimental 24 hours EC50 >10,000 mg/l
Methoxyethano
l
2- 109-86-4 Green Algae Experimental 72 hours EC50 >100 mg/l
Methoxyethano
l
Chlorothalonil 1897-45-6 Rainbow trout Experimental 96 hours LC50 0.0076 mg/l
Chlorothalonil 1897-45-6 Water flea Experimental 48 hours EC50 0.059 mg/l
Chlorothalonil 1897-45-6 Green Algae Experimental 72 hours EC50 0.0068 mg/l
Distillates 64741-89-5 Rainbow trout Experimental 96 hours LC50 >100 mg/l
(petroleum),
solvent-refined
light paraffinic
Distillates 64741-89-5 Green algae Experimental 96 hours EC50 >100 mg/l
(petroleum),
solvent-refined
light paraffinic
Formaldehyde 50-00-0 Water flea Experimental 48 hours EC50 5.8 mg/l
Formaldehyde 50-00-0 Rainbow trout Experimental 96 hours LC50 1.41 mg/l
Montan-Wax 68476-03-9 Golden Orfe Experimental 48 hours LC50 >500 mg/l
Fatty Acids
Morpholine 110-91-8 Rainbow trout Experimental 96 hours LC50 380 mg/l
Morpholine 110-91-8 Water flea Experimental 48 hours EC50 45 mg/l
Morpholine 110-91-8 Green algae Experimental 96 hours EC50 28 mg/l
2- 109-86-4 Water flea Experimental 21 days NOEC >92 mg/l
Methoxyethano
l
2- 109-86-4 Green algae Experimental 72 hours NOEC 100 mg/l
Methoxyethano
l
Distillates 64741-89-5 Green algae Experimental 96 hours NOEC 100 mg/l
(petroleum),
solvent-refined
light paraffinic
Distillates 64741-89-5 Water flea Experimental 21 days NOEC 1,000 mg/l
(petroleum),
solvent-refined
light paraffinic
Morpholine 110-91-8 Water flea Experimental 21 days NOEC 5 mg/l
Carnuba Wax 8015-86-9 Data not
available or
insufficient for
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classification
Aluminum 66402-68-4 Data not
Silicate available or
insufficient for
classification
Hydrotreated 64742-47-8 Data not
Light available or
Petroleum insufficient for
Distillates classification
Quartz 14808-60-7 Data not
available or
insufficient for
classification
Solvent- 64741-88-4 Data not
Refined Heavy available or
Paraffinic insufficient for
Petroleum classification
Distillates
Tripoli 1317-95-9 Data not
(Crystalline available or
Silica) insufficient for
classification
Material CAS Number Test type Duration Study Type Test result Protocol
2- 109-86-4 Experimental Photolytic half- 2.28 days (t Other methods
Methoxyethano Photolysis life (in air) 1/2)
l
Formaldehyde 50-00-0 Experimental Photolytic half- 3.21 days (t Other methods
Photolysis life (in air) 1/2)
Formaldehyde 50-00-0 Experimental Photolytic half- 1-2 hours (t Other methods
Photolysis life(in water) 1/2)
Morpholine 110-91-8 Modeled Photolytic half- 2.8 hours (t Other methods
Photolysis life (in air) 1/2)
Solvent- 64741-88-4 Data not N/A N/A N/A N/A
Refined Heavy available or
Paraffinic insufficient for
Petroleum classification
Distillates
Hydrotreated 64742-47-8 Data not N/A N/A N/A N/A
Light available or
Petroleum insufficient for
Distillates classification
Aluminum 66402-68-4 Data not N/A N/A N/A N/A
Silicate available or
insufficient for
classification
Quartz 14808-60-7 Data not N/A N/A N/A N/A
available or
insufficient for
classification
Tripoli 1317-95-9 Data not N/A N/A N/A N/A
(Crystalline available or
Silica) insufficient for
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classification
Montan-Wax 68476-03-9 Data not N/A N/A N/A N/A
Fatty Acids available or
insufficient for
classification
Water 7732-18-5 Data not N/A N/A N/A N/A
available or
insufficient for
classification
Distillates 64741-89-5 Experimental 28 days CO2 evolution 22 % weight OECD 301B - Modified
(petroleum), Biodegradation sturm or CO2
solvent-refined
light paraffinic
Chlorothalonil 1897-45-6 Experimental 14 days BOD 0 % weight OECD 301C - MITI
Biodegradation test (I)
Carnuba Wax 8015-86-9 Modeled 28 days BOD 82 % weight OECD 301F -
Biodegradation Manometric
respirometry
Morpholine 110-91-8 Experimental 28 days Dissolv. 93 % weight OECD 301E - Modified
Biodegradation Organic OECD Scre
Carbon Deplet
Formaldehyde 50-00-0 Experimental 28 days BOD 90 % weight OECD 301D - Closed
Biodegradation bottle test
2- 109-86-4 Experimental 14 days BOD 73 % weight OECD 301C - MITI
Methoxyethano Biodegradation test (I)
l
Material CAS Number Test type Duration Study Type Test result Protocol
Distillates 64741-89-5 Data not N/A N/A N/A N/A
(petroleum), available or
solvent-refined insufficient for
light paraffinic classification
Montan-Wax 68476-03-9 Data not N/A N/A N/A N/A
Fatty Acids available or
insufficient for
classification
Solvent- 64741-88-4 Data not N/A N/A N/A N/A
Refined Heavy available or
Paraffinic insufficient for
Petroleum classification
Distillates
Water 7732-18-5 Data not N/A N/A N/A N/A
available or
insufficient for
classification
Quartz 14808-60-7 Data not N/A N/A N/A N/A
available or
insufficient for
classification
Hydrotreated 64742-47-8 Data not N/A N/A N/A N/A
Light available or
Petroleum insufficient for
Distillates classification
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Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during
incineration processes.
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3M Marine 09005, 09006, 09007 Fibreglass Restorer And Wax
Poison Schedule:This product has not been assessed for poisons scheduling as the product is intended for industrial and professional use
only.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Safety Data Sheet or use of
the product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
Greenguard ® is a United States based program. The ‘Low VOC’ reference related to United States Federal and State
regulations exemptions for some solvents.
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