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Poligen®

Application Guide
Polyethylene based waxes,
polymers and emulsions
Oxidized polyethylene homopolymers
Poligen® Wax

Our oxidized polyethylene homopolymers… Poligen® Poligen®


Wax OA 3 Wax OA 6
 exhibit a higher polarity than unmodified Physical Forms Powder Powder
polyethylene waxes although they are still Characterization Hard Hard
highly hydrophobic polymers Food contact approval No Yes

 allow for easy emulsification in aqueous Melting Point [°C] 126 – 133 126 – 133

systems Recrystallization Point [°C] 115 – 119 114 – 119


Dropping Point [°C] 128 – 135 128 – 135
 facilitate some polar interactions in final Hardness [N/mm2] 60 – 70 56 – 66
application
Acid no. [mg KOH/g] 20 – 24 17.5 - 19
 are typically used to prepare wax emulsions Saponif. no. [m KOH/g] 24 - 30 20 - 30
for textile finishing and hard surface care Viscosity, 140 °C [mPas] 4500 6500

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Polyvinylether
Poligen® Wax

Our functionalized hydrophobic polymer…


Poligen® Wax V Flakes
 introduces functional groups (ethers) into
Physical Forms Flakes
the polyethylene chains
Characterization Vinylether
 are especially suitable for wax finishing for Melting Point [°C] 47 - 51
leather, polishes on stone floors and mold Recrystallization Point [°C] Approx. 40
release agents
Dropping Point [°C] 49 - 53

Hardness [N/mm2] 28 - 32

Acid no. [mg KOH/g] 0

Saponif. no. [m KOH/g] 0

Viscosity, 120 °C [mPas] Approx. 180

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Aqueous emulsions (I)
Poligen®

Our oxidized wax aqueous emulsions…

 provide properties of oxidized waxes Poligen® Poligen®


WE 1 WE 6
 represent an easy to use liquid form Characterization Hard Hard

Food contact approval No Yes


 are especially useful in water based
Solid content [%] 34 - 35 33 – 36
systems
Viscosity [ISO cup, 4 mm] 20 - 36 20 – 60
 are available with and without food contact pH value 9 - 10 7.5 – 9.5
approvals
Transmission (LT) Approx. 75 Approx. 65
 are used as part of coating and printing
formulations and for hard surface care

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Aqueous emulsions (II)
Poligen®

Our Montan wax based emulsion…

 has a good buffability


Poligen® MW 2
 is mainly used in hard surface cleaning and
polishing applications Characterization Buffability

Solid content [%] 38 - 42


 is used as mold release agent
Viscosity [ISO cup, 4 mm] Approx. 25

pH value 4.0 – 6.0 (10% in water)

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Aqueous emulsions (III)
Poligen®

Our copolymer based aqueous


emulsions…
Poligen® Poligen®
WE 3 WE 4
 comprise different grades of
Carboxylic Carboxylic
hydrophobic polymers containing Comonomer acid acid
carboxylic acid groups
Solid content [%] 24 - 26 20 - 22
 are free of surfactants and emulsifiers Viscosity
< 85* 25 - 170
[ISO cup, 4 mm]
 convey the specific film forming and pH value 8.5 - 9.5 8.5 - 9.5
surface modifying properties
Transmission (LT) Approx. 90 Approx. 95

 can be used in coatings, adhesives, *: ISO cup, 5 mm


sealants and laminations for protection,
hydrophobization and water repellency

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Test methods

BASF method,
Melting Point DSC (DIN 51007) Viscosity (wax melts)
RotoVisco, 120°C
DIN EN ISO 2431, ISO cup,
Recrystalization Point DSC (DIN 51007) Viscosity (emulsions)
4 mm (5 mm where indicated)
Dropping Point DIN ISO 2176 pH value DIN 19268, 23 °C
Ball hardness, 23 °C
Hardness Transmission BASF method
(Fischer, DIN EN ISO 6507-1)
Acid Number DIN EN ISO 2114 Solid content DIN EN ISO 3251

Saponification Number DIN EN ISO 3681

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Disclaimer

This document, or any answers or information provided herein by BASF, does not constitute a legally binding obligation of BASF. While the descriptions,
designs, data and information contained herein are presented in good faith and believed to be accurate, they are provided for your guidance only. Because
many factors may affect processing or application/use, we recommend that you make tests to determine the suitability of a product for your particular purpose
prior to use. It does not relieve our customers of the obligation to perform a full inspection of the products upon delivery or any other obligation. The claims and
supporting data provided in this publication have not been evaluated for compliance with any jurisdiction’s regulatory requirements and the results reported may
not be generally true under other conditions or in other matrices. Users must evaluate what claims and information are appropriate and comply with a
jurisdiction’s regulatory requirements. NO WARRANTIES OF ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR
INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA, OR INFORMATION MAY BE USED WITHOUT INFRINGING THE
INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA, OR DESIGNS PROVIDED BE
CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE.

® = Registered Trademark of BASF in many countries

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