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Biogas
Biogas is actually a mixture of components in which methane (45%–
75%) and carbon dioxide (25%–50%) dominate, together with water
vapor (1%–5%), nitrogen (0%–5%), and lower amounts of ammonia
and hydrogen sulfide, as well as trace amounts of hydrogen and
carbon monoxide [18].
From: Sustainable Resource Recovery and Zero Waste Approaches, 2019
Related terms:
Anaerobic Digestion, Biomass, Digester, Landfill, Methane, Natural Gas, Sludge,
Standardisation
Biogas Utilization
Biogas has many different applications, as summarized in Fig. 11.6. Biogas can be
directly used for cooking. This is the most common use of biogas in the developing
countries where millions of household digesters are currently in operation.
Researchers at the University of Udayana, Bali, Indonesia, are testing small-scale
biogas-based electricity generation system (1–3 kW) for household/farm
applications in the rural communities of the developing countries. Biogas (after
cleaning for H2S removal) could be used as boiler fuel. For large-scale digester, the
produced biogas is often used for electricity and heat generation using a combined
heat and power (CHP) unit with capacity ranging from several 100 kW to
megawatts. There are several large-scale facilities for biogas upgrading (with
methane content >95% v/v) to obtain a quality equivalent to natural gas to be
injected into gas grid or use as a transportation fuel (e.g., compressed natural gas).
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Biogas
Biogas technology is a complete system in itself with its set objectives (cost-
effective production of energy and soil nutrients), factors such as microbes, plant
design, construction materials, climate, chemical and microbial characteristics of
inputs and the interrelationships among these factors. Biogas is about 20% lighter
than air and has an ignition temperature in the range of 650–750°C. It is an
odorless and colorless gas that burns with clear blue flame similar to that of LPG
gas. Its calorific value is 20MJ/m3 and burns with 60% efficiency in a conventional
biogas stove (http://www.fao.org/sd/EGdirect/EGre0022.htm). High energy yields
were obtained from the production of upgraded biogas used for vehicle refueling
purposes. Comparisons indicate that energy yields from biogas derived from wheat
are twice as high as when wheat is used for ethanol production. As well as
economic and air quality benefits, studies also indicated that using biogas for
transport, CO2 emissions could be reduced on a life cycle basis by between 65 and
85% on current fuels, depending on the feedstock used
(http://www.ngvglobal.com/index.php?option=com-
content&task=view&id=83&Itemid=2&lang=en).
Compressed natural gas (CNG) comes primarily from fossil sources, although
‘biogas’, which is very similar to CNG, is produced from renewable sources. Air
quality benefits are particularly significant compared with heavy-duty diesel
vehicles and it is in these vehicles that CNG tends to be used. CNG engines are
also significantly less noisy than diesel engines. Again, this is a particular benefit
when CNG is used in heavy-duty vehicles
(http://www.defra.gov.uk/ENVIRONMENT/consult/greenfuel/response/03.htm).
Biogas from wheat has the highest energy balance and net energy output per
hectare, particularly when straw is collected and converted into transportation fuel.
Biogas from ley crops and ethanol from wheat have similar energy balances and
net energy output per hectare (about 40 GJ) when the wheat pulp from the ethanol
production is utilized for energy purposes (biogas production). When the wheat
pulp is utilized as fodder and not for biogas production, the energy balance and
net energy output per hectare for the wheat-ethanol alternative are reduced. When
both wheat pulp and straw are employed for biogas production, the net energy
output per hectare will be higher for the wheat-ethanol alternative than for the ley
crop-biogas alternative (http://www.miljolth.se/svenska/publikationer/visaInfo.asp?
ID=).
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Janardhan Bornare, ... R.R. Sonde, in Industrial Wastewater Treatment, Recycling
and Reuse, 2014
Biogas
Biogas is the anaerobic fermentation of organic materials by microorganisms
under controlled conditions. Biogas is a mixture of gasses mainly methane and
carbon dioxide gases that results from anaerobic fermentation of organic matter by
the action of bacteria. Biogas is ranked low in priority in some developing countries
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because of lack of energy policy and there is no plan of the share of biogas of the
total biomass potential.
Huge amounts of organic wastes are generated in rural communities such as
agriculture waste, sludge from municipal treatment plants, and organic waste from
garbage, food processing plants as well as animal manure and dead animals. Table
13.6 shows a sample of types and quantities of organic wastes generated in Egypt.
All these can be considered as a biomass that is organic carbon-based material,
which could be an excellent source for biogas and fertilizer.
Biogas activities in Egypt until now have focused mainly on small scale plants with
a digester volume of 5-50 m3 with a few exceptions such as the Gabel Al-Asfar
Plant located near Cairo, with a total capacity of 1 million cubic meter. The total
energy potential in Egypt of centralized biogas plants with 50 to 500 tons/day input
was estimated to be about 1 million TOE.
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There are no reliable data on the long-term effects on health of exposure to biogas.
The toxic properties of a gas mixture such as biogas cannot be determined. The
physiological effects of the individual substances are known and corresponding
limits have been laid down. When mixed, however, the toxic properties of the
individual substances may decrease or increase. Toxicologists refuse to set limits
for mixtures. Personnel employed at landfills frequently point to cases of
colleagues dying of carcinomas and believe this to result from long-term exposure
to biogas. Such claims have not yet been scientifically proved.
Fire and Explosion Hazards
Methane, an important constituent of biogas, can, when mixed with air, cause fires,
explosions, and fulminations. Within the upper and lower limits of explosion
(between 5% and 15% vol. methane), methane can be detonated. Gas mixtures
below and above the limits of explosion are not explosive but quantities ∼15%
represent a fire hazard. When methane has been mixed with air to the usual ratio
over the surface of the landfill, then there is no immediate danger. Biogas can
collect in shafts, trenches, and cavities to form an explosive atmosphere, which can
then be detonated by gas burn-offs, biogas compressors, open fires or lights, or
hot surfaces such as car or truck exhausts.
There have been many reports of explosions or fulminations at landfills, which
have, however, rarely been considered in the relevant literature. In one case,
explosive biogas was detonated at a distance of 150 m from a gas discharge shaft
and then began to burn in the discharge shaft itself.
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as the ideal approach to incorporate small-scale renewable energy sources to the
main power grid.
Multiple technologies are compared in Table 4.5. As shown, reciprocating engines
have good operational efficiency and are cost competitive, but have low fuel
flexibility, high O&M costs, and high emissions. The cost of the fuel cells that have
been operated with biogas, that is, phosphoric acid and molten carbonate, is still
very high. There has recently been increased interest in the option of combining
AD systems with solid oxide fuel cells (SOFCs) due to their relatively high operating
temperature (nominally 800°C) which makes them more robust to fuel impurities
(Cozzolino et al., 2017; Rayner et al., 2017; Rillo et al., 2017).
Table 4.5. Comparison Between Existing Combined Heat and Power (CHP)
Technologies for Biogas
Sources: EERE, 2017. Fuel Cells. Office of Energy Efficiency & Renewable
Energy; energy.ca.gov., 2017. Vol. 2017, California Energy Commission;
Fuelcells.org., 2017. Fuel Cells 2000, Vol. 2017. http://hfcarchive.org/fuelcells/;
USEPA, 2007. Biomass Combined Heat and Power Catalog of Technologies.
U.S. Environmental Protection Agency.
In a study performed in the United Kingdom, domestic food wastes were collected
and incorporated into a full-scale food waste digester (900 m3 complete mixed tank
reactor), from which biogas was harvested and used to produce electricity using a
195-kW combined heat and power (CHP) unit with an assumed electrical
conversion efficiency of 32% when run at full capacity, and the potential for 53%
recovery of heat. Electricity produced by the CHP unit and imports and exports to
the grid were all metered. The power requirements of the plant were calculated as
follows: CHP generator meter + grid import meter − grid export meter. A portion
of the heat produced by the CHP unit was reincorporated back into the process
(Banks et al., 2011).
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Introduction
Biogas production from organic wastes has technologically advanced in the recent
years; this cost-effective technology has been productive in managing energy
demands, carbon emissions, and environmental pressures. The anaerobic
digestion (AD) process to produce biogas involves many stages with specific
optimum process conditions as explained in the literature [1–3]. The digestion
process requires a consortium of microorganisms working synergistically and
sometimes the feedstock used are difficult to handle; this makes the process a bit
complex. During the digestion process, a negative effect on any of the stages
involved (hydrolysis, fermentation, acetogenesis, and methanogenesis) has a direct
effect on the other and the process can become unsteady or can fail completely [4].
There are a diversity of papers dealing with the pretreatment of feedstock [5–8],
codigestion of various feedstocks [9–13], bioaugmentation with anaerobic enzymes
[14–16], and acclimatization of microorganisms to feedstock [17,18] to stabilize the
digestion process, to reduce the inhibitory effect of harmful compounds, and to
increase the digestion rate, as well as the biogas yield and the digestate quality.
Conventional digestion processes (wet AD) to produce biogas involves the use of a
large volume of water, over 90% of the constituents of the bioreactor is water; the
total solids (TS) content of the feedstock is usually between 0.5% and 15% [19].
This is a major challenge for countries with shortage of water; it is obvious that
there will be competition for water as population increases and industrial
development progresses. Additionally, dewatering of the residue after biogas
production requires high energy consumption and results in loss of nutrients. So
the use of digestate as biofertilizer with less dewatering systems or without
dewatering is inevitable. The use of forest and crop residues with high solid
content (usually between 15% and 50%) is also becoming very attractive due to
their abundance in nature and high energy value. In view of these issues, the dry
AD technology is gaining momentum in both research and industries.
This chapter focuses on dry AD processes for biogas production. It discusses the
importance of the start-up phase and its correlation with the microbial
communities, as well as the major processes involved in solid-based AD systems. It
also addresses current applications in the industry to enhance the performance of
the process and for effective industrial feasibility.
3.7 Conclusion
The biogas production from activated sludge using TH and thermophilic AD was
investigated in this chapter. TH is a well-established technology used as a WAS
pretreatment method. It leads to higher biogas production, although the energy
benefit of AD is relatively natural due to its higher energy demand. The main
energy benefit is connected to improving the dewaterability of the sludge and
reducing the costs of downstream processes. AD following TH should not be
longer than 10–12 days. Protein degradation causes an increase of ammonia,
alkalinity, and pH and does not improve biogas generation at longer SRTs.
Thermophilic digestion is preferred over classical mesophilic AD, mainly due to
higher biogas production at shorter SRTs and faster VS degradation. Moreover,
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digestate meets the EPA's class A requirements. Because thermophilic AD is very
sensitive to the fluctuation of operating parameters and the quality of rejected
water is poor, additional research is required to address those problems.
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treated, respectively (Kalogo and Monteith, 2008; Goel et al., 2004). Xie et al. (2007)
studied the effectiveness of ultrasonic treatment at a full-scale sludge digester in
Singapore. The anaerobic digesters (4500 m3 volume, sludge retention time (SRT),
30 days) were fed sonicated sludge (20 kHz; flow rate, 200 m3/day). Over the 6-
month study, the experimental system consistently produced a minimum of
200 m3/day more gas than the control digester (methane production increased by
45%). Hogan et al. (2004) studied the feasibility of Sonix technology (20 kHz) for
the pretreatment of WAS before anaerobic digestion at the demonstration and full-
scale plants (Avonmouth, United Kingdom and Orange County, California, United
States). They reported that Sonix technology was capable of improving biogas
production (up to a 50% increase) and has a relatively short payback period of
2 years. The German company Hielscher (up to 48 kW) claimed to improve biogas
yield by 25%. Another German company, Sonotronic, claimed that the integration
of a high-output ultrasonic reactor (20 kHz) into existing biogas production
systems increased biogas production (up to 50%) and the methane content of the
biogas (to 70% of CH4). Barber (2005) reported the outcomes of several full-scale
part-stream ultrasound systems (Germany, Austria, Switzerland, Italy, and Japan).
He observed a 22% increase in biogas production and VS reduction, and up to 7%
improvement in sludge dewatering. The energy and mass balance study of the
anaerobic digester (1200 m3, 20 days SRT, flow rate 200 m3/day, and 5% DS dry
solids (DS)), treating the sludge sonicated at 2.5 W/m2/K, shows that more energy
is generated than consumed; ie, 1 kW of applied energy will generate seven times
more electrical energy after losses. Moreover, the researchers suggested that a
typical payback period for a full-scale ultrasound installation is 2–3 years.
Biogas is an excellent fuel for a large number of applications and it can be used
more or less in all applications that were developed for natural gas. The biogas can
be used for the production of heat and steam or electricity
generation/cogeneration, as vehicle fuel, and for the production of chemicals.
Biogas can be used as a fuel to generate electrical power using engine generators,
turbines, and fuel cells and as a fuel in gas vehicles (Bridger et al., 1962). An
analysis accomplished by the Combined Heat and Power (CHP) partnership
observed that if CHP were installed at all 544 wastewater treatment facilities in the
United States (influent flow rates >5 million gallons/day and that operate anaerobic
digesters), approximately 340 MW (340,000 kWh) of electricity could be generated,
which is enough to power 261,000 homes (NACWA, 2010). According to the US
Environmental Protection Agency, 2.3 million MT of carbon dioxide emissions
annually (equivalent to 430,000 cars) could be offset if existing WWTP (with
capacity over 5 million gallons/day) that employ anaerobic digestion installed
energy recovery facilities. Harnessing the energy from biosolids offers energy
security, reduced dependence on fossil fuels, and lowered greenhouse gas
emissions (NACWA, 2010).
In several Swedish cities, use of sludge-derived biogas as biofuel in transportation
sector is a well-established practice. The Henriksdal treatment plant produces and
sells biogas to Stockholm's bus company. At least 30 buses in Stockholm are
running on biogas (Salter, 2006). In the United States, various well-established
energy recovery techniques are in use, including electricity and mechanical energy
production and heat recovery through biogas generated from anaerobic digestion
of waste sludge (Kalogo and Monteith, 2008). The use of methane as a source of
hydrogen to generate energy with liquefied carbonate fuel has been effectively
exhibited at King County, Washington's South treatment plant (Parry et al., 2004).
Co-digestion of grease (from restaurant trap haulers) with sewage sludge is
practiced in Watsonville, California, to improve biogas yield by over 50% (Cockrell,
2007). Grease is composed of energy-rich compounds such as fats, carbohydrates,
and sugars (Bailey, 2007); thus, it is an appropriate substrate for biogas production
during anaerobic digestion of sludge. The Sewerage Bureau of Tokyo Metropolitan
Government (SBTMG) implemented several projects including the use of
dewatered sewage sludge to produce fuel charcoal and sold for thermal power
generation (Oda, 2007) and for electricity generation with a gas engine using
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syngas produced by the pyrolysis of sewage sludge (Takahashi, 2007). In China,
biogas harvesting from sewage sludge is a common way to recover resources. The
annual methane generation from all feedstocks including sewage sludge was
assessed at 720 million cubic meters (Aalbers, 1999). In the United Kingdom, a new
program for energy recovery was proposed by the government, including the
generation of 20% of electricity from renewable sources by 2020 (Trumper, 2007).
In 2005, 10.8% and 4.2% of all UK renewable energy was recovered by combustion
and biogas production, respectively.
Recommended publications:
Bioresource Technology
Journal
Water Research
Journal
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