Chemistry 1010 Final Practice Exam Chapters 11, 12, and 13 Instructions: ‘This exam should have 33 questions. You are allowed to use a pencil and a non-networking capable scientific calculator. ‘Additional information and a periodic table should follow this page. Information: tere t 11900,000,000.000. 10" 1 terameter (Tm) = 1 ton meters go OG 1,000,600,000. 10" 1 gigaater (Gm) = 1 bition meters meg 1,900,000. wo 1 megameter (Min) ~ 1 milion meters | bo k 1000, 1 ‘hllometer fr) — 1 thousend meters | pect 100. 0 1 hectomater thm) = 1 hundred meters dei. ds 10 10! 1 dekareter (dam) ~ ten meters | roprefix = ii ow 1 meter tn) = 4 meter | dec. 6 ay 10 1 docimetor (dm) = 1 toth ofa metor | cone oor 10? 1 centimeter fm) = 1 hunctedth of ameter | eit ” 2.001 10 1 miltmeter (mm) ~ 1 thousandth of» moter | mice 2.000 001 10+ 1 micrometer (um) = 1 milion of 9 meter | nano on 12.000 000001 10? 1 nanometer fam) = 1 bilicnth ofa meter [pe P ‘2.000000 000001 49-8 1 picometer om) = 1 worth af a meter TABLE 9.1 __ Selected Bond Energies ‘BOND ENERGY BOND ENERGY BOND (K/MOLE) BOND (KJMOLE) H-H 436 N-N 159 H-C a4 0-0 138 H-N 389 cl-cl 243 H-0 464 c=0 803 H-F 569 N=O 631 H-cl 431 498 c-0 351 837 c-c 347, 946 1 mole = Avogadro's number = 6.02 x 10% M= moles of solute/L of solution [HsO* JOH] = Kw = 1 x 10" pH = +log{Hs0"] = ~log[H"]A36_ Appendix D Useful Conversion Factors Length ‘unit: meter (mm) 0.621 37 mi 1ks 1 mi= 5280 ft 1.6093 km. 1 m= 10936 yd Lin, = 2.54 em (exactly) Jem = 039370 in. 1A=10-%m Inm=10%m Mass. Sunt: kilograms (kg) 2046 Tl Temperature St unit: Kelvin (K) OK=-273.15°C = -459.67°F K=°C #27315 5 CF -22) 2ecysse Fundamental Constants Avogadro's number = 602% 102 = 1 mole Mass of electron, mt, = 9.109 390% 10° kg = 1/1836 of mass of H Mass of neutron, 1, = 1.674 929 X 10°27 ky mass of H 1.672 623 10°” ky = mass of H Planck’s constant, t= 6.626101}. s Speed of light, c= 3.00% 108 m/s Mass of proton, my Energy ‘Sl unit: Joule Q) 239.01 cal 39 keal Veal = 4.184] Pressure SI unit: Pascal (Pa) Latm= 101,325 Pa = 760 mm Hg (torr) =29.9in. He = 14.696 Ib/in? Volume : St sit: cubic meter (mn?) 1L=107 m? 1dm? 10am’ 1.057 gt Lgal=4 qt = 3.78541. 1 mL = 0.0339 fl oz mL 106m TinS = 16.4 om?{uouoj 349 Jo adoros, gens sow ay so!eau JoquinYajoum 2x22: pauynuon akon [~] squawiaja ann>eoIpel 10} sassews 3ywory ‘siUN sseu >1Wore UI passaidxa ‘aoeyins s,yuieg ay) Uo a2UepuNge >Idoxos) kq paBeiane aie sassew Woy jeauuon | “Dvd Aq maynas sapun ‘uonedyqnd sin jo Proweraw |_|) u pasodosd e sey | 1uauiaR, eon |_| wy \s2p1unay a "3 sa ug Pa IN 3 " z a 6 8 2 dnoip SIUDWOTA IYI JO BIqRL OpoLadAppendix D A35 List of the Elements ‘ATOMIC ‘ATOMIC ‘ATOMIC ‘ATOMIC NAME syMBot NuMBER WeiGhT NAME SYMBOL__ NUMBER WEIGHT ‘Actinium Ae 8 227.028 Manganese Mo Fy 54.938 ‘Aluminum Al 13 26.982 Meitnerium Me 109 26 Americium Am 95 243, Mendelevium = Md 101 259 Antimony Sb 3 121.76 Mercury Hg 80 200.59 ‘Argon Ar 18 39.948 ‘Molybdenum Mo a2 95.94 Arsenic As 33 74.922 Neodymium Nd 60 144.28 Astatine At 85 210 Neon Ne 10 20.180 Barium Ba 56 137.327 ‘Neptunium Np 3 237 Berkelium 8k 7 247 Nickel Ni 28 58.69 Beryllium Be 4 912 Niobium Nb 4 92.906 Bismuth 8 83 208.980, Nitrogen N 7 14.007 Bohrium Bh 107 289 Nobeliumn No 102 239 Boron 8 5 10811 ‘Osmium Os % 190.23, Bromine 8 35 79.908 ‘Oxygen ° a 15.999 Cadmium cd 43 12411 Palladium Pd 46 106.42 Calcium Ca 20 40.078 Phosphorus Pp 45 30.974 Californium cr 98 251 Platinum Pt 78 195.08 Carbon c 6 12011 Plutonium Pu 94 244 Cerium Ce 58 140.15 Polonium Po 84 209 Cesium cs 55 132.905 Potassium kK 9 39.098 Chlorine cl 7 35.453, Praseodymium = Pr 39 140.908 Chromium cr ca 51.998 romathium Pm 4 145 Cobalt Co a 58.933, Protactinium Po an 231.038 Copernicium G2 285 Radium Re 88 226.025 Copper cu 2 63.546 Radon Ra 86 222 Curiam, cm 9% 207 Rhenium Re 78 486.207 Darmstactium = Ds 110 281 Rhodium Rh 45 102.908 Dubnium Db 105 268. Roentgenium Rg nt 280 Dysprosium Dy 66 1625 Rubidium Rb 37 85.468, |. Einsteinium & 9 253 Ruthenium Ru 44 4101.07 Erbium & 68 167.26 Rutherfordium RF 108 265 Eu 3 151.964 Samarium ‘Sm 62 150.36 Fm 100 237 Scandium Se 2 42.956 Flerovium A 114 289 Seaborgium Sg 106 270 Fluorine F 9 18.998 Selenium Se 34 78.96 Francium Fe 87 223 Silicon si 14 28.086 Gadolinium Gd 6a 197.25 Silver Ag a7 107.868 Gallium Ga 31 69.123 Sodium Na " 22.990 Germanium Ge 32 7264 Strontium se 38 87.62 Gold Au 7” 196.967 Sulfur s 16 32.066 Hafnium HF 2 178.49 Tentalum Te na 190.988 Hassium Hs 108 a Technetium Te 3 38 Helium He 2 4.003 Tellurium te 52 127.60 Holmium Ho a 164.93 Terbium Tb 65 158.925 Hydrogen H 1 1.0079 Thallium m Bi 208.383 Indium in 9 114.82 Thorium Th 90 232.038 Iodine 1 53 126.905 Thaliu Tm “9 168.934 leidivm ie 7 192.22 Tin Sa 50 1871 Iron Fe % 55.845 Titanium Ti 22 47.88 Keypton Ke 36 83.8 Tungsten w 74 183.84 Lanthanum la 7 138.906 Uranium u 2 238.029 Laweencium Le 103 256 Vanadium v 23 50.942 Lead Pb 82 207.2 Xenon Xe 54 131.29 Lithium ui 3 6941 Yiterbium Yb 70 173.04 Livaemerium Wy 116 293 Yetrium ¥ 39 88.906 Lutetium tu n 174.967 Zine Zn 30 65.39 Magnesium Mg 12 24.305 Zirconium ze 40 91.224Final Practice Exam (Chapters 11, 12, and 13) MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) What is a reduction? a) A) the gain of electrons B) the loss of an electron from the valence shell ©) the reaction of oxygen with a reductant ) the formation of red compounds in the presence of an oxidant E) the reduction of the number of electrons © oO © o 2) In the above diagram, which atom is oxidized, the darker colored atom or the lighter colored atom? 2) ‘A) Both of the atoms are oxidized. B) Neither of the atoms is oxidized, C) Only the darker colored atom is oxidized, D) Only the lighter colored atom is oxidized. 3) How many electrons are gained or lost in the following, half-reaction? 3) 2Na-2Na* A) 2 electrons are lost B) 2electrons are gained ©) 12electron is gained 1D) 4 electrons are gained B) 1/2 electron is lost 4) Which of the following materials is most likely to act as an oxidizing agent? » ayer B) Nat Oc D)Na B) both A and B 5) What might the relationship be between an element's ionization energy and its ability to behave as 5) an oxidizing agent? |A) As the ionization energy increases, the ability of an element to act as an oxidizing agent decreases. B) As the ionization energy increases, the ability of an element to act as an oxidizing agent stays the same. ©) As the ionization energy increases, the ability of an element to act as an oxidizing agent D) none of the above6) What element is behaves as the oxidizing agent in the following equation and what element 6) behaves as the reducing agent? sn2*42.Ag-Sn42.Ag ‘A) The tin ion, Sn2, is the reducing agent while silver, Ag, is the oxidizing agent. 5) The tin, Sn isthe oxidizing agent while silverion,Agy isthe reducing agent. ) The tin ion, Sn2, isthe oxidizing agent while silver, Ag, isthe reducing agent. 1D) The tin, Sn, isthe reducing agent while silver ion, Ag; isthe oxidizing agent. 7) The general chemical equation for photosynthesis is shown below. Through this reaction is the 2 carbon oxidized or reduced? How can you tell? 6 COpz + 6 HO ~CeH1206 + 6 02 ‘A) Oxidized, since carbon is in the +4 oxidation state in CO but in the 46 oxidation state in the product, C5H120¢, glucose. 8) Reduced, since in carbon dioxide there are two oxygen atoms for every one carbon but within the product, CgH120g, glucose), there is only one oxygen for every one carbon. ©) Neither, since carbon does not change its oxidation state and is neither oxidized nor reduced, D) Both, since the carbon atoms within the glucose molecules display two different charge states. 8) The following set of redox reactions takes place as shown. 8) Container A Container B Fe ~Fe2* + 2e~ Cu2* + 2e- Cu Ifyou had two containers filled with the ion solution described above with a wire connecting a piece of iron (in container A) and a piece of copper (in container B) and a salt-bridge connecting the {wo containers, which way do the positive ions in the salt-bridge flow? AA) The ions only move in the containers they originate in 8) The positive ions flow from container A to container B ) There is no flow of positive ions in the salt-bridge ) The positive ions flow back and forth between the two containers, E) The positive ions flow from container B to container A. 9) Ina battery, the following two oxidation-reduction reactions are taking place: » xn A: Zn = Zn2+ + 2e~ xn B: 2 NHg* + 207 -2 NHg + Hp Which reaction is taking place at the anode? Ayn A B) ren ) Both reactions are happening at the electrode. D) The reaction takes place at the electrode, not the anode. E) Both reactions are happening at both the anode and cathode.10) Ina battery, the following two oxidation-reduction reactions are taking place: rm A: Zn+2OH> -ZnO+ HO +2e~ van B: 2 MnOp + F190 + 2e- ~ MingO3 + 2 OH What is undergoing oxidation? A) MnO B) OH QZn0 D) H20 E)Zn 11) A chemical equation for the combustion of propane, C3Hg, is shown below. Through this reaction is the carbon oxidized or reduced? CaHg + 502 = 3CO) + 4F0 A) The carbon is reduced. B) The carbon is oxidized. C) Some of the carbons are oxidized while others are reduced. D) The carbon is neither oxidized nor reduced. 12) What would the formula be for the following stick model? oO A) C5H5, B) Colt2 © CsHi0 D) Celio E) none of the above SSS a b c d A)bande B)aandb C)aande D)bandd ) none of the above 10) 1) 12) 13)14) Which of the following two stick structures are different conformations of the same molecule? Ao AW A a b © a Ajaandd B)aandc C)bandd D) bande E) none of the above 15) Which bond would you rotate around to generate the structure on the right? 7 Aja Bb Oc D)d E) none of the above 16) Which ofthe following molecules would probably be isolated closest tothe top ofa fracionating tower ata refinery? A) CaHis B) CagHg2 ©) CaHio 1D) CogHa2 E) CioH2 17) How many structural isomers are there for hydrocarbons having the molecular formula CqHjg? A)none B) one Qwwo D) three 18) Which number set identifies the longest chain of carbons in the following structure? A)9,8, 7, 6,5,3,2,1 B) 9,8, 7, 6,5, 10, 11 ©)1,2,3,5,10,11,6,7,8,9 D)9,8,7,12,6,5,3,.2.1 a » c 19) Which ofthe above structures is 2,2, 4-trimethylpentane? Aja Bb oe D) None ofthe above M4) 15) 16) 17) 18) 19)AVA ho 20) Which of the above sections of this molecule would be considered a saturated portion of the 20) molecule? Aja B)b Oc D)aandb E) all of the above 21) Correctly identify the following functional groups in this organic moleculeamide, ester, ketone, 21) ether, alcohol, aldehyde, amine. amide, 4= ester, 7 = amine, 8 = ether amide, 6 = aldehyde, 7 = amine, 8 = ether C)1 = ether, 3= ester, 6 = aldehyde, 9 = alcohol D) 1 =ester, 5 = alcohol, 8 = ether, 9 = ketone 22) Which of the monomers below would be used to make the following polymer? 22) ~o-G—o-G CH, CH, A) HyC=CH—CH-C=CH-CH3 B) HyC=CH—CH3 (©) HpC-CH2—CH3 D) HyC=CH B) none of the above23) The cell nucleus contains __. 2) A) plasma B) the cytoplasm ©) genetic material D) organelles E) cell walls 24) The most abundant organic compound on Earth is 24) A) silicon dioxide B) cellulose DNA D) water 25) Glycogen is most structurally similar to 25) ‘A) cellulose B) chitin C) amylose D) pectin B) amylopectin 26) Which ofthe following polysaccharides is indigestible by humans but digestible by microorganisms 26) that live in the digestive tracks of termites? A) glycogen B) cellulose ©) starch D) triglycerides B) sucrose 27) What is one physical property that readily distinguishes lipids from other biological molecules? 27) __ A) Lipids are readily oxidized. B) Lipids have very high melting points. ©) Lipids are insoluble in water. D) Lipids form water soluble positive ions, 28) If you were to compare the synthesis of fats with the synthesis of polymers, which type of polymer 28) ‘would the synthesis be most similar to? ‘A) condensation polymers B) low density polyethylene ©) high density polyethylene D) addition polymers 29) Two proteins joining together to form a larger protein complex describes a 29) ‘A) primary structure B) secondary structure ©) tertiary structure 1D) quatemary structure 30) Which of the following is NOT a matched pair of: a protein's structural level name and an example 30) of that level? A) primary structure ~ sequence of amino acids B) quaternary structure ~ separate proteins joining to form a larger complex C) tertiary structure ~ short chain portions fold into pleated sheet D) secondary structure ~ parts of chain wrap into an alpha helix31) What functional groups are found in all amino acids? 31) A) phenols and amines B) amines and carboxylic acids ©) aminos and acids 1D) ketones and aldehydes ) alcohols and amides 32) What is the functional group that links amino acids together to form proteins? 32) A) ahydrocarbon B) an amide C)anamine D) anether E) acarboxylate 33) What would be the complimentary strand to the following sequence of DNA? 33) GATTACA A) CTAATGT 8) AGCCGTG ©) ACATTAG Dp) Greccca E) GATTACAAnswer Key ‘Testname: CHEM 1010 FINAL PRACTICE EXAM DA ac aA ac 5c oc 7B 8)B DES 10)E 1B 12)B 1) E 14) 15)B 16)c We 18) 19)B 20)C 21)B 22)B 23)¢ 2B 25)E 26)B 2c 28) A 29D 30)c 3B 32)B 33) A