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Article history: This paper reports of a comprehensive study on the durability properties of concrete containing polypro-
Received 22 February 2010 pylene fiber and fly ash. Properties studied include unit weight and workability of fresh concrete, and
Accepted 9 July 2010 compressive strength, modulus of elasticity, porosity, water absorption, sorptivity coefficient, drying
Available online 14 July 2010
shrinkage and freeze–thaw resistance of hardened concrete. Fly ash content used in concrete mixture
was 0%, 15% and 30% in mass basis, and fiber volume fraction was 0%, 0.05%, 0.10% and 0.20% in volume
basis.
The laboratory results showed that inclusion of fly ash improves; however, polypropylene fiber
decreases the workability of concrete. Moreover, polypropylene fiber addition, either into Portland
cement concrete or fly ash concrete, did not improve the compressive strength and elastic modulus.
The positive interactions between polypropylene fibers and fly ash lead to the lowest drying shrinkage
of fibrous concrete with fly ash. Freeze–thaw resistance of polypropylene fiber concrete was found to
slightly increase when compared to concrete without fibers. Moreover, fly ash increased the freeze–thaw
resistance more than the polypropylene fibers did.
Ó 2010 Elsevier Ltd. All rights reserved.
0261-3069/$ - see front matter Ó 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.matdes.2010.07.011
O. Karahan, C.D. Atisß / Materials and Design 32 (2011) 1044–1049 1045
crete studied. This study is a part of PhD thesis carried out at Table 3
Cukurova University [20,21]. Concrete compositions for a cubic meter.
Table 4
Fresh concrete properties results.
No. Density (kg/m3) V–B (s) Slump (cm) No. Density (kg/m3) V–B (s) Slump (cm) No. Density (kg/m3) V–B (s) Slump (cm)
A1 2540 6.0 17 B1 2519 3.1 18 C1 2492 2.5 19
A2 2533 7.0 17 B2 2507 5.6 18 C2 2489 4.9 19
A3 2524 8.0 16 B3 2501 6.5 16 C3 2486 5.6 16
A4 2513 10.0 14 B4 2492 7.8 15 C4 2480 6.7 15
were slightly lower than that of concrete without fibers for each strength by 17% and 30% for 15% and 30% fly ash replacement ratio,
group. It also shows that as the fly ash and polypropylene fiber respectively.
content increased in concrete the unit weight reduced. These In this work, the modulus of elasticity, which is also called se-
reductions were attributed to the difference between the specific cant modulus, is taken as the slope of the chord from the origin
gravities of the fly ash and polypropylene fibers. This finding is in to some arbitrary point on the stress–strain curve. The secant mod-
line with the published literature. The laboratory result of Han ulus calculated in this study is for 40% of the maximum stress. The
et al. [31] showed that the use of polypropylene fiber in concrete results are given in Table 5. The elasticity modulus of the concrete
result with little decrease in unit weight. Results of Yıldırım [32] containing 15% and 30% fly ash were comparable with the elasticity
also supported this conclusion. modulus of control Portland cement concrete at 28 days. Neverthe-
Table 4 also shows that inclusion of polypropylene fiber in fresh less, there is no clear indication of significant effect of fly ash on the
concrete increases V–B time and reduces slump values. Moreover, modulus of elasticity of concrete. Elastic modulus of concrete con-
increase in the fiber content causes additional increase in V–B time taining 0.05% polypropylene is slightly higher than the elastic
and reduce slump values. Therefore, it can be concluded that inclu- modulus of concrete without fibers. Addition of 0.10% and 0.20%
sion of polypropylene fiber reduced workability; increase in fiber polypropylene fibers not only did not improve the values of mod-
content dosage additionally reduces workability. However, in- ulus of elasticity but also reduced it.
crease in fly ash content additionally improves workability of fresh Puertas et al. [38], Choi and Yuan [3], Alhozaimy et al. [39],
fiber-reinforced concrete. Huang [11], Salih and Al-Azaawee [34], Zhang et al. [40] agreed
Mostoufinezhad and Hatami [33], Salih and Al-Azaawee [34], that incorporating of polypropylene fibers in concrete does
Aulia [35], Raghavan et al. [36] reported that the use of polypropyl- not affect positively the compressive strength and modulus of
ene fiber in concrete made the mixture more harsh and lowered elasticity.
the workability.
The comparisons made between V–B time and slump value
workability’s, show that V–B time measurement is more appropri- 3.3. Porosity and water absorption
ate than the slump value measurement as an indicator of the work-
ability of fresh fiber-reinforced concrete. Porosity and water absorption of the concretes are shown in
Table 6. The polypropylene fiber reinforced material with the
inclusion of the fly ash showed the most high percentage of poros-
3.2. Compressive strength and modulus of elasticity ity and water absorption. Porosity and water absorption values in-
creased with the increase of fly ash and fiber contents for all
Compressive strength test results are given in Table 5. Compres- concrete mixtures. Huang [9,11] and Aulia [35] who studied on fi-
sive strength decreased with the increase of fly ash. In the all fiber brous mixture using polypropylene, discussed that the amount of
content groups, slight reductions in compressive strength can be large pores increased with the addition of polypropylene fiber.
observed with the addition of polypropylene fiber. This can be ex- The porosity decreases with paralleling the water absorption
plained by the redistribution of void structure due to the inclusion development for all concrete with and without fly ash and fibers.
of fiber, and the presence of weak interfacial bonds between the fi- There was a close relationship between the porosity and water
ber and cement-fly ash grains [37]. The presence of fly ash, when absorption that water absorption value increases as the porosity
compared with plain concrete, decreased the average compressive value increases.
Table 5
Compressive strength and modulus of elasticity results.
No. Comp. strength Elastic modulus No. Comp. strength Elastic modulus No. Comp. strength Elastic modulus
(MPa) (GPa) (MPa) (GPa) (MPa) (GPa)
A1 63.4 37.9 B1 52.9 37.5 C1 45.3 36.8
A2 64.9 39.0 B2 52.0 39.4 C2 43.0 37.1
A3 62.2 37.2 B3 53.6 37.3 C3 42.4 34.2
A4 61.5 36.7 B4 49.5 37.2 C4 44.3 35.3
Table 6
Porosity and water absorption results.
No. Porosity (%) Absorption (%) No. Porosity (%) Absorption (%) No. Porosity (%) Absorption (%)
A1 7.09 2.86 B1 7.77 3.17 C1 8.54 3.53
A2 7.51 3.04 B2 8.53 3.52 C2 8.91 3.69
A3 8.28 3.38 B3 8.79 3.63 C3 9.07 3.77
A4 8.97 3.67 B4 9.03 3.76 C4 9.09 3.76
O. Karahan, C.D. Atisß / Materials and Design 32 (2011) 1044–1049 1047
sorptivity
pffiffi coefficient, Q/A was plotted against the square root of 0.05
time ( t ), then, k was calculated
pffiffi from the slope of the linear rela-
0.04
tion between Q/A and t [41]. Sorptivity coefficient results were
given in Table 7. Table 7 shows that the addition of fly ash and poly- 0.03 0.00%
propylene fiber to concrete significantly increases the sorptivity 0.02 0.05%
coefficient. Influence of addition of fly ash on sorptivity coefficient 0.10%
is found to be more than the addition of polypropylene fibers in 0.01 0.20%
concrete. 0
0 30 60 90 120 150 180 210
3.5. Drying shrinkage Time (Day)
The results of drying shrinkage or length change of 0%, 15% and Fig. 3. Shrinkage of fiber reinforced 30% fly ash concrete versus time.
30% fly ash concrete samples containing 0%, 0.05%, 0.10% and 0.20%
polypropylene fibers are presented in Figs. 1–3, respectively. These
figures show that addition of polypropylene fibers in concrete or increasing the percentage of volume fraction of fiber. Kırca and Sa-
fly ash concrete reduces drying shrinkage considerably. Malhotra hin [44] supported this finding and reported that the use of poly-
et al. [42] concluded that polypropylene fiber reinforced high vol- propylene restrained the movements of micro level in mortar by
ume fly ash concrete has very low drying shrinkage property. Liu bridging and stitching the fine cracks.
et al. [43] and Salih and Al-Azaawee [34] stated that polypropylene Drying shrinkage values of concrete studied at 210 days, regard-
fiber mixed into cement mortar decreased its dry-shrinkage. They less of polypropylene fiber and fly ash content, were presented in
concluded that the reduction in drying shrinkage increases with Table 8. Table 8 shows that the maximum drying shrinkage oc-
curred in Portland cement concrete mixture. Table 8 also shows
that fly ash concrete without fiber shrank less than that of counter
Table 7 part Portland cement concrete mixture. On the basis of 210 days
Sorptivity coefficient results.
drying shrinkage, when compared to Portland cement control mix-
No. Sorptivity No. Sorptivity No. Sorptivity ture, concrete mixture that contains 0.05%, 0.10% and 0.20% poly-
(103 cm/sn1/2) (103 cm/sn1/2) (103 cm/sn1/2) propylene fiber result with 5%, 13% and 17% reductions in drying
A1 0.21 B1 0.42 C1 0.51 shrinkage. Similarly concrete mixture that containing 15% fly ash
A2 0.22 B2 0.35 C2 0.53 and 0.05%, 0.10%, 0.20% polypropylene fiber, result with 6%, 8%
A3 0.27 B3 0.40 C3 0.52
and 15% reduction in drying shrinkage when compared to counter
A4 0.29 B4 0.47 C4 0.56
part fly ash concrete made without polypropylene fiber, respec-
1048 O. Karahan, C.D. Atisß / Materials and Design 32 (2011) 1044–1049
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