xr ~ 2 HOA HU'U COA Blén sogn: GS. TS. Phan Thanh Son Nam Phy trach mén hoc: TS. Lé Va Ha BM Héa hiru co, Khoa Kg thuat héa hoc, ‘Trréng Dai hoc Bach Khoa - BHQG TRHCM Phong 211 B2 DT: 38647256 ext. 5681 Email: lvha@hemutedu.vn ‘DOC TEN ALKANES Ten goi IUPAC cia olkanes mach thing (nralkones) Number Number Number of carbon ofearbon Name of eatbon Name 7 Meters 17 Undecne 21 Heniconne 2 Ethane’ 12 Dodecane 32. —Dcorane 3 Propane 12 Prdecne 33. Pcosane S Fentane 18 Pentadecane 30 Tvlacontane Hen 1g Hexedecane 31 Hentnacontane 7 Heotane 17 Heptadecane 32. Dotracontane 3 Gciane’ 18 Oetadecane 20 Tetracontane 9 Noname 19. Nonsdacone 60 Pertocortane 10 beans 20 Keorane’ "100 Hectane CHUONG 4 - ALKANES \ ined spc ors ses re oN ign er an " OC TEN CAC NHOM ALKYL co ic i cet aig mntat ce ee Senos CHER CHyCACH BOC TEN ALKANES PHAN NHANH Aemethyloctane 4. Chon mgeh e6 niu c mnde “PPE 2, Binh b sa cho Cena ce nh tb 898 thir ttng 96 thirty ahs nit 3. Si-dung tdp abu ng (2), (9), tote (4) dt tube tbc nent ‘eq nhau 88 ch 9b long ahem 38 “4. -Nnom thé ub cng wn vet en mn chic Cc hom tn due ei th theo th alphabet Abu nad {eis sec, edge bb qua nung io, neo, cycle vin dine tinh) A thgeaene METHANE - NGUYEN LIEU TIEM NANG ‘CH, [a thanh phan chinh trong natural gas, methane hydrate (nhién ligu héa thach nhung tre lugng déi dao) va biogas (san xudt duc tly biomass, rdc thai sinh hoc) Formsente NZ Ld bd ‘ature yor Nyswcaton file production an ALKANES TRONG TY’ NHIEN natural gas C14 ozone cH Dau me - petroleum veces can (hen igure jet fuel thachdang Crenastt heating ol, 18.25 dan can kit) diesel ol lubricants, asphalt heating . ‘lement TONG HOP ALKANES Tur ede hydrocarbon khéng no mach he Phan ong cong Hs Xie te: PUG, PAC, M (ee de Raney) > Cong ku cis feelTONG HOP ALKANES ‘To ede hydrocarbon khéng no mach hé Phan mg cng Hy ae the: PUC, PAI, NI ade tHe Raney) > Céng auc cucuscucn, 2, cHenc Dbutene | PIE ane oh chy, cH.C=cH, cH,cHCH, 2methytpropene PY 2mathyprepane CH,CH.O=CH pug” CH:CH.CH= CHS ee> CH/CHCHCH alkyne alkene ‘alkane TONG HOP ALKANES TORK Pin ng Wurtz, Xe the: Na CH,CH,C + BECH;CH;CHS @Téng hop alkanes abi xing © Chip dung voi alky bromides va iodides © 86% voi nhtmng alkanes khing abi ximg s@ di kém nhang alkanes khc > 6 chon loc thép. @ Ngosira cn cb sin pdm phu alkenes (ich HX) Na > CH:CH,CH, CH,CH,CHy, TONG HOP ALKANES ‘To aldehydes va ketones Pin dng cong H, ete: Zig + HCY HHH, + OFF Ang) HELA. CHACHACHs 5 “lemmrensen ° redlcton R-CCHCH, Hatt HOS. RCHLCHCH, ‘eduction TONG HOP ALKANES. TORK Phin ong Corey House Li crer.cror 4. cren.crs (ergercHy,cats Texan Segara m my ban reagent Benen @R,CuLI+RX> RF @ Téng hgp duoc alkanes bét 46 ximg tir aly bromides va iodiHOAT TINH CUA ALKANES + Alkanes chi c6 lién k8t « bonds +B am dign cia C va H xdp xinhau + Phan tir gin nhw khong phan cue > ai lve kém vai tac nha ai ‘nhan va al ign tir > Alkanes rét bén va d@ hoat dong héa hoc rét thép > Ghi phan mg véi nhumg chét oxi héa man nh OF, Ch, Bry, HNO, HALOGEN HOA ALKANES ‘Buoe 2: Phat rién mach ‘Buoe 3: Bong macn HALOGEN HOA ALKANES + Tao thanh dn xudt halogen va HX + Theo co ché ge ty do (edn chiéu sang hode gia nhigt) Phan ing chung cH ch My cas ner ‘lit Buse 1: Khoi mao DQ CHON LOC SAN PHAM a 2 I CH,CH,CH,CH, “Ps CHCHSCHsCHsCI + CHsCHSCHCHs hv expected= 60% expect experimental = 29% experimental I + cHCH ciel expected=10% expected= 90% ‘experimental= 36% experimental =64% > Wurtion thé @H gin véi C béc cao hon .DO CHON LOC SAN PHAM Phan img thé ua Br, dc bigt wu tién cho H tal C bac cao, ‘BG chon ge Cl, vét H tai Cl) > Cf) > CC) theo thirty: 50> 3.8 >4 Trong kh Br, ta: 1600> 82 >4 gh gt oh ge engcncncicn, 8. engenencen HOA HOC LAP THE CUA PHAN UNG. cnc "Vix tatogen bt hn cng ted Oo hai wrong! ‘Vi dy 4: San pdm chira 1 C*-x CHCHLCHCH + Be PS cHcHLFCH + HBr be SP lamgthén hyp racemic “ ~ =efp dBng phn aéiquang Br cu.ci,—L-cH, + cu,cH,— cr, Br 4 KHA NANG PHAN UNG CUA HALOGEN PCy — Cah + HE 105 ~ 186 a1 ini gta gy nd Ch +h OH Ew + ch ah + HL osu uy kha cay + ch — ca + in a prin fing Be + Hy > CH, + He 0s — gam Hy + By — Cie + Be ap ain 1+ cy cy + tos ch +h c+ ee Ton Qusehim . HOA HOC LAP THE CUA PHAN UNG. ‘Vidy 2: San phdm chira 1 C* ¢6 sin tir tac chdt va 1 C7 ots Fa + wwe aime dayat ais ‘SP la mot hén hyp hai déng: + HEC phan khéng d6i quang Br-H Gases 6% voi trréng hep nay ‘ave hai edu hinh cho: