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Tutorial 3: PPE 309L-Process Engineering Computing Lab Fall-2020-5th Semester
Q: 1. Find the molar volume of ammonia gas at 56 atm and 450 K using the RK equation of
state.
Tc=405.5 K, Pc=111.3 atm, a=4.2527, b=0.02590; units of a and b corresponds to Ѵ in L/g
mol.
b) Use Matlab
Q: 2. A stream of Propane at temperature T=423 K and pressure p( atm ) flows at rate of 100
K mol/hr. Use the SRK equation of state to estimate the volumetric flow rate of the stream for
p=0.7,7and 70 atm. In each case calculate the difference between the predictions of SRK
equation and the ideal gas equation of states.
Q: 3. Calculate the molar volume of carbon dioxide at 400 K and 50 bar using Peng-Robinson
equation of state.
Q: 4. A brick wall of 0.2 m thick (L) separates a hot combustion gas of a furnace from the
ambient air and its surroundings. Under steady-state condition, the temperature of the inner
surface of the brick wall (T i) is 623.15 K and of the ambient air (T a) is 293.15 K. Free
convection heat transfer to the air is characterized by a convection coefficient (h) of 15
W/m2.K. Thermal conductivity of the brick wall (k) is 1.2 W/m.K and its surface emissivity (ϵ) of
0.7. The temperature of the surrounding (T s) can also be assumed 293.15 K.
a. What is the brick outer surface temperature (T o)?
b. Plot the brick outer surface temperature (T o) as a function of the brick inner surface
temperature (Ti) assuming all of the other parameters constant.
From energy balance:
Energy transferred to the outer surface = Energy transferred from the outer surface
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Tutorial 3: PPE 309L-Process Engineering Computing Lab Fall-2020-5th Semester
Q: 5. The reduction of iron ore (Fe304, molecular weight More = 232 g/mole) of density Pore =
4.6 g/cm3 and size R = 5 mm by hydrogen (A) can be approximated by the unreacted core
model. The reaction is:
In this model, the reaction occurs first at the outer skin of the particle. The reaction boundary
then moves into the inner particle as the unreacted solid Fe 304 shrinks and leaves behind the
inert solid product Fe, as depicted in the figure below. The radius of the particle can be
assumed constant (R).
The hydrogen gas then must diffuse through the inert solid product and react when it reaches
the unreacted core surface. The effective diffusivity of hydrogen through the product layer (D e)
= 0.03 cm2/s and the concentration of hydrogen at the outer surface of the particle (CA1) =
1.16 x 10-5 mole/cm3. At the conditions of interest, it is known that mass diffusion controls the
process, not the reaction kinetics. It means that the reaction is fast and the concentration of
hydrogen at the surface of the unreacted core (C A2) can be assumed zero.
If the average time that the particle spends in the reduction zone (t) is 40 min. What is the
average size of the unreacted particle core (rc) exiting the zone?
From material balance, the following expression can be derived:
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Tutorial 3: PPE 309L-Process Engineering Computing Lab Fall-2020-5th Semester
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Tutorial 3: PPE 309L-Process Engineering Computing Lab Fall-2020-5th Semester
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Tutorial 3: PPE 309L-Process Engineering Computing Lab Fall-2020-5th Semester
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