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ABSTRACT
In recent years, drilling fluid use and discharge regulations have become increasingly restrictive and
complex. Regulators have been principally influenced by European or US policy. This paper will give
a brief history of the evolution of drilling fluid regulations in these two arenas, and give an overview of
use and discharge regulations on a global basis. Finally, the paper will examine future developments of
regulatory regimes by government departments and the strategies that operators may adopt in order to
achieve compliance.
INTRODUCTION
It is clear that as a result of the nature of chemicals in use in the drilling fluids industry, the
environment can be impacted by both uncontrolled releases and controlled releases of waste as a
disposal route. In order to minimize the impacts of either intentional or unintentional discharges,
drilling fluid suppliers have endeavored to minimize the environmental impacts of the chemicals they
use. It is important to note that minimization of environmental impact must be considered in
conjunction with the technical performance of the fluids used. The very products that have a strong
technical appeal may be the ones that show greatest impact due to the action of the active ingredient.
For example, a particularly effective surfactant may also show higher toxicity than a less effective
surfactant. If lower volumes of the active material are used, the impacts on the environment on
discharge can be lessened. If “green chemicals” are less effective than conventional counterparts then a
balance must be drawn between environmental impact and technical performance.
In order to establish the potential for environmental impact of a product of material it is clearly
unreasonable, wasteful and harmful to apply it to the environment into which it may be released to
study potential for impact, so a series of surrogate tests have been derived. These are aimed at
examining the following ecotoxicological characteristics of the material:
• Toxicity
• Biodegradability
• Bioaccumulation potential.
TOXICITY
Many materials will show toxicity to plant or animal life if applied in sufficient quantities. This may
even include commonplace materials that the human race may consider as food stuff. In the context of
drilling fluid chemistry, chemically active materials such as emulsifiers, alkalinity modifiers and
thinners are expected to show greater toxicity than more inert materials such as mineral powders,
polymeric gels and lost circulation fibers. Therefore it is important to prioritize the assessment of some
chemicals above others. After a thorough investigation, materials that are especially toxic may even be
flagged as candidates for substitution by some governments. Fluids suppliers then face the challenge of
producing materials that show good environmental acceptability without any trade-off in technical
performance.
100
90
80
70
Percent Survival
60
50
40
30
20
10
0
0 20,000 40,000 60,000 80,000 100,000
Concentration (ppm)
Figure 1- Relationship of Survival and Concentration, with arrow indicating lethal concentration
at which 50% of the population shows mortality (LC50).
The species used for toxicity testing in Europe under OSPAR requirements include a sediment bioassay
using amphipod crustacean Corophium volutator, a fish toxicity test using juvenile Scopthalamus,
toxicity to marine copepods using Acartia, and a marine algal growth inhibition test using Skeletonema
costatum. In the United States, sediment toxicity tests are carried out using the amphipod Leptocheirus
plumulosus as the test organism. Suspended particulate phase (water column) toxicity tests are carried
out using the Mysid shrimp (Americamysis bahia).
Tests are not always confined to aquatic media. In some areas, toxicity tests have also been done on
soils- for example wastes have been mixed into soil and the germination and subsequent growth of
plants and survival of earthworms has been observed.
BIODEGRADATION
Once we have intentionally or unintentionally discharged a substance to the environment, whether it is
toxic or not, unless that material is one that is naturally occurring, then it is desirable that it degrade to
something less toxic, or preferably a material that is naturally occurring. Mineralization to CO2 and
H2O is even more desirable. One example may be that of drill cuttings piles. It is clearly undesirable
to have the base fluid present in drill cuttings still be present in sediments on the seafloor underneath an
offshore rig several years after drilling has ceased. A more favorable outcome would be for the base
fluid to completely degrade, i.e. to CO2 and H2O, and for there to be indistinguishable differences on
comparing near-field and far-field sediment hydrocarbon concentrations. We may even be able to
enhance disposal sites by designing fluids that have beneficial effects while breaking down, for
example in a land farming situation it may be useful to have fluids that will break down and release
plant nutrients Nitrogen, Potassium or Phosphorus in controlled amounts if the material is spread to
land.
BIOACCUMULATION
Some organic materials have potential to bioaccumulate- that is; they can accumulate in tissues of
animals that live in the environment into which they are discharged. This is undesirable as the eating
quality or toxicity to humans and other predators of those animals can be increased. Bioaccumulation
tends to occur because accumulative chemicals can easily pass through cell membranes, and also
accumulate in fats. The accumulation can be measured using actual animals, but this is very time
consuming, and costly, so a surrogate fat is used. In the OECD Guideline for Testing of Chemicals
1981, 107 a “shake flask” method using n-octanol and water is described. In this, build up in fatty
tissues of animals is simulated by adding the substance to n-octanol and water layered in a separating
funnel, shaking this mixture for 24hrs at 20-25ºC, and then analyzing the n-octanol and water to
examine which phase the substance has partitioned to. From this, the octanol/water Partition
coefficient (Pow) can be calculated.
The affinity of a High Performance Liquid Chromatography HPLC Column for a substance can also be
used as an alternative to the shake flask method. This is described in OECD guidelines for testing of
chemicals, 1989-117. The US regulators have determined that sufficient is known about the
bioaccumulation of oilfield chemicals, and that this has been sufficiently described in the literature that
they do not require testing. However, in European OSPAR countries, testing of organic components of
drilling fluid chemicals with a molecular weight of <300 is required.
HEAVY METALS
The potential for heavy metals to impact the environment has been well described in the literature, with
the high toxicity of cadmium (Cd) and mercury (Hg) receiving particular attention. Barite, a mineral
widely used for weighting up drilling fluids, has potential to bear heavy metals. Therefore controls
have been put on Cd and Hg in some countries. In the US, this is 1mg/kg for mercury and 3mg/kg for
cadmium.
OIL SHEENS
When oil is present on the surface of a body of water, only very small amounts can give a distinctive
sheen. In the US, the presence of a surface sheen is used as an indicator of the presence of free oil.
Since this is used as a regulatory tool in determining whether an unplanned release of oil has occurred,
if sheening of the surface of a water body is observed during or after discharge of drill cuttings, or
drilling fluids, this is a reportable to the US Coastguard under Section 311 (33 USC 1321) in
enforcement of oil spills (Section 311 is also known as the Oil Pollution Act).
SALINITY
Spills of brines, drilling fluids, produced waters and other salty materials can have a profound and long
term effect on the quality of soils and freshwaters. Brine spills can be very difficult to remove-
inorganic brines do not biodegrade, and the organic materials- e.g. formates and acetates are not widely
used, frequently because of high cost. Brines must be washed out of soil to remove effectively, which
can have an effect on local water tables, thus restrictions can be placed on the electrical conductivity
(EC), sodicity or chloride content of wastes that are to be applied to land. Frequently this is dictated at
the state or provincial level.
CONTROLLING ENVIRONMENTAL IMPACTS
QUALITY OF MATERIAL
The existence of tests to investigate toxicity, biodegradation, bioaccumulation and other characteristics
that can cause environmental impact means that regulators can use as tools means that they can reduce
or minimize environmental impacts by insisting that materials meet certain standards of biodegradation
and toxicity before they can be discharged, or even used in certain environments. Regulators can
identify Best Available Technology (BAT) can be identified by comparing test performance, and
materials can even be ranked in terms of environmental performance.
QUANTITY OF MATERIAL
However innocuous a material is in terms of toxicity and biodegradation, it is generally best to
minimize the amount of material that is discharged. This waste minimization is usually in the interest
of the operator, especially in the case of use of expensive materials such as synthetic based fluids. In
this case governments may rely on the cost savings achievable by minimizing discharges as a
regulatory tool. Alternatively, restriction can be placed on the amounts of fluid that can be retained on
drill cuttings. This has been done in the US, with the EPA using data on performance of various
cuttings drying and cleaning equipment to set limits at which synthetic based fluids can be discharged
on drilled cuttings.
STOCK LIMITATIONS VS. RIG SITE REGULATION
Some regulators ask for testing of chemicals to be carried out before they can be used. Others like us
to examine what we are discharging- “end of pipe” regulations. There is a clear dichotomy in the US
and Europe over the issue of stock vs. discharge limitations. While discharge limitations measure the
direct toxicity of materials as they are discharged, the repeated testing and uncertainty of compliance
while operations are continuing is a drawback. The cost of this testing activity is borne mainly by the
operators. In contrast, the stock limitations allow operators to seek permission to discharge materials
before use and, in the absence of discharge limitations, are more confident of compliance with permits
to operate, while the service companies pick up the costs of testing.
Applicability
Test Type Test Name USA Europe
Biodegradability
OECD Guideline for testing of Chemicals 306 ●
(1992). Biodegradability in Seawater, Closed
Bottle Method.
Modified ISO11734:1995 method: Water quality - ●
Evaluation of the ‘ultimate’ anaerobic
biodegradability of organic compounds in digested
sludge - Method by measurement of the biogas
production (1995 edition).
Toxicity
PARCOM (1995), A sediment bioassay using an ●
amphipod Corophium sp. Oslo and Paris
Commissions Protocol.
Paris Commission (PARCOM 1995). Protocol for ●
a Fish Acute Toxicity Test. Oslo and Paris
Commission Protocol.
OECD Guideline for Testing of Chemicals 203 ●
(1992). Fish, Acute Toxicity Test.
ISO 14669:1999(E) Water Quality - Determination ●
of Acute Lethal Toxicity to Marine Copepods
(Copepoda, Crustacea).
EN ISO 10253 : 1998 Water Quality - Marine ●
Algal Growth Inhibition Test with Skeletonema
costatum and Phaedodactylum tricornutum
OECD Guidelines for the Testing of Chemicals ●
Method 201 - Alga Growth Inhibition Test
ASTM E1367–92 method: Standard Guide for ●
Conducting 10-day Static Sediment Toxicity Tests
with Marine and Estuarine Amphipods.
Leptocheirus plumulosus as the test organism and
sediment preparation procedures specified in
Appendix 3 of 40 CFR 435, Subpart A.
“Suspended Particulate Phase Toxicity” as applied ●
to BAT effluent limitations and NSPS for drilling
fluids and drill cuttings refers to the bioassay test
procedure presented in Appendix 2 of 40 CFR 435,
Subpart A.
Bioaccumulation Potential
OECD Guideline for Testing of Chemicals 117 ●
Partition Coefficient (n-octanol/water) by HPLC
1989.
Free Oil Appendix 6 to Subpart A of Part 435— ●
Reverse Phase Extraction (RPE) Method for
Detection of Oil Contamination in Non-
Aqueous Drilling Fluids (NAF) Federal Register
Vol. 66, No. 14. January 22, 2001.
Entrained Oil Appendix 5 to Subpart A of Part 435— ●
Determination of Crude Oil Contamination
in Non-Aqueous Drilling Fluids by Gas
Chromatography/Mass Spectrometry (GC/
MS) Federal Register Vol. 66, No. 14. January 22,
2001.
PAH Content EPA Method 1654, Revision A, PAH Content of ●
Oil by HPLC/UV,Methods for the Determination
of Diesel,Mineral, and Crude Oils in Offshore Oil
and Gas Industry Discharges, EPA–821–R–92–
008, December 1992.
APPENDIX 2
Useful sources of further information
Country/Region Website
Canada
Canada- British Colombia http://www.ogc.gov.bc.ca/default.asp
Canada- Alberta http://www.eub.gov.ab.ca/BBS/default.htm
Canada- Canada-Newfoundland Offshore Petroleum Board http://www.cnopb.nfnet.com/
Canada- Canada-Nova Scotia Offshore Petroleum Board http://www.cnsopb.ns.ca/index.html
Canada-National Energy Board http://www.neb.gc.ca/
USA
USA-Alabama State Oil and Gas Board http://www.ogb.state.al.us/
USA-Alaska Oil and Gas Conservation Commission http://www.aogcc.alaska.gov/homeogc.htm
USA-Arizona Oil and Gas Conservation Commission http://www.azgs.state.az.us/OGCC.htm
USA-California Department of Conservation Division of http://www.consrv.ca.gov/dog/index.htm
Oil, Gas and Geothermal Resources
USA-Colorado Bureau of Land Management http://www.co.blm.gov/oilandgas/oilgas.htm
USA-Florida Department of Environmental Protection http://www.dep.state.fl.us/geology/
USA-Illinois Department of Natural Resources Division of http://dnr.state.il.us/mines/dog/welcome.htm
Oil and Gas
USA-Indiana Department of Natural Resources Division of http://www.state.in.us/dnroil/
Oil and Gas
USA-Kansas Corporation Commission Conservation http://www.kcc.state.ks.us/conservation/index.htm
Division
USA-Louisiana Office of Conservation http://www.dnr.state.la.us/CONS/conserv.ssi
USA-Michigan Department of Environmental Quality http://www.michigan.gov/deq/0,1607,7-135-3311_4111_4231-
--,00.html
USA-Mississippi State Oil and Gas Board http://www.ogb.state.ms.us/
USA-Montana Board of Oil and Gas Conservation http://bogc.dnrc.state.mt.us/
USA-State of Nevada Commission on Mineral Resources http://minerals.state.nv.us/
Division of Minerals
USA-New Mexico Energy, Minerals and Natural Resources http://www.emnrd.state.nm.us/ocd/
Department
USA-New York State Department of Environmental http://www.dec.state.ny.us/website/dmn/
Conservation
USA-Welcome to the North Dakota Industrial Commission, http://www.oilgas.nd.gov/
Oil and Gas Division
USA-Oklahoma Corporation Commission, Oil and Gas http://www.occ.state.ok.us/Divisions/OG/oginfo.htm
Conservation Division
USA-Ohio Department of Natural Resources, Mineral http://www.dnr.state.oh.us/mineral/oil/index.html
Resources Management
USA-Pennsylvania Department of Environmental Protection
Bureau of Oil and gas Management http://www.dep.state.pa.us/dep/deputate/minres/oilgas/oilgas.h
tm
USA-Railroad Commission of Texas Oil and Gas Division http://www.rrc.state.tx.us/divisions/og/og.html
USA-Gulf of Mexico MMS http://www.gomr.mms.gov/index.html
USA-The Utah Division Of Oil, Gas And Mining http://dogm.nr.state.ut.us/oilgas/
USA-Washington State Department of Natural Resources http://www.dnr.wa.gov/geology/
division of Geology and Earth Resources
USA-West Virginia Department of Environmental http://www.dep.state.wv.us/item.cfm?ssid=23
Protection Office of Oil and Gas
USA-Wyoming Oil and Gas Conservation Commission http://wogcc.state.wy.us/
Europe
Europe-NE Atlantic/North Sea (OSPAR Commission for the http://www.ospar.org/eng/html/welcome.html
Protection of the North-East Atlantic- OSPAR)
Europe-Barcelona Convention (Mediterranean) http://www.greenyearbook.org/agree/mar-env/barcelon.htm
Europe-Baltic Sea (Helsinki Convention- HELCOM) http://www.helcom.fi/helcom/convention.html
Europe-UK (Centre for Environment Fisheries and http://www.cefas.co.uk/ocns/index.htm
Aquaculture Science-CEFAS)
Europe-Norway (The Norwegian Pollution Control http://www.sft.no/english/legislation/
Authority-SFT)
Europe-The Netherlands (State Supervision of Mines- http://www.sodm.nl/index_engfr.htm
SodM)
Table 3 Examples of drilling fluid use and discharge regulations in offshore producing countries. Note: These regulations are
subject to change at short notice and regulators should be consulted for updated information 2
Country Water Based Drilling Fluids and Diesel, Mineral oils, Low Toxicity Synthetic Based Drilling Fluid
Cuttings Mineral Oils Cuttings
Angola Discharge allowed Cuttings discharge allowed
Australia Risk assessments required by regulator, fluid 1% oil limit on cuttings retention effectively Discharges assessed on a case-by-case basis
plans are described, operators make eliminates discharge In Western Australia, technical aspects, local
commitments for additional testing or monitoring Restriction on fluids with aromatics >1% environment, and environmental performance of
in Environment Plans are binding once submitted fluid evaluated. Retention on cuttings limited to
and accepted by government. Discharge allowed 10%. Paraffin-based fluid cuttings, Esters and IO
subject to 1% oil limit. 17% limit on KCl cuttings discharged recently. Whole synthetic
content of fluids for exploratory drilling. fluids cannot be discharged. Monitoring program
Sampling of fluids required before discharge, details determined on a case-by-case basis.
flow rate monitored but not reported or limited.
Some dischargers monitor Hg/Cd
Azerbaijan All discharges subject to meeting negotiated No discharge of fluid or cuttings. Permitted. Synthetic fluid cuttings can be discharged, but
terms of specific Production Sharing Agreements Injection of cuttings or onshore treatment, such not whole fluids. Further restrictions expected,
as fixation and / or landfilling is planned. primarily for production drilling. Discharge of
Operators in inshore/ environmentally sensitive cuttings allowed as long as a low toxicity,
areas have more monitoring requirements; and acceptable biodegradability fluid is used
more stringent standards. Discharge rate is not Toxicity & biodegradability standards have not
subjected to limits, but is reported monthly in the been set. Some operators have imposed a limit
form of daily logs records Fluids must show low of 10% SBM fluid on cuttings, or even zero
toxicity, good biodegradability. Toxicity testing discharge. Discharge of enhanced-mineral-oil-
is carried out after periodic sampling. Chloride based fluids is not allowed
content of discharges is limited. Before drilling,
Country Water Based Drilling Fluids and Diesel, Mineral oils, Low Toxicity Synthetic Based Drilling Fluid
Cuttings Mineral Oils Cuttings
fluid program is assessed for toxicity and
biodegradability. A daily inventory of
discharged fluid additives is maintained.
Canada Cuttings may be discharged if cuttings injection Cuttings may be discharged if cuttings injection SBF bulk discharges prohibited. Cuttings may
is not economically or technically feasible. Bulk is not economically or technically feasible. OBF be discharged if cuttings injection is not
disposal of water based drilling fluids is bulk discharge not allowed. Specific approval is economically or technically feasible, and subject
discouraged, but allowed. required to use OBF. Aromatic content of oil to a 15% Oil on cuttings limit. Draft guidelines
must be <5% and meet toxicity requirements for propose cuttings discharge only if treated with
water soluble fraction (WSF). WBF or SBF use BAT prior to discharge. SBM definition includes
is preferred. Cuttings from diesel or highly paraffins. Operators should reduce fluids on
aromatic oils not allowed to be discharged, cuttings to as low a level as is reasonably
otherwise subject to 15% oil of cuttings limit. practicable, with a target of 6.9%.
China WBM discharge is allowed. Oil use is Discharge of fluids on cuttings is not allowed at SBM fluid/cuttings regulations are not known.
discouraged , with notification required for >10% oil. If cuttings oil content <10% and
WBM containing oils with sample submission. further cleanup not possible, discharge allowed
Discharge of cuttings with oil content in drilling subject to approval and payment of a discharge
fluid >10% is not allowed. If oil <10% and fee
cannot be recovered, agency approval, discharge
is allowed subject to payment of a fee. Residual
oil, waste oil, oil-containing waste discharge is
prohibited and must be shipped to shore.
Dispersant use is not allowed. Operator
responsible for daily measurement of flow rate of
Country Water Based Drilling Fluids and Diesel, Mineral oils, Low Toxicity Synthetic Based Drilling Fluid
Cuttings Mineral Oils Cuttings
1
Munro, P.D., B Croce, C.F. Moffet, N.A Brown, A.D. McIntosh, S.J.Hird, R.M. Stagg. 1998. Solid-phase test for comparison for
degradation rates of synthetic mud base fluids used in the off shore drilling industry. Environ. Toxicol. Chem. 17:1951-1959.
2
CAPP (2001) Canadian Association of Petroleum Producers Drilling Waste Management Review CAPP Technical Report Publication
#2001-0007 Calgary, Alberta, Canada, February 2001.