DISAIN REAKTOR

ISOTERMAL

Reaktor Membran
Micro-Reactor
Prof. Dr. Ir. Slamet, M.T.
Departemen Teknik Kimia FTUI
Maret 2021
Algoritma disain
reaktor isotermal

2. Neraca MOL
dalam bentuk
MOL FLOWRATE

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 MEMBRANE REACTOR

• Reaksi: C6H12⇌ 3 H2 + C6H6

A ⇌ 3B + C
Homogen
• Neraca mol B: FB |V −FB |V +V −RB V + rB V = 0
dFB RB = k C CB
= rB − RB
dV
 MEMBRANE REACTOR
(Heterogen)
Reactions:

Mole Balances:
Rate Laws:

y y y

y = P/Po
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 MEMBRANE REACTOR

Parameters:
▪ Po = 8.2 atm
▪ To = 227 oC
▪ FAo = 20 mol/s
▪ kA = 10 dm3/(kg-cat.s)
▪ kcm = 20 dm3/(kg-cat.s)
▪ KC = 0.02 mol2/dm6
▪  = 0.003 1/kg
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MEMBRANE REACTOR
(ada pressure drop)

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MEMBRANE REACTOR

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MEMBRANE REACTOR
(ada pressure drop)

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Reaktor PBR vs Membran
(Contoh Soal 13.10)

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Konversi PFR vs Membran

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Pengaruh jenis produk permeate

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Pengaruh Penurunan Suhu
(reaksi endotermis)

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Pengaruh Kenaikan Suhu
(reaksi endotermis)

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Pengaruh Penurunan Suhu
(reaksi eksotermis)

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Pengaruh Kenaikan Suhu
(reaksi eksotermis)

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MICROREACTOR
➢ New technology in CRE
➢ High surface area-to-volume
ratio (ca. 10,000 m2/m3)
➢ Eliminate heat & mass
transfer resistances
➢ Eliminate hot spots in highly
exothermic reactions
➢ Isothermal operation of
highly exothermic reactions
➢ To study the intrinsic kinetics
of reactions
➢ Suitable for toxic or
explosive production
➢ Shorter residence time
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Latihan soal-soal Microreactor
Contoh Soal 13.9
- Reaksi elementer fasa gas:
2 NOCl ⎯
⎯→ 2 NO + Cl2 (2 A ⎯
⎯→ 2B + C )

- Neraca mol total, variabel X (metode 1): SALAH

FAo F  X 
V=  dX = Ao2   = 0,0057 dm = 5,7 cm
3 3
− rA kCAo  1 − X 

- Neraca mol total, variabel X (metode 2):

FAo FAo  (1 +  ) 2 X 
V=  dX = 2 (1 +  ) ln( 1 − X ) +  X +
2

− rA 2
kC Ao  1 − X 
V = 0,01 dm 3 = 10 cm 3 17
 Neraca mol komponen,
variabel mol flowrate:
Latihan soal-soal Microreactor

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Latihan soal-soal Microreactor

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