Uppp2 2020 Sem 2

*CONFIDENTIAL| 1
Candidate's Name : …………………………………… Form : ……………………………

(Nama calon) (Tingkatan)
SMK TASEJ UTARA, JOHOR BAHRU SMK TASEJ UTARA, JOHOR BAHRU SMK TASEJ UTARA, JOHOR BAHRU
962/2 CHEMISTRY
SMK TASEJ UTARA, JOHOR BAHRU SMK (KIMIA)
TASEJ UTARA, JOHOR BAHRU SMK TASEJ UTARA, JOHOR BAHRU
STPM 2020
PAPER 2 (KERTAS 2)
One and a half hours (Satu jam setengah)
UJIAN PERCUBAAN STPM PENGGAL 2
SMK TASEJ UTARA, JOHOR SMK
BAHRUTASEK UTARA,
SMK TASEJ JOHOR
UTARA, JOHOR BAHRU
BAHRU SMK TASEJ UTARA, JOHOR BAHRU
(SEKOLAH KLUSTER KECEMERLANGAN)
SIJIL TINGGI PERSEKOLAHAN MALAYSIA
SMK TASEJ UTARA, (MALAYSIA
JOHOR BAHRUHIGHER SCHOOL
SMK TASEJ UTARA,CERTIFICATE)
JOHOR BAHRU SMK TASEJ UTARA,
Instructions to candidates: For examiner's use

DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD (Untuk kegunaan
TO DO SO. pemeriksa)
There are fifteen questions in Section A. For each question, four choices of
answers are given. Choose one correct answer and indicate it on the Multiple-choice Section A (Bahagian A)
Answer Sheet provided on page 4. Read the instructions on the Multiple-choice Answer
1 - 15
Sheet very carefully. Answer all questions. Marks will not be deducted for wrong
answers. Section B (Bahagian B)
Answer all questions in Section B. Write your answers in the spaces provided.
Answer any two questions in Section C. Write your answer on the answer sheet 16
provided. All working should be shown. Numerical answers should be given to an
appropriate number of significant figures; units should be quoted wherever appropriate. 17
Begin each answer on a fresh sheet of paper and arrange your answers in numerical
order.
Section C (Bahagian C)
Do not tear off the front page of this question paper and tie together your answer
sheets of Section B, and tie both of them together with your answer sheets of Section C.
Answers may be written in either English or Bahasa Melayu.
A Periodic Table is provided in separate sheet
Total (Jumlah)
Arahan kepada calon:

JANGAN BUKA KERTAS SOALAN INI SEHINGGA ANDA DIBENARKAN BERBUAT
DEMIKIAN.
Ada lima belas soalan dalam Bahagian A. Bagi setiap soalan, empat pilihan jawapan diberikan. Pilih satu
jawapan yang betul dan tandakan jawapan itu pada Borang Jawapan Aneka Pilihan yang dicetakkan di muka surat 4.
Baca arahan pada Borang Jawapan Aneka Pilihan itu dengan teliti. Jawab semua soalan. Markah tidak akan ditolak
bagi jawapan yang salah.
Jawab semua soalan dalam Bahagian B. Tulis jawapan anda di ruangyang disediakan.
Jawab mana-mana dua soalan dalam Bahagian C. Tulis jawapan anda pada helaian jawapan yang diberikan.
Semua jalan kerja hendaklah ditunjukkan. Jawapan berangka hendaklah diberikan hingga bilangan angka bererti yang
sesuai; unit hendaklah dinyatakan di mana-mana yang sesuai. Mulakan setiap jawapan pada helaian kertas jawapan
yang baharu dan susun jawapan anda mengikut tertib berangka.
Koyakkan muka hadapan kertas soalan ini dan helaian jawapan anda bagi Bahagian B, dan ikatkan kedua-duanya
bersama-sama dengan helaian jawapan anda bagi Bahagian C.
Jawapan boleh ditulis dalam bahasa Inggeris atau Bahasa Melayu.
Jadual Berkala dibekalkan pada helaian berasingan
This question paper consists of 6 printed pages and 0 blank page
(Kertas soalan ini terdiri daripada 6 halaman bercetak dan 0 halaman tidak bercetak)
© SMK TASEK UTARA, JOHOR BAHRU (SEKOLAH KLUSTER KECEMERLANGAN)
STPM 962 / 2 2020

*This question paper is CONFIDENTIAL until examination is over.
(Kertas soalan ini SULIT sehingga peperiksaan kertas ini tamat.)
*CONFIDENTIAL| 2
Section A [15 marks]
Answer all questions in this section. Write your answer in the space provided at Page 4
1. Enthalpy changes that are difficult to measure directly can often be determined using Hess’ Law to
construct an enthalpy cycle. Which enthalpy change is indicated by X in the enthalpy cycle shown?
A. – 4 × the enthalpy of combustion of hydrogen

B. + 4 × the enthalpy of combustion of hydrogen
C. – 2 × the enthalpy of formation of water
D. + 2 × the enthalpy of formation of water
2. A student mixed 25.0 cm3 of 0.350 mol dm–3 sodium hydroxide solution with 25.0 cm3 of 0.350 mol
dm–3 hydrochloric acid. The temperature rose by 2.50 °C. Assume that no heat was lost to the
surroundings. The final mixture had a specific heat capacity of 4.20 J g-1 K–1. What is the molar enthalpy
change for the reaction?
A –150 kJ mol–1 B. –60.0 kJ mol–1

C. –30.0 kJ mol–1 D. –0.150 kJ mol–1
3. The e.m.f. of a simple cell was found to be 1.2V under standard conditions. The following standard
electrode potentials are given.
P+ / P Q2+ / Q R+ / R S2+ / S
–1.8 V +0.3 V –0.9 V – 0.3V
What were the two electrodes of the cell?
A. P and Q B. P and S C. Q and R D. Q and S
4. A student set up the hydrogen electrode shown in the diagram below.
What would have to be changed to make this a standard hydrogen electrode?

A. the temperature of the gas and the acid solution
B. the pressure of the hydrogen gas
C. the metal comprising the electrode
D. the thickness of the layer of platinum black
5. The electrolysis of brine using the diaphragm cell is an important industrial process. What happens at the
anode?
A. Chloride ions are oxidised. B. Hydrogen gas is produced.
C. Hydroxide ions are formed. D. The reaction is 2 Cl– (aq) + 2 e– → Cl2 (g).
STPM 962 / 2 2020
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6. The table shows the physical properties of four substances. Which substance has a giant covalent
structure?
electrical
melting boiling electrical electrical
conductivity of
point / °C point / °C conductivity of solid conductivity of liquid
aqueous solution
A –119 39 poor poor insoluble
B –115 –85 poor poor good
C 993 1695 poor good good
D 1610 2230 poor poor insoluble
7. Which graph correctly shows relative electronegativity plotted against relative atomic radius for the
elements Na, Mg, Al and Si?
8. When equal volumes of saturated solutions of barium hydroxide and calcium hydroxide are mixed, a
white precipitate, Y, forms. The mixture is filtered and carbon dioxide is bubbled through the filtrate,
producing a second white precipitate, Z. What are Y and Z?
A B C D
Y Ba(OH)2 Ba(OH)2 Ca(OH)2 Ca(OH)2
Z Ca(OH)2 CaCO3 BaCO3 Ba(OH)2
9. Solutions of Mg(NO3)2 and Ba(NO3)2 separately undergo a series of reactions.
M, N and P are magnesium compounds while Q, R and S are barium compounds. How many of M, N, P,
Q, R and S are white precipitates?
A. 2 B. 3 C. 4 D. 5
STPM 962 / 2 2020
*CONFIDENTIAL| 4
10. In the Group 14 elements, from C to Pb, which property increases?
A. acidity of oxides B. thermal stability of covalent chlorides
C. stability of the +2 oxidation state D. stability of the +4 oxidation state
11. Carbon monoxide burns readily in oxygen to form carbon dioxide. What can be deduced from this
information?
I. The +4 oxidation state of carbon is more stable than the +2 state.
II. Standard enthalpy change of formation of carbon dioxide is more negative than carbon monoxide.
III. Value of the equilibrium constant for the reaction, 2CO(g) + O2(g)  2CO2(g), is likely to be high.
IV. Rate of reaction for the reaction, 2CO(g) + O2(g)  2CO2(g), is likely to be high.
A. I, II and III only correct B. I, II and IV only correct

C. I, III and IV only correct B. II, III and IV only correct
12. Redox reactions occur very frequently in the chemistry of Group 17. Which statement is correct?
A. Chlorine will oxidise bromide ions but not iodide ions.
B. Fluorine is the weakest oxidising agent out of F2, Cl2, Br2 and I2.
C. Iodide ions are the weakest reducing agent out of F– , Cl– , Br– and I–.
D. When chlorine reacts with water, chlorine is both oxidised and reduced
13. A test-tube of HI gas and a test-tube of HBr gas are placed together in an environment at temperature, T.
Which combinations of observations are possible depending on the temperature, T?
A. A brown vapour appears in one of the test-tubes. No change is apparent in the other test-tube.
B. A brown vapour appears in one of the test-tubes. A purple vapour appears in the other test-tube.
C. A purple vapour appear in one of the test-tubes. No change is apparent in the other test-tube.
D. No change is apparent in either test-tube
14. Which statement concerning the transition metals is correct?

A. They are the only metals of which the anhydrous chlorides have covalent bonds.
B. They are the only metals which give coloured ions in an aqueous solution.
C. They are the only metals which have more than one valency (oxidation state).
D. They are the only metals with a complete 4s orbital in their atoms.
15. When drops of NH3 (aq) are added to Cu(NO3)2 (aq), a pale blue precipitate is formed. This precipitate
dissolves when an excess of NH3 (aq) is added, forming a deep blue solution. Which process does not
occur in this sequence?
A. dative bond formation B. formation of a complex ion

C. precipitation of copper(II) hydroxide D. reduction of Cu2+ ions
Section A - Answer Sheets
1. 2. 3. 4. 5.
6. 7. 8. 9. 10.
11. 12. 13. 14. 15.
STPM 962 / 2 2020

*CONFIDENTIAL| 5
Section B [15 marks]
Answer all questions in this section
16. (a) Chlorate(V) ions are powerful oxidising agents. The reduction of chlorate(V) ions, ClO3–, with SO2
forms chlorine dioxide, ClO2, and sulphate ions, SO42–, as the products.
(i) Write the oxidation and reduction half equations for the conversion of [2 marks]
–
ClO3 to ClO2 : ………………………………………………………………………………………
SO2 to SO42– : ………………………………………………………………………………………
(ii) Based on the equation in (a)(i), construct an overall equation for this reaction. [1 mark]
………………………………………………………………………………………………………..
(b) Chlorate(V) ion can be formed via disproportionation of chlorine in alkaline solution.
(i) Define the terms disproportionation [1 mark]
………………………………………………………………………………………………………...
(ii) When chlorine reacts with hydroxide ion aqueous solution under suitable condition, it
disproportionate to form aqueous chlorate(V) ion, ClO3- and chloride ion, Cl-. Suggest the condition
for the reaction and hence write the ion equation occur and state the oxidation states changes
[3 marks]
Condition of reaction : …………………………………………………………………………..
Reaction equation : …………………………………………………………………………..
Oxidation states changes : …………………………………………………………………………..
17. Silicon is mainly used as a semiconductor in electronic industry. For this purpose, the silicon used has to
be of highest purity. The initial step in the purification of silicon is to convert impure silicon into silicon
tetrachloride which is volatile, under dry condition. The silicon tetrachloride formed is then reacted with
hydrogen gas to form pure silicon.
(a) Write balanced chemical equations for the reaction which occur in the purification of silicon
[2 marks]
………………………………………………………………………………………………………….
………………………………………………………………………………………………………….
(b) State why silicon tetrachloride is volatile [2 marks]

………………………………………………………………………………………………………….
………………………………………………………………………………………………………….
(c) Explain the observation if silicon tetrachloride formed is exposed to moist [2 marks]
………………………………………………………………………………………………………….
………………………………………………………………………………………………………….
(d) State two methods which can be used to increase electrical conductivity of silicon [2 marks]
………………………………………………………………………………………………………….
………………………………………………………………………………………………………….
STPM 962 / 2 2020

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Section C [30 marks]
Answer TWO of these questions below in the examination pad
18. Stearic acid (C18H36O2) is a typical fatty acid, a molecule with a long hydrocarbon chain and an organic
acid group (COOH) at the end. It is used to make cosmetics, ointments, soaps, and candles and is found
in animal tissue as part of many saturated fats. In fact, when you eat meat, chances are that you are
ingesting some fats that contain stearic acid.
(a) Define standard enthalpy change of combustion and write a balanced equation for the complete
combustion of stearic acid. [3 marks]
(b) Given the standard enthalpy change of formation of stearic acid, carbon dioxide and water are –1948
kJ mol-1, –393 kJ mol-1 and –286 kJ mol-1 respectively
(i) By using Hess Law, calculate the standard enthalpy change of combustion of stearic acid
[4 marks]
(ii) Construct an energy level diagram for the combustion of stearic acid based on the information
provided in (b)(i) [3 marks]
(c) Enthalpy change of combustion can be determined experimentally by using bomb calorimeter.
Complete combustion of 13.6 g of stearic acid in bomb calorimeter caused the temperature of the
calorimeter to increase by 63.0oC. Given the heat capacity of bomb calorimeter is 7.32 kJ oC-1,
calculate the enthalpy change of combustion of stearic acid in bomb calorimeter, and hence compare
the effectiveness of combustion using bomb calorimeter to that of the standard enthalpy change of
combustion calculated from (b)(i) [5 marks]
19. Lithium, sodium and potassium are elements in Group 1 of the Modern Periodic Table.
(a) Explain the ionisation energy trend for lithium, sodium and potassium when going down Group 1
[5 marks]
(b) Lithium and sodium mildly burned in oxygen to form different products of oxide.
(i) By writing balanced chemical equations, name the oxides formed from the reaction of and compare
the reactivity of lithium and sodium with oxygen [6 marks]
(ii) Oxides of lithium and sodium when dissolved in water, formed colourless solutions that turned
purple on universal indicator. Explain these observations [4 marks]
20 (a) Discuss the acid-base properties of the oxides of Group 14 elements of the Periodic Table. Write
equations of the reactions involved. [12 marks]
(b) 'Red lead' is an oxide of lead used extensively as a surface coating to prevent corrosion of iron and
steel. It contains 90.66% by mass of lead, which is present in both the +2 and +4 oxidation states.
Calculate the empirical formula of red lead, and state the ratio of lead (II) oxide to lead (IV) oxide
[3 marks]
STPM 962 / 2 2020


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*CONFIDENTIAL| 1

Candidate's Name : …………………………………… Form : ……………………………

Instructions to candidates: For examiner's use

Arahan kepada calon:

STPM 962 / 2 2020

A. – 4 × the enthalpy of combustion of hydrogen

A –150 kJ mol–1 B. –60.0 kJ mol–1

4. A student set up the hydrogen electrode shown in the diagram below.

What would have to be changed to make this a standard hydrogen electrode?

9. Solutions of Mg(NO3)2 and Ba(NO3)2 separately undergo a series of reactions.

A. I, II and III only correct B. I, II and IV only correct

14. Which statement concerning the transition metals is correct?

A. dative bond formation B. formation of a complex ion

Section A - Answer Sheets

11. 12. 13. 14. 15.

STPM 962 / 2 2020

(b) State why silicon tetrachloride is volatile [2 marks]

STPM 962 / 2 2020

STPM 962 / 2 2020

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