Professional Documents
Culture Documents
Mineral Processing
Prof. Rodrigo Serna and Dr. Robert Hartmann
Spring 2019
Aalto University
Unit operations in a Cu processing
plant
1. Comminution
From mine
2
A. Lossin “Copper” in Ullman’s Encyclopedia of Industrial Chemistry (2001)
Unit operations in a Cu processing
plant
From mine
2. Screening/Classification
3
Unit operations in a Cu processing
plant
From mine
Grinding circuits
are a combination
of comminution
and sizing
2. Screening/Classification
4
Unit operations in a Cu processing
plant
Degree of liberation A:
• The degree of liberation expresses the share of mass or volume of a component, which
is free or as a compound included in a sufficient amount of material, i.e. how much of
the targeted mineral/component is liberated (free) or still grown together with other
compounds
𝑚𝑚𝑙𝑙𝑙𝑙𝑙𝑙 𝑚𝑚𝑙𝑙𝑙𝑙𝑙𝑙
𝐴𝐴 = ∗ 100% = ∗ 100%
𝑚𝑚𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡 𝑚𝑚𝑙𝑙𝑙𝑙𝑙𝑙 + 𝑚𝑚𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔
A complete liberation of the desired mineral is seldom achieved, even if the ore is ground
down to the grain size of the desired mineral particles (see lectures last week)
Screening
Characteristics of screening
Feed
Overflow
Underflow
6
Screening
Type of screens
• Grizzly
- Fixed bars
- Rotating rolls
• Sieve bends
• Vibrating
- Inclined screens
- Horizontal
- Resonance
- Multiple inclinations
(Banana)
- High frequency
• Shaking
7
Screening
Other types
• Revolving screens
- Trommel
- Centrifugal
• Rotary sifters
- Reciprocating
- Gyrating
8
Screening
Water or no water?
• The purpose of using spray water is to wash smaller particles from
larger ones to improve separation effectiveness, reduce “sticking” fines
DRY WET
Spray water mainly to achieve Spray water crucial as
certain %solids in undersize transport mechanism of fine particles
Grizzly
Flat screens Fine screens
Scalping
following and sieve
screens in
primary mills bends
crushing
circuits
9
Screening
Screening surfaces
Standard choice Improved capacity
Grizzlies
10
Screening
Mass balance: Ideal vs. Actual screens
Screen analysis of feed Analysis of ideal products
%Passing
%Passing
Cut Point
dp dp
u
f
o
dp
11
Screening
Mass balance and screen effectiveness
• Screen efficiency formulae
Feed mass flow
General mass balance: Undersize mass flow mass flows in t/h
Commonly, the fine product stream is the important one and efficiency is defined by the
recovery of finished product (material less than the cut-size) to the fine (underflow) stream, Eu:
These formulae assess the efficiency of the screen under different conditions, however, give not
an absolute value of the efficiency, as no allowance is made for the difficulty of the separation,
i.e. the more particles have approx. the size of the meshes, the more difficult the separation
The efficiency definition here refer to the recovery of finished product to either stream, e.g. EU
is recovery of finished product to the underflow stream
BUT
It does not consider the “composition” of the material in each fraction
f - mass of material finer than a defined cut-point (or cut-size)
o - mass of material finer than the apparatus size in the coarse product
u - mass of material finer than the apparatus size in the coarse product 13
Screening
Separation efficiency
Here, efficiency is the recovery of target mineral minus recovery of non-target mineral
With respect to a screen, for the underflow we could consider the difference in recovery of
undersize to the underflow minus recovery of oversize to the underflow, and analogous
statement to the overflow
14
Screening – standard separation function
The standard separation function shows, which mass fraction is separated for each differential
size interval into the coarse fraction (overflow)
𝑶𝑶(∆ζ𝒊𝒊 )
𝑻𝑻𝑶𝑶 (ζ) =
𝑭𝑭(∆ζ𝒊𝒊 )
Imperfect discharge
Separation efficiency
ζ25
0,3 < κ < 0,6 satisfying
κ=
0,6 < κ < 0,8 good
0,8 < κ < 0,9 very good
ζ75
κ=1 ideal
Cut point
Separation characteristic ζ
15
Screening
Factors affecting performance
• Particle size and ratio particle size- mesh size
• Feed rate (height of the particle bed moving over the sieve)
• Screen angle (effective mesh opening, dwell time)
• Particle shape
• Open area
• Vibration (amplitude and frequency)
• Moisture
16
Screening
Factors affecting performance
• Capacity and effectiveness are opposing factors… to drive high
capacities, the effectiveness will be penalized
• The actual capacity of a screen is affected by the probability of a
particle to pass through the screen “p”
Particle diameter
Diameter of wire
• Number of contacts of the particle at the screen surface (n), for example in a
vibrating screen (where p’ is the probability of particles staying on the screen)
17
Screening
Factors afecting performance Ratio of particle
Chance of
passage per
Number of
apertures
to aperture size
• The actual capacity of a screen is 1000 required in path
0,001 998 1
affected by the probability of a
0,01 980 2
particle to pass through the screen
0,1 810 2
- In turn, this is a function of
0,2 640 2
(cont’d):
0,3 490 2
• Ratio of particle size-to-mesh
opening size 0,4 360 3
0,5 250 4
18
Screening
Other correlations are required if the particle does not approach
the screen perpendicularly as assumed by Gaudin’s equation
• If the screen has an inclination, the effective area the particle will “see”
is affected
Nominal size of opening
Effective opening
19
Screening
Bed depth Initial bed depth
Feed
• The thickness of the ore layer passing through the
screens depends on the flow rate
• Three distinct regions can be found along the screen
length Width of screen
- Segregation is desired, a phenomenon in which Travel rate
smaller particles migrate to the bottom of the along screen
bed and larger particles to the top Feed Bulk density
- As region II is the most efficient, it is desired to Pan
maintain it for as long as possible Screen
- It has been claimed that by varying the slope of
the angle in inclined screens, the area of the
screens can be reduced significantly
• General rules of thumb
20
Screen Types
1. Vibrating screens
• Dominant type of screen used for coarse
and fine screening applications (e.g.
sizing, grading, scalping, de-watering, wet
screening and washing)
• Most versatile, enables separations from
300mm down to 45 µm
• Usually manufactured as multiple deck
(i.e. feed enters from the top and each
consecutive sieve has smaller mesh sizes
21
Screen Types
2. Grizzly screens
• Characterized by parallel steel bars or
rails set in a fixed distance and in line
with the flow of the ore
• Usually for very coarse material
• Gap between bars greater than 50 mm
and as large as 300 mm with feed top size
of 1 m
• The inclination is about 20°and capacities
exceed 5000 t/h
• Used to separate feed before primary and
secondary crushers
22
Screen Types
Horizontal screen
23
Screen Types
24
Screening Surfaces
25
Bolt-in screen surface
26
Bolt-in screen surface
• Tensioned screening surfaces
Surfaces consist of cloths that are stretched
taut to ensure screening efficiency and prevent
premature failure, available as wire weaves,
polyurethane or rubber
• Woven-wire cloth
Constructed from (stainless) steel, cheapest
screen surface, high open area and thus high
capacity
• Self-cleaning wire
Constructed to minimize “blinding” (particles
blocking the openings), wires form a pattern
but individual wires are free to vibrate Self-cleaning wire meshes
preventing particles to stick, have higher cost
but longer life time at similar accuracies as
conventional woven wire mesh
27
Screening
Sizing
• Due to the various factors influencing screen operation, tests
performed with representative samples of the actual material are
recommended
• As a first approach, empirical correlation methods can be applied to
obtain an initial estimate
- These empirical methods use correction factors that can vary between
manufacturers
28
Screening
Feed mass flow rate
Area of Product of the
Sizing screening surface various correction factors
29
Screening
Sizing
K3
K2
30
Screening
K4
Sizing
31
Screening
K5 K6 K9
Sizing
K7
K10
K8
32
Sizing: Sieves
Example:
The following crusher circuit has a fresh feed of 200 ton/h dry ore. The screen has an opening of 13 mm and an
efficiency of 80%*. It is estimated that 20% of the fresh feed is finer than 13 mm. The crusher will operate with a
closed side setting of 10 mm. Based on the product size data provided by the manufacturer with this setting
(below).
Your task now is to determine the required area for the screen in the circuit. The unit capacity “Iu” of the used
sieve type is 10 t/(m2h).
* NOTE: The efficiency of the screen is defined as the fraction of particles fed to the screen with a size smaller
than the screen opening that are actually passing
Feed
Screen
Crusher
To Milling
Unit operations in
minerals
processing and
recycling
Week 2
Classification
• Separation based on settling velocity of particles
- A function of size, specific gravity and shape
- Particles with settling velocities less than the velocity of fluid will produce an
overflow; those with greater velocities produce the underflow or spigot product
• Hydrocyclones is a classifying operation extensively used in grinding circuits
- Use centrifugal force to accelerate the settling rate of particles
- Preferred over screening for high throughput of fine particles
Overflow
Settling velocity < V
Overflow
Fluid Feed
Velocity
(V)
Underflow
Settling velocity > V Underflow
35
Principles of Classification
• When a solid falls freely in vacuum, there is no resistance and the particle will
accelerate under the action of gravity independently of its size and density, i.e. a
brick would fall with the same speed as a feather
• In a viscous medium, such as air or water, there is a resistance to this
movement, which increases with increasing speed of the particle
• When equilibrium between gravitational and resistance force is reached, the
particle falls with its constant terminal velocity
vresist
vVacuum
vgrav
36
Principles of Classification
• The resistance, or drag force, depends on the velocity of the descent
• At low velocity, the layer of fluid in contact with the particle moves with it, while
the fluid at short distance is motionless → between these positions, a zone of
intense shear in the fluid all around the descending particle is formed
• Effectively, all the resistance of the motion origins from the shear forces (with the
viscosity of the fluid) and thus called viscous resistance
37
Principles of Classification
• At high velocities the main resistance is due to the displacement of fluid by the
body (turbulent resistance), with the viscous resistance being relatively small
• With increasing drag forces, the acceleration of the particles decreases and the
terminal velocity is reached relatively quickly
38
Sorting column
• In a sorting column, a fluid rises
with constant velocity → particles
are introduced and either sink or rise
according to their terminal velocity
• This results in the separation of the
particles in two products, an overflow
and underflow
39
Principles of Classification- free settling
• Free settling refers to sinking particles in a large volume, so that particle-particle
interactions are negligible (usually when solid weight is less than 15-wt%)
• A particle of diameter d and density ρS is falling under gravity in a viscous fluid
with ρF , so that 3 forces are acting: gravitational, buoyant and drag force
• When the particle falls with its terminal velocity, the acceleration is zero, and
hence:
The range in which the Stoke´s or Newtons´s law is valid is determined by the Reynolds
numer, i.e. for Reynolds number below 1 the Stoke´s law is applicable (laminar flow), while
for high Reynolds number > 1000 the Newton´s law should be used
41
Principles of Classification
There is an intermediate range of Reynolds numbers, which corresponds to the
range in which most wet classifications take part and neither law fits
→ a number of empirical equations are derived to estimate the terminal velocity
42
Principles of Classification
For the special case of a rigid and smooth spherical particle, the drag forces can be
derived as a function of the Reynolds number introducing the drag coefficient
43
Principles of Classification
For the special case of a rigid and smooth spherical particle, the drag forces can be
derived as a function of the Reynolds number introducing the drag coefficient
1 Stoke´s region
2 Approximation formula
3 Newton´s region
44
Types of Classifiers
• The most important categorization is based on the forces acting, either
gravitational or centrifugal
• In mineral processing, centrifugal classifiers are used due to their high efficiency
at low particle sizes (<70 µm)
• Gravitational classifiers are very inefficient for the separation of particles
smaller 100 µm
45
The hydrocyclone
The hydrocyclone is a continuously
operating classifier that uses centrifugal
forces to accelerate the settling rate of
particles.
46
The hydrocyclone- basic design and operation
• A hydrocyclone consists of a conically
shaped vessel, open at its apex, joined
to a cylindrical section, which has a
tangential inlet
• The top of the cylindrical section is
closed with a plate through which
passes an axially mounted overflow
pipe, which is extended into the body
of the cyclone by a short, removable
section (vortex finder)
• The vortex finder forces the feed to
travel downward, which prevents
short-circuiting of the feed to the
overflow
47
The hydrocyclone- basic design and operation
• The feed is introduced under
pressure through the tangential
entry, introducing the a swirling
motion to the pulp
• A vortex is formed in the cyclone with
a low pressure zone along the vertical
axis, where an air core develops
• The air core is connected to the
atmosphere through the apex
opening
48
The hydrocyclone- basic design and operation
• Particles within a cyclone are subjected to
an outward acting centrifugal force and an
inwardly acting drag force
• The centrifugal force develops an
acceleration the settling rate, separating
particles according to their size, specific
gravity (density) and shape
• Fast settling particles move to the wall of
the cyclone and migrate down to the apex
opening
• The slow settling particles move toward the
zone of low pressure along the axes and are
carried upward through the vortex finder
to the overflow
49
The hydrocyclone- basic design and operation
• The existence of an outer region with
downward flow and an inner region with
upward flow implies a position at which no
vertical velocity exists, called envelope of zero
vertical velocity, throughout the greater part
of the cyclone body
• Particles lying in the envelope of zero velocity
have equal chances to move to either the
over- or underflow → represents the
cut-point described later
50
Classification - Hydrocyclone operation
Slurry in vortex
Flow to apex
51
Classification - Hydrocyclones
52
Classification - Hydrocyclones
Tangential and axial velocity profiles
• There is in addition, a radial velocity profile of a comparatively much
lower magnitude
53
Classification - Hydrocyclones
54
Classification - Hydrocyclone operation
Beware of roping and spraying
55
Classification - Hydrocyclones
Hydrocyclone efficiency
• Efficiency can be simply
defined as:
Hydrocyclone efficiency
• And for a particular size range, an
analogous reduced grade* efficiency
- *NOTE: in this context, “grade” refers to
the separation of particles, not the
concentration of valuables, ”grade
efficiency is also called ”partition value”
57
Classification - Hydrocyclones
Several authors have proposed correlations (mainly empirical, but not always), trying to
predict the cut-point size based on the dimensions of the hydrocyclone and flow rate
parameters:
Dahlstrom (where C is an experimentally determined constant):
58
Classification - Hydrocyclones
(…continued)
Lynch and Rao (K is a function of material and hydrocyclone, e.g., 2 for silica, 2.5 for
copper ore)
…and there are some more (see Will´s “Mineral Processing Technology”)
59
Classification - Hydrocyclones
Hydrocyclone efficiency
• Analogous to screening, hydrocyclones
use an ideal d50 size as nominal cut point
Ideal
• Some correlations have been proposed to
0
produce a “corrected” d50 to account for d50
the size fraction reporting to the Size (microns)
60
Cyclone efficiency- Partition curve
• The efficiency of a classifier is (mostly)
represented with the help of a partition
curve
• It states the weight fraction of each
particle size, which is accumulated in the
underflow
• The cut-point (d50) is the size for which
the chance is 50% to end up in either
over- or underflow
• In reality, some of the feed material
moves as short-circuit directly to the
underflow without any separation, and
thus a corrected partition curve is
sometimes presented
61
Operation parameters affecting performance
Cut size: Flow split of water to underflow:
Increase with cyclone diameter Increases with larger apex or
Increase with solid concentration in feed smaller vortex finder
Increases with viscosity Decrease with flowrate
Decrease with flowrate Increases with solid concentration
Increase with small apex or large vortex in feed and/or viscosity
finder Flowrate:
Classification efficiency: Increases with pressure
Increases with correct cyclone size Increases with cyclone diameter
selection Decreases with solid
Decrease with feed solid concentration concentration in feed and / or
Decreases with viscosity viscosity (at const. pressure)
Increases by limiting water to underflow
Due to many dependencies, the parameters of the cyclone should be as constant as possible!
62
Classification - Hydrocyclones
63
Classification - Hydrocyclones
64
Classification - Hydrocyclones
65
Classification - Hydrocyclones
66
Classification - Hydrocyclones
67
Gravitational Classifiers (GC)
• GC are best suited for coarser
classification, or as dewatering or
washing equipment
• Simple operation and low energy
requirements
• Capital outlay comparably high to
cyclones
• Two groups of GC: sedimentation and
hydraulic or counter-flow classification
68
Sedimentation Classifiers
• Simplest form of classifiers, which basically separate
solids from liquids
• Also as de-watering unit
• Not suitable for fine classification
• Used for de-sliming coarse sand products in
aggregate industry
• Pulp is fed into tank as a distributed stream, valve S
initially closed
• When the tank is full, overflow of water and slimes
begins
• A bed of settles coarse material until it reaches a
certain level
• Valve is opened and coarse discharged
• Classification takes part horizontally in zone D
• Challenge is the disposition rate of coarse
69
Mechanical Sedimentation Classifiers
• Classifiers in which material with lower
settling velocity carried away through a liquid
overflow
• Material with high settling velocity is disposed
on the bottom and mechanically removed
• Used in closed-circuit grinding operations and
in ore-washing plants for sizing
• Pulp is introduced into an inclined through
and coarse particles quickly reach the bottom
• Above is a quick sand zone in which settling is
hindered (depth and size depends on feed)
• Above, free settling material, which partly
moves over the overflow → fines collection
• Solid concentration often too low and de-watering
required before further processing
70
Mechanical Sedimentation Classifiers
• Settled sands are moved by mechanical rake
or helical screw
• Conveying mechanism serves to keep fines in
the suspension by gentle agitation
• When sands leave the pool, they are slowly
turned over by the raking action, or washed
with spray liquid to remove the fines from the
coarse and so improve the efficiency
71
Mechanical Sedimentation Classifiers
• The size at which separation is made depends
on the feed rate (the higher, the bigger the
particle sizes collected in the overflow), speed
of rakes or spiral (the finer the product in the
overflow, the more slowly the agitation), the
height of the overflow weir (the higher the
weir the more volume in the pool, the lower
the pulp density in the overflow and the
smaller the size in the overflow)
• Most important is the solid content in the feed
for the operation of sedimentation classifiers,
e.g. from the grinder, a concentration of 65%
is provided, but classifiers work at max. 50%,
however min at 10% (critical dilution, increase
of coarse in the overflow)
72
Hydraulic Classifiers (HC)
• Characterized by the use of additional water to that of the feed pulp, and its
direction is in opposite direction to the settling movement of particles
• Usually as a series of sorting columns
• In the first column, the rising velocity of the water is the highest and reduced
consecutively with each following column
• The underflow passes a spigot and collect below the HC
• The finest fraction overflows the final sorting column
• The size of each successive vessel increases to reduce surface velocity steadily
73
Hydraulic Classifiers (HC)
• Free-settling classifiers barely used because of low efficiency, although high
capacities
• Hindered-settling HC´s used for sorting the feed to certain gravity concentration
processes so that the size effect can be suppressed and the density effect enhanced
74
Experience without theory is blind,
but theory without experience is mere intellectual play
-Immanuel Kant, philosopher
75