9AACA0A16893 Revlsidn date: 201 2J0tl22

PESGUARD ALPlIA 5FI

.;, 5liMtloirro cl {:tMtcaL ao,ltd

MATERIAL SAFETY DATA SHEET

i
1 P Ro qu cr AN Lqs!LP.A\y.. !qF_N-r.! ilqA-r! oN- -.._
Produci [3lnoi PISGUARD ALPXA 5FL

Synonynrs, Taade Names: astenvaierate 5% FL

L:.nltation on use: Plblic hygiene inseciicide

Snpplier:
Company Narne: SUMITO|O C$rilllCAL COMPANY, ll[rllTED
ContactDcfn*,nellt/ VectorControlDivision
S!!tion: ?7-?, Shinkawa 2-chome, Chuo-k!, Tokyo, 104-8260,llpan
T?lophorei +81-3-5543,5622
Fax: +81-3"5543'5947

Emergency telophone: Asia - Paciiic reglon (excluding Clrin€)i a65-3150-1074 (CARECHaM24.

Sing€pore)
China: +86-10-5100'3039 {cARlcl'lEl"'121, asljins, chln6J
Amercas (excluding USAJ, [r]iddle Fasl, Airica, lsrael (Esrope and Engla3h
Language speaking counlnes)i 141-'1235-239-670 (cAREcHElvll4,
UK)
Middle East/Af rica (Arabic spaaLng couniries)i +44"1 235'23S'671
(cAR€CHElV24, UK)

l? na+loCtqrNllllS4lloN _*___:l
Extlosives Not apphcable

Noi €pplicable
Nol applicabl€
Gases under press!re
Nol c asslfied
Not aDDlicable
Selt-f3aclive slbsiances and mixtures
Pwooho c liouids Nol c assfed
Not aDolicable
-P-vigl!g!! 99!gq
Seli-h?alnq subslances and m xLures Clr$silication nol possible
Sulallnces and mixlures, !,ir6h rn coniact Nclclessliied
wi{h waler, emit flamnrable q?ses
Oxidizino liouids lassillcalion nol oossible
Oxidizing so ids
Not aDD icabie
Classilrcation nnl rossible
Healt! hazards Caleqory4
Acuie loxi.ii, (rer.3ll NoL cla5silled
Acute ioxicitv (lnhalalion - qasJ Nol applicable
Acule lo:iailv alnhalalion - vaoour) C assilcaion not po6sible
A.ute:oviNl:v llnhriallon - dlsl and misu Clastilcallon nol possibl€
Skin cofi osion,,l(llrlion
Se ous eve danraoe/eve iriieiion Noi classiled
Resp rdloe sensir zer Clr*ii.aUon not oossible
Sl.rn sens tzer Not ciassliled
Gelm .:ll mlbreniciiv classtticalion noi oossible

General MSDS_EN SDS No: |VTJ631sVC-WORLD-EN 118

 900000016893 Revision daie: 2012l05/22
PTSGUARDALPHA 5'!

Crra Classillc6tion nol oossible

Classilication not
Stea,aa la,gal orlrn lcxaaity s;ngle :ilrsui€ Cslegory 1 (Centri Netuous
9vi!e].1),,, . -
Specta aatg6: orga n loxicily - repealed Category 2 (Neruous Syslem.
B
n9!Pq!:!19
E']vironmrntalhrzrtd: Ac!le la4qrd! !oiltqqq!t?!i,S-e.ny-if9!!I9t'!., .. Cal€grfy 1

Chronic fazards lo ihe aoUslic environnenl cqlegory .l . _-.,.. .,--..., _..,..

Ha?ardous to lia ozone layer .Class,i,carLon no!pors !!L
GHS lrb6l dlemrnir
Syhbollsli

.frU_ '. 'b (^dl:b '. 'l*{

". '
.i.-
.'siit-
l':

SignaI{,,/ordsi aar'|!et

Hazard Stalornertls): H302. Hamful ii sv€l'cu/ed.

H370: Caus?! damageio CenlralNervous Sysiem.
H373: l\,lay.arse da6age lo Nervous Systern, Krdneysand Blood iiroull
prolonged or ral,ilaled 6xpcsurs.
H400: Very loxic lq 3quailc llie.
H410i Very tlxjclaaquatic ite wilh lonq lasilng effects.

Slatement
P270i Do nalgai daink or sfiokev/hen using th s prodlct.
P260i Do noi brealire drsl/fume/gaslnri6trepo!rslspray.
P273: Avoid a€lerse io lhe Fn1]iron eni
P261: [rash i"ce and hands tholoughly alter handling.

P391: Coll.clspillsge.
P330: Ri se !!tlr.
P30'1 r'P312: 1F SWALLOWEO: Call a PC16ON CEl']::ll!! docior/physioian lf
,aar lr.l!.well.
P31r: Gel mgaiaal adlice/alieniion if you jeel unwell.
P321: Spsriclrsalaenl (See 4. Firsl'ald measLrre").

Storagei P405r Slore loakld !t.

Oisposal: P501 : Dispose oi conie.ls/coala:n$ aptratrr:ely !a accodance wiih
locallregionaVnationalllnlerraiional rcgulailars.

ls
3 aoMPOSTIOI l.j
codrPo:i:lolil NFOR!IA,f|ON ON tNGREDtgNtS I
S0bs€rce or Pa6pg&lion: trirt!re
CAS.li.,

(SJ-s'cyano'3'phenoxybenzyl (S)-2-(4-chlorophenyl) 6621t"0r-4 5 0'/o

-3- .ethylbuty.aie
(lSO common narn6 : esienvalorale)

Olirers 154/.

Genelal MSDS_EN SDS No: LWJ631lVC-nrORlD'El'l 2IB

 6893
9AOOO0A1 Revrslor daler :1112105/22
PESGUARD AIPHA iIL

l+' Fin-sr lto lt-rnsuREs -

-- -l
lnhalaUoni nemove victiD io fresh air and k€ep at,!r11. a tos lion comf.iarle ior
bre?1nind. Adminlster otlgen ribreaihing is dllii.uli. Apply altit€bl
respiraiion ifviclirn is nolbrealhirc. Do nol ].]ss nrollh_to_fiortn melhod
Keer vi:tim wafln witir a blanketetc. oal ianmediale medical
advi;e/aiteni on. lf vomiiing occuts, keep lread ow 6r) ihai slom.rh .onlenl
daasn1 get nio lhe llrnqs, ffi€r:1of exposua.:o slbsiance n,lay be delayed
Medical observation is ind;caled.

3!h contact: Remolellake o{i Inlnledialgl!' conlarninaied cbtiring and tlrces Gerlly
wastr v/lth plen:y olsoap and wtlet. lfskin irriiation or ralll occurs;Oei
medical advice/aiier1l.n.

Eye conllil: to not rub eye Hold eyalids apad. Begin :n rlnst with walei as soon aa
pa3sible and r nse cauirously jt,sevelal minllea, Remove conaacl lensSa, ij
presenland easy todo. Conllnlr€ inslru. Goi immediale medical

lngeslion Rrns€ moulh. Do aoigive viclim aiything lo drink il heis unconsclous Try to
inducr voniting bt iaving affecled person iouch ba4koillre throatwith his
ling€. oi r! giving him gtiup of ipecac as directed on th? package Remove
viciim ic iresh air and l€ep al resl in a goslion comfodable Lrbrcaihing.
Keep tll.iim wann rliih a blankel etc.6ei i
mediale medical
advlce/alienuon. llvomiilng occurs, keei),lead low so that siornach conlenl
doesn'l gel inloihe ltrngs. Adminisier olrgt.lf lrteathing is diLltrlt. Apply
adii c;al respiraiion ifvictim is nol breeihing.:iLal ofexpos!roi! subsltlce
aaay bed€layed. l,4edical ob:e.!ric,n as indlcaied

Personal Protectlon,or Use pel.onal prolecilre equlp'nenlas requircd.

Firs!"aid Respondersl

Notes to the physici.n: Phenabg$ltal treaimetl nay be eilective lo conlu s:on ln the seiiing oi
acuie poisoning. as pal|allve lreatrnent Publish.d dala indicale lilamin E
Leatm€nt ls efieclive to s,( n garesthesia.

]5 FIRE.FI'!'IINGMEASURES
Exllnguishing rn6dlal Smallfir€s: dry chemical poltdar, carbon d oxide, waler spray
Large iires: llaier spray, iog

Unsui!able sxtinguishing High pressure !tal{ slrea ms

media:

Un!s!alFlre & gxpl€i, For b.seiirei, wlihdraltrom lire area and lelfire burn. Contact may cause
Hazards: bums io lkln and eyes. Corjta;ners may explode when heated. Risk oJ fire
aNd explooion o. conlaclwitL incompallb:e malerial(s) Rurcl'r?nd ire
conlro water may po lute wate$.

Spe.ialFire Figitirg Keep !pwhr. Keep unaulhaized paBonnelrway :fposslble, remove

corlalnerc etpos€d 1o heai or cool\t1lh waler. Dike iire waler for laler
d sposal;aanol spread lhe male al.

Protsci:ve Measur€s: \{,aa. reglonal, naiional, and local slafldaids approv€d tire rghil.g turnout
gear:.d posilive press!€ sell-contained breathing appara{!s (5CBA)
Skuclural firefighters' pioteclive clothirg will only provlde imiied piolectjon
from heai, and may not troviie adequaie proieclion from the harlnfLll
vapors orliquids.

Generr ltlSDS_EN s05 No: lViJ6315VC-W0RLO-EN 3t8

94400A016893 Revision datti 2!12/05/22
PESGUARD ALPi,IA 5FL

RE LEAs_E _M EAsuREs
Porsonal Dr.carrtions: Wear appropriaie proleclive eqoipnren!. Use perso.al lrolecllon
recomne.raed in "8. Exposre contlol/personal prclsclon" lsolale spillor
leal( are€ ior proper disiance ir all dileciiorls. plavideadequale venlilalon
-AccTDENTAL Keep l.lpwind. Do nol aouch damaged conlainers or stlllea lnale al unlesg
wea;ing al!.lpriate prolecllvo clolhing. Do nol eal, dank or smoke when .
using ihls p.odrci. Do not bre.iae dusl/fur.elgstnisuvapou.s/spray. Wash
i3ai: and hsnas lloroughly aller hand ing.

Emergency proceduresi (erp all unrlliorized personnel upwlnd atat. Ctnsult an etperl. WaJn
ltabliafls strricllaa fgs, Navigation lock on \talcawsys Fornr1a.ge safely

Enviaonrn€naal preca!tiorsl Preveni eniry spilied matsraland tunoiffrom spillage controlinlo

\ryaterwayg, a€wers, bas4irenls or conlined areas Alcd releSseto lhe
envlronnlent. Collect sPillage-

Clean-up methods ard :LIMINA'ff ,:l lgniilon sou:c?s s:rch as heal/spa*roler flames/hol
mhtorals and cortaltment 3lrJaceslslaila drscharges. Conalll an expel1. Stop leakit possiblew,lho|l
any isk. Absorb rema:.ing llquid in dry ea*l|, sand or olher non conb!$llble
,:lal,arial and rgtnove lo sale plsct. $e4 "13. Disposal consideralions".

Preventlon ofsecondary fllNllNATE al ignilion scurces $uch as lrearsparks/open llsrxerhoi

surfaces/siatrc discl'rarge!. Prepare approptiate exiingLrish ng ?geni (See
"5. Fire'fightng rneasu.et'JFor large spilJ, conslder inliial dosr'nwind
evacuaiion Jor proper disiance.

7 trillo1'rlqlllA sron-ace - -_--

Handling:
Technicrl ln€:srrus: Use only olidoors or ln a vr'lll"vent laled aaea. K&p upwind for handling
-
oulala9t3 as mu6h ?i rosslble Keep urelrlaaiz*d personnelaway
Fl:r1lNl'l€ alll!nlliln solrces. Us€ clEsr ter_gparkrng loo:s Avoid conlatl
wilh eyes, skin, €nd alcih:ng

Exhaustlng, Venlllatlor!: Venljlalo by applopriais neihod. {See 8. Exto:uro control/perconal

proiecilon"J

l(rtes: lnstall appropriate equiprnenl ard wear apploprlate proiecllv. clolh ng. {See
"8. Expo6uF contol/perconal p.otection")

Safoly measrra!l Wash hai:.]: and iec€ thororghly after handling. aaling, ddnking and
s*aking in woak araas is prohibred. Contatninaled work alothing shtuld &i
be allorad oul ol lle $orkplace oo nol brealle
dusuiuhelgas,h jsYvltorrs/sptay.

Siorsge:
Iechnicat measures: Keep conla ners lighily closed.

tondltions: Wellvenlilale by paoper ananner according to regional. nallonaland lotal

regulations. siore in a dry plac€. Keep aray ftom inconpsiibie maleria's.
See'10. Slabilily and reacilviiy'. Keep alvay trom iood and leedsluffs. Saote
locked up.

Packaging materials: Noia,ornalion,

8 :XPOSURE CONTROLS I P:RSONA!

'ROTECTION
Approp.,alo en gineering iialnlain eye wasb founiain and quick-drenoh facilities in wo*area.
conlrolsi

0ererel MSDS_FN SDS No: LWJ6316VC.WORLD'EN 4B

 9AA00AAt 8893 Ae!lsion dais: 2C12/05/22
P€SOUARD ALPHA 5FL

Perso na I prctective eau ipm€ni (!E[

Respkatory P.otecllon: Breallrlng pol€c1lve eilripnrent should be chosen only according lo specific
reg!]dory €qlircmen&. Wear posiiive prcssure scllconlained brealhing
apparaitrs ISCBA) in ci.rmstance above occupalonal expoeure standalds
lor drsl lncllcling emetgancy proceduresand cleanlng tor aacidenlal

lland tllsralor: Hand prolective equlpmeni shorld bechasen only accordin, iaspecillc
regulalory requirements. lmpetuior]s glores,

Eye protecUo.: Eye protective eq ipment sholld be chos€n or'rlyracording to specilia

reg!la{ory reqlkements. Chemical saieiy gogglos or glasses andfulliac.
slried.

S:in proiectioni perconal protective eqliprnani

itpe)!!t!ia lrt.hosen only accodlnt io
specfic regulaiory requ rcnrenb. Suiltblo lnrpenious proteciive elothh!,
inohding proteciive lootwear, gloves lrb coat, apron orco!6ralls.

Speclfic Hygi6ns l,llasure$: 0o nol eal, drink o.smoke d!nn! {orlt. Wash lho.olghly afler handlingar'ld
bofore ealrng or drirking. Clnlaninalc, wo* clolhing sho!lrl not be allo!&d
oul of ihe workplace. Do not breaihe dusufu meigaslmiswapourslspray.
--:j
lg-pnvstcil lr'tp-criarvricnr- Fnop*EnI]];s _- -:,-.-,,, _ ____::
Parysical State: Vlscous llquid

C.:ori Pae yellowish $/hile opaqu.

Odorl Slighily characterisllc odor

PX; 5.5 (1olo emulsion, 20 'C)

Freezing polnt: No dala available.

8.::tng Poinl: No data available.

Fl!sh Point, Non (Pensky-Mariens cJosed cup)

Al'tgigni(on lonperalure: No dala availa e

Flammability Limit - Upper No data avallable.

l%')-l

Flanmabilityllmlt,:-ower l.,lodataBvailable.
(" )-:

No data availab e,

Vapordell9ity 1?:r-l): No dala ava lable.

Rala:;vc alensity: No data available.

0ohsity: 1.03 g/nl(20 'C)

Sohbillty i,: Waler: Emulsfiable n waler

S.l:rbility ioth€.il No dala available.

Paniiion coofticienl No1 applicable.

(n-.clanol/wate:):

Decomposition No data aval16ble.

Gengral[,,lsDS EN SDS No LWJ6315VC-WORLD-rN 5/8

944000016893 Rovision date: 20 12105/22
PESGIJARD AIPHA sFt

evaporation Rate: No data ava lable.

665 mPa.s {60rpm,20'a, Etype rotation viscomelei

,IO STABILI]Y AND RSACTIVITY

Stability: llr.ierial is 3bble u.d?r rormalc.nd tion!.

Possib:l:{y of hazardous $lrong gxidizers, slrong aclds, slrcng bases I iire and exploslon ilszards

Coaditions to avoid. Healing

lnco:rpalible materials: Sarong oxidi2ers siror'rg ?cids, slroJrg bases

Hazardous d€compos*loa Carbon monoxide, carbon dioxide, hyd.ocarbons, nikogen oxides' hyd.ogen
cyanlde, hydrogen chlo de, phosgene, cho de co pourdt, sool

11 IOXICO!aG|CALlNlORMA.ttOtl
are nol a,ril3ble, l]1! d:ta oilngredienis is

Aculoloxicity:
Oral: Rar L D50 980 mg/kg

Deamal: Rat.lD50 > 2,000 ng/kg

lntalationl D.lsrllist Ra!: LC50 (4 h)' 1,900 mg/m3

skin coirosion/itritallon : Rabb.l!s, I r' al o_,corfosor L€sr) .f 'ol/

rf'lalrg

Serious aye damage/eye Rabbii (eye irrilaiion/corosion les0 i minimally iriil?ling

lrritation:

Re€plritory sensiti2elSkln Gui.3a pig sii:r sensilzer (buehlerlesiJ : non'sensitz€r

sensltker:

Cerm ftll mltagericity:

No daia available.
Esi6nlalerate Anieg lest (S. typhim!riumsnd E. coli) : negatlve
Chrar.osome abdrralion te3l {r ammalclJllured cell) : negaiive
Oene nuistion llsl l$ammal cdlirred coll) i nelalive
Urschedllad DNA synthesis as3at imammalcullured cell) :negalive

No data available.
l\,4icronucleus iest (mouss) negailve

Caactaogenicity: No drta ?vailable.

tsianvalerale l\4oLse carc loger c,ly sldd/ (d,et 'e_va e rlcr : ror carc'noqen '
Rel carc''oge" crty st .JJ {d et fenva.eraLo) -o.1_carciroge']ic

Reprodr6tive toxicityi
lerato96nicity:
Esfenvsle,:le Ra1:eratology sludy i non-le€logenlc
Raaall leralalrgy sludy I nol]-leralogeni.

Rep:.duatlon: No data availalrlt.

Esltfivalerale R?l reproduciive loxicitysiudy: no effecl on reproduction

Spe.ifjc aar!et organ (inhalolion) | cenllal nervous syatem

toxiclty - slrgl. exposlrs:

OeneGlIlSDS_EN SDS No: |VTJ6315VC-WORLSCN 6/8

9000a0016893 Revisian dater 2012/05/??
PESGUARD ALPHA 5FL

Sp!clfic target organ

l.)aaity - repeated

Ra190-day ntealed dosc toxicly sludy {diet) inervous sy$em

Ral 28-dsy repealsd dose toxicity study idermal) i neNolrs syslefl
Solvent Ra:29 dai rc;laled do3e loxicly study (o.al): neryous syslem, kidneys,

Aspiral;on hrzard: No data aloilab e.

Otlrar lffects:

ht ..oroGrcAl- rNFontrnrioN---
are nol alailable' ihe data ol ingredienL is disp]ayed
ii tr,e aaia ot itris 9[ltrct
gcsloxicltyl
Aqrdtic Organismsl
Aclte !oxiclty:
Fish: Rriibovr lroul: LC50 {96 hrs) 4.8 !g/l
Ci!slacea: Oapnnia magna: ECs0 (40lrs)25 ug/l
Alga: No dala available.
Esfenvale€le Alga r EC50 (0-S6 hrs) 0 0065 mg/l
Cbro ic Toxicityl
Fish:
Cr(ls:aara: No daia arailable.
Esienvaleraie Dathnia mrgna : NofC 0 0014 pg/l
Algal Na dala avaiable.
Esler\talglate Alga i NOFC 0 001 mS/
othe6i No data available.

Blodegradation: No data av:rllalrle

Eslenvalerate Lack of iatid liodeg,ad:bility

Bioaccll]'rlalionl No dala ava lable.

Esfenvab*1e BCF (Falhead N.llnnow) " 1,400

Parliiior coefficienl (n- Not applicable.

Eslenvalgraie !09 Pow. t.0 i23'C)

6oil d issipation: No dala available.

Hazardous tg the o?one No d6ia availabie.

layea:
eslenvalerate Montreal P'!l!col. St3$iances lhatDeplele the Ozole Leyer, as amended
: not lisied lo the lvont€al Prolocol

,t3 DtsPosAL cattstDERATI0Ns

0istosalMelhods: Dispose of coolenlsloonlainer app,oldately in accordrnce wiih
locaLregiaialhat onal/ialerruijonal regulat ons

Genea fvlsos,aN SDS No LWJ6315V6-niORLO-EN

 904000416893 Rsrisicn dale: 2012/05/2!
PESGIJARDALPHA 5FL

1
14,,:84flsf!Rr rN FoRMA.Tio!
Interfintiona I sta nda rds:

lM06 - lnternation?l lllarlihe Dangero!s Goods Code:

uN3082
Prcprr S:ripping Name Environmenially hazarddus substance, liqulci n.o.s
{estonvelerale nllxlurc)
Class
Packing grolt Ill
Srbsidiary isk labat
Ma ne PollLra.l
fms No.

UN numbe, uN3082
Proper Shlp!ing Nanre Env?onrn€nlallyhazardoussubsiance, :iq!id, n o.s.
(esfenvalerale m xlu.e)
C:ass 9
Packing grolp ,1'
Subsidiary rjsi lAbei

9oilostic Standard: ln coirpllance wilh dc.neslir l6w.

speclai, safety Meas!res
and aoa(ilfions for
Transpoalallo :
Make sure noaanage, corroslon. leaks, and so on on lhe containe(s)
Netore lransporlaiict. Load noi lol3ll, aiaop, damage lhe prgdalcl, and make
surs to take measvreslo secLrre {he loaded prcducls EqLip ln edomobile
or ship for kansporlaiior itrilh proiectjve equip enl {gloves, eyeg,asses,
mask. elc) and fire exling! sher, tools necessary for enelg€ncy.

i1 5 REGULATORYIiIFORMATION

Please follcw local regllalions

!16 OTTIER INFORMATION

Disclaimer: The provided nioamalion is based on currently available la!r', maierials,

information. and daiat howevet, inlormalion regarding aoncenhalion'
phyaical and chemical prope es, and ha:sd idenlii€llon is not
gu,l&nleed. Precaulonsfo. sais handlillg are ntendtd ior a norm?l
;ondliion. ln case ol specifrc cordltlon, please handlo a lroductwiih
applopiiale $aiely areasures lhal are comttlible 10 the product usage

cenelal lr,lSDS_EN SDS No:.WJ6315VCWOR.D-EN 0/8