Professional Documents
Culture Documents
Dangerous goods are substances or articles that are potentially dangerous to people, property and the
environment. They include:
1 Explosive Explosive substances or articles used to produce explosions, which have a mass
explosion hazard or present no significant hazard (i.e. Nitroglycerin 硝化甘油 has been
used as an active ingredient in the manufacture of explosives)
2 Flammable Substances can be in the form of gas, liquid, or solid.
For example, gases that can ignite in air on contact with a source of ignition
i.e. Butane 丁烷
3 Spontaneously Substances likely to heat spontaneously and catch fire without being lit, i.e. Coal
combustible
4 Water reactive Substances when in contact with water emit flammable gases, i.e. Magnesium 鎂)
5 Oxidizing Substances which produce oxygen, help a fire to burn more fiercely, thus increasing
the intensity of fire in other materials with which they may come into contact, i.e.
Potassium 鉀
6 Toxic Substances likely to cause death or serious injury if swallowed, inhaled or brought
into contact with the skin
7 Corrosive Solid and liquid substances that can severely damage living tissue or attack other
materials such as metals, i.e. Sulphuric Acid 硫酸
Legal Framework
(1) The Carriage of (1) dangerous goods and (2) marine pollutants in sea-going ships is regulated by:-
(a) International Convention for the Safety of the Life at Sea (SOLAS) and;
(b) International Convention for the Prevention of pollution from Ships (MARPOL).
(2) Relevant parts of both the International Convention for the Safety of the Life at Sea (SOLAS) and the
International Convention for the Prevention of pollution from Ships (MARPOL) are included in the
International Maritime Dangerous Goods (IMDG) Code, making this Code the primary legal instrument
dealing with stowage, segregation and carriage of dangerous goods and marine pollutants by sea.
For example, see “Marine Department Notice No. 2 of 2009” for 2008 Amendment to IMDG Code and its Supplement.
DG Classes
1. Dangerous goods are classified in 9 different classes according to their properties.
2. Some of the classes are sub-divided into divisions.
3. Individual dangerous goods are listed in the “Dangerous Goods List (DGL)”
4. A number of dangerous substances in the various classes have also been identified as “Substances Harmful to the
Marine Environment” known as MARINE POLLUTANTS.
Class 1: Explosives (i.e. Nitroglycerin). The six hazard divisions of class 1 are as follows:-
Division 1.1: substances and articles which have a mass explosion hazard
Division 1.2: substances and articles which have a projection hazard but not a mass explosion hazard
Division 1.3: substances and articles which have a fire hazard and either a minor blast hazard or a minor
projection hazard or both, but not a mass explosion hazard
Division 1.4: substances and articles which present no significant hazard
Division 1.5: very insensitive substances which have a mass explosion hazard
Division 1.6: extremely insensitive articles which do not have a mass explosion hazard
Class 3: Flammable Liquids (Liquids, “the vapours of which” can ignite in air on contact
with a source of ignition)
Class 7: Radioactive material (Material for which the specific activity exceeds
70kBq/kg, i.e. Titanium 鈦)
Class 8: Corrosive substances (Solid and liquid substances that can severely damage living tissue or attack other
materials such as metals, i.e Sulphuric Acid)
Class 9: Miscellaneous dangerous substances and articles (Substances and articles that present a danger, but are not
covered by other classes)
IMO DG Classes
The hazard presented by each class is identified by an internationally accepted Hazard Warning Label (diamond).
Identification Label
Class 8 Class 9
Corrosive Substance Misc Dangerous Goods
IMDG Code
The Code comprises 7 parts, presented in two books (Volume 1 and Volume 2).
Both books are used to obtain the required information when shipping dangerous goods by sea.
The Code also contains One Supplement.
EmS Guide
The purposes of the EmS Guide contained in the IMDG Code Supplement, and the EmS Guide is helpful in
fulfilling the requirements of ISM Code.
(1) The full name for EmS is Emergency Procedures for Ships carrying DGs;
(2) The purpose of the EmS Guide is to provide guidance for dealing with fires and spillages (leakages) on board
ships involving the DGs listed in the IMDG Code;
(3) In accordance with the ISM Code, all ships, and the companies responsible for their operations, are required
to maintain a Safety Management System (SMS). Within the SMS, procedures for responding to potential
shipboard emergency are required;
(4) This guide is intended to assist ship-owners, ship operators and other parties concerned with developing such
emergency response procedures, which should be integrated into the ship’s contingency plan.
IMDG Code
Use of Code
(1) Prior to loading consignments of dangerous cargo or marine pollutant onboard, you must refer to the ship
specific DOC issued by the flag state or a body authorized by the flag state;
(2) This will specify the spaces available onboard for loading the DGs and the additional equipment that may be
required on board.
7.2.1.3 For the implementation of this requirement, two substances or articles are considered mutually incompatible
when their stowage together may result in undue hazards in case of leakage or spillage, or any other accident.
7.2.1.4 The extent of the hazard arising from possible reactions between incompatible dangerous goods may vary and
so the segregation arrangements required may also vary as appropriate. Such segregation is obtained by maintaining
certain distances between incompatible dangerous goods or by requiring the presence of one or more steel bulkheads or
decks between them, or a combination thereof. Intervening spaces between such dangerous goods may be filled with
other cargo compatible with the dangerous substances or articles in question.
7.2.1.5 The following segregation terms are used throughout this Code:
a) "Away from";
b) "Separated from";
c) "Separated by a complete compartment or hold from";
d) "Separated longitudinally by an intervening complete compartment or hold from".
7.2.1.6 The general provisions for segregation. Between the various classes of dangerous goods are shown in the
"segregation table" of 7.2.1.16. Particular provisions for segregation are indicated in the Dangerous Goods List.
For example:
In the Dangerous Goods List, entry for ACETYLENE. DISSOLVED, Class 2.1, UN 1001, the following
particular segregation requirement is specified:
"Separated from" chlorine
In the Dangerous Goods List, entry for BARIUM CYANIDE, Class 6.1, UN 1565, the following particular
segregation is specified:
"Separated from" acids
7.2.1.6.1 Where the Code indicates a single secondary hazard (one subsidiary risk label), the segregation provisions
applicable to that hazard shall take precedence where they are more stringent than those of the primary hazard.
Notes:
Subsidiary risk (sub-risk)
Where dangerous goods present more than one hazard, the less significant hazards are termed "sub-risk";
When specific Dangerous Goods have more than one significant hazard, they are assigned a Class on the most
significant hazard, and are assigned one or more subsidiary risks (‘sub-risks’) according to the other hazards.
SEGREGATION SHALL ALSO TAKE ACCOUNT OF A SINGLE SUBSIDIARY RISK LABEL
How can I determine if different dangerous goods stored together are compatible?
1. Two or more dangerous goods are deemed compatible if their interaction does not result in a reaction that may give
rise to a fire, explosion, harmful reaction, or the evolution of flammable, toxic, or corrosive vapors.
2. Compatibility charts can be used as an aid in determining if two classes of dangerous goods are compatible.
a) Away from:
b) Separated from:
Legends:-
1) Reference package
Another example refers to the “Table of Segregation of Cargo Transport Units on board ro-ro Ships” below;
a distance of at least 3 meters must be maintained between the units. In the case of that a freight container which
is not a closed freight container, but an open transport unit.
Note. All bulkheads and decks shall be resistant to fire and liquids
Situation “fore & aft”: 1 container space & “athwartship”: 2 container spaces
Situation “fore & aft”: 2 container spaces & “athwartship”: 3 container spaces
Part B
Covers construction and equipment of ships carrying dangerous liquid chemicals in bulk, and
Requires chemical tankers built after 1 July 1986 to comply with the International Bulk Chemical Code (IBC
Code).
Part C
Covers Construction and equipment of ships carrying liquefied gases in bulk, and
Requires gas carriers constructed after 1 July 1986 to comply with the requirements of the International Gas
Carrier Code (IGC Code).
Part D
Includes special requirements for the carriage of packaged irradiated nuclear fuel, plutonium and high-level
radioactive wastes on board ships, and
Requires ships carrying such products to comply with the International Code for the Safe Carriage of Packaged
Irradiated Nuclear Fuel, Plutonium and High-Level Radioactive Wastes on Board Ships (INF Code).
Class 8: Corrosives
Documentation
UN No. is assigned to a DG by the United Nations Sub-committee of Experts on the Transport of DGs (UN List)
Notes:
Identification of Dangerous Goods by Proper Shipping Name (PSN) and United Nations Number (UN Number)
A four-digit number known as the UN Number which is preceded by the letters UN, assigned to a dangerous good
by the United Nations Committee of Experts on the Transport of Dangerous Goods (UN List).
Notes:
Packing Group (PG) - the degree of danger presented by dangerous goods as follows
Packing Group I - high danger
Packing Group II - medium danger
Packing Group III - low danger
Notes:
Dangerous Container Packing Certificate
The IMDG Code requires the person responsible for packing a freight container / vehicle to provide a Container
Packing Certificate certifying that the container has been properly packed, labeled, marked, segregated, and secured.
The cargo consolidator / shipping container packer has a duty to ensure that every package of dangerous goods he
loads into a shipping container has been correctly marked and labeled as in the examples below:
MARKS:
Proper Shipping Name
UN Number
Marine pollutant mark (if applicable to the substance)
LABELS:
Hazard Class Label for “each class” and “sub-risk” (diamond-shaped at least 100mm x 100mm)
Notes:
Subsidiary risk (sub-risk)
Where dangerous goods present more than one hazard, the less significant hazards are termed "sub-risk";
When specific Dangerous Goods have more than one significant hazard, they are assigned a Class on the
most significant hazard, and are assigned one or more subsidiary risks (‘sub-risks’) according to the other
hazards.
SEGREGATION SHALL ALSO TAKE ACCOUNT OF A SINGLE SUBSIDIARY RISK LABEL
-----------------------------------------------------------------------------------------------------------
Contained in an over pack” means a number of packages placed in a box / crate, to form a unit for
convenience of handling and stowage during transport.
The Over pack should be marked and labeled.