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DESCRIPTION JPH06220583A
10 INDUSTRIAL APPLICABILITY The present invention relates to an iron-based vibration damping
alloy having essential strength and toughness as a structural material, and at the same time
having high vibration damping and corrosion resistance.
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14 【産業上の利用分野】本発明は、構造用材料として必須の強度と靱性を具備し、同時に高い制

振性及び耐食性を有する鉄系制振合金に関するものである。

18 [Conventional Technology] For example, the materials for bridges and industrial machinery of
new railways whose location and place of use are close to the residential area and located in
the beach area have high vibration damping and toughness in addition to the strength that is
the basic characteristic of structural materials. Corrosion resistance tends to be required at the
same time. In other words, the problem of reducing the impact on the surrounding
environment is to be solved by suppressing the noise during high-speed vehicle running on
the bridge and during large-scale civil engineering work by the damping effect of the
structural material itself.
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27 【従来の技術】例えば立地及び使用場所が居住地域に近く且つ海浜地区に位置する新鉄道の橋

梁及び産業機械の材料には、構造材料の基本特性である強度に加え高い制振性と靱性及び耐食
性が同時に要求される傾向にある。 すなわち、橋梁上の高速車両走行時及び大規模土木作業時
の騒音を構造材料そのものの制振効果で抑えることによって、周辺環境への影響低減という課
題を解決しようというのである。

34 Conventional iron-based materials used for members intended for vibration damping use a
ferrite former in order to obtain high vibration damping characteristics due to hysteresis due
to the irreversible motion of magnetic wall movement under the action of alternating stress
due to vibration. It is divided into two types, one is a material to which Al and Si are added,

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 and the other is a material to which Cr is positively added, with the aim of making the
structure into a ferrite monophase by addition. As an example of the former, there is a
ferromagnetic type vibration damping alloy in which Al is added up to 7.05% and Si is added
up to 4.5% as described in JP-A-4-99148, and an example of the latter is There is a
ferromagnetic vibration damping alloy to which 8 to 30% of Cr is added as described in JP-A-
52-73118.
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45 制振性を目的とした部材に供される従来の鉄系材料は、振動による交番応力作用下での磁壁移

動の非可逆運動によるヒステリシスに起因した高い制振特性を得るため、フェライトフォーマ
ーを添加して組織をフェライト単相化することをねらい、Ａｌ及びＳｉを添加した材料と、
Ｃｒを積極的に添加した材料との２種類に分けられる。 前者の例としては、特開平
４−９９１４８号公報に記載されるようにＡｌを最高７．０５％及びＳｉを最高４．５％まで
添加した強磁性型制振合金があり、後者の例としては、特開昭５２−７３１１８号公報に記載
されるようにＣｒを８∼３０％添加した強磁性制振合金などがある。

54 On the other hand, N is considered as an element that imparts pitting corrosion resistance
under seawater, which is an indispensable property as a structural material used for the above
purpose. For example, "CAMP-ISIJ" vol. 5 (1992) p. In 2015, it is reported that solid-dissolved
N improves pitting corrosion resistance. It is considered that this is due to the mechanism that
suppresses the decrease in pH by forming a nitrogen compound (NH4) in the corroded pores,
and as a result, significantly reduces the erosion progress of the corroded pores. N is the key
element of this mechanism.
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62 一方、上記目的に供される構造材料として必要不可欠な特性である海水下の耐孔食性を与える

元素としてＮが考えられ、例えば「ＣＡＭＰ−ＩＳＩＪ」
ｖｏｌ．５（１９９２）ｐ．２０１５には、固溶したＮが耐孔食性を改善することが報告され
ている。 これは、腐食孔中に窒素化合物（ＮＨ4 ）を生成することによってｐＨ低下を抑制し
、結果的に腐食孔の侵食進展を著しく減ずる機構によるものと考えられる。 Ｎはこの機構のか
なめになる元素である。

70 However, among these alloys, the alloy described in JP-A-4-99148 has excellent vibration
damping properties because the upper limit of the amount of Al and Si added is inappropriate.
It leads to the formation of coarse Al-based and Si-based inclusions, which act as the point of
occurrence of fracture and thus impair the impact properties, or toughness.
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75 【発明が解決しようとする課題】しかしながら、これらの合金のうち特開平４−９９１４８号

公報記載の合金はＡｌ及びＳｉ添加量の上限規制が不適当であるため、制振性は優秀であるが
粗大なＡｌ系及びＳｉ系介在物の生成をまねき、これが破壊の発生点として作用するため衝撃
特性すなわち靱性を損ねる。

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81 Further, since the alloy described in JP-A-52-73118 has an excessive amount of Cr added, it
causes a decrease in toughness due to the formation of Cr-based inclusions as described
above.
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85 また、特開昭５２−７３１１８号公報記載の合金はＣｒ添加が過剰なため、上記同様Ｃｒ系介

在物の生成に起因した靱性の低下をまねく。

89 On the other hand, the N-adding technique described in "CAMP-ISIJ" for the purpose of
corrosion resistance is not a technique for improving vibration damping property, and in fact,
N-addition itself does not have a function of improving vibration damping property. , Al and Cr
form compounds to reduce toughness, so upper limit regulation is required.
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94 一方、耐食性を目的とした前記「ＣＡＭＰ−ＩＳＩＪ」記載のＮ添加の技術は特に制振性向上

のための技術ではなく、現にＮ添加それ自身は制振性を向上させるはたらきが無いばかりでな
く、ＡｌやＣｒと化合物を形成して靱性を低下させるため上限の規制が必要である。

99 A gist of the present invention is C: 0.02% or less, Si: 1.5 to 3%, Mn: 0.01 to 0.2%, P: 0 in terms
of weight ratio. .02% or less, S: 0.02% or less, Cr: 1 to 5%, Al: 0.01 to 5%, N: 0.0045 to 0.025%,
Ti: 0.005 to 0 if necessary .1% and / or Cu: 0.1 to 1%, and is composed of the balance Fe and
unavoidable impurities, and is a ferromagnetic type system with excellent strength, toughness
and corrosion resistance, which is characterized by being a ferrite single phase systematically.
It is a vibration alloy.
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106 【課題を解決するための手段】本発明の要旨は、重量比で、Ｃ：０．０２％以下、

Ｓｉ：１．５∼３％、Ｍｎ：０．０１∼０．２％、Ｐ：０．０２％以下、Ｓ：０．０２％以
下、Ｃｒ：１∼５％、Ａｌ：０．０１∼５％、Ｎ：０．００４５∼０．０２５％、必要に応
じＴｉ：０．００５∼０．１％及び／又はＣｕ：０．１∼１％、且つ残部Ｆｅ及び不可避的
不純物からなり、組織的にフェライト単相であることを特徴とする強度、靱性及び耐食性に
優れた強磁性型制振合金である。

114 The present invention has been made in view of the above circumstances, and Cr, Si, and Al,
which are ferrite formers and are effective for solid solution strengthening, are added to a
ferromagnetic iron-based ferrite alloy in an appropriate range. Furthermore, by
simultaneously adding N, which is indispensable for improving corrosion resistance, we
succeeded in obtaining an alloy having strength, toughness, and corrosion resistance in
addition to excellent vibration damping properties.
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121 【作用】本発明は前記事情に鑑みなされたもので、強磁性型の鉄系フェライト合金に、フェラ

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 イトフォーマーであり且つ固溶強化に有効なＣｒ、Ｓｉ、Ａｌを適切な範囲で添加し、さら
に耐食性向上に不可欠なＮを同時添加することにより、優れた制振性に加えて強度と靱性及
び耐食性を一度に有する合金を得ることに成功した。

127 In the present invention, in order to obtain high vibration damping characteristics due to
hysteresis due to irreversible motion of magnetic wall movement under the action of
alternating stress due to vibration, a ferrite four is used within a range that does not impair
toughness. Cr, Si, and Al, which are mer, are added in an appropriate range, and N is added
for the purpose of improving corrosion resistance, and as a result, vibration damping,
strength, toughness, and corrosion resistance are simultaneously satisfied.
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134 本発明では、振動による交番応力作用下での磁壁移動の非可逆運動によるヒステリシスに起因

した高い制振特性を得るため組織をフェライト単相化することを目的として、靱性を損なわ
ない範囲でフェライトフォーマーであるＣｒ、Ｓｉ、Ａｌを適切な範囲で添加し、さらに耐
食性向上を目的としてＮを添加し、結果的に制振性、強度、靱性及び耐食性を同時に満足さ
せる。

141 Next, the reason for limitation of the present invention will be described.
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143 次に、本発明の限定理由を説明する。

146 First, C is preferably as low as it is in a solid solution state or when it is precipitated as a

carbide because it acts as an obstacle to the movement of the domain wall and lowers the
vibration damping property, and the upper limit is 0.02%.
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150 まず、Ｃは固溶状態でも炭化物として析出しても磁壁移動の障害として作用して制振性を低下

させるため低いほど好ましく、上限を０．０２％とする。

154 In addition to being important as a deoxidizing material, Si is an important ferrite former and
solid solution strengthening element, so it is indispensable for ensuring vibration damping
and corrosion resistance, and addition of 1.5% or more is important. is necessary. On the
other hand, if it is added in excess of 3%, inclusions such as SiO2 are formed and act as a
point of occurrence of fracture, which significantly reduces toughness. Therefore, the
addition range of Si is 1.5 to 3%.
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161 Ｓｉは脱酸材として重要である以外に、重要なフェライトフォーマー且つ固溶強化元素である

ため制振性確保上不可欠であり、且つ耐食性上も重要であり、１．５％以上の添加が必要で
ある。 一方、３％を超えて添加するとＳｉＯ2 などの介在物の生成をまねき、破壊の発生点

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 として作用するため靱性を著しく低下させる。 したがってＳｉの添加範囲は１．５∼３％と
する。

168 It is necessary to secure at least 0.01% of Mn in order to suppress deoxidation and S and
suppress intergranular embrittlement, but addition of 0.2% or more causes a decrease in
vibration damping property. Therefore, the amount of Mn is set to 0.01 to 0.2%.
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172 Ｍｎは脱酸およびＳを固定して粒界脆化を抑制するため最低０．０１％を確保する必要がある

が、０．２％以上の添加では制振性の低下が起こる。 このためＭｎ量は０．０１∼
０．２％とする。

177 P is an impurity element whose upper limit needs to be regulated to 0.02% because it
segregates at the grain boundaries and remarkably embrittles the grain boundaries, resulting
in a decrease in toughness.
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181 Ｐは粒界に偏析して粒界を著しく脆化させ、結果的に靱性を低下させるため、上限を

０．０２％に規制する必要がある不純物元素である。

185 Like P, S is also an impurity element whose upper limit needs to be regulated to 0.02%
because it segregates at the grain boundaries and remarkably embrittles the grain
boundaries, resulting in a decrease in toughness.
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189 ＳもＰ同様粒界に偏析して粒界を著しく脆化させ、結果的に靱性を低下させるため、上限を

０．０２％に規制する必要がある不純物元素である。

193 Cu is an important element that strengthens the ferrite phase by strengthening precipitation.
A minimum of 0.1% is required to exert the effect, but if it exceeds 1%, the movement of the
domain wall is inhibited and the vibration damping property is inhibited. Therefore, the
addition range of Cu is preferably 0.1 to 1%.
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198 Ｃｕは析出強化によってフェライト相を強化する重要な元素である。 その効果を発揮させる

ため最低０．１％を必要とするが、１％を越えると磁壁移動を阻害して制振性を阻害する。
このためＣｕの添加範囲は０．１∼１％が望ましい。

203 Cr is an important element. Cr is an important ferrite former and is indispensable as an

element for improving overall corrosion resistance and strengthening. Therefore, a minimum
of 1% is required, but if it exceeds 5%, precipitates such as Cr2N are generated and act as a

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 point of occurrence of fracture, which significantly reduces toughness. Therefore, the amount
of Cr is set to 1 to 5%.
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209 Ｃｒは重要な元素である。 Ｃｒは重要なフェライトフォーマーであり、耐全面耐食性向上及

び強化元素として不可欠である。 そのため最低１％必要であるが、５％を超えるとＣｒ2
Ｎなどの析出物が生じ、破壊の発生点として作用するため靱性を著しく低下させる。 したが
ってＣｒ量は１∼５％とする。

215 Like Si and Mn, Al is important as a deoxidizing material and is also an important element for
improving vibration damping and strength. It is necessary to secure at least 0.01%, but
excessive addition causes inclusions such as Al2 O5 and also combines with N, which is
indispensable for addition in the present invention, to form precipitates such as AlN,
resulting in a significant decrease in toughness. It is necessary to limit the upper limit to 5%
for the sake of imitation.
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222 ＡｌはＳｉやＭｎと同様脱酸材として重要であるほか、制振性と強度を向上させる重要な元素

である。 最低０．０１％を確保する必要があるが、過剰添加によりＡｌ2 Ｏ5 などの介在物

のほか、本発明において添加不可欠のＮと化合してＡｌＮなどの析出物を生成し、著しい靱
性の低下をまねくため上限を５％に制限する必要がある。

228 Ti is an important element that suppresses a decrease in vibration damping property by fixing
the solid solution C and the solid solution N, which hinder the movement of the domain wall.
A minimum of 0.005% is required to exert the effect, but if it exceeds 0.1%, coarse
carbonitride is formed and the toughness is rather impaired. Therefore, the proper addition
range of Ti is 0.005 to 0.1%.
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234 Ｔｉは磁壁移動の障害となる固溶Ｃと固溶Ｎを固定することにより制振性低下を抑制する重要

な元素である。 その効果を発揮するため最低０．００５％を必要とするが、０．１％を超え
ると粗大炭窒化物の生成を招き、かえって靱性を損ねる。 したがってＴｉの適正添加範囲は
０．００５∼０．１％である。

240 Next, N is the most important element. N is indispensable for pitting corrosion resistance, and
it is necessary to add at least 0.0045% in order to exert its effect by producing a compound
for the purpose of lowering the pH in pitting corrosion. On the other hand, the addition of a
large amount leads to the formation of precipitates such as Cr2N and AlN, and significantly
reduces the toughness as a fracture point, so the upper limit is 0.025%. Therefore, the
addition range of N is set to 0.0045 to 0.025%.
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247 次に、Ｎは最も重要な元素である。 Ｎは耐孔食性上不可欠であり、孔食内のｐＨ低下を目的

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 とした化合物生成によりその効果を発揮させるため最低０．００４５％の添加が必要である
。 一方、多量の添加はＣｒ2 ＮやＡｌＮなどの析出物の生成をまねき、破壊の発生点として
靱性を著しく低下させるのでその上限は０．０２５％である。 よってＮの添加範囲は
０．００４５∼０．０２５％とする。

254 [Example] A plate-shaped test piece having a thickness of 20 mm, a width of 40 mm, and a
length of 200 mm was prepared from a match metal having a component range shown in
Table 1, and vibration damping property was measured by a mechanical impedance method.
Furthermore, a tensile test and a Charpy impact test at room temperature were also
performed. In addition, a test was conducted in which a change in the pitting corrosion depth
margin (unit: mm) when a 5% NaCl aqueous solution was sprayed and the Fe-5Cr-0.005N
alloy was used as a reference was measured after one year. The results are shown in Table 2.
Table 1 also shows whether or not the structure is a ferrite single phase.
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263 【実施例】表１に示す成分範囲の供試合金を作製し、これより２０ｍｍ厚×４０ｍｍ幅

×２００ｍｍ長さの板状試験片を加工し、機械インピーダンス法による制振性測定を行った
。 さらに、室温での引張試験及びシャルピー衝撃試験も行った。 また、５％ＮａＣｌ水溶液
を散布してＦｅ−５Ｃｒ−０．００５Ｎ合金を基準とした場合の孔食深さしろ（単位
ｍｍ）の変化を１年後に測定する試験を行った。 結果を表２に示す。 表１には組織がフェラ
イト単相であるか否かも記載した。

271 No. 1-No. Reference numeral 4 denotes an alloy having a component range of the present
invention. 5-No. Reference numeral 20 denotes a comparative example alloy outside the
component range of the present invention.
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275 【００２５】Ｎｏ．１∼Ｎｏ．４は本発明の成分範囲の合金であり、Ｎｏ．５∼Ｎｏ．２０は

本発明の成分範囲外の比較例合金である。

279 Comparative Example Alloy No. 5, No. 6, No. 11, No. No. 20 had low vibration damping
property due to the effect of inhibiting the movement of the domain wall due to the excessive
addition of C, Mn, Cu, and N, respectively.
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283 比較例合金Ｎｏ．５、Ｎｏ．６、Ｎｏ．１１、Ｎｏ．２０は、それぞれＣ、Ｍｎ、Ｃｕ、Ｎの

過剰添加による磁壁移動の阻害効果によって制振性が低かった。

287 Comparative Example Alloy No. 7 is Si, No. 12 and No. No. 13 was inferior in vibration
damping property and strength because Cr was below the lower limit of the present
invention.

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----------------------------------------------------------------------------------------------------------------------------
291 比較例合金Ｎｏ．７はＳｉ、Ｎｏ．１２及びＮｏ．１３はＣｒが本発明の下限を下回るため制

振性、強度が劣った。

295 Comparative Example Alloy No. 8, No. 9, No. 10, No. 14, No. 15 was inferior in toughness
because Si, P, S, Cr, and Al exceeded the upper limit of the present invention, respectively.
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298 比較例合金Ｎｏ．８、Ｎｏ．９、Ｎｏ．１０、Ｎｏ．１４、Ｎｏ．１５はそれぞれＳｉ、Ｐ、

Ｓ、Ｃｒ、Ａｌが本発明の上限を上回るため靱性が劣った。

302 Comparative Example Alloy No. 16 and No. 17 was inferior in toughness because Ti exceeded
the upper limit of the present invention.
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305 比較例合金Ｎｏ．１６及びＮｏ．１７はＴｉが本発明の上限を上回るため靱性が劣った。

308 Comparative Example Alloy No. 18 and No. No. 19 was inferior in pitting corrosion resistance
because N was below the lower limit of the present invention.
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311 比較例合金Ｎｏ．１８及びＮｏ．１９はＮが本発明の下限を下回るため耐孔食性が劣った。

314 On the other hand, the alloy No. 1-No. No. 4 showed excellent properties in terms of vibration
damping, strength, toughness, and corrosion resistance.
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317 これらに対し、本発明合金Ｎｏ．１∼Ｎｏ．４は制振性、強度、靱性、耐食性全てが申し分な

い特性を示した。

321 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to supply

structural materials for bridges and industrial machines that are required to have strength,
vibration damping property, toughness and corrosion resistance at the same time, and the
effect on the industry is extremely large.
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326 【発明の効果】本発明により、強度、制振性、靱性及び耐食性が同時に要求される橋梁や産業

機械用構造物材料の供給が可能となり、工業界に与える効果は極めて大きい。

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