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Summary of Articles

1,2,3

by Rudolf Graef, Walther Dick, and Ludwig Von Bogdandy

ROTOR STEELMAKING PROCESS

The recent revolution in steelmaking brought about through the develop-


ment of low-cost tonnage oxygen has resulted in yet another new steel pro-
ducing technique. The rotor process, now in the plant-scale operation stage
at Oberhausen in Germany, may hold the promise of economic production
of open-hearth grades of steel from plants supplied with widely varying
types of iron ore.

Fbeen
OR over one hundred years the story of steel has
a dynamic history of continually mounting
some years the proportion of converter steel in
Europe has been declining steadily, but the grades
production to fill the needs of the smoking factories of iron ore available, the lack of adequate scrap
of this ever more industrialized world. This produc- supplies, and the fuel requirements of the open
tion marathon has been more than accentuated since hearth prevent a complete change-over to the open
World War II, and today with capacity generally hearth. Thus what is required in Europe is a steel
being forced to the limit, the world is anxiously producing technique, not heavily dependent upon
searching for new and more economic production scrap and with low fuel requirements, capable of
techniques designed to make use of widely varying producing steel of open-hearth quality or better.
raw materials.
Statistical analysis cries for new process Requirements for a new steel process
All of the requirements for established steel pro-
In Fig. 1, W. Dick and K. Daeves show in graph-
ducing methods-low capital and operating costs,
ical form the development of ferrous production
suitability for mass production, and the production
techniques in western Germany since 1800, with
of high quality steel-remain valid for any new
some projection to the year 2000, thus output on
technique. There are, however, a number of im-
a logarithmic scale for a 200 year period. This
provements in the converter process which a new
presentation clearly shows that three distinct types
oxygen steel producing technique must solve.
of ferrous production have been practiced: first,
charcoal iron, reaching its peak about 1840; sec- 1) Heat Economy: Fig. 2 shows the theoretical
ond, puddle iron reaching its peak about 1880; heat available in the converter from the oxidation
and third liquid steel without the use of oxygen. of the elements in an average basic converter pig
The output of each of these methods has followed an iron, containing 3.65 pct C, 0.4 pct Si, 1.3 pct Mn,
exact parabola on the logarithmic scale, and the 1.75 pct P, and with the oxidation of 2.65 pct Fe.
production of liquid steel without the use of oxygen Some 501,000 Kcal could be available from every
has now reached the peak of its parabolic path. ton of pig iron, but in the converter process the
Whether or not there be some underlying law-it greater part of this heat is lost. This is largely be-
could be called the parabolic law of production, for cause very little of the exothermic oxidation of CO
it is found in fields other than steel-it would seem to CO. takes place within the converter itself; this
from this statistical presentation of the history of heat, amounting to 200,000 Kcal, is wasted regardless
steelmaking that a new technique of steel production of whether the traditional converter practice is used
must certainly be developed. And this is actually the or some type of oxygen blowing. Due to this loss, pig
case! During the past few years the production of iron must contain at least 1.60 pct P in order to pro-
liquid steel without the use of oxygen has fallen off vide sufficient heat for casting.
as oxygen steel producing techniques have been
2) Flexibility of operation: A new steelmaking
introduced.
process must have a wide degree of flexibility, being
Today in Europe the standard of steel quality is
not only adapted to the use of wide range of raw
based more and more on open-hearth grades. For
materials, but also being capable of producing dif-
RUDOLF GRAEF, WALTHER DICK, and LUDWIG VON BOG- ferent grades of steel. A large number of western
DANDY are with the Hiittenwerk Oberhausen AG., Oberhausen, European mills are forced to rely upon supplies of
Germany. ore purchased abroad from a large number of mines

NOVEMBER 1957, JOURNAL OF METALS-1435


20,000,000

~
~-;. -- and transported long distances. The chemical analy-
ses of such ores vary widely, resulting in pig iron

..
10,000,000
I- ~. - with any percentage of P, Mn, and Si, and with a
comparatively high content of S. If advantage is
/. '.it. taken of all the possibilities which the international
/J: \ market offers, pig iron grades containing from 0.5 to
1,000,000
T~~~UYCE~~~~
h li.. LIQUID STEEL WITHOUT
OXYGEN 1.7 pct P will be obtained. Such pig iron, however, is
not desirable for the open hearth process and is
I- -
4~ ~":. hardly suitable for the orthodox basic bessemer
r~x • , process.
!. i'i· I~ 3) Dust control: Dust in the brown smoke of the

100,000 It' \ converters is very fine grained and therefore diffi-


cult to separate. What is needed is a process which
I- J<, ~ - either produces less dust or dust of a larger particle
, , size. Hot, though undiluted, reaction gases produce
I t the best condition for the formation of dust particles
L~ :'l;l.pUDDLE IRON

V7! ?\i
of a large particle size.
,\
10,000
I- CHARCOAL
IRON
" , The rotor process of Oberhausen--an
~ x answer to many steelmaking problems
I I .<\ \
I In order to solve many of the problems faced at
1,000
the Huttenwerk Oberhausen-particularly that of
1800 1820 1840 1860 1880 1900 1920 1940 1960 1980 2000 the economic production of open-hearth quality
Fig. I-Two hundred years of German steel production on a steels from pig iron of varying composition-devel-
logarithmic scale. Major producing techniques follow an opment work began some years ago on the use of
exact parabolic path and point to the introduction of a new oxygen in steelmaking. Treatment of pig iron in a
technique today. mixer as well as treatment of the steel bath using
oxygen lances in the open hearth furnace turned out
to be less promising than anticipated, because the
I03X
-""""""
life of the refractories was unsatisfactory. Engineers
200
TOTAL HEAT THOMAS PIG IRON at Oberhausen then turned to the possibilities of-
p~~~~~~g~~N
3.65 PCT C
004 PCT Si fered through the use of a rotating vessel.
z
Q
PIG IRON
WITH LOSSES AND
1.3 PCTMn
1.75 peT P
In a casting bay, installation was made of a rotary,
>-
() 150
SLAGING
INCLUDED
WITH 2,65 PCT Fe LOST horizontal, cylindrical vessel, sufficiently large to
-
«
UJ
BY OXIDATION
receive the whole tap of the adjoining blast furnace,
a::
() amounting to 60 tons-Fig. 3. The vessel has an
~
a::
UJ
overall length of 14.6 m, inside diam of 2.7 m, and
J:
>- 100 outside diam of 3.7 m. There are openings in the end
0
x
UJ
walls: one in the front for charging as well as the
::; injection of the oxygen lance, and one in the rear for
0
a::
u..
tapping, removal of waste gases, and flushing of slag.
~ 50 The speed of rotation is infinitely variable between
UJ
1: 0.1 and 0.5 rpm. The rotor lining comprises two
CO P C I Si I I Fe Mn layers: a tar-dolomite layer rammed over a perma-
TO TO TO I TO I I TO rT8'I nent magnesite lining of 120 mm thickness. Rings
CO2 PzOs CO L SiOzJ L FeO LMnOJ
°
Fig. 2-The heat available from the exothermic oxidation of
around the front and rear end openings are made of
chrome-magnesite brick. After the first large-scale
various elements shows that the greatest amount of heat is experimental program, the rotor was furnished with
created by the burning of CO to CO•. This heat is lost in all a tilting device to facilitate tapping. Fig. 4 shows
steelmaking operations except the rotor process. the rotor in operation.

CHARGING DISCHARGING
SIDE SIDE

SLAG~
POT~

_R_OT_O_R_~
~
~~:Q I I
I I
Fig. 3-Pig iron may be charged directly from the blast fur- Fig. 4-The 6O-ton rotor in operation at Oberhausen. Instal-
nace into the rotor at Oberhausen. It is capable of producing lation is now being made of a second rotor, this one of
open-hearth grade steel from varying grades of iron. lOO-ton capacity.

1436-JOURNAL OF METALS, NOVEMBER 1957


The oxygen feed has been arranged in such a in the rotor. Rapid dephosphorization is promoted by
manner that the rotor is supplied with two separate early formation of a highly reactive slag, which in
streams-primary and secondary oxygen-which turn is dependent upon fast melting of lime and the
may be controlled independently. Primary oxygen utilization of a large quantity of ore in the furnace.
is introduced beneath the surface of the metal bath Both are the result of the high operating tempera-
through a water-cooled blowpipe, thereby ensuring tures in the rotor. Fig. 6 provides a comparison with
oxidation and stirring of the bath. For burning the normal converter and oxygen-enriched converter
CO, evolved during the refining process, secondary practice.
oxygen is directed over the surface of the bath- Combustion of carbon monoxide and the resulting
Fig. 5. rise in temperature in the rotor have a positive effect
on the refining rate, partially due to the greater ore
The Rotor-to prerefine pig iron additions. But the speed of refining also depends on
When producing basic pig iron for the open hearth the quantity of gaseous oxygen supplied, and the
from pig iron of any phosphorus content, lime and stirring effect caused by the injection of primary
ore are first fed into the preheated rotor through the oxygen and the rotating action of the vessel. Fur-
charging hole. About 60 tons of pig iron are then thermore, a considerable penetration of secondary
added from the blast furnace through a portable oxygen into the metal is obtained where the bursting
runner; after the removal of this runner, the blow- CO bubbles and the simultaneous displacement of
pipe carriage is brought up, and the blowpipes are slag causes an immediate contact with the oxygen
put into position within the rotor. Following a blow- atmosphere in the rotor.
ing time of about 40 min, the major part of the slag
is removed, and prerefined basic pig iron, contain- Desulfurization effective
ing about 1 pct C, is tapped for transfer to the open Desulfurization in the rotor is much more efficient
hearth. than in the basic bessemer converter or in the open-
hearth furnace-Fig. 7. Reasons for this are the high
The Rotor-steel from low-phos iron temperature of the slag as well as the immediate
The refining of low-phosphorus pig iron to fin- contact between the metal and the oxidizing, sulfur-
ished steel is similar to the production of prerefined free atmosphere. Suitable conditions are created for
metal so far as the operational practice is concerned. a partial oxidation of sulfur, which can be confirmed
The refining process is completed as soon as the re-
quired carbon content is reached.
CONVERTER: ROTOR
WITH OXYGEN
The Rotor-steel from high-phos iron 5
WITH AIR ENRICHED BLOW

For refining high-phosphorus pig iron to produce


steel, the double slag process is used. When the bath
contains about 2 pct C and only 0.1 to 0.2 pct P, then 4

a low-iron, high-phosphorus slag is drawn off and


t-
on. 1'0... .....
ground to make thomas phosphate. With burnt lime
and ore additions a second slag is prepared for de-
phosphorization. Under this slag, refining is brought
~ 3
Q.
o
z
«
'c
\
\c
\ "' \c

~
to an end, and the finished steel is tapped into the
ladle. This secondary slag remains in the rotor, be-
C2
~
.. . .\
\ '
.... of' \p \
ing used as primary slag for the next heat after the
addition of lime and ore. The time between tappings
in
U, .'.• " ~ \p

~~ I, :S.; '..Lt- - 1\rl... ~ ,(


'\~.1n \~ Si
... ~ ~
is about 2 hr: 15 min for charging ore and lime, 10 to Si r--
~ ~~
Si
15 min for charging pig iron, 50 to 60 min blowing ~-
o
time, and 10 min each for the removal of the slag 02040 60 80020406080020406080 100
and the tapping of steel. BLOWING TIME, peT

Fig. 6-Blowing curves for different processes operating on


Dephosphorization more rapid basic-bessemer iron. The rotor shows more rapid early de-
During the first third of the blowing time dephos- phosphorization.
phorization proceeds in advance of decarburization
0.10 RELATIVE SULFUR
REMOVAL
IN PCT BY:
0.08
ROTOR

t-
o
n. 0.06

'":::>
IL
.J i""""" ....... 1::... SASIC SEs
~ 0.04 ~.. ~P,fER
f - - OPENHEARTH .. ....

0.02 ~'oR- r-=


~
i'
o
o 20 40 60 80
BLOWING TIME,PCT

Fig. 5--There are two oxygen lances used in the rotor, Fig. 7-Desulfurization, a comparison between the rotor
one submerged in the bath to refine the iron and the second and other steelmaking processes shows the high efficiency
above the bath with relatively impure oxygen to burn the CO. of the rotor method.

NOVEMBER 1957, JOURNAL OF METAL5--1437


by analysis of the waste gases. The sulfur balance As cooling ore, practically any oxidic iron mate-
between pig iron and the other raw materials on the rial with more than 50 pct Fe may be used. Fines,
one side, and steel and slag on the other, shows a de- concentrates, and mill scale may be used advanta-
ficit of about 15 pct, which corresponds to the geously. Under local conditions, replacement of cool-
amount of sulfur oxidized. The suitability of the ing ore by scrap may be desirable.
process for the treatment of pig iron of increased The iron yield-iron contained in the molten steel
sulfur content was clearly demonstrated, and extra divided by the total iron contained in the charge-is
provisions for the removal of sulfur are not neces- 97.8 pct for the rotor process including dust recov-
sary. The low sulfur content of the steel is remark- ery, 96.9 pct for the basic bessemer process without
able; the maximum is 0.012 pct S. oxygen addition, and 95.3 pct with oxygen enrich-
ment. The low pig iron consumption of the rotor-
Slag relatively low in Fe 997 Kg per metric ton of steel-results from the fa-
vorable utilization of the iron as well as the high
Before starting a new heat, ore and burnt lime are ore imput-100 kg of iron per metric ton of yield.
added to the residual slag in the rotor; in this way
the slag is enriched to about 37 pct Fe and 40 pct
CaO. Refining causes a heavy reduction in the iron Lime consumption
content, and early dephosphorization quickly en- Consumption of lime amounts to 125 kg per metric
riches the slag in phosphoric oxide. ton of steel and is somewhat lower than for the basic
When the metal has reached about 2 pct C, some bessemer process. When pre-refining basic pig iron it
50 pct· of the iron from the ore has been reduced so is reduced to a minimum of 20 kg. Instead of burnt
that the slag still contains approximately 17 to 18 pct lime, crushed limestone may be used without detri-
Fe. At this moment it is necessary to limit the speed of mental effect; however, in this case the ore charge
oxidation for a few minutes so that further reduc- must be reduced to compensate for the dissociation
tion of iron is obtained before tapping the slag. To- heat of limestone.
gether with the high temperature reserve within the
rotor, the slowing down of the oxidation rate en- Oxygen Consumption
sures a sudden sharp reduction of the iron content
of the slag, reaching limiting values of 4 to 5 pct Fe. Total consumption of oxygen per ton of steel
With this low Fe content the degree of fluidity of amounts to 90 std cu m, a third of which is used for
the slag is heavily impaired, and at present from the burning of CO. Some 27 std cu m of O. are fixed
8 to 12 pct Fe in the primary slag is regarded as in the ore and introduced with it. The rest, 63 std cu
economically and metallurgically permissible. m is supplied by gaseous oxygen. Assuming a 90 pct
The primary slag contains 18 to 20 pct p.a•. Under utilization, about 70 std cu m O. will be needed per
the secondary slag the 0.1 to 0.2 pct P in the metal metric ton of steel. The distribution between pri-
is cut to less than 0.030 pct. Rephosphorization has mary and secondary oxygen is at present in the
not been noticed. ratio of 1 :4. The secondary oxygen has a purity be-
tween 70 and 90 pct, but by preheating its concen-
tration may be reduced. By raising the preheating
High slag temperatures temperature to between 800° and 1000°C, which
Thermocouple measurements showed that on the may be done in the exhaust duct with the help of a
average the slag temperature is about 40°C above regenerator, secondary oxygen may be replaced by
the temperature of the steel bath. This is analogous an air blast.
to the open hearth, but contrary to the converter.
The burning of CO in the rotor results in flame tem-
peratures of more than 2000°C, which is higher than Dust control not a problem
in the open hearth furnace. Theoretical estimation Pneumatic steelmaking practice has generally
of the heat transfer shows that 60 pct of the heat been troubled with the problem of air pollution and
arising from the burning of CO is absorbed by the dust control. Oxygen enrichment techniques, includ-
bath. This high heat absorption of the bath is pro- ing the oxygen lance or LD process, have resulted
moted by a bath length of 13 m. in a considerable increase in the problem of dust
When using the air-blown converter only 33.2 pct removal, largely due to the finer particle size.
of the heat is utilized and the remainder is lost in As a possible means of dust removal in the LD
heating nitrogen ballast, escaping CO, and heat process, a suggestion has been put forth for heating
radiation. The corresponding figure for a blast en- the gases to 2000°C to vaporize the iron particles,
riched to 30 pct O2 is 42.9 pct, and for the rotor it is then following with slow cooling so as to prevent
75.2 pct. any sudden oversaturation of metal vapor. The fre-
quency of nucleus formation would be low and the
resulting particle size large. This complex method
Greater direct reduction of ore of enlarging the particle size of steelmaking dust is
The higher operating temperature permits a con- easily realized in the rotor process, for the burning
siderable quantity of iron ore to be charged, thereby of CO, provides the necessary heat for maintaining
providing for a higher degree of direct reduction the iron vapor in an undersaturated state, while the
than is generally possible with other techniques. As slow passage of gases through the rotor into the flue
has been pointed out, high furnace temperatures system permits the slow cooling necessary for the
directly and in,directly promote early dephosphor- formation of large particles.
ization, speed-up of refining, and promote effective The waste gas is exhausted through one pipe im-
desulfurization. Furthermore, since combustion of mediately adjacent to the rotor and is purified in a
CO develops more heat than the oxidation of phos- simple dust collecting plant. Electronic microscope
phorus, the hitherto usual principal heat producer, pictures showed that this comparatively simple
the process is not limited to a certain phosphorus method of dust removal is possible because of the
content of pig iron. linear particle size is on the average 4 to 5 times

1438-JOURNAL OF METALS, NOVEMBER 1957


that of dust particles from the converter, while the rotors, 23 men per shift will be necessary so that
particle weight is almost 100 times greater The wages to the amount of 0.3 man-hr ton may be as-
iron-rich dust collected is recirculated to the' rotor sumed for melting. The number of personnel for the
as raw ore feed. See Fig. 8. pitside will be not more than 0.2 man-hr per ton of
raw steel. For the ancillary installations about 0.50
Process control automatic man-hr per metric ton may be required. Thus, the
total expenditure will not surpass 1 man-hr per
With regard to the measuring and controlling metric ton of steel.
technique, great importance was attached to the
knowledge of the laws of reaction kinetics, so that Other operating expenses: At the present life of
controlling pulses could be derived for practical use. the lining, the consumption of tarred dolomite plus
The decisive factor of measurement is the CO con- sintered dolomite for patching will be approximately
tent of the waste gases. For each phase of the process 50 kg per metric ton of raw steel. With the mechani-
the CO content is the indicator of the main vari- cal modifications of the rotor planned, less than 35
ables, namely refining velocity, heat utilization in kg will be a safe estimation, which is by no means
the vessel, and iron content of the slag. more than the consumption of dolomite in the open
The CO content is influenced by the depth of im- hearth. Maintenance costs seem to be less than for
mersion of the primary blowpipe into the metal as the basic-bessemer steel works, since the mechanical
well as by the ratio of primary to secondary oxygen. parts of the rotor are not heavily taxed.
This interdependence permits automatic control in Oxygen consumption has already been given as
an easy and safe way. Further possibilities of control 70 std cu m per metric ton of steel. This figure will
arise from the adjustability of the speed of revolu- be raised by 5 or 10 cu m when including the oxygen
tion of the vessel and the type of oxygen feed. which is necessary for heating up the rotor after
shutdown and during repairs. The normal working
High quality steels rotor produced pressure is 4 atm gage, ahead of the blowpipes.
According to the experience gained at Oberhausen,
the rotor will probably be used in an integrated steel
works to relieve open-hearth mills with production
programs which are often more versatile than in the
U. S. The rotor may well take over the field of
quantity steels with high quality requirements. It
could be used for melting special structural steels,
e.g., shipbuilding steel, unalloyed boiler steel, as
well as high-quality semi-products for steel wire, Fig. 8--The electronic microscope shows dust particles from
strip, sheet, and bars. Its proper domain is steel the rotor, right, to be on the average 4 to 5 times the linear
with a carbon content between 0.05 and 0.25; how- size of dust particles from the basic converter, left.
ever, there is no objection to increasing this to 0.8
pct C. The process costs are definitely less than the cor-
From the temperature point of view, optimum responding costs of the open-hearth steel works and
conditions are provided for deoxidation. The oxygen may be comparative to the process costs of the basic
content in finished steel amounts to 0.005 to 0.015 bessemer steel works.
pct which compares favorably with highest quality
open-hearth and electric-furnace steel. In addition,
the nitrogen content of fully killed rotor steel aver- Future prospects
ages 0.004 pct, without showing any noticeable In addition to the 60 ton rotor steelmaking unit
spread. already in operation at Oberhausen, a 100 ton unit
is now under construction and should be in operation
Lining life seems satisfactory shortly. Its successful operation can well be ex-
pected to provide the impetus for similar installa-
Thus far at Oberhausen the lining life has been
quite satisfactory, except in the immediate blowpipe tions elsewhere.
The South African Iron & Steel Industrial Corp.
area. At this weak point the new tilting rotor will
has announced plans to install rotor steelmaking
enable the operator to work with an increased depth
plants at its Vanderbijl Park and at its Pretoria
of the bath. Then flow conditions will be improved
works, thereby increasing the firm's crude steel
so that a normal wear of the lining can be antici-
pated. Moreover, the easier discharging of the tilting capacity by some 600,000 tons annually. These rotors
rotor will facilitate the patching of damaged linings, -50 ft in length and 15 ft in diam-will treat 100-
ton heats. Furthermore, it is reported that in the
as is the case with the open hearth furnace.
reconstruction work taking place at the Burbach
steel plant in the Saar, operated by the ARBED
Estimated capital and operating costs firm, sufficient space has been provided for instal-
Capital costs: At present, operational results can lation of two lOO-ton rotors.
be given only approximately. Investment costs have There has, thus, already been a positive response
been estimated at about $24 per metric ton per by the steel industry to the rotor steelmaking process.
annum for a rotor steel works with a yearly pro-
duction of 600,000 tons-buildings and cranes in- References
cluded. This figure corresponds to the costs of the
Rudolf Graef: Grundlagen und Ergebnisse des Stah!erzeugung im
conventional basic-bessemer steel works, while ap- 1
Rotor, Stahl u Eisen, No. 1, Jan. 10, 1957.
proximately $34 was calculated for an open-hearth 2 Remarks made by WaIther Dick to the Vereln Deutscher In-
installation. genieur, July 5, 1957 in Slegen, Germany.
Labor costs: The daily production of a lOO-ton 3 Ludwig von Bogdandy: Untersuchung uber den simu!tanen
rotor may be estimated at 1000 to 1200 metric tons Ab!auj von Tropjchenkeimbi!dung und -wachstum, er!autert am
Beispie! der Staubentstehung bei pneumatischen Stah!/riSchver-
of steel. For operating an installation of two lOO-ton jahren, Zeitschrift fur Elektrochemie. vo!. 1, 1957, pp. 222 to 226.

NOVEMBER 1957, JOURNAL OF METALS-1439

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