Professional Documents
Culture Documents
1,2,3
Fbeen
OR over one hundred years the story of steel has
a dynamic history of continually mounting
some years the proportion of converter steel in
Europe has been declining steadily, but the grades
production to fill the needs of the smoking factories of iron ore available, the lack of adequate scrap
of this ever more industrialized world. This produc- supplies, and the fuel requirements of the open
tion marathon has been more than accentuated since hearth prevent a complete change-over to the open
World War II, and today with capacity generally hearth. Thus what is required in Europe is a steel
being forced to the limit, the world is anxiously producing technique, not heavily dependent upon
searching for new and more economic production scrap and with low fuel requirements, capable of
techniques designed to make use of widely varying producing steel of open-hearth quality or better.
raw materials.
Statistical analysis cries for new process Requirements for a new steel process
All of the requirements for established steel pro-
In Fig. 1, W. Dick and K. Daeves show in graph-
ducing methods-low capital and operating costs,
ical form the development of ferrous production
suitability for mass production, and the production
techniques in western Germany since 1800, with
of high quality steel-remain valid for any new
some projection to the year 2000, thus output on
technique. There are, however, a number of im-
a logarithmic scale for a 200 year period. This
provements in the converter process which a new
presentation clearly shows that three distinct types
oxygen steel producing technique must solve.
of ferrous production have been practiced: first,
charcoal iron, reaching its peak about 1840; sec- 1) Heat Economy: Fig. 2 shows the theoretical
ond, puddle iron reaching its peak about 1880; heat available in the converter from the oxidation
and third liquid steel without the use of oxygen. of the elements in an average basic converter pig
The output of each of these methods has followed an iron, containing 3.65 pct C, 0.4 pct Si, 1.3 pct Mn,
exact parabola on the logarithmic scale, and the 1.75 pct P, and with the oxidation of 2.65 pct Fe.
production of liquid steel without the use of oxygen Some 501,000 Kcal could be available from every
has now reached the peak of its parabolic path. ton of pig iron, but in the converter process the
Whether or not there be some underlying law-it greater part of this heat is lost. This is largely be-
could be called the parabolic law of production, for cause very little of the exothermic oxidation of CO
it is found in fields other than steel-it would seem to CO. takes place within the converter itself; this
from this statistical presentation of the history of heat, amounting to 200,000 Kcal, is wasted regardless
steelmaking that a new technique of steel production of whether the traditional converter practice is used
must certainly be developed. And this is actually the or some type of oxygen blowing. Due to this loss, pig
case! During the past few years the production of iron must contain at least 1.60 pct P in order to pro-
liquid steel without the use of oxygen has fallen off vide sufficient heat for casting.
as oxygen steel producing techniques have been
2) Flexibility of operation: A new steelmaking
introduced.
process must have a wide degree of flexibility, being
Today in Europe the standard of steel quality is
not only adapted to the use of wide range of raw
based more and more on open-hearth grades. For
materials, but also being capable of producing dif-
RUDOLF GRAEF, WALTHER DICK, and LUDWIG VON BOG- ferent grades of steel. A large number of western
DANDY are with the Hiittenwerk Oberhausen AG., Oberhausen, European mills are forced to rely upon supplies of
Germany. ore purchased abroad from a large number of mines
~
~-;. -- and transported long distances. The chemical analy-
ses of such ores vary widely, resulting in pig iron
..
10,000,000
I- ~. - with any percentage of P, Mn, and Si, and with a
comparatively high content of S. If advantage is
/. '.it. taken of all the possibilities which the international
/J: \ market offers, pig iron grades containing from 0.5 to
1,000,000
T~~~UYCE~~~~
h li.. LIQUID STEEL WITHOUT
OXYGEN 1.7 pct P will be obtained. Such pig iron, however, is
not desirable for the open hearth process and is
I- -
4~ ~":. hardly suitable for the orthodox basic bessemer
r~x • , process.
!. i'i· I~ 3) Dust control: Dust in the brown smoke of the
V7! ?\i
of a large particle size.
,\
10,000
I- CHARCOAL
IRON
" , The rotor process of Oberhausen--an
~ x answer to many steelmaking problems
I I .<\ \
I In order to solve many of the problems faced at
1,000
the Huttenwerk Oberhausen-particularly that of
1800 1820 1840 1860 1880 1900 1920 1940 1960 1980 2000 the economic production of open-hearth quality
Fig. I-Two hundred years of German steel production on a steels from pig iron of varying composition-devel-
logarithmic scale. Major producing techniques follow an opment work began some years ago on the use of
exact parabolic path and point to the introduction of a new oxygen in steelmaking. Treatment of pig iron in a
technique today. mixer as well as treatment of the steel bath using
oxygen lances in the open hearth furnace turned out
to be less promising than anticipated, because the
I03X
-""""""
life of the refractories was unsatisfactory. Engineers
200
TOTAL HEAT THOMAS PIG IRON at Oberhausen then turned to the possibilities of-
p~~~~~~g~~N
3.65 PCT C
004 PCT Si fered through the use of a rotating vessel.
z
Q
PIG IRON
WITH LOSSES AND
1.3 PCTMn
1.75 peT P
In a casting bay, installation was made of a rotary,
>-
() 150
SLAGING
INCLUDED
WITH 2,65 PCT Fe LOST horizontal, cylindrical vessel, sufficiently large to
-
«
UJ
BY OXIDATION
receive the whole tap of the adjoining blast furnace,
a::
() amounting to 60 tons-Fig. 3. The vessel has an
~
a::
UJ
overall length of 14.6 m, inside diam of 2.7 m, and
J:
>- 100 outside diam of 3.7 m. There are openings in the end
0
x
UJ
walls: one in the front for charging as well as the
::; injection of the oxygen lance, and one in the rear for
0
a::
u..
tapping, removal of waste gases, and flushing of slag.
~ 50 The speed of rotation is infinitely variable between
UJ
1: 0.1 and 0.5 rpm. The rotor lining comprises two
CO P C I Si I I Fe Mn layers: a tar-dolomite layer rammed over a perma-
TO TO TO I TO I I TO rT8'I nent magnesite lining of 120 mm thickness. Rings
CO2 PzOs CO L SiOzJ L FeO LMnOJ
°
Fig. 2-The heat available from the exothermic oxidation of
around the front and rear end openings are made of
chrome-magnesite brick. After the first large-scale
various elements shows that the greatest amount of heat is experimental program, the rotor was furnished with
created by the burning of CO to CO•. This heat is lost in all a tilting device to facilitate tapping. Fig. 4 shows
steelmaking operations except the rotor process. the rotor in operation.
CHARGING DISCHARGING
SIDE SIDE
SLAG~
POT~
_R_OT_O_R_~
~
~~:Q I I
I I
Fig. 3-Pig iron may be charged directly from the blast fur- Fig. 4-The 6O-ton rotor in operation at Oberhausen. Instal-
nace into the rotor at Oberhausen. It is capable of producing lation is now being made of a second rotor, this one of
open-hearth grade steel from varying grades of iron. lOO-ton capacity.
~
to an end, and the finished steel is tapped into the
ladle. This secondary slag remains in the rotor, be-
C2
~
.. . .\
\ '
.... of' \p \
ing used as primary slag for the next heat after the
addition of lime and ore. The time between tappings
in
U, .'.• " ~ \p
t-
o
n. 0.06
'":::>
IL
.J i""""" ....... 1::... SASIC SEs
~ 0.04 ~.. ~P,fER
f - - OPENHEARTH .. ....
Fig. 5--There are two oxygen lances used in the rotor, Fig. 7-Desulfurization, a comparison between the rotor
one submerged in the bath to refine the iron and the second and other steelmaking processes shows the high efficiency
above the bath with relatively impure oxygen to burn the CO. of the rotor method.