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com Current Opinion in

ScienceDirect Environmental Science & Health

Plastic pollutants: effective waste management for pollution


control and abatement
Kunju Vaikarar Soundararajan Rajmohan1, Chandrasekaran Ramya2,
Manakkal Raja Viswanathan1 and Sunita Varjani3

Abstract Keywords
Plastics have been reported as one of the major pollutants Plastic, Micropollutants, Regulations, Plastic as a resource, Remedia-
among various pollutants that are disposed of in the envi- tion, Waste management.

ronment. They play a pivotal part in human life as they are


cost-effective and are versatile. Plastics are known to have a
mixture of many chemical components and are used for Introduction
various domestic applications. Despite various useful appli- The word plastic comes from the Greek term plastikos,
cations, plastics take a long time to degrade. The burning of which means that it can remain shaped in various sys-
plastics releases chemicals such as phosgene and dioxides tems. Plastics consist of long-chain polymer molecules
that are considered a hazard to the ecosystem. The toxic and are extracted from petroleum, coal, and natural gas
debris that is released from the plastics enters the food chain as its by-product. About 22e43% of plastic wastes end
and water bodies in the form of microplastics. Microplastic- up as landfills, causing the soil to lose its fertility. This is
polluted foods and the presence of meager amounts of because most of the plastic wastes are nonbiodegrad-
phthalates in toys lead to serious health consequences such able, contain lethal additives, and can take up to 500
as congenital diseases and malignant cancers. The dioxins years to decompose. Research indicates that tons of
released from the plastic polymers are lethally persistent ‘microplastic’ debris pollute the world’s oceans. The
organic pollutants which cause tumor and neurological consumption of plastic is increasing by 5% every year,
damage in humans. Inadequate waste management practices and global production is about 150 million tons annually
have led to significant plastic pollution of water bodies. [1]. Chemicals affect people and ecosystems because
Plastics tend to settle on beaches, which decreases esthetic they are present in the form of plastic wastes. Plastic
and recreation values. In this article, we have discussed ways wastes can appeal to contaminants, including persistent
for resource recovery from plastic wastes and the possible organic pollutants. In the marine context, this is the case
effects of plastics on the environment and available safety because many of these contaminants are hydrophobic
regulations for the use of plastics. This article also discusses and are suitable to contaminate the marine life, espe-
scientific literature about the remediation of plastics using cially when buried/disposed of in the sea level [2].
various methods, which can help to promote further
improvement of the existing system by competent authorities Plastics are not inert but contain several toxic chemicals
and researchers. and are also able to disperse in the form of microplastic
contaminants. They contain chemicals that cause
Addresses chronic respiratory disorders and other health problems.
1
National Institute of Technology, Warangal 506004 Telangana, India The dioxins released from plastic polymers are fatal
2
Department of Biochemistry, National University of Singapore 117
organic pollutants that cause cancer and neurological
543, Singapore
3
Gujarat Pollution Control Board, Gandhinagar, Gujarat 382 010, India damage and impair the development of reproductive
systems [3]. In comparison with other materials, plastics
Corresponding author: Varjani, Sunita (drsvs18@gmail.com) have significant advantages in aspects of weight, dura-
bility, and low cost in terms of manufacture [4]. Most
plastics manufactured today are nondegradable, finding
Current Opinion in Environmental Science & Health 2019,
12:72–84 applications in medical, domestic, and commercial
purposes [5].
This review comes from a themed issue on Environmental Impact
Assessment: Green technologies for environmental remediation
The sturdiness of plastic polymers is due to high CH
Edited by Huu Hao Ngo, Wenshan Guo and Raj Boopathy
linkage. One way of degrading such regenerated plastics
For a complete overview see the Issue and the Editorial is to biologically degrade them, which is usually called
https://doi.org/10.1016/j.coesh.2019.08.006 biodegradation [6]. Polymer strength and density are
2468-5844/© 2019 Elsevier B.V. All rights reserved. the most important parameters for the study of plastic
film degradation. The Plastic Bottle Institute has

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Plastic pollutants: effective waste management Rajmohan et al. 73

designed a common system to help reduce and recycle In this article, we discuss the environmental impacts of
disposable products [7]. plastics and e-waste and their possible health effects,
with special focus on India. The plastic biodegradation
With technological advancement and rapid economic techniques reported in this review article will provide
growth worldwide, plastic supplies continue unabated. relevant knowledge about the multiple remediation
Yet a great number of plastics such as polyethylene and techniques available in India. This article also discusses
poly(vinyl chloride) are nonbiodegradable and thus grow regulations and legislation available to monitor the
as accrual pollutants. Plastic polymers affect the degra- excess use of plastics. Finally, this review sheds light on
dation process owing to properties such as unique the impact of overuse of plastics and laws for controlling
chemical structures, molecular weight, melting tem- and ensuring safer use of plastics.
perature, elasticity, modality, and crystalline structures
[8]. The molecular size is a vital aspect of biodegradable Types and properties of plastics that affect
processes [9]. degradation
Plastics are used for a wide range of applications. They
Biodegradable plastics are plastics that decompose are blended with resins (or with other components) that
because of the activity of microbes such as bacteria and are called additives [16]. These additives may include
algae. Aromatic polyesters are most susceptible to mi- artificial fillers (e.g. silica, adipates, polymers, trimelli-
crobial attacks, while aliphatic polyesters are biode- tates, 1,2-cyclohexanedicarboxylic acid diisononyl ester,
gradable owing to their possibly hydrolyzable ester citrates, phthalates) for the reinforcement of plastic
bonds. Some biodegradable plastics may degrade to the fabrics and can be used as stabilizers to avoid disinte-
extent that the microorganisms can metabolize them gration. Some of the important characteristics to indi-
entirely into carbon and water [10]. Conventional plas- cate the level of degradation [17] are as follows: (a)
tics are often mixed with organic wastes and liquids, weight of plastics, (b) thickness of plastics, and (c)
rendering them to be hard and impractical to recycle the density [18].
polymer without the involvement of expensive treat-
ment processes. Recyclable papers are found to be a Two main categories of plastics are widely used for
potential strategy for the rehabilitation of large quanti- commercial purposes. The classification is based on
ties of wastes by composting mixed organic food waste their chemical structure and properties, namely, ther-
scraps and yard trimmings. mosetting and thermoplastics. A thermoset is a polymer
that irreversibly solidifies or ‘sets’ when heated. It is
Phthalates are mainly used as plasticizing materials in mainly used in automobiles, construction, adhesives,
toys such as teethers. In India, most toys contain inks, and coatings [19]. A thermoplastic is a polymer, in
appalling levels of lead and cadmium alloys. Children which weak bonds in the molecules are held together.
tend to suck these toys. All these plastic toxins lead to Thermoplastics can be easily molded and shaped into
serious developmental disorders [11]. However, owing jugs, floor covers, credit cards, and carpet fibers.
to the lack of definite plastic waste mitigation policies Although hundreds of plastic products are available in
and legislation, there have been no clear environmental the market, only some of these are qualified as com-
policies and legislation on plastic waste in India until modity thermoplastics available in large quantities and
recently. Inadequate plastic waste disposal practices are at comparatively low prices [20].
leading to challenges that affect flora and fauna. It is a
great threat to conservation. Although biological Thermoset composite material recycling technology
methods have priority when compared with chemical occurs through three processes. These include (a) me-
treatments in the Indian context, the cost is still a chanical combination technique, which reduces scratch
concern [12]. Incineration is a combustion process that dimensions to create filling products; (b) chemical
is followed commonly for solid waste management. This breakdown into easy chemical components of polymeric
process involves high organic and inert materials, which matrices; and (c) thermal degradation, which reduces
are further difficult to degrade on burning [13]. Polymer plastics and energy waste [21].
degradation also involves microbes in the process of
degradation of plastics. In this process, both natural and
synthetic plastics can be degraded using microbes. The Problems associated with plastics
microplastics-containing debris when burnt results in management in India
airborne contamination by releasing noxious gases [14]. As per the report of worldwide pollution control asso-
The recalcitrant nature of plastics creates an enormous ciation, 5 trillion plastic bags are used every year. It is
burden on the degradation process. For plastics, a lack of believed that the annual accumulation of plastic waste
adequate disposal techniques and inefficient regulations in seas and oceans is estimated at around 13 million
make plastic waste disposal an insurmountable chal- tons. Among all countries, India consumes 50% of single-
lenge [15]. use plastics. In every household, plastic wastes

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74 Environmental impact assessment: green technologies for environmental remediation

account for more than 10% of the total wastes that are Plastics and their associated health and
produced every day. India’s annual plastic manufacture environment risks
growth is nearly 16%, compared with China (10%) and Humans tend to face risks from plastic polymers,
the UK (2.5%) [22]. especially when they are mixed with additives [28].
Besides, burning of poly(vinyl chloride) releases hal-
Plastics were not regarded as a significant risk, and they ogens that contaminate the air. Plastic additives
were simply regarded as an esthetic interference. The produce dioxins or toxic substances. Most plastic
importance of legislating the use of plastics is due to the wastes are sublethal but can become lethal in com-
reasons that they affect soil and marine habitats. Plastics bination with other solid wastes [29]. Polystyrene
tend to undergo photo-oxidation processes when they plastics are detrimental to humans. Without proper
are subjected to sunlight or UV radiation [23]. Most implementation of disposal methods, dumping or
often, toxic gases that contain dioxins, furans, and burning of these polymers leads to serious risks such
polychlorinated biphenyls are released into the atmo- as cardiac malfunction, severe respiratory problems
sphere [24]. including asthma and emphysema, vomiting, kidney
or liver damage, and damage to the reproductive
Besides, plastic wastes that are dumped into the landfill system. Dioxins deposit on the surface of plants and
lead to soil decay and increase the danger of plastic aquatic systems and find their way to enter the
consumption by domestic animals. Plastics that are human food chain. Significant phthalate pathways
disposed of in the aquatic environment result in include direct releases into humans consuming plas-
extinction of aquatic creatures and the danger of bio- tic-contaminated materials, unknowingly. Several
magnification and bioamplification because of toxic chemical substances such as bisphenol A (BPA) are
compounds [25]. Recyclable plastics and biodegradation added to the plastic polymers to enhance their ap-
methods have received attention in recent years plications. Lethal monomers have been linked to
because of the increased pressure from environmental- cancer and reproductive problems [30].
ists to reduce environmental dumping [26]. However,
not all disposed plastics are suitable for recycling, Impact of plastics in marine and fresh water
including plastic bags, packaging wastes, or metalized Even though 80% of marine litters come from land, most
packaging wastes [27]. This is due to the recalcitrant plastics are disposed of in river systems [31]. This is
nature of the disposal product in the low-lying areas, and particularly common along coastal areas. The greatest
hence, the landfills that carry plastic wastes pose a risk consequences of this pollution are faced by birds and
to the ecosystem. fishes. More serious consequences occur if zooplanktons

Table 1

Sources of phthalates exposure and its health effects [37].

Sr. no Phthalates Sources of exposure Health impact

1 Dimethyl phthalate (DMP) (1) Industrials: In petroleum production (1) Fatal toxicity
(2) Insect repellents, plastic (2) Affects musculoskeletal system
(3) Developmental abnormalities of the
eye and ear
2 Diethyl phthalate (DEP) (1) Personal care products such as shampoo, (1) Reduced growth rate
cosmetics, creams, soap (2) Decrease food consumption
(2) Pharmaceuticals, medications
(3) Industrial solvents and pesticides
3 Di-n-butyl phthalate (DBP) (1) Adhesives (1) Decreases sperm production but
(2) Personal care products returns to near normal levels
(3) Industrial solvents after elimination of exposure
(4) Medications (2) Mild skin irritation
4 Benzyl butyl phthalate (BBP) (1) Vinyl flooring (1) Testicular toxicity
(2) Adhesives and sealants (2) Cryptorchidism
(3) Synthetic leather (3) Reduced anogenital distance
(4) Car care products
5 Diethyl hexyl phthalate (DEHP) (1) Soft plastics used in household products (1) Hepatocellular carcinoma
(2) Blood banks storage devices (2) Testicular toxicity
(3) Food containers and packaging (3) Anovulation
(4) Fetal growth restriction

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Plastic pollutants: effective waste management Rajmohan et al. 75

Figure 1

Technologies available for solid waste management.

tend to ingest this microplastic debris as it would additives such as BPA have been associated with adult
disturb their food web [32]. The average density of diabetes, early puberty, and even obesity. However,
plastic pellets in the world’s oceans has been recorded to there have been concerns with the release of chemicals
be between 1000 and 4000 km surrounding the seabed such as BPA, polybrominated diphenyl ether (PBDE),
and coastal areas. Most researchers believe that ingested and polybrominated biphenyl (PBB) from plastics
plastic is likely to injure seabirds that eat fish, which are [38]. Studies on American women’s breast milk con-
becoming extinct. These will result in detrimental ef- tents have revealed the owing to the exposure to
fects affecting the digestive system [33]. Inadequate plastics, brominated flame retardants are highly pre-
recycling costs and improper waste management tech- sent in breast milk. Inducing molecular epigenetic
niques have led to significant amounts of plastics modifications in many organ systems can also
affecting coastal areas [34]. contribute to transgenerational effects [39].

India has 43% of natural coastlines. Unfortunately, most BPA additives present in the plastics degrade their
plastic wastes are disposed of in the coastal areas and monomeric structure because of the heat. These can be
along the lakes [35]. Research into microplastics in the drained from their sources and affect air or food products
sediments of Vembanad Lake, a Ramsar site in India, [40]. Current research indicates that BPA breaks down
showed that microplastics with a particle size of <5 mm in the human body. However, these chemical additives
are found in the intestines of aquatic organisms. The were shown to transform into a compound that can
dominant sort of the polymer element from these stimulate obesity. Research has shown that BPA-O-beta-
microplastics contains a low-density polyethylene. As D -glucopyranoside (BPAG) compound was not estro-
fishes are a major source of food and business in coastal genic and that adipogenesis was caused by the additives
areas, these plastics pose a danger to the food web of the present in the plastics [41]. Repeatedly storing acidic or
lake [36]. basic food items in plastic containers for a long period
results in breaking down of the polymers. Brominated
Health impact of plastics to humans flame retardants are a group of chemical products
Additives are often introduced to plastics to enhance commonly used in electronic equipment, textiles, and
their hardness or to make them colorful for their healthcare sector, the annual consumption of which
respective applications [37]. Many of the additives in being more than 1.5 million tons. In vitro studies have
plastics have been associated with severe health dis- shown that both ovarian and testis functions have been
orders that include sexual disorders and disruption of altered after exposure to PBDEs, resulting in thyroid
endocrine systems. Reports have shown that traces of hormonal imbalance [42]. Prenatal PBDE exposure is

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76 Environmental impact assessment: green technologies for environmental remediation

associated with a low IQ and hyperactivity in children sustainability remain a challenge in India [51].
[43]. There are several technologies available for the
management of plastic solid waste management as
Impact of plastic phthalates used in children’s toys discussed in Figure 1.
Phthalates are the group of heavily exploited com-
pounds, containing phthalic acids that are used in toys. Chemical treatment methods
These additives act as stabilizers to provide flexibility These methods are based on the use of chemicals that
and elasticity in toys [44]. The ingestion of phthalate- can break the polymeric linkage of plastics and convert
contaminated materials occurs through household arti- polymers to a nonhazardous state. These methods
cles, food packed in plastic containers, cosmetics, or cannot be used in large-scale operations because
exposure to air through wall paints [45]. The prevalent chemicals used for plastic degradation will create huge
causes of pollution and effects of different phthalates chemical waste debris [52]. Traditional practices of
are shown in Table 1. plastic waste treatment and disposals cause more
damage than benefits. The gases emitted by the com-
The intake of the phthalate-containing plastics has a bustion of plastic wastes are extremely risky and can
risk because of unexpected higher exposure to them trigger a range of respiratory disorders. Disposal of
during the time of children’s growth, which leads to plastic waste in municipal waste disposal systems pro-
physiological illness [46]. duces poisonous leachate when it gets in contact with
soil [53].
Plastic bags: a major threat to cattle life
Thousands of polythene bags are used throughout the Physical methods
world every year by individuals. Polythene obstructs These techniques include physical methods that help in
water drains, pollutes the earth, and slowly but surely decreasing the volume of plastic waste by the process of
poisons the environment. In India, around 95% of urban squeezing, pulverizing, and incinerating. Some of the
stray bovine animals suffer from various illnesses caused commonly used physical methods of waste management
by dangerous materials (mainly plastic bags) that get include UV degradation and photo-oxidation. Moreover,
trapped inside their intestines [47]. People often use these methods generate additional environmentally
plastic bags and polythene bags to store wastes, which hazardous by-products [54].
are eventually disposed of as municipal wastes. Un-
knowingly, animals such as cattle and donkeys consume Thermal treatment techniques
these plastics that contain food products from the Thermal treatment of solid waste can be achieved by
dumping sites. The naive eating habits and mineral incineration, pyrolysis, and plasma arc gasification.
deficit make the cattle susceptible to involuntary Incineration is a process of thermal waste treatment,
digestion of these toxic foreign materials [48]. Depres- which can be used for raw or unprocessed garbage [55].
sion, incomplete anorexia, weight loss, ruminal disorder, Incineration processes take place in air at a temperature
and decreased milk yields are clinical symptoms. Milk of 850  C, and the effluent is converted into carbon
and weight reduction in animals are commonly dioxide, water, and strong waste fuel material [56].
observed. All these will affect their lactation stage, Incineration eliminates the need for landfilling resulting
resulting in infection. In acute stages, these toxins cause in the production of energy that can be useful for other
bloating in the animals, causing their death. When these applications. However, burning of plastics releases many
animals suffer intestinal disorders, a highly expensive harmful gases which cause air pollution. The only
medical technology such as rumenotomy is the only advantage incineration has over a landfill is that in the
option to save the life of cattle. The death of cattle former, we can get some amount of energy from plastic
exercises negative impact on farmers’ day-to-day life, which is not possible to be achieved in the latter process
resulting in disruption of normal agricultural activities [57].
[49].
Pyrolysis is another method of thermochemical
Plastic waste treatments in India conversion in which solid fuel is burned without the
Plastics are now part of our lives. In India, proper- presence of an oxidizing agent (in an inert envi-
ties of plastic waste debris vary significantly with ronment). There are two different techniques of
respect to structure and toxicity in comparison with thermal transition: fast pyrolysis for bio-oil
solid wastes in Western countries. It also relies on manufacturing and slow pyrolysis for charcoal
broad parameters such as food habits, social tradi- manufacturing [58]. The gasification process is used
tions, environment, and income [50]. Although ini- for converting carbonated organic or fossil fuel into
tiatives taken for plastic disposal techniques have commonly used gases such as carbon monoxide,
been proven and evaluated in advanced nations hydrogen, carbon dioxide, etc. in the presence of a
with positive outcomes, financial viability and controlled amount of oxygen or air. The process

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Plastic pollutants: effective waste management Rajmohan et al. 77

takes place at extremely elevated temperatures  In India, MSWs are produced mainly in low-level areas
(>600  C) and oxidizes the hydrocarbon which can that violate plastic dumping process. Not all urban
be used as an energy source [59]. local bodies and states in India are equipped with
appropriate sewage deposits, and wastes are dumped
Biological methods on highways and in the periphery of the city.
In this process, plastic polymers are degraded without  Landfilling is still widely accepted in India although
producing toxic by-products. Biomethanation is the the availability of land for waste disposal is limited.
method of converting organic polymers or solid wastes The penetration of leachate debris into soil is the
into methane and manure by microbial intervention. biggest issue in waste disposal. However, in metro-
This process takes place in the absence of oxygen politan locations such as Delhi, Mumbai, Kolkata, and
through a method called anaerobic digestion [60]. Solid Chennai, there is limited space for waste disposals.
wastes from agro-based sectors are used in this process, The development of new site settlement/extension is
resulting in helpful products such as biogas and soil being reported in states such as Andhra Pradesh
manures. A two-stage method of acidification and (Vizianagaram), Goa, Gujarat (8 sites), Haryana (Sirsa
methanation is discussed in Figure 2. and Ambala), Punjab (Adampur), Rajasthan
(Jodhpur), Navi Mumbai (12 sites), and Maharashtra
Solid waste management in the Indian scenario (Nashik and Sonpeth). Landfills generate toxic gases
Municipal solid waste management (MSWM) is that can damage human and aquatic life. Methane and
controlled by environmental authorities in India. Most carbon dioxide (up to 90 percent) are mainly used in
of the urban local bodies do not have adequate solid waste gas systems (land fill gas [LFG]) and are
waste intervention or implementation schemes. generated as a result of decomposition of not only
Regrettably, no town in India can assure 100% separation methanogenic agents but also CO, N2, alcohol, hy-
of landfill at housing sites. Only 12.45% of the landfills draulic carbon, organic acid compounds, and heavy
gathered are scientifically handled and approved as metals [62].
disposal sites with proper accessible dumping [61].
Figure 3 shows existing and prospective property Role of Asian countries in plastic pollution
demand for storage of municipal solid waste (MSW) of ocean
along with population growth and production of MSW. Plastic bags are convenient and cost-effective way to
pack groceries. They are also nonbiodegradable and
The review of significant MSWM parameters that are usually end up in oceans. Tackling plastic pollution has
observed in the Indian scenario is outlined as follows:
Figure 2

Biomethanation process of solid waste removal.

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78 Environmental impact assessment: green technologies for environmental remediation

Figure 3

Estimate prediction of solid waste generation from 2001 to 2051 [55]. MSW, municipal solid waste.

been less of a priority in Asia, which is the world’s including developing biodegradables and other in-
biggest producer of the material and plastic waste. An novations, in the Group of Twenty (G20) summit held
estimated 1.3 million to 3.5 million metric tons of plastic in June 2019 at Osaka [69].
is estimated to enter oceans annually from the coastlines
[63]. More than 80% of plastic in oceans has originated A nongovernmental organization, One Island One Voice,
from land [64]. A study has revealed that 90% of ocean led a massive effort with more than 20,000 people
plastic originates from just 10 rivers, and among them, 8 gathering to clean up 120 beaches around the popular
rivers are in Asia and 2 are in Africa [65]. The Great Indonesian island of Bali in March 2018. The Indonesian
Pacific garbage patch is an example of large plastic ac- government has set itself the ambitious target of
cumulations on the surface waters. The Great Pacific cleaning up the Citarum River and making the water
garbage patch has 79,000 tons of plastic with a large drinkable within seven years. The Philippines govern-
particle size (mesoplastics and macroplastics) due to ment has ordered the half-year closure of Boracay to
fishing lines, nets, hard plastics, and films. Asian coun- tourists since April 2019 to clean up marine waste [70].
tries such as China, the Philippines, Indonesia,
Thailand, India, and Vietnam contribute more than 50% Vietnam and Thailand will block all imported plastic
of ocean plastic waste [66]. In 2017, one-third of 1.67 waste in the next few years. Taiwan is moving to ban all
million tons of domestic waste disposed of in Singapore one-time-use plastic, including bags, beverage cups, and
consisted of packaging waste, primarily plastic bags, and cutlery issued by restaurants and businesses by 2030. It
food packaging. Japan, although not a major marine has already taken steps to ban single-use plastic straws.
plastic polluter, is the world’s second consumer of Successful outcomes include decreased material-spe-
plastic packaging per person after the United States. cific waste, increased total recycling rates (64% in-
crease), and decreased total garbage volumes (27%
As a plastic waste management measure, if the plastic decrease) [71,72].
input from the catchment areas of the rivers is reduced
to half, it would be a major success. Systematic efforts Indian government regulations for the use
are already being made. In 2013, China introduced a of plastics
temporary restriction on waste imports, naming it To ensure the effective segregation, transport, process-
‘Green Fence,’ that resulted in significantly less ing, and storage of MSWs and to improve current infra-
contamination [67]. Later, in 2017, China announced a structure to prevent soil and ground water contamination,
new import policy permanently banning the import of the Ministry of Environment and Forest of the govern-
nonindustrial plastic waste [68]. Japan had committed ment of India has released MSW (governance and
to lead the world in reducing marine plastic trash,

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Plastic pollutants: effective waste management Rajmohan et al. 79

handling) regulations. Municipal corporation acts have achievement. In India, however, the current situa-
been promulgated from various regions such as the Delhi tion shows that almost none of the waste produced at
Municipal Corporation Act 1959, Uttar Pradesh Munic- the source site is segregated into multiple ecological
ipal Corporation Act 1959, and Karnataka Municipal issues, which results in very ineffective waste man-
Corporation Act 1976 to regulate the management of agement [75].
plastic solid wastes. These acts also address the envi- ➢ Municipal solid waste characterization: India is a vast
ronmental pollution by improper MSW dissipation, for nation separated into distinct climate zones, distinct
example, the Delhi Plastic Bag Act of 2000 on the pre- food habits, and distinct living standards, generating
vention of consumption of foods carried in recycled disposal of distinct kinds. So far, there has been no
plastic bag and disposal of nonbiodegradable waste in extensive research covering nearly all Indian cities to
toilets, highways, and sites [73]. identify garbage produced and disposed of in land-
fills. Government authorities are dependent on the
In efforts to reduce the environmental impact of plas- limited data that are sourced from a few places
tics, legislation and regulations came into use. Such because of inadequate solutions for the waste pro-
regulation often aims to reduce the use of plastic duced in a particular region.
packaging. Some rules can be strictly followed to solve ➢ Implementing ground-level laws: With population
the problems caused by untreated plastic waste to growth, the task of providing appropriate infrastruc-
resolve the issue of waste management. The packaging ture in metropolitan areas and fresh choice of landfill
waste directive of the European Union, Council Direc- sites are becoming crucial. The implementation of
tive 94/62/CE, has been adopted in 1994. It requires the strict laws at the basic levels creates a challenge as
member states of the European Union to take any action most locations in metropolitan towns are not
necessary to collect 50e65% of solid wastes and recycle equipped.
about 25e45% of package waste, with at least 15% for ➢ Need for reliable technology: There is a need to
packaging material of each type [74]. export economically viable and established waste
management techniques in India. Structures with
Some of the important considerations for waste man- adequate capacity to dispose of waste materials,
agement are being implemented by the government. availability of professionally qualified staff , techno-
logically feasible alternatives, suitable and rapid
➢ To ease plastic waste recovery, the size of the debris urban land-clearing choice ensuring clean delivery,
to be recycled has been increased from 40 to 50 mm. are necessary for landfill crops to be identified as
➢ Brand owners, who promote the need for plastic landfill material and supplied separately in accor-
products, must also arrange for collection of all dance with requirements.
wastes generated by their products. This helps to
minimize the production cost and give an insight into Reduction of e-plastic wastes and legal regulations
the need for reduction of production cost. e-waste refers to used electronic products that are
➢ Wastes can be reused for various purposes, for intended to be reused or recycled. e-waste processing
example, as concrete and for solar energy production may cause major health and pollution problems in
in buildings. developing countries owing to few regulations. e-waste
has recently become an important target for the man-
agement of domestic and international material cycles
Safety considerations and challenges for preventing with a view to the preservation of the environment and
plastic usage in the Indian scenario the use of resources [76]. The emission from hazardous
Sustainable low-cost solid waste management ap- materials is mainly due to primitive methods of mining
proaches are essential to be scheduled and executed in metals as well as combustion of e-waste in the open.
developing nations such as India. Lack of consciousness,
financial resources, responsibility, and application of e-wastes, in particular cables and wires, result in the
legislation and policy and inappropriate technical release of persistent organic pollutants. Electronic scrap
expertise are key factors for the lack of proper sanitation components (such as cathode ray tubes, cadmium,
techniques. The following challenges involved in the beryllium, and brominated flame retardants) may
proper management of plastics wastes in India have contain lead. Keeping in mind the harmful effects of
been discussed. hazardous waste on both the atmosphere and hygiene,
several nations have called for a worldwide arrangement
➢ Environmental awareness: Ecological awareness and to tackle these issues. In India, e-waste strategy projects
involvement in the segregation of the landfill at the are rudimentary and need careful consideration.
origin, door-to-door compilation, and storage of
wastes in suitable bins are essential. This is the most The following are some of India’s e-waste strategy
critical stage of the entire MSWM cycle that enables efforts:
proper disposal, leading to the eventual
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80 Environmental impact assessment: green technologies for environmental remediation

➢ The hazardous waste (management and handling) technology will expand the plastic recycling infrastruc-
amendment rules, 2003: Under schedule 3, e-waste ture by making it more efficient and cost-effective
is described as ‘waste electrical and electronic [81,82]. The various health effects of e-waste are
equipment including all parts, subassemblies, and discussed in Table 2.
their fractions except batteries fell under these
guidelines.’ The concept given here is comparable Life cycle assessment of plastic waste
with the Basel Convention Concept, in which e- Life cycle assessment is pragmatically applied for
waste is not covered in depth but only shortly in the products and processes to quantitatively understand
regulations [77]. their effect on land and fresh water [83]. Unfortunately,
➢ e-waste Management and Handling Rules, 2011: life cycle assessment (LCA) that guides designers
The 2011 e-waste management and handling rules neglect plastics and impact indicators for marine plastic
were notified on May 2011, and it has been effective pollution is currently unavailable. Structural, as well as
since 01-05-2012. The concerned company will be data-related, uncertainties pose challenges in the fore-
notified in advance, and sufficient time is given to casting of plastic pollution. Owing to lack of LCA data,
implement these regulations and also to provide the no simple solution is available for this complex global
infrastructure it needs [78]. problem. Well-organized metrics accounting for plastic
➢ In India, unfortunately, there are no e-waste collec- debris in the ocean are required to come up with sound
tion centers and no definite information on the waste management approaches while accounting for
amount of e-waste disposed of each year and that intricate ecological impact trade-offs. Research focuses
created an economic danger. As main measures to on the integration of the nonlinear behavior of global
eradicate these wastes, the electronic products in circulation models within an LCA framework and
Germany must be replaced by new products. Sev- enhancing spatial differentiation, particularly the
enty-eight percent of all personal computers assem- depiction of coastal zones in global circulation models
bled in India are projected in the business sector. and ocean carbon cycle models which are to be solved to
Official information on e-waste, that is, how much mark LCA as an all-inclusive and vigorous ecological
electrical waste is produced or disposed of every year, impact assessment tool [84]. Any LCA model should be
is not accessible. However, some reports of autono- data-dependent, considering the different type and
mous research by nongovernmental organizations and sizes of plastics including the input, transport, distri-
public organizations are available [79]. bution, and lifetime of plastic debris in the ocean [85].
➢ In 2003, Korea enacted Recycling Law 22, according Advancement in life cycle impact assessment method-
to which the principle of extended manufacturer ologies to calculate the effects of plastic waste in LCA is
accountability is that TVs, freezers, laundry ma- a promising approach to alleviate the problem of disposal
chinery, etc., are to be recycled. In the Philippines, of plastics.
the law Ecological Solid Waste Management Act of
2000 was signed. It classifies consumables and white Future perspectives on plastic waste
goods as special waste, which must be treated management
distinctly from other residential and commercial As plastic polymers form an important aspect in
waste. contemporary living, there is an utmost need for the
creation of better products for potential safe use. The
Reuse of plastics for domestic purposes: need for absence of biodegradability of numerous plastics creates
recycling a huge toxicological impact. To avoid the accumulation
Plastics are becoming a part of everyone’s life and are of plastic particles in terrestrial and marine habitats, the
used every day. Reduce, reuse, and recycle are keywords next generation of plastics and plasticizers should
for the control and management of any pollutants, and consist of nonpetroleum and carbon-neutral monomers.
this scenario is also applicable to plastics. However, very Nonpetroleum products are nontoxic and degradable.
few plastic products wind up only in a disposal flow The life cycle of plastics must be considered from the
owing to its single usage. Reusing of plastics is better development and manufacture of biodegradable plastics
than regeneration because they cause less pollution and to their application. Necessary steps must be taken to
are less toxic [80]. In recent years, the recycling of systematically address the strategy and governance stage
plastics has increased significantly. An extensive di- through appropriate legislations. The manufacture and
versity range of products are being developed and consumption of plastics that are not within standard
packaged in the after-use plastics such as accessories regulations is unethical. Conventional reuse of plastic is
and toys that can be used in everyday life. It is estimated endeavored to reduce the dumping of plastic. Reuse of
that 65%e70% of plastics produced end up as waste plastics by converting into different products without
disposals. A related estimate is that only 25% of plastic reproducing them helps save time and resources. Energy
beverage bottles are recycled. According to a packaging and raw material economies are reduced by substituting
expert Sterling Anthony, the advancements in one-time-use products with a recyclable one. Reuse of a

Current Opinion in Environmental Science & Health 2019, 12:72–84 www.sciencedirect.com


Plastic pollutants: effective waste management Rajmohan et al. 81

broader variety of plastics will further improve the

acidize fish or flora. Brominated dioxins, heavy and


Lead, barium, and other heavy materials are leached
recycling rates of plastic waste and prevents landfill

Air and glass dust, tin, plumes, brominated dioxins,

Air, water, and soil releasing hydrocarbon ashes


sewage dumping in urban areas. Reusable cloth bags,

materials are directly released into rivers that


into soil, and toxic phosphorous is released.

Hydrocarbons, heavy metals, and brominated


jute bags, and other natural fibers are durable and eco-

hydrocarbon emissions air. Air emissions.


Potential environmental hazard
friendly. This reduces the problem of waste plastic
management and solves an environmental problem.
Simultaneously, a few other useful items can be

and mercury emissions to rivers


extracted from recycling processes that will decrease the
productivity of plastics. Although the LCA of plastic
waste is limited, research on converting plastic waste
into energy and fuel is emphasized mainly due to the
economic potential that the plastic-to-energy conver-
sion holds [86]. The research is still in infancy in India,
and limited published results are available on this topic.
Waste blends containing biodegradable and reclaimed
plastic solid waste are being studied. Upscaling this into
pilot and industrial scale is needed for a better and green
planet.

Conclusions
In the world we inhabit, exposures to plastics, plasti-
Chemical removal with nitric acid and HCL and then
Desuction and removal of chips, burning open, and

cizers, and other polymer additives are omnipresent.


While these are often expected to be below critical
acid bath for finished metals to be removed

threshold numbers, in some cases, excessive amounts


Breaking and removal followed by dumping

are recognized, causing major impacts on certain sensi-


Open combustion and removal of copper

tive communities of the environment. Although the


potential risk due to plastic wastes is likely to vary ac-
Process used

cording to the type, it has an adverse impact on the


environment. Microplastic debris consumed by marine
organisms poses a threat to human beings. Moreover, the
deposition of plastic debris in soil leads to soil corrosion
and landslides. The impact of these pollutants has to be
chip burning

addressed carefully to identify the associated hazards.


Dumping plastic or simply burying it in the soil is a
threat to the environment. Reduce, reuse, and recycle
are keywords for plastic management. However, owing
to the nonavailability of LCA and lack of sound knowl-
edge on disposal techniques and remediation of soil and
environment from plastic waste, the question of
disposing of plastic waste remains a big challenge. New
innovations in the field of solid waste management are
Circuit boards (a thin plate on which chips and other

in nascent stages and need to be explored by


Cathode ray tubes (used in TVs, ATMs, and video

researchers.
Effect of e-wastes in the environment [76].

Conflict of interest statement


Nothing declared.
Gold-plated chips and other parts

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