CHEMISTRY Max

Marks: 60
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.

21. Ceric ammonium Nitrate reagent can be used to distinguish

A) mono saccharides from disaccharides

B) reducing disaccharides from non-reducing disaccharides

C) alcohols from carbonyl compounds D) All of these

22. Which of following is/are correctly matched.

I. Nitrates in drinking water – minamata disease

II. Cadmium and Lead present in drinking water – Kidney disfunction

III. Fluorides in water – enamel on teeth much harder

IV. Mercury in fishing water – blue baby syndrome

A) I, II and III B) II, III only C) II, III and IV D) all are incorrect

23. .

The major product ‘P’ is

A) B) C) D)

24. Which of the following dienol is thermodynamically most stable?

A) B) C) D)
25. What is the product of the following sequence of reaction?

A) B)

C) D)

26. Choose the reaction that is incorrectly shown.

NH2

(i) NaNO 2/H2SO4

0 – 5ºC
A) (ii) H 2O/H 3PO2 B)

C) D)

27.

Predict major product of the above reaction is

A) B) C) D) None of these

28. Arrange the following compounds in increasing order of their basic strength.
 A) IV < III < I < II < V B) I < II < V < III < IV

C) I < II < III < IV < V D) IV < III < I < II < V

29. When methyl D-glucopyranoside is treated with HIO4 its number of mole consumed per mole
of sugar is

A) 2 B) 3 C) 4 D) 5

30. In the reaction, the acid obtained will be

CH 3CHO  HCN  CH 3CH  OH  CN 

H OH
 CH 3CH  OH  COOH

A) d – isomer B) l – isomer

C) (80% d+20% l) mixture D) (50%d+50%l) mixture

 SECTION - II
(PARAGRAPH TYPE)
This section contains 3 Paragraph of questions. Each paragraph has 2 multiple choice questions based on
a paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE IS
correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.

Paragraph for Question Nos. 31 & 32

There are nine elements A to I, these are belong to p-block other than halogen. If atomic
number of B is average of atomic number A and C and atomic number of E is average of atomic number
of D and F and atomic number of H is average of atomic number of G and I.

Atomic numbers of B, E and H are 7, 15 and 83 respectively and atomic numbers of C, I and F
are greater than A, G and D respectively.

Answer the following questions.

31. The incorrect order is

A) F > E : second ionization Energy B) B > C: Zeff on valence shell

C) I > H: first ionization Energy D) C > F > E : Electronegativity

32. Which of the following statement is incorrect

A) B2C5 is acidic in nature B) AC2 is acidic in nature

C) FC3 is basic in nature D) GC2 is amphoteric in nature

Paragraph for Question Nos. 33 & 34

A German physicist gave a principle about the uncertainties in simultaneous measurement of
position and momentum of small particles. According to that physicist,it is impossible to measure
simultaneously the position and momentum of small particle with absolute accuracy. If an attempt is
made to measure any one of these two quantities with higher accuracy, the other becomes less
accurate.

The product of the uncertainty in position  x  and uncertainty momentum  p  is always

h
constant and is equal to or greater than h , where h is Plank’s constant, i.e  x  p  
4 4
33. If uncertainty in position is twice the uncertainty in momentum, then uncertainty in velocity is

h 1 h 1 1 h
A) B) C) h D)
 2m  2m 2 2m 
34. If uncertainty in the position of an electron is zero, the uncertainty in its momentum would be

A) zero B)  h C)  h D) Infinite
4 4
Paragraph for Question Nos. 35 & 36
Consider the following system to answer the below two questions.

1
35. If the above compound is treated with boiling water SN reaction takes place through a
carbocation intermediate. The Chlorine lost in the first step is substituted by hydroxyl group in the given
experimental condition, the major product would be

A) B)

C) D)

36. If the given starting compound is to lose a Cl ion, forming a carbanion, the Chlorine that will
be lost first is

A) 1 B) 2 C) 3 D) 4

SECTION - III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the
correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.

37. Consider the terms in Column I and match it with species in Column II to which it applied
approximately.

Column I Column II
 A) Anti aromatic P)

B) Quasi aromatic Q)

C) Homo aromatic R)

D) Non-aromatic S)

A) A – S, B – R, C – P, D – Q B) A – S, B – P, C – R, D – Q

C) A – Q, B – R, C – P, D – S D) A – Q, B – P, C – R, D – S

38. Math the following:

Column I Column II

A) PhMgBr  Cl  NH 2 P) Ph  CN

B) PhMgBr  Cl  CN Q) Ph  NH 2

o o
|| ||
C) PhMgBr  CH 3  C  Cl R) Ph  C  CH 2  CH 3

o o
|| ||
D) PhMgBr  C2 H 5  C  OC2 H 5 S) Ph  C  CH 3

A) A – P, B – Q, C – S, D – R B) A – Q, B – P, C – S, D – R

C) A – R, B – Q, C – S, D – P D) A – R, B – P, C – Q, D – S

39. Math the Column I and Column II:

 A) A – P, B – R, C – Q, D – S B) A – S, B – R, C – P, D – Q

C) A – S, B – R, C – Q, D – P D) A – P, B – Q, C – R, D – S

40. Math the polymers given in Column I with their repeating units given in Column II

Column I (Polymer) Column II (Mechanism)

A) HDPE P) Cationic addition polymerisation

B) Polypropene Q) Condensation polymerisation

C) PVC R) free radical addition polymerisation

D) Dacron S) Anionic addition polymerisation

A) A – P, B – Q, C – S, D – R B) A – S, B – R, C – Q, D – P

C) A – R, B – P, C – S, D – Q D) A – R, B – Q, C – S, D – P