HARBHAJAN’S INSTITUTE OF COMPETITIONS

SUBJECT – CHEMISTRY DATE: 01-11-06

GROUP – (+1 Basic) ISOMERISM TIME: 1 Hour.
Room No.  Marks: 25

Q1. (10)
(i) Number of isomers represented by the molecular formula C 5 H 12 will be:
(a) 5 (b) 3 (c) 4 (d) 2
(ii) Monohydric alcohol may be isomer with:
(a) Aldehyde (b) Acid (c) Ketone (d) Ether
C H O
(iii)Number of isomers represented by the molecular formula 4 10 will be:
(a) 4 (b) 6 (c) 7 (d) 10
(iv)Which one of the following compound show position isomerism?
(a) Propionic Acid (b) 1-butene (c) n-butane (d) Ethanol
(v) Metamerism is happen in:
(a) Aldehyde (b) Alcohol (c) Ether (d) All of them
(vi)2-butene shows:
(a) Chain isomerism (b) Optical isomerism (c) Functional isomerism (d) Geometrical isomerism
(vii) Monocarboxylic acid is isomers with:
(a) Ketone (b) Alcohol (c) Easter (d) Ether
(viii) Which of the following compound can show geometrical isomerism?
(a) CH 3 CH  CH 2 (b) CH 3 CH  C CH 3  2 (c) CH 3 CH  CHCH 3
(d)  CH 3  2 C  C  CH 3  2
(ix) Number of isomers of C 6 H 14 will be:
(a) 7 (b) 5 (c) 6 (d) 4
(x) Which of the following compound has optical activity equal to zero?
(a) 1, 1-dichloroethylene (b) trans-1, 2-dichloroethylene
(c) cis-1, 2-dichloro ethylene (d) None of these
Q2. (a) Draw the structures of 2, 2, 4-trimethyl hexane and find how many each of 1o, 2o, 3o and 4o carbon
atoms are there in it. (2)
(b) Write all the acyclic and cyclic isomers having molecular formula, C3H6O. (2)
(c) Differentiate between Tautomerism and resonance. (2)
Q3. (a) An alkane has a molecular mass equal to 72. Give the all possible structures alongwith their IUPAC
names. (2)

(b) [A] Indicate whether each of the following compound is ‘E’ or ‘Z’. (3)

(i) (ii) (iii)

(iv) (v) (vi)

(c) “CH4, C2H6 and C3H8 do not exhibit any isomerism”. Justify the statement giving reasons. (1)
Q4. (a) What is no-bond resonance? Write two application of hyperconjugation. (3)