11dpp25a 25ggoc I

EMERGE 2024
GENERAL ORGANIC CHEMISTRY

INDUCTIVE EFFECT 25A
Marking Scheme : Single Correct (+3,-1) M M: 42 Time : 30 min
1. How many following molecules / ions show correct direction of inductive effect.
  
(i) CH3CH2CHCH2CH3 (ii) (iii) CH3CH2 (iv) CH3O  (v) CH3NH3


F
(vi) ClCH==CH2 (vii) CH3CH==CH2 (viii) CH3CH2OH (ix) CH3Li (ix) CH3MgBr
(a) eight (b) ten (c) seven (d) six
2. How many following molecules / ions show correct direction of inductive effect.
(i) (ii) (iii) (iv)
(v) (vi) (vii) (viii)
(ix) (ix)
(a) ten (b) seven (c) eight (d) six

3. Inductive effect involves :
(a) delocalisation of -electrons (b) delocalisation of -electrons
(c) displacement of -electrons (d) displacement of -electrons
4. Which statement is correct regarding Inductive effect ?
(a) Electron displacement along a carbon chain and develops partial charges on atoms.
(b) Complete transfer of one of the shared pair of electrons to one of the atom joined by a double bond.
(c) Implies transfer of lone pair of electron from more electronegative atom to the less electronegative atom.
(d) I effect increases with increase in the distance.
5. Select the correct statement about Inductive effect :
(a) Inductive effect transfer electrons from one carbon atom to another.
(b) Inductive effect is the polarisation of  bond electrons.
(c) Net charge develops in the molecule by inductive effect.
(d) Inductive effect is distance independent.
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6. Which of the following has incorrect direction of Inductive effect.
(a) (b) (c) (d)
7. Which of the following has correct direction of Inductive effect.

(a) CH3—CH2Li (b) H2NCCH
(c) H2NCCH (d)
8. Which of the following alkyl group has the maximum +I effect ?

(a) (CH3)2CH— (b) (CH3)3C— (c) CH3CH2— (d) CH3—
9. Which of the following group shows + I effects :

(a) —F (b) —CHO (c) —N H (d) —CN
10. Decreasing –I effect of given groups is :
(i) –CN (ii) –NO2 (iii) –NH2 (iv) –Cl
(a) iii > ii > i > iv (b) ii > iii > iv > i (c) iii > ii > iv > i (d) ii > i > iv > iii
11. Which is the correct order of inductive effect ?
(a) –NH2 > –OR > –F (b) –F > –OR > –NH2 (c) –NH2 > –F > –OR (d) –OR > –F > –NH2
12. Which of the following statement is correct?
(a) + I group stabilises the carbocation. (b) + I group stabilises the carbon free radical
(c) – I group stabilises the carbanion. (d) all of these
13. Arrange following compounds in decreasing order of their dipole moment.
I. CH3–CH2–NO2 II. CH3–CH2–Cl III. CH3–CH2–Br IV. CH3–CH2–I
(a) IV > III >I > II (b) IV > I > III > II (c) I > III > IV > II (d) I > II > III > IV
14. Which compound has non-zero dipole moment?
(a) (b) (c) (d)

EMERGE 2024
RESONANCE EFFECT 25B
1. Resonance effect involves :

(a) Delocalization of -electrons along a conjugated system.
(b) Delocalization of lone pair along a conjugated system.
(c) Delocalization of negative charge along a conjugated system.
(d) All are correct.
2. Resonance structures of a molecule do not have :
(a) Identical bonding (b) Identical arrangement of atoms
(c) The same number of paired electrons (d) Nearly the same energy content
3. In which of the following delocalisation of -electron is possible.
(a) CH2==CH—CH2—CHO (b) CH2==CH—CH==O
(c) CH3—CH—CH3 (d) CH2==CH—CH2—CH==CH2
|
OH
4. Which of the following compound show resonance ?
(a) (b) (c) (d)
5. Number of delocalised  electrons in the following structure is.
(a) six (b) eight (c) four (d) ten
6. Find the total number of positions where positive charge can be delocalized by true resonance.
(Excluding the given position)
(a) four (b) eight (c) two (d) six

7. Identify the number of compounds in which positive charge will be delocalised ?
(a) two (b) three (c) four (d) five

8. How many of the following species, the negative charge is delocalised?
(a) seven (b) four (c) six (d) five

9. In which compound delocalisation is not possible :
(a) 2-Butene (b) 1, 3-Butadiene (c) 1, 3, 5-Hexatriene (d) Benzene
10. Which of the following pairs are resonating structures ?
(a) and (b) and
(c) and (d) CH3–CH=CH–CH3 & CH3–CH2–CH=CH2
+
11. Stability of CH2—CH==CH2 can be explained by :
(a) Inductive effect (b) Electromeric effect (c) Resonance (d) Polar effect
12. How many equally stable resonating structures are possible for (tropylium cation) ?
(a) 2 (b) 4 (c) 5 (d) 7

13. Which of the following is not acceptable resonating structure of Buta-1, 2, 3-triene.
     
(a) CH2—CC—CH2 (b) CH2==C==C==CH2 (c) CH2—CC—CH2 (d) C H2—CC—C H2
   
14. The least and most stable resonating structure respectively are :
(i) (ii)
(iii) (iv)
(a) (i), (iv) (b) (ii), (iii) (c) (iv), (i) (d) (iii), (ii)
15. Which will be the least stable resonating structure?

   
(a) CH2==CH—CH—CH—NH2 (b) CH2—CH—CH==CH—NH2
   
(c) CH2==CH—CH—CH—NH2 (d) CH2==CH—CH—CH==NH2
16. HNCO (isocyanic acid) has following resonating structures :
   
(I) H—N==C==O  (II) H—N—CO  (III) H—NC—O
The order of stablity is :
(a) I > III > II (b) I > II > III (c) II > III > I (d) II > I > III

17. The decreasing order of stability of the following resonating structures is :
   
(I) CH2==CH—Cl:  (II) CH2==CH—Cl:  (III) CH2==CH—Cl:
: :
: :
: :
(a) I > II > III (b) II > III > I (c) III > II < I (d) I > III > II
18. Which of the following resonating structure will contribute minimum to resonance hybrid?
(I)  (II)  (III)

(a) I (b) II (c) III (d) All contribute equally
19. In each of the following pairs which ion is more stable :
(x) (y)
 
(i) CH2—CH==CH—NH2 & CH2==CH—CH==NH2
(ii) & CH2==CH—CH==CH—CH==CH2
(iii) &
(iv) CH2==CH—CH==CH—CH==CH2 & CH2==CH—C—CH==CH2

||
CH2
(a) x|y|y|y (b) y|x|y|x (c) x|x|x|x (d) y|x|y|y

EMERGE 2024
MESOMERIC EFFECT 25C
1. Mesomeric effect involves the delocalisation of :

(a) Protons (b) Sigma electrons (c)  electrons (d) None of these
2. Which of the following group show +M effect?
(a) —CN (b) —O—NO (c) —CCl3 (d) —CHO
3. Which of the following group show –M effect?
(a) —CMe3 (b) (c) (d)
4. Which of the following group show +M and –I effect ?


(a) (b) (c) —O (d) —OH
5. Which of the following group show +M > –I effect ?
(a) —F (b) (c) (d) —COOH

6. Which of the following group show –M and –I effect ?
(a) —NO2 (b) —NH2 (c) —OH (d) —F
7. How many groups (attached with benzene ring) show +M effect?
(a) five (b) six (c) eight (d) four

8. The weakest + M group of the given species is :
(a) —OCH3 (b) —F (c) —I (d) —N(CH3)2
9. Arrange the following groups in order of decreasing –M effect.
(i) NO2 (ii) COOH (iii) CN (iv) CHO
(a) i > iii > ii > iv (b) i > ii > iii > iv (c) i > iii > iv > ii (d) iv > iii > ii > i
10. Arrange the following groups in order of decreasing +M effect.

(i) —O (ii) – NH2 (iii) – OH (iv) –NHCOCH3
(a) i > ii > iii > iv (b) iv > iii > ii > i (c) i > iii > ii > iv (d) i > iv > iii > ii
11. In which of the following molecule, the mesomeric effect is present ?
(a) (b) (c) (d)

12. In which of the following molecule, the mesomeric effect is not with the benzene nucleus ?
(a) (b) (c) (d)
13. Electron density order in the benzene nucleus is:
(I) (II) (III) (IV)
(a) I > II > III > IV (b) I > III > II > IV (c) IV > II > III > I (d) I > IV > II > III
14. Rank the following compounds in order of decreasing electron density in the benzene nucleus.
(I) Chlorobenzene (II) 4-nitrochlorobenzene
(III) 2, 4-dinitrochlorobenzene (IV) 2, 4, 6-trinitrochlorobenzene
(a) I > II > III > IV (b) I > III > II > IV (c) III > I > IV > II (d) IV > III > II > I

EMERGE 2024
HYPERCONJUGATION EFFECT 25D
1. Hyperconjugation effect involves :

(a) Delocalization of lone pair into an adjacent -bond.
(b) Delocalization of -electrons into an adjacent double bond.
(c) Delocalization of -electrons into an adjacent -bond.
(d) All are true.
2. In hyperconjugation there is overlap between :
(a) p- and -orbitals (b) 2 - orbitals (c) d- and -orbtial (d) - and p - orbitals
3. Which of the following group has the maximum hyperconjugation effect ?
(a) CH3— (b) CH3CH2— (c) (CH3)2CH— (d) (CH3)3C—
4. Hyperconjugation is possible in which of the following species ? CH 3

(a) CH3—C H2 (b) C6H5—CH3 (c) CH2==CH2 (d) CH3 C CH CH2
CH3
5. Which of the following alkenes will show maximum number of hyperconjugation forms ?
CH 3
(a) CH2==CH2 (b) CH3—CH==CH2 (c) CH3—CH2—CH==CH2 (d) CH 3 CH CH CH2
6. Observe the following compound and write the number of hydrogen atoms involved in hyperconjugation ?
(a) eight (b) nine (c) seven (d) ten
7. Which of the following cannot exhibit hyperconjugation ?

 
(a) CH3—CH2 (b) (c) CH3CH==CH2 (d) (CH3)3C—CH2
8. The C—C bond length in propene is little shorter (1.49 Å) than the C—C bond length (1.54 Å) in ethane.
This is due to:
(a) +I effect of CH3 (b) Mesomeric effect (c) Resonance effect (d) Hyperconjugation effect
9. Among the following alkenes the order of decreasing stability is :
(I) 1-Butene (II) Cis-2-butene (III) Trans-2-butene
(a) II > I > III (b) III > I > II (c) I > II > III (d) III > II > I
10. Arrange in the stability order of following :
(I) (II) (III)
(a) I < II < III (b) II < I < III (c) I < III < II (d) II < III < I
11. The order of heat of hydrogenation in following compound is :
(I) (II) (III) (IV)
(a) I < II < IV < III (b) III < IV < II < I (c) II < III < I < IV (d) II < IV < I < III

EMERGE 2024
A, NA, AA 25E
Marking Scheme : Single Correct (+3,-1) M M: 95 Time : 1 hr
1. Point out the wrong statement in relation to the structure of benzene

(a) It is aromatic compound.
(b) The C—C bond distance in benzene is uniformly 1.397 Å
(c) It is a resonance hybrid of a number of canonical forms
(d) It has three delocalised - molecular orbitals
2. Which of the following compound is an Aromatic in nature.
(a) (b) (c) (d)
3. Which of the following ion is nonaromatic in nature.
(a) (b) (c) (d)
4. Which of the following compound is not aromatic in nature.
(a) (b) (c) (d)
5. Which of the following molecules have all C—C bonds are of equal length?
(a) (b) (c) (d) All of these
6. The hybridisation of nitrogen in (pyrrole) is :
(a) sp3 (b) sp2 (c) sp (d) Cann't be predicted

7. Which of the following is aromatic hydrocarbon ?
(a) (b) (c) (d)
8. Identify the aromatic compound:
(a) (b) (c) (d)

9. Classify the following as aromatic, antiaromatic and nonaromatic compounds.
(a) 12, 5, 8 (b) 8, 9, 8 (c) 10, 8, 7 (d) 14, 5, 6

10. Number of  electrons in conjugation for these compounds
, , and will be respectively :

(a) 8, 6, 6, 6 (b) 6, 4, 6, 6 (c) 6, 6, 6, 6 (d) 6, 6, 8, 6
11. Among the given molecules, identify aromatic, anti-aromatic and non-aromatic molecules.
(1) (2) (3) (4)
(5) (6) (7) (8)
(9) (10) (11) (12)
(13) (14) (15) (16)
(17) (18) (19) (20)
(21) (22) (23) (24)

(25) (26) (27) (28)
(29) (30) (31) (32)
(33) (34) (35) (36)
(37) (38) (39) (40)
(41) (42) (43) (44)
(45) (46) (47) (48)
(49) (50) (51) (52)
(53) (54) (55) (56)
(57) (58) (59) (60)
(61) (62) (63) (64) (65)

EMERGE 2024
MIXED (INDUCTION, RESONANCE, MESOMERIC) 25F
Marking Scheme : Single Correct (+3,-1) M M: 96 Time : 1 hr
1. Which of the following statement is CORRECT regarding the inductive effect?

(a) electron-donating inductive effect(+I effect) is generally more powerful than electron-withdrawing
inductive effect(-I effect)
(b) it implies the shifting of  electrons from more electronegative atom to the lesser electronegative
atom in a molecule
(c) it implies the shifting of  electrons from less electronegative atom to the more electronegative atom
in a molecule
(d) it increases with increase in distance.
2. What is the % s character in hybridisation of carbon when it exerts strongest –I effect ?
(a) 25% (b) 50% (c) 75% (d) 100%
3. Which order of I effect is correct.
(a) —NH2 > —NO2 [–I] (b) —NH2 > —NHCH3 [–I]
(c) —OH > —Cl [–I] (d) —CD3 > —CH3 [+I]
4. Minimum –I effect is exerted by the group
(a) OH (b) —OCH3 (c) —NH—CH3 (d) —NH2
5. Which of the following statements is INCORRECT about inductive effect ?
(a) Inductive effect is distance dependent and decreases drastically on increase in distance.
(b) Inductive effect is transmitted through -bond.
(c) Inductive effect is transmitted through -bond
(d) Inductive effect is permanent effect
3 2 1
6. In which C – C bond of CH3—CH2—CH2—Br , the inductive effect is expected to be the least.
(a) C1—C2 (b) C2—C3 (c) C1—Br (d) All are same
7. How many groups show —I effect?
  
—CH3, —NH3, —OH, —O, —N(CH3)2, —SO3H, —CHO, —Cl, —COO
(a) 5 (b) 4 (c) 6 (d) 7
8. Which of the following is a conjugated system ?
(a) CH2==C==C==CH2 (b) CH2==C==O (c) CH2==CH—CH==O (d) All of these
9. Among the following alkenes the order of decreasing stability is :
(I) 1-butene (II) cis-2-butene (III) trans-2-butene
(a) II > I > III (b) III > I > II (c) I > II > III (d) III > II > I

10. Resonance energy is :
(a) equal to the energy of resonance hybrid
(b) equal to the energy of most stable canonical structure
(c) equal to the energy of least stable canonical structure
(d) equal to the difference in energies of the most stable canonical structure and resonance hybrid
11. Which of the following statements is true about resonance.
(a) In resonating structure hybridisation of atom will be change.
(b) Cannonical structures are imaginary
(c) Cannonical structure explains all features of a molecule
(d) In resonating structures position of nuclei change.
12. (I) (II) (III)
Among these compounds, the correct order of resonance energy is :

(a) (I) > (II) > (III) (b) (II) > (I) > (III) (c) (III) > (I) > (II) (d) (I) > (III) > (II)
13. Which of the following alkenes will show maximum number of hyperconjugation forms ?
(a) (b) (c) (d)
14. In Which of the following molecule positive charge is not in conjugation.
(a) (b) (c) (d)
15. Which positive charge stabilised by resonance.
(a) (b) (c) (d)
16. Which of the following is not correctly ordered for resonance stability?
(a) (II > I > III)
(b) (I > III > II)
(c) (I > II)

(I) (II)
(d) (II = I)
17. Which of the following is the major contributor to the resonance hybrid of CH3COOCH3 ?
(a) (b) (c) (d)

18.
The least stable cannonical structure among these is:

(a) I (b) II (c) III (d) IV
19. The most stable resonating structure is :
 
(a) H 2N—CH—CH==CH—OCH3 (b) H2N==CH—CH==CH—OCH3
   
(c) H2N—CH==CH—CH==OCH3 (d) H2N—CH—CH—CH==OCH 3
20. Identify which of the following group acts as +m as well as –m ?
(a) —NO2 (b) —OCH3 (c) —NO (d) —CHO
21. Identify which of the following shows – m effect ?

(a) —NH—CH3 (b) —NH (c) —O—C—CH3 (d) —C—Cl
|| ||
O O
22. Decreasing + m-power for the given groups is :

(I) —O—CH3 (II) —F (III) —CH2 (IV) —Cl
(a) I > III > IV > II (b) III > II > I > IV (c) III > I > II > IV (d) II > I > IV > III
23. The correct decreasing order of electron density in aromatic ring of following compounds is :
(I) (II) (III) (IV)
(a) II > III > IV > I (b) III > II > IV > I (c) IV > I > III > II (d) III > II > I > IV
24. Arrange the following compounds in the order of decreasing reactivity towards electrophilic substitution
OH OCH3
(I) (II) (III) (IV) (V)
(a) V > IV > III > II > I (b) I > II > III > V > IV (c) I > II > IV > III > V (d) I > III > IV > II > V
25. Hyperconjugation is possible in which of the following species ?
CH3
(a) CH3 CH 2 (b) C6H5 CH3 (c) (d) H 3C C CH 2
CH3
26. Which of the following carbocation will show highest number of hyperconjugation structures?
CH3 C2H5
(a) CH3 CH 2 (b) C6H5 CH2 (c) H 3C C (d) H 5C2 C
CH3 C2H5

27. Hyperconjugation is not present in : CH 3
H
C
(a) (b) (c) (d) CH 3
28. Which of the following aromatic rings have less electron density than
CH 3
H :NH2 CHO CH3 CH2CH 3
C
CH 3 (a) (b) (c) (d)
29. The total number of contributing structures showing hyperconjugation (involving C—H bonds) for the
following molecule is:
(a) 7 (b) 3 (c) 16 (d) 4
Assertion and Reason .

(a) If both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(b) If both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
(c) If Assertion is true but Reason is false.
(d) If Assertion is false but Reason is true.
(e) If both Assertion and Reason are false.
30. Assertion : Carbon–oxygen bonds are of equal length in acetate ion.
Reason : Bond length decreases with the multiplicity of bond between two atoms.
31. Assertion: C—C single bond of 1,3- Butadiene is shorter than C—C bond in ethane.
Reason : In 1,3-Butadiene partial double bond character has been developed due to resonance .
32. Assertion: Bond length of double bond in benzene is more than the bond length of double bond in buta-
1,3-diene.
Reason : Increase in delocalisation of  electrons increases the bond length of double bond in benzene.

EMERGE 2024
ACID AND BASES 25G
Marking Scheme : Single Correct (+3,-1) M M: 84 Time : 1hr
1. The acidity of the protons H in each of the following is:
(i) (ii) (iii)
(a) (i) > (ii) > (iii) (b) (iii) > (ii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
2. Identify correct acidic strength order in the following compounds
(i) (ii) (iii)
(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (ii) > (i) > (iii) (d) (iii) > (i) > (ii)
(i) (ii) (iii)
(i) (ii) (iii)
(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
(i) (ii) (iii)
(a) (ii) > (i) > (iii) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)

(i) (ii) (iii)
(a) (i) > (ii) > (iii)

(b) (ii) > (iii) > (i)
(c) (i) > (iii) > (ii)
(d) (iii) > (i) > (ii)
(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i)
(c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i)
(c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
10. The acidity of the protons H in each of the following is
(i) (ii) (iii)
(a) (i) > (ii) > (iii) (b) (ii) > (iii) > (i) (c) (ii) > (i) > (iii) (d) (iii) > (i) > (ii)
11. The acidity of the protons H in each of the following is
(i) (ii) (iii)
(i) (ii) (iii)
(a) (iii) > (ii) > (i) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)

(i) (ii) (iii)
(i) (ii) (iii)
(i) (ii) (iii)
(a) (iii) > (ii) > (i) (b) (ii) > (iii) > (i) (c) (i) > (iii) > (ii) (d) (iii) > (i) > (ii)
(i) (ii) (iii)
(i) (ii) (iii)
(i) (ii) (iii)
(i) (ii) (iii)
(i) (ii) (iii)

21. Which nitrogen in LSD is most basic?
(a) 1 (b) 2
(c) 3 (d) All are equally basic
22. The decreasing order of basic strength is:

(a) (i) > (v) > (iii) > (iv) > (ii)
(b) (iv) > (i) > (v) > (iii) > (ii)
(c) (v) > (iv) > (i) > (ii) > (iii)
(d) (iv) > (v) > (iii) > (i) > (ii)
23. Arrange the following in the decreasing order of their acidic strength
(i) (ii) (iii) (iv)

(a) (i) > (ii) > (iii) > (iv) (b) (iv) > (iii) > (ii) > (i) (c) (ii) > (i) > (iv) > (iii) (d) (i) > (ii) > (iv) > (iii)
24. Arrange the following hydrogens in the order of their acidic behaviour
(a) (i) > (iii) > (ii) (b) (ii) > (iii) > (i)
(c) (i) > (ii) > (iii) (d) (iii) > (ii) > (i)
25. Which of the following acid gives evolution of CO2 with NaHCO3?
(i) (ii) (iii) (iv) (v)
(a) (i), (iii), (iv), (v) (b) (iii), (iv), (v) (c) (i), (ii), (iii), (iv), (v) (d) (i), (iii), (v)
26. Select the correct statement
(a) is more basic than (b) is more basic than
(c) is more basic than (d) All of them
27. Which of the following is most basic?
(a) (b) (c) (d)
28. Which of the following is most basic?
(a) (b) (c) (d)

All students are advised to solve DPPs within allowed time only.
All discussions are scheduled in every 4th doubt discussion class
–MKA Sir (Guruji)


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EMERGE 2024

GENERAL ORGANIC CHEMISTRY

Marking Scheme : Single Correct (+3,-1) M M: 42 Time : 30 min

(i) (ii) (iii) (iv)

(v) (vi) (vii) (viii)

(a) ten (b) seven (c) eight (d) six

1 Newtown, Kolkata-700 156

(a) (b) (c) (d)

7. Which of the following has correct direction of Inductive effect.

(c) H2NCCH (d)

8. Which of the following alkyl group has the maximum +I effect ?

(a) (b) (c) (d)

2 Newtown, Kolkata-700 156

Marking Scheme : Single Correct (+3,-1) M M: 57 Time : 40 min

1. Resonance effect involves :

(a) (b) (c) (d)

5. Number of delocalised  electrons in the following structure is.

(a) six (b) eight (c) four (d) ten

(Excluding the given position)

(a) four (b) eight (c) two (d) six

(a) two (b) three (c) four (d) five

3 Newtown, Kolkata-700 156

(a) seven (b) four (c) six (d) five

(a) and (b) and

(c) and (d) CH3–CH=CH–CH3 & CH3–CH2–CH=CH2

(a) 2 (b) 4 (c) 5 (d) 7

15. Which will be the least stable resonating structure?

4 Newtown, Kolkata-700 156

(I)  (II)  (III)

(ii) & CH2==CH—CH==CH—CH==CH2

(iv) CH2==CH—CH==CH—CH==CH2 & CH2==CH—C—CH==CH2

5 Newtown, Kolkata-700 156

Marking Scheme : Single Correct (+3,-1) M M: 42 Time : 30 min

1. Mesomeric effect involves the delocalisation of :

(a) —CMe3 (b) (c) (d)

4. Which of the following group show +M and –I effect ?

(a) —F (b) (c) (d) —COOH

(a) five (b) six (c) eight (d) four

(a) (b) (c) (d)

6 Newtown, Kolkata-700 156

(a) (b) (c) (d)

13. Electron density order in the benzene nucleus is:

(I) (II) (III) (IV)

7 Newtown, Kolkata-700 156

Marking Scheme : Single Correct (+3,-1) M M: 33 Time : 25 min

1. Hyperconjugation effect involves :

(a) eight (b) nine (c) seven (d) ten

7. Which of the following cannot exhibit hyperconjugation ?

(I) (II) (III)

(I) (II) (III) (IV)

8 Newtown, Kolkata-700 156

Marking Scheme : Single Correct (+3,-1) M M: 95 Time : 1 hr

1. Point out the wrong statement in relation to the structure of benzene

(a) (b) (c) (d)

3. Which of the following ion is nonaromatic in nature.

(a) (b) (c) (d)

4. Which of the following compound is not aromatic in nature.

(a) (b) (c) (d)

(a) (b) (c) (d) All of these

6. The hybridisation of nitrogen in (pyrrole) is :

(a) sp3 (b) sp2 (c) sp (d) Cann't be predicted

(a) (b) (c) (d)

8. Identify the aromatic compound: