EXCEL 2023

GENERAL ORGANIC CHEMISTRY

INDUCTIVE EFFECT 25A

Marking Scheme : Single Correct (+3,-1) M M: 42 Time : 30 min

1. How many following molecules / ions show correct direction of inductive effect.
  
(i) CH3CH2CHCH2CH3 (ii) (iii) CH3CH2 (iv) CH3O  (v) CH3NH3


F
(vi) ClCH==CH2 (vii) CH3CH==CH2 (viii) CH3CH2OH (ix) CH3Li (ix) CH3MgBr
(a) eight (b) ten (c) seven (d) six
2. How many following molecules / ions show correct direction of inductive effect.

(i) (ii) (iii) (iv)

(v) (vi) (vii) (viii)

(ix) (ix)

(a) ten (b) seven (c) eight (d) six

3. Inductive effect involves :
(a) delocalisation of -electrons (b) delocalisation of -electrons
(c) displacement of -electrons (d) displacement of -electrons
4. Which statement is correct regarding Inductive effect ?
(a) Electron displacement along a carbon chain and develops partial charges on atoms.
(b) Complete transfer of one of the shared pair of electrons to one of the atom joined by a double bond.
(c) Implies transfer of lone pair of electron from more electronegative atom to the less electronegative atom.
(d) I effect increases with increase in the distance.
5. Select the correct statement about Inductive effect :
(a) Inductive effect transfer electrons from one carbon atom to another.
(b) Inductive effect is the polarisation of  bond electrons.
(c) Net charge develops in the molecule by inductive effect.
(d) Inductive effect is distance independent.

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6. Which of the following has incorrect direction of Inductive effect.

(a) (b) (c) (d)

7. Which of the following has correct direction of Inductive effect.

(a) CH3—CH2Li (b) H2NCCH

(c) H2NCCH (d)

8. Which of the following alkyl group has the maximum +I effect ?

(a) (CH3)2CH— (b) (CH3)3C— (c) CH3CH2— (d) CH3—
9. Which of the following group shows + I effects :

(a) —F (b) —CHO (c) —N H (d) —CN
10. Decreasing –I effect of given groups is :
(i) –CN (ii) –NO2 (iii) –NH2 (iv) –Cl
(a) iii > ii > i > iv (b) ii > iii > iv > i (c) iii > ii > iv > i (d) ii > i > iv > iii
11. Which is the correct order of inductive effect ?
(a) –NH2 > –OR > –F (b) –F > –OR > –NH2 (c) –NH2 > –F > –OR (d) –OR > –F > –NH2
12. Which of the following statement is correct?
(a) + I group stabilises the carbocation. (b) + I group stabilises the carbon free radical
(c) – I group stabilises the carbanion. (d) all of these
13. Arrange following compounds in decreasing order of their dipole moment.
I. CH3–CH2–NO2 II. CH3–CH2–Cl III. CH3–CH2–Br IV. CH3–CH2–I
(a) IV > III >I > II (b) IV > I > III > II (c) I > III > IV > II (d) I > II > III > IV
14. Which compound has non-zero dipole moment?

(a) (b) (c) (d)

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All students are advised to solve DPPs within allowed time only.
All discussions are scheduled in every 4th doubt discussion class
–MKA Sir (Guruji)

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