EXCEL 2023

BOC
MIXED 01A

Marking Scheme : Single Correct (+3,-1) M M: 108 Time : 1 hr

1. CH2I2 is a ___halide.
(a) vicinal (b) secondary (c) gerninal (d) Vinyl
2. Atorvastatin is a member of the drug class known as statins, and are used for lowering blood cholesterol.
O OH OH O

OH

Atorvastatin
F
(a) Carboxylic acid (b) Alcohol (c)Amide (d)Alkane (e)Aldehyde
3. Double bond equivalent (DBE) of C10H10 is:
(a) 3 (b) 4 (c) 5 (d) None of these
4. How many different functiohal groups are present in given compound ?
OH
HOOC

O
(a) 3 (b) 4 (c) 1 (d) 5

O
5. Which of the following compounds has DBE equal to benzene ?
CH 3

(a) (b) (c) (d) All of these

6. Which of the following compound is heterocyclic compound.

(a) (b) (c) N

|
(d) Both (b) & (c)
S
H
7. How many 2° carbon present in given compound ?

(a) 4 (b) 5 (c) 6 (d) 7

8. The double bond equivalent (D.B.E.) value of the following compounds respectively are :
O O O O O O

(i) HO C C OH (ii) O C C OH (iii) O C C O

(a) 2. 3, 4 (b) 2, 3, 5 (c) 2, 2.5, 3 (d) 2, 2.5, 3.5
9. Double bond equivalent (DBE) of C10H8 is:
(a) 5 (b) 6 (c) 7 (d) 8

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10. Which of the following functional group is not present in the given compound:
O
O

(a) Ether (b) Ketone (c) Carboxylic acid (d) Aldehyde

OH
O
11. Total number of 2° carbon present in given compound is x, so the value of x — 7is

Br Cl

(a) 6 (b) 8 (c) 9 (d) None of these

12. The carbon frame work of the molecule adamantane, C10H16, is shown below. Choose the correct
number of bromoadamatanes (C10H15Br) that are possible.

(a) 1 (b) 2 (c) 3 (d) 4 (e) 5

13. Epinephrine is a hormone and neurotransmitter produced by the adrenal medulla and has the following
structure. Choose the statement that correctly identifies some of the functional groups present in
epinephrine.
OH
(a) Alcohoi, ester, aromatic (b) Amine, alcohol, amide
HO
CH 3 (c) Amide. aromatic, alkane (d) Amine, alcohol, aromatic
HO (e) Alkane, ether, aromatic
14. Cyclohexa-1,4-diene contains ____ vinylic and ____ allylic hydrogen atoms?
(a) 2 and 2 respectively (b) 4 and 4 respectively
(c) 2 and 4 respectively (d) 4 and 2 respectively
15. Which of the following functional group is not present in the given compound.
O
O
OH
(a) Ether (b) Ketone (c) Carboxylic acid (d) Anhydride
O
16. Sum of total number of functional group and Double bond equivalent (DBE) value in given compound is:
O NH2 O
OH

OH
(a) 13 (b) 14 (c) 15 (d) 16
O O
O OC2H 5
17. Identify which of the compound having 2° alcohol

(a) (b) (c) (d)

18. The difference in Double Bond Equivalent (DBE) value between and is:

(a) 0 (b) 1 (c) 2 (d) 3

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19. Find the DBE(Double Bond Equivalent) value of the following compound ?
O

OH
N
CH3 (a) 13 (b) 14 (c)15 (d) 16
O

20. O Shown left molecule is Guanosine. How many Alcohol functional groups are
N
present in the molecule?
H—N

H 2N N
HO
O
(a) 0 (b) 1 (c) 2 (d) 3
HO OH

21. Which functional group(s) are NOT present in given compound ?

O
OH
O

OH
N
(a) alcohol (b) Ketone (c) carboxylic acid (d) amide
H 2N O

OH
22. Which of the following structures represent the same compound ?
H3C CH 2
H 3C CH CH CH2 CH3
CH CH3
H 3C CH CH2 CH CH 2 CH 3
CH2 CH 3
(i) CH 3 CH 2 CH (ii) (iii)
CH 3 CH3
CH3
CH 3
(a) (i) and (ii) (b) (ii) and (iii) (c) (i) and (iii) (d) All are same
23. Rank in order of increasing double bond equivalent (D.B.E.) value or index of Hydrogen deficiency
(I.H.D).
CH3 O
O
(i) (ii) H (iii) O (iv) C N

(a) (i) < (iii) < (ii) < (iv) (b) (i) < (iii) < (iv) < (ii) (c) (iii) < (i) < (iv) < (ii) (d) (iv) < (iii) < (ii) < (i)
24. Gestrinone is a synthetic steroid hormone that is marked as a treatment for endometriosis. What is the
Index of Hydrogen Deficiency (I.H.D) or Double Bond Equivalant (D.B.E.) for Gestrinone ?
OH

H
(a) 8 (b) 9 (c) 10 (d) 11
H
O
25. What is the Index of Hydrogen Deficiency (I.H.D) or Double Bond Equivalant (D.B.E.) for the follow-
ing compound?

(a) 6 (b) 7 (c) 8 (d) 9

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26. What is the Molecular formula of Carvone ?

O (a) C8H10O (b) C10H14O (c) C10H12O (d) C9H12O

Carvone (responsible for odor of spearmint)

27. Find the sum of total number of different Functional groups and Double bond equivalent (D.B.E.) value.
O
OH
O

OH
N
(a) 12 (b) 13 (c) 14 (d) 15
H 2N O

OH
28. Which of the following compounds is a secondary alcohol ? OH

OH OH OH
(a) (b) (c) (d)

29. How many different functional groups are present ?

OH

(a) 3 (b) 4 (c) 5 (d) 6

O
30. Which of the following is a heterocyclic compound ?
O
OH OH

(a) (b) (c) (d)

O

OH
31. The number of sigma() and pi()-bonds in 1-butene-3-yne are:
(a) 5 sigma and 5 pi (b) 7 sigma and 3 pi (c) 8 sigma and 2 pi (d) 6 sigma and 4 pi
CH3

32. The structure shown CH3CH 2CHCHCH 2CH 2CHCH 3

CH 2CH3 CH 2CH3
(a) 1°, 2°, and 3° carbon atoms (b) 1° and 2° carbon atoms only
(c) 1° and 3° carbon atoms only (d) 2° and 3° carbon atoms only
33. How many l° carbon atom will be present in a simplest hydrocarbon having two 3° and one 2° carbon
atom?
(a) 3 (b) 4 (c) 5 (d) 6
34. 1°, 2°, 3° and 4° carbon atoms are present in:
(a) 2, 2, 3-trimethyl pentane (b) 2, 3, 4-trimethyl pentane (c) both (d) none.
35. Number of chlorine atom in DDT are:
(a) 2 (b) 3 (c) 5 (d) 6
36. What is the maximum number of hydrogens that could be present in a seven-carbon compound?
(Assume that no rings or double bonds are present.)
(a) 10 (b) 12 (c) 14 (d) 15 (e) 16

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All students are advised to solve DPPs within allowed time only.
All discussions are scheduled in every 4th doubt discussion class
–MKA Sir (Guruji)

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