ASSIGNMENT NO.

TECHNICAL REPORT WRITING

SUBMITTED TO:-

Asad Ali

SUBMITTED BY:-

Muhammad Usama Zubair

REGISTRATION NO:-

UW-19-CHE-BSC-025

SUBMISSION DATE:-

05th-May -2021

DEPARTMENT OF CHEMICAL ENGINEERING

WAH ENGINEERING COLLEGE

Title

Soluble base cations help carbon dioxide decrease into feedstock substance

Authors

Norihito Ikemiya: Keisuke Natsui; Clark Karen Chan

Subject

Soluble base cations help carbon dioxide decrease into feedstock substance

Theme

The electrochemical reduction of CO2 offers a means for storing electrical energy produced by
renewable but intermittent resources, such as wind and solar radiation.1, 2 Hydrocarbons and
alcohols, rather than carbon monoxide and formic acid, are the preferred products of CO2
reduction because of their high energy density. Despite extensive efforts to identify electrocatalysts
that can produce these products, copper (Cu) remains the only material capable of doing so with
significant yields. Nevertheless, Cu requires a high overpotential (~−1 V versus RHE) and
produces a broad spectrum of products. Clearly, discovering novel means for reducing CO2 to
desirable products with higher efficiency and selectivity is needed. To do so requires
understanding the fundamental processes occurring at the electrode surface. In addition to metal-
adsorbate interactions, a complete description of electrochemical reactions must include the effects
of solvation and interfacial electric fields. Some studies have shown that one way of influencing
product distribution is through changes in electrolyte cation.

Abstract
The electrochemical decrease of CO2 is known to be affected by the character of the antacid metal
cation in the electrolyte; in any case, a palatable clarification for this marvel has not been created.
Here we present the consequences of exploratory and hypothetical examinations pointed toward
clarifying the impacts of electrolyte cation size on the characteristic action and selectivity of metal
impetuses to lessen CO2. Inquiries were directed under conditions where the effect of electrolyte
polarization is insignificant to show that cation size influences the natural paces of arrangement of
certain response items, most quite for HCOO-, C2H4, and C2H5OH over Cu(100)- and Cu(111)-
situated dainty movies, and for CO and HCOO-over polycrystalline Ag and Sn. Studies educated
translation regarding the discoveries for CO2 decrease in glyoxal and CO, essential intermediates
along the response pathway. Thickness utilitarian hypothesis computations show that the salt metal
cations impact the dispersion of items shaped because of electrostatic collaborations between
solvated cations present at the outer Helmholtz plane and adsorbed species having critical dipole
minutes. The noticed patterns in action with cation size are ascribed to an expansion in the
centralization of cations at the external Helmholtz plane with expanding cation size.

Related Article

Title: Advertiser Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon
Dioxide (July 2017).

Title: Effect of alkali-metal cations on the electrochemical reduction of carbon dioxide to formic
acid using boron-doped diamond electrodes. ( March 2017).

Reader’s Viewpoint

The electrochemical reduction of CO2 offers a means for storing electrical energy produced by
renewable but intermittent resources, such as wind and solar radiation.1, 2 Hydrocarbons and
alcohols, rather than carbon monoxide and formic acid, are the preferred products of CO2
reduction because of their high energy density. Despite extensive efforts to identify electrocatalysts
that can produce these products, copper (Cu) remains the only material capable of doing so with
significant yields.3-5 Nevertheless, Cu requires a high overpotential (~−1 V versus RHE) and
produces a broad spectrum of products.6,7 Clearly, discovering novel means for reducing CO2 to
desirable products with higher efficiency and selectivity is needed. To do so requires
understanding the fundamental processes occurring at the electrode surface. In addition to metal-
adsorbate interactions, a complete description of electrochemical reactions must include the effects
of solvation and interfacial electric fields. Many studies have shown that one way of influencing
product distribution is through changes in the electrolyte cation.

The role of cations is exciting because many studies have shown that both the activity and
selectivity of Ag, Ag, and Cu for the CO2 reduction reaction (CO2RR) are influenced significantly
by the size of the alkali metal cation in the electrolyte.8-13 Similar effects have also been observed
for the electrochemical reduction of oxygen, the oxidation of hydrogen, and low molecular weight
alcohols.14-18 For Ag and Hg, which are selective for CO2 reduction to carbon monoxide (CO)
and formate anions (HCOO-), respectively, increasing the alkali metal cation size increases the
rates of formation of these products.8, 10, 11 For Cu, increasing alkali metal size leads to higher
selectivities to C2 products, e.g., ethylene and ethanol.9, 12, 13 Explanations for these phenomena
have been attributed to differences in local pH or differences in kinetic overpotentials due to the
electrochemical potential in the outer Helmholtz plane being affected by cation size. One of the
challenges to finding a consistent interpretation for the effects of cation size on the intrinsic
kinetics of CO2 reduction is that many studies are carried out under conditions where mass
transport also contributes to the observed activity and product distribution. In a recent study, we
reported the effects of cation size on the rate of the CO2RR under mass-transport solid limitations.

Reference

1. Lewis, N. S.; Nocera, D. G., Powering the planet: Chemical challenges in solar energy
utilization. Proceedings of the National Academy of Sciences 2006, 103 (43), 15729-15735.
2. Chu, S.; Majumdar, A., Opportunities, and challenges for a sustainable energy future. Nature
2012, 488 (7411), 294-303.
3. Hori, Y., Electrochemical CO2 Reduction on Metal Electrodes. In Modern Aspects of
Electrochemistry, Vayenas, C. G.; White, R. E.; Gamboa-Aldeco, M. E., Eds. Springer New
York: New York, NY, 2008; pp 89-189.
4. Kuhl, K. P.; Hatsukade, T.; Cave, E. R.; Abram, D. N.; Kibsgaard, J.; Jaramillo, T. F.,
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal
Surfaces. Journal of the American Chemical Society 2014, 136 (40), 14107-14113.
5. Hori, Y.; Wakebe, H.; Tsukamoto, T.; Koga, O., Electrocatalytic process of CO selectivity in
the electrochemical reduction of CO2 at metal electrodes in aqueous media. Electrochimica
Acta 1994, 39 (11), 1833-1839.
6. Hori, Y.; Murata, A.; Takahashi, R., Formation of hydrocarbons in the electrochemical
reduction of carbon dioxide at a copper electrode in aqueous solution.1989, 85 (8), 2309-2326.