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Product Name: NUTO H 68

Revision Date: 12 Oct 2012


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MATERIAL SAFETY DATA SHEET


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name: NUTO H 68
Product Description: Base Oil and Additives
Product Code: 20156010H540, 583211-00, 97N582, 97Q125
Intended Use: Hydraulic fluid

COMPANY IDENTIFICATION
Supplier: EXXON MOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency 609-737-4411
Transportation Emergency Phone 800-424-9300
ExxonMobil Transportation No. 281-834-3296
Product Technical Information 800-662-4525, 800-947-9147
MSDS Internet Address http://www.exxon.com, http://www.mobil.com

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS

No Reportable Hazardous Substance(s) or Complex Substance(s).

SECTION 3 HAZARDS IDENTIFICATION

This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

POTENTIAL HEALTH EFFECTS


Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may
cause serious damage.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0


HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.

SECTION 4 FIRST AID MEASURES

INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
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adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.

SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Inappropriate Extinguishing Media: Straight Streams of Water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.

Unusual Fire Hazards: Pressurized mists may form a flammable mixture.

Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur oxides, Incomplete combustion
products, Oxides of carbon

FLAMMABILITY PROPERTIES
Flash Point [Method]: >218°C (424°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D

SECTION 6 ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
Product Name: NUTO H 68
Revision Date: 12 Oct 2012
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National Response Center can be reached at (800)424-8802.

PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification
Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum
requirements for personal protective equipment. Additional protective measures may be necessary, depending
on the specific circumstances and/or the expert judgment of the emergency responders. For emergency
responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g.,
formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained
Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the
exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated,
SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of
polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are
recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are
usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.

Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may
cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite
any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations).
Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard
from static accumulation. Consult local applicable standards for guidance. Additional references include
American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray
Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC
CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity).

Static Accumulator: This material is a static accumulator.

STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store
in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION


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Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols
can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL.

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a


level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
No protection is ordinarily required under normal conditions of use.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
Product Name: NUTO H 68
Revision Date: 12 Oct 2012
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ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.

GENERAL INFORMATION
Physical State: Liquid
Color: Amber
Odor: Characteristic
Odor Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION


Relative Density (at 15 °C): 0.883
Flash Point [Method]: >218°C (424°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: > 316°C (600°F)
Vapor Density (Air = 1): > 2 at 101 kPa
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 68 cSt (68 mm2/sec) at 40 °C | 8.5 cSt (8.5 mm2/sec) at 100°C
Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point: -12°C (10°F)
DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION


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Revision Date: 12 Oct 2012
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ACUTE TOXICITY
Route of Exposure Conclusion / Remarks
Inhalation
Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.

Ingestion
Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.

Skin
Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.

Eye
Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components.

CHRONIC/OTHER EFFECTS
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified
Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-
specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test
animals.

Additional information is available by request.

The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED--


1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.

MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITY


Biodegradation:
Base oil component -- Expected to be inherently biodegradable
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Revision Date: 12 Oct 2012
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BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.

OTHER ECOLOGICAL INFORMATION


VOC: 0 G/L [ASTM E1868-10]

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the
environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents,
brake fluids or coolants.

REGULATORY DISPOSAL INFORMATION


RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND (DOT): Not Regulated for Land Transport

LAND (TDG): Not Regulated for Land Transport

SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code

AIR (IATA): Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION


Product Name: NUTO H 68
Revision Date: 12 Oct 2012
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OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.

Complies with the following national/regional chemical inventory requirements:: AICS, DSL, IECSC, PICCS,
TSCA

EPCRA SECTION 302: This material contains no extremely hazardous substances.

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.

SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.

The following ingredients are cited on the lists below:

Chemical Name CAS Number List Citations


ZINC ALKYLDITHIOPHOSPHATE 68649-42-3 15

--REGULATORY LISTS SEARCHED--


1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293

Code key: CARC=Carcinogen; REPRO=Reproductive

SECTION 16 OTHER INFORMATION


N/D = Not determined, N/A = Not applicable

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:


Revision Changes:
Section 09: Boiling Point C(F) was modified.
Section 08: Comply with applicable regulations phrase was modified.
Section 09: Vapor Pressure was modified.
Section 07: Handling and Storage - Storage Phrases was modified.
Hazard Identification: Health Hazards was modified.
Section 11: Dermal Lethality Test Data was modified.
Section 11: Dermal Lethality Test Comment was modified.
Section 11: Oral Lethality Test Data was modified.
Section 11: Inhalation Lethality Test Data was modified.
Section 11: Dermal Irritation Test Data was modified.
Section 11: Eye Irritation Test Data was modified.
Section 11: Oral Lethality Test Comment was modified.
Section 11: Inhalation Lethality Test Comment was modified.
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Section 11: Dermal Irritation Test Comment was modified.
Section 11: Eye Irritation Test Comment was modified.
Section 11: Inhalation Irritation Test Data was modified.
Section 09: Relative Density - Header was modified.
Section 09: Flash Point C(F) was modified.
Section 09: Viscosity was modified.
Section 09: Viscosity was modified.
Section 14: LAND (TDG) - Header was modified.
Section 15: List Citations Table was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 15: Community RTK - Header was modified.
Section 12: Other Ecological Information - Header was added.
Section 12: California VOC was added.
Section 12: California VOC was added.
Section 15: Special Cases - Header was deleted.
Section 15: Special Cases Table was deleted.
Section 15: Inventory - Header was deleted.
Section 15: Status - Header was deleted.
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The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.

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Internal Use Only


MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A

DGN: 2006864XUS (1012737)


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Copyright 2002 Exxon Mobil Corporation, All rights reserved
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
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MATERIAL SAFETY DATA SHEET


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name: MOBIL MULTIPURPOSE ATF
Product Description: Base Oil and Additives
Product Code: 525238-00, 971582
Intended Use: Automatic transmission fluid

COMPANY IDENTIFICATION
Supplier: EXXON MOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency 609-737-4411
Transportation Emergency Phone 800-424-9300
ExxonMobil Transportation No. 281-834-3296
Product Technical Information 800-662-4525, 800-947-9147
MSDS Internet Address http://www.exxon.com, http://www.mobil.com

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS

Reportable Hazardous Substance(s) or Complex Substance(s)


Name CAS# Concentration*
HYDROTREATED LIGHT PARAFFINIC DISTILLATES, 64742-55-8 10 - 20%
PETROLEUM

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.

SECTION 3 HAZARDS IDENTIFICATION

This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

POTENTIAL HEALTH EFFECTS


Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.

ENVIRONMENTAL HAZARDS
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0


HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
Page 2 of 10

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SECTION 4 FIRST AID MEASURES

Inhalation
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.

SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

Ingestion
First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Inappropriate Extinguishing Media: Straight Streams of Water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.

Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur Oxides, Incomplete combustion
products, Oxides of carbon

FLAMMABILITY PROPERTIES
Flash Point [Method]: >156C (313F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D

SECTION 6 ACCIDENTAL RELEASE MEASURES

Notification Procedures
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
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regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.

SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.

Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Prevent small spills and leakage to avoid slip hazard.

Static Accumulator: This material is a static accumulator.

STORAGE
Do not store in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE LIMIT VALUES

Exposure limits/standards (Note: Exposure limits are not additive)

Source Form Limit / Standard NOTE Source


HYDROTREATED LIGHT Mist. STEL 10 mg/m3 N/A ACGIH
PARAFFINIC DISTILLATES,
PETROLEUM
HYDROTREATED LIGHT Mist. TWA 5 mg/m3 N/A ACGIH
PARAFFINIC DISTILLATES,
PETROLEUM

Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols
can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL.

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.


Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
Page 4 of 10

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ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.

Personal Protection

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a


level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
No protection is ordinarily required under normal conditions of use.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.

ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.

GENERAL INFORMATION
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
Page 5 of 10

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Physical State: Liquid
Color: red
Odor: Characteristic
Odor Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION


Relative Density (at 15 C): 0.861
Flash Point [Method]: >156C (313F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: N/D
Vapor Density (Air = 1): > 2 at 101 kPa
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 C
Evaporation Rate (N-Butyl Acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 32.3 cSt (32.3 mm²/sec) at 40 C | 7 cSt (7 mm²/sec) at 100C
Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
Route of Exposure Conclusion / Remarks
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m³ Minimally Toxic. Based on assessment of the components.
Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.

Ingestion
Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.

Skin
Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
Page 6 of 10

______________________________________________________________________________________________________________________
materials.
Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.

Eye
Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.

CHRONIC/OTHER EFFECTS
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified
Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-
specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test
animals.

Additional information is available by request.

The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED--


1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY
Material -- Expected to be harmful to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.

MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITY


Biodegradation:
Base oil component -- Expected to be inherently biodegradable

BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
Page 7 of 10

______________________________________________________________________________________________________________________

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION


RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND (DOT): Not Regulated for Land Transport

LAND (TDG): Not Regulated for Land Transport

SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code

AIR (IATA): Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.

NATIONAL CHEMICAL INVENTORY LISTING: AICS, IECSC, DSL, ENCS, KECI, PICCS, TSCA

EPCRA: This material contains no extremely hazardous substances.

CWA / OPA: This product is classified as an oil under Section 311 of the Clean Water Act (40 CFR 110) and the Oil
Pollution Act of 1990. Discharge or spills which produce a visible sheen on either surface water, or in
waterways/sewers which lead to surface water, must be reported to the National Response Center at 800-424-8802.

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.

SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
Page 8 of 10

______________________________________________________________________________________________________________________

The following ingredients are cited on the lists below:

Chemical Name CAS Number List Citations


HYDROTREATED LIGHT 64742-55-8 1, 17, 18
PARAFFINIC DISTILLATES,
PETROLEUM

--REGULATORY LISTS SEARCHED--


1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293

Code key: CARC=Carcinogen; REPRO=Reproductive

SECTION 16 OTHER INFORMATION


N/D = Not determined, N/A = Not applicable

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:


Revision Changes:
Section 04: First Aid Inhalation - Header was modified.
Section 04: First Aid Ingestion - Header was modified.
Section 06: Notification Procedures - Header was modified.
Section 13: Disposal Considerations - Disposal Recommendations was modified.
Section 10 Stability and Reactivity - Header was modified.
Section 13: Regulatory Disposal Information was modified.
Section 13: Disposal Recommendations - Note was modified.
Section 09: Color was modified.
Section 09: Boiling Point C(F) was modified.
Section 09: Evaporation Rate - Header was modified.
Section 08: Personal Protection - Header was modified.
Section 08: Personal Protection was modified.
Section 07: Handling and Storage - Handling was modified.
Section 11: Inhalation Lethality Test Data was modified.
Section 11: Inhalation Lethality Test Comment was modified.
Section 05: Hazardous Combustion Products was modified.
Section 06: Accidental Release - Spill Management - Water was modified.
Section 09: Relative Density - Header was modified.
Section 09: Flash Point C(F) was modified.
Section 09: Viscosity was modified.
Section 09: Viscosity was modified.
Section 14: Sea (IMDG) - Header was modified.
Section 14: Air (IATA) - Header was modified.
Section 14: LAND (TDG) - Header was modified.
Section 14: LAND (DOT) - Header was modified.
Section 15: List Citations Table was modified.
Section 15: List Citation Table - Header was modified.
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
Page 9 of 10

______________________________________________________________________________________________________________________
Section 14: LAND (DOT) - Default was modified.
Section 14: LAND (TDG) Default was modified.
Section 14: Sea (IMDG) - Default was modified.
Section 14: Air (IATA) - Default was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 09: Relative Density was modified.
Section 16: MSN, MAT ID was modified.
Section 08: Exposure limits/standards was modified.
Composition: No components was modified.
Hazard Identification: OSHA - May be Hazardous Statement was modified.
Section 09: Oxidizing Properties was modified.
Hazard Identification: Environmental Hazard was added.
Hazard Identification: Environmental Hazard - Header was added.
Composition: Component Table was added.
Composition: Primary Ingredient Name was added.
Composition: CAS Number was added.
Composition: Concentration - Header was added.
Composition: Substances Table - Header was added.
Composition: Concentration Footnote was added.
Section 08: Exposure Limits Table was added.
Section 08: Exposure Limit Values - Header was added.
Section 12: Ecological Information - Acute Aquatic Toxicity was added.
Section 12: Ecological Information - Acute Aquatic Toxicity was added.
Section 08: OEL Table - Form Column - Header was added.
Section 08: OEL Table - Limit Column - Header was added.
Section 08: OEL Table - Notation Column - Header was added.
Section 08: OEL Table - Source Column - Header was added.
Section 08: Exposure Limit Values - Header was added.
Section 09: Pour Point - Header was deleted.
Section 09: Pour Point C(F) was deleted.
Section 13: RCRA Information Header was deleted.
Section 13: RCRA TCLP was deleted.
Section 13: RCRA TCLP was deleted.
Section 12: Ecological Information - Acute Aquatic Toxicity was deleted.
Section 12: Ecological Information - Acute Aquatic Toxicity was deleted.
-----------------------------------------------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------------------------------------------------
The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.

-----------------------------------------------------------------------------------------------------------------------------------------------------

Internal Use Only


MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A
Product Name: MOBIL MULTIPURPOSE ATF
Revision Date: 24 Dec 2009
Page 10 of 10

______________________________________________________________________________________________________________________

DGN: 2005999XUS (1008229)


-----------------------------------------------------------------------------------------------------------------------------------------------------
Copyright 2002 Exxon Mobil Corporation, All rights reserved
Product Name: MOBIL AGRI FLUID 424
Revision Date: 19May2005
Page 1 of 8

______________________________________________________________________________________________________________________

MATERIAL SAFETY DATA SHEET


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name: MOBIL AGRI FLUID 424
Product Description: Base Oil and Additives
Product Code: 522367-00, 97D388
Intended Use: Hydraulic fluid

COMPANY IDENTIFICATION
Supplier: EXXON MOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency 609-737-4411
Transportation Emergency Phone 800-424-9300
ExxonMobil Transportation No. 281-834-3296
MSDS Requests 713-613-3661
Product Technical Information 800-662-4525, 800-947-9147
MSDS Internet Address http://www.exxon.com, http://www.mobil.com

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS

Reportable Hazardous Substance(s) or Complex Substance(s)


Name CAS# Concentration*
ZINC DITHIOPHOSPHATE 68649-42-3 < 2.5%

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.

SECTION 3 HAZARDS IDENTIFICATION

This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

POTENTIAL HEALTH EFFECTS


Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0


HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.

SECTION 4 FIRST AID MEASURES


Product Name: MOBIL AGRI FLUID 424
Revision Date: 19May2005
Page 2 of 8

______________________________________________________________________________________________________________________

INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.

SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Inappropriate Extinguishing Media: Straight Streams of Water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.

Unusual Fire Hazards: Pressurized mists may form a flammable mixture.

Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Smoke, Fume, Oxides of
carbon, Sulfur oxides

FLAMMABILITY PROPERTIES
Flash Point [Method]: >198°C (389°F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D

SECTION 6 ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
Product Name: MOBIL AGRI FLUID 424
Revision Date: 19May2005
Page 3 of 8

______________________________________________________________________________________________________________________
regulations. U.S. regulations require reporting releases of this material to the environment which exceed the
reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National
Response Center can be reached at (800)424-8802.

SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.

Water Spill: Confine the spill immediately with booms. Stop leak if you can do it without risk. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Prevent small spills and leakage to avoid slip hazard.

Static Accumulator: This material is a static accumulator.

STORAGE
Do not store in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols
can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL.

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION
Product Name: MOBIL AGRI FLUID 424
Revision Date: 19May2005
Page 4 of 8

______________________________________________________________________________________________________________________
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a


level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged
gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.

ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.

GENERAL INFORMATION
Physical State: Liquid
Color: Amber
Odor: Characteristic
Odor Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION


Relative Density (at 15 °C ): 0.884
Flash Point [Method]: >198°C (389°F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: > 316°C (600°F)
Product Name: MOBIL AGRI FLUID 424
Revision Date: 19May2005
Page 5 of 8

______________________________________________________________________________________________________________________
Vapor Density (Air = 1): > 2 at 101 kPa
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20°C
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 55 cSt (55 mm²/sec ) at 40 °C | 9.6 cSt (9.6 mm²/sec) at 100°C
Oxidizing Properties: See Sections 3, 15, 16.

OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point: -36°C (-33°F)
DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
Route of Exposure Conclusion / Remarks
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m³ Minimally Toxic. Based on assessment of the components.
Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.

Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.

Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.

Eye
Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components.

CHRONIC/OTHER EFFECTS
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified
Product Name: MOBIL AGRI FLUID 424
Revision Date: 19May2005
Page 6 of 8

______________________________________________________________________________________________________________________
Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-
specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test
animals.

Additional information is available by request.

The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED--


1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.

MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITY


Biodegradation:
Base oil component -- Expected to be inherently biodegradable

BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION


RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
Product Name: MOBIL AGRI FLUID 424
Revision Date: 19May2005
Page 7 of 8

______________________________________________________________________________________________________________________

Empty Container Warning PRECAUTIONARY LABEL TEXT: Empty containers may retain residue and can be
dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY
MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult
to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum
reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with
governmental regulations.

SECTION 14 TRANSPORT INFORMATION

LAND (DOT) : Not Regulated for Land Transport

LAND (TDG) : Not Regulated for Land Transport

SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code

AIR (IATA) : Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.

NATIONAL CHEMICAL INVENTORY LISTING: AICS, DSL, EINECS, ENCS, KECI, PICCS, TSCA

EPCRA: This material contains no extremely hazardous substances.

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.

SARA (313) TOXIC RELEASE INVENTORY:


Chemical Name CAS Number Typical Value
ZINC DITHIOPHOSPHATE 68649-42-3 < 2.5%

The Following Ingredients are Cited on the Lists Below:*


Chemical Name CAS Number List Citations
PHOSPHORUS 7723-14-0 1, 4
TOLUENE 108-88-3 15
ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17

--REGULATORY LISTS SEARCHED--


1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
Product Name: MOBIL AGRI FLUID 424
Revision Date: 19May2005
Page 8 of 8

______________________________________________________________________________________________________________________
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293

Code key: CARC=Carcinogen; REPRO=Reproductive

* EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm
whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list.

SECTION 16 OTHER INFORMATION


N/D = Not determined, N/A = Not applicable

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:


No revision information is available.
-----------------------------------------------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------------------------------------------------
The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.

-----------------------------------------------------------------------------------------------------------------------------------------------------

Internal Use Only


MHC: 0, 0, 0, 0, 0, 0 PPEC: A

DGN: 2005947XUS (538859)


-----------------------------------------------------------------------------------------------------------------------------------------------------
Copyright 2002 Exxon Mobil Corporation, All rights reserved
Product Name: MOBILGREASE SPECIAL
Revision Date: 29Feb2008
Page 1 of 8

______________________________________________________________________________________________________________________

MATERIAL SAFETY DATA SHEET


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name: MOBILGREASE SPECIAL
Product Description: Base Oil and Additives
Product Code: 530303-00, 970060
Intended Use: Grease

COMPANY IDENTIFICATION
Supplier: EXXON MOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency 609-737-4411
Transportation Emergency Phone 800-424-9300
ExxonMobil Transportation No. 281-834-3296
MSDS Requests 713-613-3661
Product Technical Information 800-662-4525, 800-947-9147
MSDS Internet Address http://www.exxon.com, http://www.mobil.com

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS

Reportable Hazardous Substance(s) or Complex Substance(s)


Name CAS# Concentration*
ZINC DITHIOPHOSPHATE 68649-42-3 < 2.5%

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.

SECTION 3 HAZARDS IDENTIFICATION

This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

POTENTIAL HEALTH EFFECTS


Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0


HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.

SECTION 4 FIRST AID MEASURES


Product Name: MOBILGREASE SPECIAL
Revision Date: 29Feb2008
Page 2 of 8

______________________________________________________________________________________________________________________

INHALATION
Under normal conditions of intended use, this material is not expected to be an inhalation hazard.

SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Inappropriate Extinguishing Media: Straight Streams of Water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.

Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke,
Fume, Sulfur oxides

FLAMMABILITY PROPERTIES
Flash Point [Method]: >200C (392F) [ EST. FOR OIL, ASTM D-92 (COC)]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D

SECTION 6 ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations. US regulations require reporting releases of this material to the environment which
exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry
creeks. The National Response Center can be reached at (800)424-8802.
Product Name: MOBILGREASE SPECIAL
Revision Date: 29Feb2008
Page 3 of 8

______________________________________________________________________________________________________________________

SPILL MANAGEMENT
Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal.

Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Skim from surface.

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Prevent small spills and leakage to avoid slip hazard.

Static Accumulator: This material is not a static accumulator.

STORAGE
Do not store in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE LIMIT VALUES

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a


level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
Product Name: MOBILGREASE SPECIAL
Revision Date: 29Feb2008
Page 4 of 8

______________________________________________________________________________________________________________________
respirators to be considered for this material include:
No protection is ordinarily required under normal conditions of use and with adequate ventilation.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
No protection is ordinarily required under normal conditions of use.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.

ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.

GENERAL INFORMATION
Physical State: Solid
Form: Semi-fluid
Color: Gray
Odor: Characteristic
Odor Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION


Relative Density (at 15 C ): 0.94
Flash Point [Method]: >200C (392F) [ EST. FOR OIL, ASTM D-92 (COC)]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D
Boiling Point / Range: > 316C (600F)
Vapor Density (Air = 1): N/D
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 C
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Product Name: MOBILGREASE SPECIAL
Revision Date: 29Feb2008
Page 5 of 8

______________________________________________________________________________________________________________________
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 150 cSt (150 mm2/sec ) at 40 C
Oxidizing Properties: See Sections 3, 15, 16.

OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/D
DMSO Extract (mineral oil only), IP-346: < 3 %wt

NOTE: Most physical properties above are for the oil component in the material.

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
Route of Exposure Conclusion / Remarks
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on assessment of the components.
Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.

Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.

Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.

Eye
Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components.

CHRONIC/OTHER EFFECTS
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified
Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-
specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test
Product Name: MOBILGREASE SPECIAL
Revision Date: 29Feb2008
Page 6 of 8

______________________________________________________________________________________________________________________
animals.

Additional information is available by request.

The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED--


1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.

MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITY


Biodegradation:
Base oil component -- Expected to be inherently biodegradable

BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION


RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
Product Name: MOBILGREASE SPECIAL
Revision Date: 29Feb2008
Page 7 of 8

______________________________________________________________________________________________________________________
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND (DOT) : Not Regulated for Land Transport

LAND (TDG) : Not Regulated for Land Transport

SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code

AIR (IATA) : Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.

NATIONAL CHEMICAL INVENTORY LISTING: ENCS, TSCA, DSL, AICS, EINECS

EPCRA: This material contains no extremely hazardous substances.

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.

SARA (313) TOXIC RELEASE INVENTORY:


Chemical Name CAS Number Typical Value
ZINC DITHIOPHOSPHATE 68649-42-3 < 2.5%

The Following Ingredients are Cited on the Lists Below:


Chemical Name CAS Number List Citations
DIPHENYLAMINE 122-39 -4 5, 18
ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17

--REGULATORY LISTS SEARCHED--


1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293

Code key: CARC=Carcinogen; REPRO=Reproductive


Product Name: MOBILGREASE SPECIAL
Revision Date: 29Feb2008
Page 8 of 8

______________________________________________________________________________________________________________________

SECTION 16 OTHER INFORMATION


N/D = Not determined, N/A = Not applicable

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:


No revision information is available.
-----------------------------------------------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------------------------------------------------
The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.

-----------------------------------------------------------------------------------------------------------------------------------------------------

Internal Use Only


MHC: 0, 0, 0, 0, 0, 0 PPEC: A

DGN: 2006111XUS (553407)


-----------------------------------------------------------------------------------------------------------------------------------------------------
Copyright 2002 Exxon Mobil Corporation, All rights reserved
Lubricants - Material and Safety Data Sheets

MSDS Search
Search Help
Click here for the PDF version
NO. 2 DIESEL FUEL

---------------------------------------------------------------------------
# 1. CHEMICAL PRODUCT/COMPANY IDENTIFICATION
---------------------------------------------------------------------------

No. 2 Diesel Fuel

MSDS Code: GASC0220 Revised: 12-Oct-2000


Version: 2
CAS Number: 68476-34-6

Tradenames: Diesel Fuel No. 2, Low Sulfur


Diesel Fuel No. 2, High Sulfur

MANUFACTURER/DISTRIBUTOR
Conoco Inc.
PO Box 2197
Houston, TX 77252
PHONE NUMBERS
Product Information : 1-281-293-5550
Transport Emergency : CHEMTREC 1-800-424-9300 or
1-703-527-3887 (international; call collect)
Medical Emergency : 1-800-342-5119 or 1-281-493-2767
WEB SITE : www.conoco.com
---------------------------------------------------------------------------
2. COMPOSITION/INFORMATION ON INGREDIENTS
---------------------------------------------------------------------------
Components CAS Number %
Diesel Fuel, No. 2 68476-34-6 100

Petroleum distillate standard applies. (See Section 8.)


---------------------------------------------------------------------------
3. HAZARDS IDENTIFICATION
---------------------------------------------------------------------------
--- EMERGENCY OVERVIEW ---

APPEARANCE / ODOR

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Lubricants - Material and Safety Data Sheets

Red or Undyed (Clear or Straw-Colored) Liquid / Aromatic Odor

OSHA REGULATORY STATUS


This material is hazardous as defined under OSHA regulations.
Combustible.
See below for health effects.

HMIS RATING
Health: 1; Flammability: 2; Reactivity: 0
___________________________________

Potential Health Effects


Primary Routes of Entry: Skin, inhalation

The product may cause irritation to the eyes, nose, throat, lungs,
and skin after prolonged or repeated exposure. Extreme
overexposure or aspiration into the lungs may cause lung damage or
death. Overexposure may cause weakness, headache, nausea,
confusion, blurred vision, drowsiness, and other nervous system
effects; greater overexposure may cause dizziness, slurred speech,
flushed face, unconsciousness, and convulsions.

Combustion Product - Carbon Monoxide:


Carbon monoxide decreases the ability of the blood to carry oxygen.
Inhalation may cause headache, nausea, rapid respirations,
vomiting, dizziness, confusion, impaired judgement, personality
changes, memory impairment, weakness, shortness of breath,
unconsciousness, convulsions and death if not treated. It may
cause chest pains in persons with heart disease. Carbon monixde
poisoning can cause pallor (whiteness) or cyanosis (blueness) of
the skin and extremities.
High exposures to carbon monoxide may cause heart irregularities.
Carbon monoxide may adversely affect the unborn babies of pregnant
women.

Carcinogenicity Information
None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.
---------------------------------------------------------------------------
4. FIRST AID MEASURES
---------------------------------------------------------------------------
First Aid
INHALATION
If inhaled, remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
Call a physician.

SKIN CONTACT

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Lubricants - Material and Safety Data Sheets

Wash skin thoroughly with soap and water. If irritation develops


and persists, consult a physician.

EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.

INGESTION
If swallowed, do not induce vomiting. Immediately give 2 glasses
of water. Never give anything by mouth to an unconscious person.
Call a physician.

Notes to Physicians
Activated charcoal mixture may be administered. To prepare
activated charcoal mixture, suspend 50 grams activated charcoal in
400 mL water and mix thoroughly. Administer 5 mL/kg, or 350 mL
for an average adult.
---------------------------------------------------------------------------
# 5. FIRE FIGHTING MEASURES
---------------------------------------------------------------------------
Flammable Properties
Flash Point : 130 F (54 C)
Method : PMCC
Flammable limits in Air, % by Volume
LEL : 0.4
UEL : 6
Autoignition : 494 F (257 C)

Vapor forms explosive mixture with air. Vapors or gases may


travel considerable distances to ignition source and flash back.

NFPA Rating : Health 0; Flammability 2; Reactivity 0.

Extinguishing Media
Water Spray, Foam, Dry Chemical, CO2.

Fire Fighting Instructions


Use water to keep fire-exposed containers cool. If a leak or
spill has not ignited, use water spray to disperse the vapors and
to provide protection for personnel attempting to stop a leak.
Water spray may be used to flush spills away from sources of
potential ignition.

Products of combustion may contain carbon monoxide, carbon dioxide,


and other toxic materials. Do not enter enclosed or confined space
without proper protective equipment including respiratory protection.
---------------------------------------------------------------------------
6. ACCIDENTAL RELEASE MEASURES
---------------------------------------------------------------------------

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Lubricants - Material and Safety Data Sheets

Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Remove source of heat, sparks, flame, impact, friction and


electricity including internal combustion engines and power tools.
If equipment is used for spill cleanup, it must be explosion proof
and suitable for flammable liquid and vapor.

NOTE: Vapors released from the spill may create an explosive


atmosphere.

Initial Containment
Dike spill. Prevent material from entering sewers, waterways, or
low areas.

Spill Clean Up
Soak up with sawdust, sand, oil dry or other absorbent material.
---------------------------------------------------------------------------
7. HANDLING AND STORAGE
---------------------------------------------------------------------------
Handling (Personnel)
Avoid breathing vapors or mist. Avoid contact with eyes, skin, or
clothing. Wash thoroughly after handling. Wash clothing after use.

Handling (Physical Aspects)


Ground container when pouring. Keep away from heat, sparks and
flames. Close container after each use. Do not pressurize, cut,
weld, braze, solder, grind, or drill on or near full or empty
container. Empty container retains residue (liquid and/or vapor)
and may explode in heat of fire.

Storage
Store in a well ventilated place. Keep container tightly closed.
Store in accordance with National Fire Protection Association
recommendations. Store away from heat, sparks and flames,
oxidizers.
---------------------------------------------------------------------------
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
---------------------------------------------------------------------------
Engineering Controls
Use only with adequate ventilation. Keep container tightly closed.

Personal Protective Equipment


RESPIRATORY PROTECTION
Select appropriate NIOSH-approved respiratory protective equipment
when exposed to sprays or mists. Select appropriate NIOSH -approved
respiratory protection where necessary to maintain exposures below

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Lubricants - Material and Safety Data Sheets

acceptable limits. Proper respirator selection should be determined


by adequately trained personnel and based on the contaminant(s), the
degree of potential exposure, and published respirator protection
factors.

PROTECTIVE GLOVES
Should be worn when the potential exists for prolonged or repeated
skin contact. NBR or neoprene recommended.

EYE PROTECTION
Safety glasses with side shields. Chemical splash goggles or face
shield for spray/mists or if splashing can occur.

OTHER PROTECTIVE EQUIPMENT


Coveralls with long sleeves if splashing is probable.

Applicable Exposure Limits


Petroleum distillate standard applies.
PEL (OSHA) : 500 ppm, 2000 mg/m3, 8 Hr. TWA
TLV (ACGIH) : None Established
---------------------------------------------------------------------------
9. PHYSICAL AND CHEMICAL PROPERTIES
---------------------------------------------------------------------------
Physical Data
Boiling Point : 350-690 F (177-366 C)
Vapor Pressure : 1 mm Hg @ 68 F (20 C)
Vapor Density : >1 (Air=1.0)
% Volatiles : Nil
Solubility in Water : Insoluble
Odor : Aromatic.
Form : Liquid.
Color : Red or Undyed (Clear or Straw-Colored)
Specific Gravity : 0.84-0.88 @ 60 F (16 C) )
---------------------------------------------------------------------------
10. STABILITY AND REACTIVITY
---------------------------------------------------------------------------
Chemical Stability
Stable at normal temperatures and storage conditions.

Conditions to Avoid
Heat, sparks, and flames.

Incompatibility with Other Materials


Incompatible or can react with strong oxidizers.

Decomposition
Carbon monoxide may be formed from incomplete combustion.

Polymerization

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Lubricants - Material and Safety Data Sheets

Polymerization will not occur.


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# 11. TOXICOLOGICAL INFORMATION
---------------------------------------------------------------------------
Animal Data
Animal studies have shown that prolonged or repeated inhalation
exposures to high concentrations of some petroleum distillates have
caused liver tumors in mice and kidney damage and tumors in male rats.
However, kidney effects were not seen in similar studies involving
female rats, guinea pigs, dogs, or monkeys. Present studies indicate
the kidney effects will only occur in male rats. Also, human studies
do not indicate this peculiar sensitivity for kidney damage and
studies reported in 1992 showed that this particular type of rat
kidney damage is not useful in predicting a human health hazard.
The significance of liver tumors in mice exposed to high doses of
chemicals is highly speculative and probably not a good indicator for
predicting a potential human carcinogenic hazard.

Mouse skin painting studies have shown that petroleum middle


distillates (boiling range 100-700 F; naphtha, jet fuel, diesel fuel,
kerosene, etc.) can cause skin cancer when repeatedly applied and
never washed from the animal's skin. The relative significance of
this to human health is uncertain since the petroleum distillates were
not washed from the skin and resulting skin effects (irritation, cell
damage, etc.) may play a role in the tumorigenic response. A few
studies have shown that washing the animal's skin with soap and water
between treatments greatly reduces the carcinogenic effect of some
petroleum oils. Other laboratory studies indicate that middle
distillates caused the skin tumors by promoting, rather than
initiating, the formation of tumors, so the effect is probably dose-
related and low level exposure should not be carcinogenic.

Studies in mice and rats have shown that chronic exposure (8


hours/day, 7 days/week, 24 months) to unfiltered diesel exhaust
produced tumors of the lungs and also lymphomas. On the basis of
these studies, NIOSH recommends that whole diesel exhaust be
regarded as a potential carcinogen. The National Toxicology Program
(NTP) listed diesel exhaust particulates as "reasonably anticipated to
be a human carcinogen" (Report on Carcinogens, 9th edition, 2001).

Acute toxicity data from studies supported by the American


Petroleum Institute with a generic #2 fuel oil sample:
Oral, LD50 (rats) : 7-21 mL/kg
Skin, LD50 (rabbits) : >5 mL/kg
Skin Irritation (rabbits; index, 0-8) : 3-4
Eye Irritation (rabbits; index, 0-110) : 1
Skin Sensitization (guinea pigs) : Non-sensitizing
---------------------------------------------------------------------------
12. ECOLOGICAL INFORMATION

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Lubricants - Material and Safety Data Sheets

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Ecotoxicological Information
No specific aquatic data available for this product.
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13. DISPOSAL CONSIDERATIONS
---------------------------------------------------------------------------
Waste Disposal
Treatment, storage, transportation, and disposal must be in
accordance with applicable Federal, State/Provincial, and Local
regulations. Do not flush to surface water or sanitary sewer
system.

By itself, the liquid is expected to be a RCRA ignitable hazardous


waste.

Container Disposal
Empty drums should be completely drained, properly bunged, and
promptly shipped to the supplier or a drum reconditioner. All other
containers should be disposed of in an environmentally safe manner.
---------------------------------------------------------------------------
14. TRANSPORTATION INFORMATION
---------------------------------------------------------------------------
Shipping Information
DOT
Proper Shipping Name : Diesel fuel
Hazard Class : Combustible liquid
I.D. No. (UN/NA) : NA1993
Packing Group : III
DOT Label(s) : None
DOT Placard : Combustible

ICAO/IMDG
Proper Shipping Name : Gas Oil
Hazard Class : 3
UN/NA Number : UN1202
Packing Group : III
Label : Flammable liquid
Placard : Flammable
---------------------------------------------------------------------------
15. REGULATORY INFORMATION
---------------------------------------------------------------------------
U.S. Federal Regulations
OSHA HAZARD DETERMINATION
This material is hazardous as defined by OSHA's Hazard Communication
Standard, 29 CFR 1910.1200.

CERCLA/SUPERFUND
Not applicable; this material is covered by the CERCLA petroleum
exclusion.

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Lubricants - Material and Safety Data Sheets

SARA, TITLE III, 302/304


This material is not known to contain extremely hazardous
substances.

SARA, TITLE III, 311/ 312


Acute : Yes
Chronic : Yes
Fire : Yes
Reactivity : No
Pressure : No

SARA, TITLE III, 313


This material is not known to contain any chemical(s) at a level
of 1.0% or greater (0.1% for carcinogens) on the list of Toxic
Chemicals and subject to release reporting requirements.

TSCA
This material is in the TSCA Inventory of Chemical Substances (40
CFR 710) and/or is otherwise in compliance with TSCA.

RCRA
This material, when discarded or disposed of, is not specifically
listed as a hazardous waste in Federal regulations; however, it
meets criteria for being ignitable according to U. S. EPA
definitions (40 CFR 261). This material could also become a
hazardous waste if it is mixed with or comes in contact with a
listed hazardous waste. If it is a hazardous waste, regulations
at 40 CFR 262-266 and 268 may apply.

CLEAN WATER ACT


The material contains the following ingredient(s) which is
considered hazardous if spilled into navigable waters and
therefore reportable to the National Response Center
(1-800-424-8802).
Ingredient : Petroleum Hydrocarbons.
Reportable Quantity : Film or sheen upon or discoloration of
any water surface.

State Regulations (U.S.)


CALIFORNIA "PROP 65"
This material is not known to contain any ingredient(s) subject to
the Act.

PENNSYLVANIA WORKER & COMMUNITY RIGHT TO KNOW ACT


This material may contain the following ingredient(s) subject to
the Pennsylvania Worker and Community Right to Know Hazardous
Substances List.
Ingredient : Diesel Fuel Oil

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Lubricants - Material and Safety Data Sheets

Category : Hazardous Substance.

Canadian Regulations
CLASS B Division 3 - Combustible Liquid.
CLASS D Division 2 Subdivision B - Toxic Material.
Chronic Toxic Effects.
---------------------------------------------------------------------------
16. OTHER INFORMATION
---------------------------------------------------------------------------
Additional Information: None.
_______________
The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.

Prepared By : MSDS Coordinator


Conoco Inc.
Address : PO Box 2197
Houston, TX 77252
Telephone : 1-281-293-4386

# Indicates updated section.


End of MSDS

Questions can be directed to our MSDS administrator.

© Conoco Inc., 2000 All rights reserved. Legal, Privacy, and Security Notices.

http://lubes.conoco.com/msds/find.asp?q1=&wordno=0&pstr=&number=51GASC0220 (9 of 9) [9/9/2001 6:28:12 AM]


Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Revision Date: 30Apr2009
Page 1 of 8
______________________________________________________________________________________________________________________

MATERIAL SAFETY DATA SHEET


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Product Description: Base Oil and Additives
MSDS Number: 12560
Intended Use: Engine oil

COMPANY IDENTIFICATION
Supplier: Imperial Oil Products Division
240 4th Avenue
Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency 519-339-2145
Telephone
Transportation Emergency Phone Number 519-339-2145
Product Technical Information 1-800-268-3183
Supplier General Contact 1-800-567-3776

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS

No Reportable Hazardous Substance(s) or Complex Substance(s).

SECTION 3 HAZARDS IDENTIFICATION


This material is not considered to be hazardous according to regulatory guidelines see Section 15.

HEALTH EFFECTS
Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0


HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0

Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from
person to person.

SECTION 4 FIRST AID MEASURES

INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.
Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Revision Date: 30Apr2009
Page 2 of 8
______________________________________________________________________________________________________________________

SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.

Eye Contact
Flush thoroughly with water. If irritation occurs, get medical assistance.

Ingestion
First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Inappropriate Extinguishing Media: Straight streams of water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams,
sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.

Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion
products, Oxides of carbon

FLAMMABILITY PROPERTIES
Flash Point [Method]: 215C (419F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D

SECTION 6 ACCIDENTAL RELEASE MEASURES

Notification Procedures
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations.

SPILL MANAGEMENT
Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.

Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Revision Date: 30Apr2009
Page 3 of 8
______________________________________________________________________________________________________________________
before using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard.

Static Accumulator: This material is a static accumulator.

STORAGE
Do not store in open or unlabelled containers. Keep away from incompatible materials.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols
can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL.

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a


level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Revision Date: 30Apr2009
Page 4 of 8
______________________________________________________________________________________________________________________

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
No protection is ordinarily required under normal conditions of use.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practise good housekeeping.

ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.

GENERAL INFORMATION
Physical State: Liquid
Colour: brown
Odour: Characteristic
Odour Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION


Relative Density (at 15 C): 0.872
Flash Point [Method]: 215C (419F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D
Boiling Point / Range: N/D
Vapour Density (Air = 1): N/D
VAPOUR PRESSURE: < 0.013 kPa (0.1 mm Hg) at 20°C
Evaporation Rate (N-Butyl Acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: [N/D at 40°C] | 15 cSt (15 mm²/sec) at 100C
Oxidizing properties: See Sections 3, 15, 16.

OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Revision Date: 30Apr2009
Page 5 of 8
______________________________________________________________________________________________________________________
Pour Point: -27°C (-17°F)
DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Acute Toxicity
Route of Exposure Conclusion / Remarks
INHALATION
Toxicity (Rat): LC50 > 5000 mg/m³ Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.

Ingestion
Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.

Skin
Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.

Eye
Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.

CHRONIC/OTHER EFFECTS
For the product itself:
Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any
carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may
become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in
vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion
products of gasoline and/or thermal degradation products.
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified
Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-
specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test
animals.

Additional information is available by request.


Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Revision Date: 30Apr2009
Page 6 of 8
______________________________________________________________________________________________________________________
CMR Status: None.

Chemical Name CAS Number List Citations


Phosphorus 7723-14-0 4

--REGULATORY LISTS SEARCHED--


1 = IARC 1 3 = IARC 2B 5 = ACGIH A1
2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY
Material -- Expected to be harmful to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.

MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITY


Biodegradation:
Base oil component -- Expected to be inherently biodegradable

BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.

Regulatory Disposal Information


Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain
residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty
drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty
containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor
and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR
OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION


Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Revision Date: 30Apr2009
Page 7 of 8
______________________________________________________________________________________________________________________

LAND (TDG) : Not Regulated for Land Transport

LAND (DOT) : Not Regulated for Land Transport

SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code

AIR (IATA) : Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

WHMIS Classification: Not controlled

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
(M)SDS contains all the information required by the Controlled Products Regulations.

CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have
been notified under CEPA.

National Chemical Inventory Listing: DSL, TSCA

The Following Ingredients are Cited on the Lists Below: None.

--REGULATORY LISTS SEARCHED--


1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b
2 = TSCA 5a2 4 = TSCA 6 6 = NPRI

SECTION 16 OTHER INFORMATION


N/D = Not determined, N/A = Not applicable

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:


Revision Changes:
Section 04: First Aid Eye - Header was modified.
Section 04: First Aid Ingestion - Header was modified.
Section 06: Notification Procedures - Header was modified.
Section 11: Ingestion Acute Lethality - Header was modified.
Section 08: Hand Protection was modified.
Section 09: Vapour Pressure - Header was modified.
Section 07: Handling and Storage-Storage Phrases was modified.
Section 11: Dermal Lethality Test Data was modified.
Section 11: Oral Lethality Test Data was modified.
Section 05: Hazardous Combustion Products was modified.
Product Name: MOBIL DELVAC 1300 SUPER 15W-40
Revision Date: 30Apr2009
Page 8 of 8
______________________________________________________________________________________________________________________
Section 09: Flash Point C(F) was modified.
Section 15: National Chemical Inventory Listing - Header was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 09: Pour Point - Header was added.
Section 09: Pour Point C(F) was added.
Section 12: Ecological Information - Acute Aquatic Toxicity was added.
Section 12: Ecological Information - Acute Aquatic Toxicity was added.
Section 11: Chemical Name - Header was added.
Section 11: CAS Number - Header was added.
Section 11: List Citation - Header was added.
Section 11: Tox List Cited Table was added.
Composition: No components was added.
Section 13: Regulatory Disposal Information - Header was added.
Section 13: Regulatory Disposal Information - Header was deleted.
Composition: No components was deleted.
Section 12: Ecological Information - Acute Aquatic Toxicity was deleted.
Section 12: Ecological Information - Acute Aquatic Toxicity was deleted.
-----------------------------------------------------------------------------------------------------------------------------------------------------
WHMIS Classification: Not controlled

-----------------------------------------------------------------------------------------------------------------------------------------------------
The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate
and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the
document is the most current available from an official Imperial Oil distribution system. The information and
recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy
itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be
consulted to insure proper health, safety and other necessary information is included on the container. Appropriate
warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly
prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is
not permitted.

-----------------------------------------------------------------------------------------------------------------------------------------------------
DGN: 5010580 (1011991)
-----------------------------------------------------------------------------------------------------------------------------------------------------
Copyright 2002 Imperial Oil Limited, All rights reserved

Prepared By: Imperial Oil Limited, IH and Product Safety


Material Safety Data Sheet https://www.cbest.chevron.com/msdsServer/controller?module=com.c...

Material Safety Data Sheet


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Texaco Havoline® DEX-COOL® Extended Life Prediluted 50/50


Anti-Freeze/Coolant
Product Use: Antifreeze/Coolant
Product Number(s): CPS227995
Company Identification
Chevron Products Company
a division of Chevron U.S.A. Inc.
6001 Bollinger Canyon Road
San Ramon, CA 94583
United States of America
www.chevronlubricants.com

Transportation Emergency Response


CHEMTREC: (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800) 231-0623 or
(510) 231-0623
Product Information
email : lubemsds@chevron.com
Product Information: 800-LUBE-TEK
MSDS Requests: 800-414-6737

SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Ethylene Glycol 107-21-1 40 - 55 %weight

Diethylene glycol 111-46-6 1 - 5 %weight

Potassium 2-ethylhexanoate 3164-85-0 1 - 5 %weight

SECTION 3 HAZARDS IDENTIFICATION

************************************************************************************************************************
EMERGENCY OVERVIEW

- HARMFUL OR FATAL IF SWALLOWED


- CONTAINS MATERIAL THAT MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS BASED ON ANIMAL DATA
- POSSIBLE BIRTH DEFECT HAZARD - CONTAINS MATERIAL THAT MAY CAUSE BIRTH DEFECTS BASED
ON ANIMAL DATA
- CAUSES DAMAGE TO:
- KIDNEY
************************************************************************************************************************

IMMEDIATE HEALTH EFFECTS


Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be harmful to
internal organs if absorbed through the skin.
Ingestion: Toxic; may be harmful or fatal if swallowed.
Inhalation: The vapor or fumes from this material may cause respiratory irritation. Symptoms of respiratory irritation
may include coughing and difficulty breathing. Breathing this material at concentrations above the recommended
exposure limits may cause central nervous system effects. Central nervous system effects may include headache,

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dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion, or disorientation.
At extreme exposures, central nervous system effects may include respiratory depression, tremors or convulsions,
loss of consciousness, coma or death.

DELAYED OR OTHER HEALTH EFFECTS:


Reproduction and Birth Defects: Contains material that may cause adverse reproductive effects if swallowed
based on animal data.Contains material that may cause birth defects based on animal data.
Target Organs: Contains material that causes damage to the following organ(s) if swallowed: Kidney
See Section 11 for additional information. Risk depends on duration and level of exposure.
SECTION 4 FIRST AID MEASURES

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes
with water.
Skin: To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or
thoroughly clean before reuse.
Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by mouth to
an unconscious person.
Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention if breathing difficulties continue.
SECTION 5 FIRE FIGHTING MEASURES

FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.

NFPA RATINGS: Health: 2 Flammability: 0 Reactivity: 0

FLAMMABLE PROPERTIES:
Flashpoint: Not Applicable
Autoignition: No Data Available
Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not Applicable

EXTINGUISHING MEDIA: Dry Chemical, CO2, AFFF Foam or alcohol resistant foam.

PROTECTION OF FIRE FIGHTERS:


Fire Fighting Instructions: This material will not burn.
SECTION 6 ACCIDENTAL RELEASE MEASURES

Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further
contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in
Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent
materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in
disposable containers and dispose of in a manner consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800)
424-8802 as appropriate or required.
SECTION 7 HANDLING AND STORAGE
Precautionary Measures: Do not get in eyes, on skin, or on clothing. Do not breathe vapor or fumes. Wash
thoroughly after handling.
General Handling Information: Do not taste or swallow antifreeze or solution. Keep out of the reach of children
and animals.
General Storage Information: Do not store in open or unlabeled containers.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it
may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks,
static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should
be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other
substances in the work place when designing engineering controls and selecting personal protective equipment. If
engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the

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personal protective equipment listed below is recommended. The user should read and understand all instructions
and limitations supplied with the equipment since protection is usually provided for a limited time or under certain
circumstances.

ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the
recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT


Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety
glasses with side shields as a good safety practice.
Skin Protection: No special protective clothing is normally required. Where splashing is possible, select protective
clothing depending on operations conducted, physical requirements and other substances in the workplace.
Suggested materials for protective gloves include: Natural rubber, Neoprene, Nitrile Rubber, Polyvinyl Chloride
(PVC or Vinyl).
Respiratory Protection: Determine if airborne concentrations are below the recommended occupational exposure
limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an approved respirator
that provides adequate protection from this material, such as: Air-Purifying Respirator for Organic Vapors, Dusts
and Mists.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide
adequate protection.
Occupational Exposure Limits:
Component Agency TWA STEL Ceiling Notation
Ethylene Glycol ACGIH -- -- 100 mg/m3 --

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Orange
Physical State: Liquid
Odor: Faint or Mild
pH: 8 - 8.6
Vapor Pressure: <0.01 mmHg @ 20 °C (68 °F)
Vapor Density (Air = 1): 2.1
Boiling Point: 107.8°C (226°F) (Typical)
Solubility: Miscible
Freezing Point: -36.7°C (-34°F) (Typical)
Specific Gravity: 1.06 - 1.09 @ 15.6°C (60.1°F) / 15.6°C (60.1°F)
Viscosity: No data available
SECTION 10 STABILITY AND REACTIVITY

Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling
conditions of temperature and pressure.
Hazardous Decomposition Products: Aldehydes (Elevated temperatures), Ketones (Elevated temperatures)
Hazardous Polymerization: Hazardous polymerization will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION

IMMEDIATE HEALTH EFFECTS


Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components.
Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product
components.
Skin Sensitization: No product toxicology data available.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar materials or
product components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or product
components.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials
or product components.

ADDITIONAL TOXICOLOGY INFORMATION:

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This product contains diethylene glycol (DEG). The estimated oral lethal dose is about 50 cc (1.6 oz) for an adult
human. DEG has caused the following effects in laboratory animals: liver abnormalities, kidney damage and blood
abnormalities. It has been suggested as a cause of the following effects in humans: liver abnormalities, kidney
damage, lung damage and central nervous system damage.

This product contains ethylene glycol (EG). The toxicity of EG via inhalation or skin contact is expected to be slight
at room temperature. The estimated oral lethal dose is about 100 cc (3.3 oz.) for an adult human. Ethylene glycol is
oxidized to oxalic acid which results in the deposition of calcium oxalate crystals mainly in the brain and kidneys.
Early signs and symptoms of EG poisoning may resemble those of alcohol intoxication. Later, the victim may
experience nausea, vomiting, weakness, abdominal and muscle pain, difficulty in breathing and decreased urine
output. When EG was heated above the boiling point of water, vapors formed which reportedly caused
unconsciousness, increased lymphocyte count, and a rapid, jerky movement of the eyes in persons chronically
exposed. When EG was administered orally to pregnant rats and mice, there was an increase in fetal deaths and
birth defects. Some of these effects occurred at doses that had no toxic effects on the mothers. We are not aware
of any reports that EG causes reproductive toxicity in human beings.

2-Ethylhexanoic acid (2-EXA) caused an increase in liver size and enzyme levels when repeatedly administered to
rats via the diet. When administered to pregnant rats by gavage or in drinking water, 2-EXA caused teratogenicity
(birth defects) and delayed postnatal development of the pups. Additionally, 2-EXA impaired female fertility in rats.
Birth defects were seen in the offspring of mice who were administered sodium 2-ethylhexanoate via intraperitoneal
injection during pregnancy.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material should be
kept out of sewage and drainage systems and all bodies of water.

ENVIRONMENTAL FATE
This material is expected to be readily biodegradable.
SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. Oil collection services are available for used oil recycling
or disposal. Place contaminated materials in containers and dispose of in a manner consistent with applicable
regulations. Contact your sales representative or local environmental or health authorities for approved disposal or
recycling methods.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods
Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific
shipping requirements.

DOT Shipping Description: Anti-freeze Preparations, Proprietary


Additional Information:Bulk shipments with a reportable quantity (5000 pounds) of ethylene glycol are a
hazardous material. The Proper Shipping Name is: Environmentally Hazardous Substance, Liquid, N.O.S. (ethylene
glycol), 9, UN3082, III, RQ (ethylene glycol).

IMO/IMDG Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORTATION


UNDER THE IMDG CODE

ICAO/IATA Shipping Description: Anti-freeze Preparations, Proprietary; NOT REGULATED AS DANGEROUS


GOODS FOR TRANSPORT UNDER ICAO

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES


2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: NO
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

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Material Safety Data Sheet https://www.cbest.chevron.com/msdsServer/controller?module=com.c...

REGULATORY LISTS SEARCHED:


01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

The following components of this material are found on the regulatory lists indicated.
Diethylene glycol 07
Ethylene Glycol 03, 05, 06, 07

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL (Canada),
EINECS (European Union), IECSC (China), PICCS (Philippines), TSCA (United States).

One or more components does not comply with the following chemical inventory requirements: ENCS (Japan),
KECI (Korea).

NEW JERSEY RTK CLASSIFICATION:


Refer to components listed in Section 2.

WHMIS CLASSIFICATION:
Class D, Division 1, Subdivision B: Toxic Material -
Acute Lethality
Class D, Division 2, Subdivision A: Very Toxic Material -
Teratogenicity and Embryotoxicity
Reproductive Toxicity

SECTION 16 OTHER INFORMATION


NFPA RATINGS: Health: 2 Flammability: 0 Reactivity: 0

HMIS RATINGS: Health: 2* Flammability: 0 Reactivity: 0


(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *-
Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the
National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings).

LABEL RECOMMENDATION:
Label Category : ANTIFREEZE/COOLANT 3 - AFC3

REVISION STATEMENT: This revision updates the following sections of this Material Safety Data Sheet: 15
Revision Date: August 22, 2007

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:


TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
CAS - Chemical Abstract Service Number
ACGIH - American Conference of Government IMO/IMDG - International Maritime Dangerous Goods Code
Industrial Hygienists
API - American Petroleum Institute MSDS - Material Safety Data Sheet
CVX - Chevron NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on Cancer OSHA - Occupational Safety and Health Administration

Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI
MSDS Standard (Z400.1) by the Chevron Energy Technology Company, 100 Chevron Way, Richmond,
California 94802.

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Material Safety Data Sheet https://www.cbest.chevron.com/msdsServer/controller?module=com.c...

The above information is based on the data of which we are aware and is believed to be correct as
of the date hereof. Since this information may be applied under conditions beyond our control and
with which we may be unfamiliar and since data made available subsequent to the date hereof may
suggest modifications of the information, we do not assume any responsibility for the results of its
use. This information is furnished upon condition that the person receiving it shall make his own
determination of the suitability of the material for his particular purpose.

6z7 2009-06-22 18:35

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