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TAIKABUTSU OVERSEAS Vol.10No.

Progress of Refractories Used in Blast Furnaces

YASUAKISHINOHARA *

1. Introduction furnace be11y an the lower part of the furnace shaft it has a
decisive influence on the life of the blast furnace.
Recently, blast furnace have been increasing in capacity.
Blast-furnace, that may be considered as the symbo1 of This has caused an increase in the internal furnace pressure
the iron and steel-making industry at the end of 1960s, had a rise in the quantity of molten pig iron. Thus, the condi-
a capacity usually around 15oo cubic meter. Since then, tions that blast-furnace hearth refractories experience are
however, they have grown increasingly, and in the middle becoming increasingly severe.
of the 1970s many super-large blast furnace with a capacity
as large as 50oo cubic meter were put into operation. 2-1. Refractory Application in Hearth
Recently, re-arrangement of the production structure of
steel mills has resulted in a sharp decrease in the number of Until carbon blocks were tried in Kukioka blast furnace
blast-fumaces in operation, No.3 of Nippon Steel Corporation (then Yawata Iron & Steel
Under these circumstances, improvement of the rate of Co. Ltd.) in 1961, the blast furnace hearths were wholly
blast furnace operation as well as an extension of blast fur- built of chamotte bricks, One blast furnace could therefore
nace life is required more intensely than ever before. ln tap no more than one million tons of pig iron during its
order to improve blast furnaces to meet these requirements, whole life.
iron and steel-making companies have been investigating When carbon blocks were first applied to the stmcture of
many aspects of refractory technology; this technological the heanh of blast furnaces, hearth structure, in terms of the
study has not been confined to checking the quality of sort of refractories used was ehanged to carbon block at the
refractory materials, but involves lining profile studies, upper part combined with chamotte brick at the lower part,
structural stress analysis, detection of breakage and damage, and then it was changed again to a lining built of
repairs during operation, and other matters. Good results chamotteihigh alumina brick at the upper part combined
have been steadily obtained in this research. with carbon blocks (ceramic cuff) at the lower part. This
Thus, with a combination of improvement of operation type of blast fumace has been able to produce a cumulative
. refractory technology
management and the result of this total of 30 million tons of pig iron in the lifetime of one
research, the industry recently reached a level where many furnace (Fig.1).
blast furnaces have an operating life of more than 10 years, Many investigationsi), conducted after blowout, of the
and the cumulative quantity of pig iron tapped for the whole wear profile in the hearth revealed phenomena observed that
life of a furnace exceeds 30 million tons. deserve special notice; among these is the embrittled layer
found 300 to 500mm inward from the hot face, and local
erosion (the so-called "Elephant foot" wear pattern) often
2. Refractories for Hearths observed on the fumace bottom wall.
This type of wear, irrespective of furnace capacity, occurs
at positions to 2m below the level of the molten iron tap
The blast furnace hearth is the most important part of the hole, and the deeper this type of erosion grows in the direc-
fumace as it is constantly exposed to pig iron, and like the tion of the bottom of the furnace, the less the erosion occurs.

* Nippon Steel Corporation Ltd., 2-6-3, Ootemachi, Chiyoda-ku, Tokyo 1oo-71, Japan
[Received August 30, 1990; Accepted September 4, 1990]

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TAIKABUTSU VoL1O No.4

i ""
-Å~- - Tuyere Tuvere level

t
-. -- ,
.

13. 7oo P,,


Substance stuck
t g.
N Embrittled layer
Tap hole (molten lron) Molton pig lron t:':•x:.
-N..
st
Metal/siag/coke Tap hole
----
iolelevelT
--.----..-.----.
"i:::':'

,vv.,:
N -
.
.
.
-t-
lt-N
,

..TA':t
- :
t

d-X' Alumina bricks t;--]---


9
l .
Y-
tttt- V-!=.......L'

.et (5 steps) x'


-- -

-T'` -
'tJ---- t- -- it -
xl-,.. s

'l
J-- 11

H Carbon blo61Åqs
t6 SXNNsv,NNsN"v"Nstx"N"r::.E.kt,'.v.
NxxNx-xx""""xxNXXr'"'Ne..-v,
n Metal
(4 steps)
S..v--' ,A, .,
sNSNNNN .) sSNN-NNs-Ns
- V.V.--N- . "1.N '..J.svC.'.L.t.., "v",....
:.,Vx.. ,.'. ' 'ÅqN,V...Ns; 'v :c

-
llliiLl.llLtiliil i.S/ ::Iiili L: 'iL;l iili.1 [::; i•ii ;•i,!llPii•,.f.!,i'i'iliii',

Fig. 1. Example BF hearth wear pattern (Mizushima BF No. 4)

c] Carbon block

A 50 Micro-pore carbon block

S`iO 2Tecose/i3 tw Chamotte (fireclay brick)


:6
co 3U-
ao
.t!.. High-alumlna
20 Dlel.
oo
1. Jnint
ilO
:r,' ,' C/SiC ( Carbon SiC-C brick År
:"----e--..--.....---•••--ii w

o
1 2 3, •l 5 6 ,
lnternal furnace pressure (Atrn)

Fig. 3. Relationship between the lnternat furnace pressure


and pore dia. of molten pig iron intiltration Fig. 2. Hearth brickwork2)

The reason for this is thought to be related to the


As mentioned above, in aimost all blast furnace carbon
phenomenon that substances sticking to the central part of
the furnace bottom are caused to grow by inactivity in that blocks examined after furnace blowout, an embrittled layer
was found. There are some reports3) that chamotte applied
part and over-cooling, and thereby causing a circular flow
of pig iron at the furnace bottom.2) in the lower hearth, as well as carbon blocks, had an embrit-
tled layer. also there are reports that in blast furnaces that
Figure 2 illustrates, as a typical example, the structure
were blown out only 18 months after starting operation, the
of a blast fumace hearth that was relined in 1984. For
embrittled layer was found in the hearth carbon blocks.4)
preventing the circular flow of molten pig iron, the molten
iron basin is established as 2.5m in that structure. Refrac- ln all the examinations of carbon blocks after use, a
common trend was indicated,5) as shown below:
tories composing the bottom of the blast furnace are, from
top to bottom, chamotte brick, high-alumina, and carbon 1) Much penetration of iron from the hot face to the
material. embrittled layer was observed. The maximum amount of
iron penetration reached 40wt9o.

2-2. Damage Mechanism for Hearth Refractories 2) In many cases, ZnO was found to have accumulated
in the embrittled layer.
3) In the course of operation the hot temperature strength
Besides carbon blocks, chamotte and high-alumina bricks
are used in the hearth of a blast fumace, and they all play during heating, for carbon block in the fore portion of the

important roles. In this anicle, however, discussion will embrittled layer, becomes remarkably lowered.
mainly concentrate on the occurrence of the embrittled layer 4) The nearer to the hot surface, the more it graphitizes.
It has been calculated that, under conditions of high-pres-
in carbon blocks.
sure operation, molten iron can penetrate into carbon block

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TAIKABUTSU OVERSEAS
Vol.1O No.4

Table 1. Refractories properties

Carbon block Hlgh-alumina brick

General l ir; ;;,r rovcrJ• Gen, eral lrnproved

Bulkdensity(gr/cm3) 1.58 I.70 2.56 2.60


Compressive strength 392 639 1,138 1,224
(kg/cm2)
Porositlvt (96) Entire Ent 'i re
Apparent Apparent
porosity porosity porosity porosity
18.0 18.8 13.3 14sl
Mean pore Jr.o o.orJ 4.3 1.7
diameter (Lsm)
Molten iron Much No Much Almos{
infiitration'ik infiltration inf"tration Infiltration no infiltration

'Test was conducted at 15500C, 5kg/cm2

of the embrittled carbon block layer.


so Figure 4 shows observations of the change in carbon
block characteristics afterblast furnace blowout.8'9) the dif-
ik.

ference between the degenerated layer and the originally


laid layer can be clearly observed in the figure,
This difference is considered to take part to a great extent
in causing cracks in the interface between these layers.
Embrlttied layer
iiii'

2-3. Refractories for Hearth

Carbon blocks for the blast furnace hearth are required


2oo to have the following properties:
1) It should not be easily solved.
2) It should not easily allow foreign substances to
penetrate lt.
l oo'
3) It should have a high thermal conductivity.
4) It should be resistaRt to alkali.
5) It should have excellent volumetric stability.
o
1 The principal raw materials for carbon block previously
O 2oo 4co 6co 8oo 10co !2co 14co 16oo }8oo used for blast furnaces in Japan was anthracite, and this was
Dlstance from operating face(mm)
later replaced by metallurgical coke. In the middle of the
1960s, anthracite was again considered for use, and it has
Fig. 4. Carbon block characteristics after use5) been used up to now.iO)

Recently, however, efforts have been made to improve


the solultion resistance and the penetration resistance of
pores of up to some 1pm; examinations of carbon block has carbon block by molten pig iron. For the solutiion resis-
supported this calculated result6'7) (Fig.3), tance, the addition of A1203 to the matrix of carbon block
The mechanism of embrittlement of carbon block has not has been put in practical use.
yet been fully clarified, but it is supposed to be caused by On the other hand, studies are being conducted on ways,
any of the factors below: of filling pores with tar or similar substances, as a means of
1) Thermal stress generated by changes in temperature improving resistance to penetrate by molten iron.ii)
immiediately after blow-in or during operation. Another method for this problem, which has been put to
practical use,i2) is to add meta11ic Si, so that silicon oxide-
2) Degeneration caused by the infiltration of substances
such as iron. nitride whiskers are produced during sintering, thereby
3) A combination of the above 2 factors. micronizing pores. Figure 5 shows the extent of penetra-
Factor 3) is considered to be the most significant cause tion of pressurized molten iron when carbon block treated

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TAIKABUTSU Vol.1O No.4

in this way is immersed in pressurized molten iron. High- and strength (hardness) of the contents of the furnace vary
alumina brick employed for ceramic cups, is also being greatly. Lining materials and brickworks must be selected
improved with respect to penetration of molten iron (Table according to these conditions (Fig.6).
1). The most important damage to refractories composing
the wal1 of the blast furnace are in the upper shaft wal1
below fixed throat armor, and the lower shaft wall; the
3'. Refractories for Start and Bosh former has been considered to be affected greatly by
abrasion and the latter by alkalis and zinc. Recently it vvas
made clear that the temperature of the wall lining fluctuates
In the blast furnace, iron ore is charged at the top of the more than was previously thought, by up to 500Clmin. The
furnace, reduced and melted by gases and coke, so that the influence that thermal spalling due to such great temperature
iron is separated from the ore and gradually drops to the fluctuation has on the furnace wall is therefore significant.
bottom of the furnace. Accordingly, from the top of the Since, after the second oil crisis, heavy-oil blowing-in has
furnace to the bosh, the atmosphere, temperature, pressure, been eliminated in favor of by all-coke operation, the

Table 2. Properties of blast furnace refractories

Hlgh-density Fireclay
castable brick
refractorles

Chemlcal composition(%) Si02


Al203
g8g 2g;

Apparent porosity(ok)
gooeC x 3Hr 13 8 14O
Hot modulus of rupture(kg/cm2)
9000C 200 230
Airpermeabmtyfactor ( 80m'22:CcMm3}:i:oM
) O 03 1.4

Abrasim resistance Sand blast


test zo 60 'v 133

;-- c v vt e" ,,
-J "--tsJe g s.
tl 'el . ufl tM fi ls L.c!

v rl ""
E
. ",. vi
S ,;"ii..."wa}
"v'.b,tm
.i." - sy Jn
•es•ee,/xi,ee,,is'eies'
Sgms"tsme,.,.
S,.ew1eeg".',tfu'l'si$`

tYweeWest"t,.
,.a s."
vgl,gE"'l,si,g//.Itfw",$.
$.er3"{'"./l,,,.tt,x.,s

. . ,'-
.g,g-,'sl=,eipt!
iS.'teet-egeff

za,kllss, t.`
.f?-- 'l` ,et is•'.,.gX.i
'Jt "va-fiA"iticvttifC lc .i')-

gM\jll•llll)"'tg..
.z'..itvetsczzS"S:.g.sg "! '..$tl i t-geEt9ptr cdic..

,e•k;ww,x'tts/,/k/'/y/Y.gigl"'"
g" sekx'$.-W,lg-

tuest.'tug:'fietn'ttre'""

f3rf;s's.m- :,L"eV" ."".tl


twTi=c.",.eeeest sgv ie.-eeeeas.iee #'" as ,i,
"gtSgfottiS•"g'.
ss
g i ee
ggee ., ,:ee,;•N. .Eg.s,l. f".e, =j $- i"
geeeWE'.mmael"" fitwtl- ee- -ewwt E ree= - 12't/S.ltrk,eg".",•,,,//,llllll/S,.,.....,$ss,,."./k,\i,',Iig'iglSll"/k'SlsEsc,.i.i'ss'g.'A-li,"i"g'li"i,g'l,'/S':.i'"d#"ll:"""vrier/eg"/S'`'/agg.".t-..'lfg
tr=,

x
t."ll

gl..lj.lg"i.'ee',s.S/I'i,'ge'g..,/ii,/1..iii.i.iwa/iLl,i,tme.atsi."g/./:'me'"ig'S"ma"-"re',.".l,,}ssllitt".fS'ee"l.,$,;,ll'.ss$'#X,,gge1,-,...

v veutC . -.st#
i.. "e ." diU" != t:, :.i".{.
.a s gt,,,'
,ss'c"Li/ptsl'ee '
lrlgdv
! fi Hp vr
M "ee J
eenventledal malerw ' imptovtiet lmatetial
.

Fig. 5. Molten pig ion infiltration compared, 5kfg/cm, 2 lssoOC

236
TAIKABUTSU OVERSEAS Vol.10 No.4

peripheral gas flow inside the furnace has relatively in- 3-1. Upper Shaft Refractories
.creased. This also has a great influence on damage to the
furnace wall refractories. Conventionally low porosity chamotte bricks were laid
in the upper part of the blast furnace shaft. In the past, when

Table 3. Properties of test bricks (Blast furnace, Muroran Works, Nippon Steel Corporation)8)

Apparent Bulk Apparent Compressive Thermal Chemical


specific density porosity strength conductMty composition
gravity (gr/cm3) (%År (Kg!cm2) (Kcallm • hoCÅr

Fireclay briclÅq 2.67 2.27 15.1 5oo 1.5 AI203


gg ge.

High-alumina 3,19 2.48 14.2 800 2.0 Al203


brick
Pure alumina 3.85 3.14 11.5 1,400 3.2 -A12O3 9 g o/o
brick
SiC-C brick 2.35 1.99 15.5 450 2.0 c 86,2,
lg
go

sic
Silicate 3.12 2.63 15.8 817 13.5 sic
bonded
SiC brick
Silicon nitride 3.1O 2.65 14.6 1,500 14.1
sic
sic
9g gg
oo

bonded
SiC brick Si3N4
i 22 %

TUyere
Temperature Furnacernarerlalswear
ll
withlnReaction
fum.'a'cewithlnfurnaceCause Mechanlsm

m/-IN.g 2
R
nE
200ÅéCharpedrops
lndirectcause
Abraslon

t' Slkll'Sl:iS:t:'.:'x::: 500lnd[rectcause


3 Zincdeposltlng Expans1on
800Dlrect
Coke deoxldliatlon
.s.".-";. DeoxidlzationofA]kallgasphase
lron ore År'i.t:.t:.'}1'.:':}.

lronoxldebyreactlon Expanslon,Cracklng,
L!me stone 22D C02 jncreaseinpofes
'fi`';""w' Carbonoxldatlon lowerlngofstrength
•h.•..•"i•31.,}
OfC02
-g[
Watergasrececllon'
Soft/ ened charge k/#.}ff,".11 tto
1,OOOCarbonatedCa:bondeposlting
oco
dissolution
Carbonaddltlonto
g.poagylroB
Substaricvs stuck 1,400CompletionoforeAIkalislag
reductlon Softeningmeltlng
Moltc.n plg lrbn "ifanganese
o
slnlÅqlng Eo
{,E
reductlon
$iagtormatlonSIag
Furnace core
\. 1"
):hr.',"tlt i
O Mel:•lng&slnking
2,500C02,H2formatlon
TuyprB byhotblast
e
Melted.. slag CaSfornallon
E-;".•:.t
Tap hole
f:-b
.r".
c= o2.

1,500Moltenpigiron reaction
Sdutlonlnro(Carbon
moltenlronbrlck)
Mo1tenpig iro rt
..m. "-"'
:.':' j
M oa
Epta Highternperature Sottenlngand(Clay
meltlngbrlck)

Fig. 6. Blast furnace temperature distribution and reaction inside furnaoei3)

237
TAIKABUTSU OVERSEAS Vol.10 No.4

the designed life of a blast furnace was 5 to 6 years, there There were examples in other countries of using this
was no big problem in using this kind of refractory material method of castable lining repair by gunning work in inter-
in that part. mediate blast furnace repair. As a Japanese examples, in
When, as a result of improvements in the lower part of the 5th relining (not including repair of the furnace hearth)
the furnace shaft and the hearth, extension of the life of the of the smal1 blast furnace (157mm3) of Sanei lron Works,

blast furnace was attempted, it became more necessary to done in 1962, the furnace shaft was repaired using castable
refractories.i5)
reduce damage to the upper shaft. Despite the increased
damage caused to the upper shaft due to al1-coke operation, Blast furnace No.2, Fukuyama Works, NKK Corporation
it was not easy. to control peripheral gas flow through con- that was blown-in 1985, has been operating since its upper
trolled charge distribution because of a decrease in the shaft was relined with high-strength castable lining over a
ore/coke ratio. Therefore, to prevent damage in the 6-meter area. The characteristics of the castable refractories
ore/coke charged mixture layer, it became increasingly im- are shown in Table 2i6,i7)
portant to maintain the profile of this part satisfactorily.i3)

Several measures were taken for this purpose, Sil-


limanite bricks, that have excellent spalling resistance and
wear resistance was adopted. Gunning repair using castable 5OO
"lg
refractories were introduced. ln the latter part of furnace
life, a process for repairing the profile of the top of the 4, oo

fumace by using pre-cast castable panels or water-cooled


panels .has been put into practical use.
3oo
Another technique of upper shaft repair that deserves
mention is using a lining with monolithic refractories.
2oo

Table 4. Temperature fluctuations ef hot tace of blast furnace


lining brick8) (Measured at BF No.3, Kimitsu Works, Nippon 1oo
Steel Corporation)

ill gi-
1si;c o
'/6.. '/s i"
211711981 -
3110!1981

Normal temperarure eC 100 - 2oo


Temperature elevation rate eClmln 13 - 55
Temperature lowerlng rate ec/mln O,3 '- t
Temperature varlatlon range eC too --12oo
How often temperature varled No, of 3
at rate exceedlng soTb!mln tlmes
Fig. 7. Remaining thickness of test bricks

Lower shaft (312mm)


g 6oo Furnace belty (312mm)
No.4 BF

/11i

soo N N•. trevbeO Lower shaft (468mm)

4oo ol 'A-"-A Furnace belly (468mm)


Ne
3oo 9; : •'s
Ax. A...A
NO."' N-....i:'":A
2oo :====U
o N
"e' Ae - e. ee rn en .- .. -ea-A .- e. .- :.JL. aO"n
1OO

a 2 3 4 g e 7 s g .lo na
Year elapsed after blow-in

Fig. 8. Brick damage from wear in BFs Nos.3 & 4, Kimitsu Works, Nippon Steel Corporation

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TAIKABUTSU OVERSEAS
Vol.1O No.4

N4 briclÅq

,
,it'-
.:--xt..-.-"i"--

iTlii1:ltl

k---

1IITIt1

Fig. 9. Copper cooling plate i9) --

3-2. Refractories for Lower Shaft and Bosh

The refractories used for lining the bosh shaft in the Fig.10. New type stave2)
1950s were generally super-duty chamotte and bricks. it is
clear that damage to refractories in this part will be caused
by the infiltration of alkali, carbon and zinc. Improvement
laid in the lower shaft and the be11y between the blast fur-
and development of refractory materials have proceeded
nace No.3 (where the cooling plate is inserted at 463mm
with this in mind;' combined with efforts in devising
pitch) and No.4 (cooling plate insertion pitch, 313mm) at
methods for cooling and supporting refractories and finding
the Kimitsu Works, Nippon Steel Corporation. The figure
measures to counter stress to the structure such as expansion
gives a good indication that, in a case where the cooling
joints, these activities have accomplished great results.
plate insertion pitches have been set at around 300mm, the
1) Cooling plate type blast furnace:
cooling plates have a greatly increased effect on cooling the
Unlike stave-type blast furnaces, furnaces which use
refractory lining in these parts, thus contributing greatly to
cooling plates have refractories to directly protect the steel decrease in the lining damage and wear speed.2)
shell. Accordingly, the life of the blast furnace depends
Since consideration of the cooling plate pitch is also im-
greatly on the life of the refractory lining.
portant for supponing more firmly the inner lining brick,
Examination of refractory materials have been done on
the insertion pitch should be decided with regard to the
many occasions. A typical example was the test of many
directions of height and circumference.
kinds of bricks conducted in the blast furnace No.3,
2) Stave-type blast furnace:
Muroran Works, Nippon Steel Corporation in 1974.
Two sorts of refractories are used for parts undergoing
The characteristics of the refractories employed in this
high thermal load in the stave-type blast furnace; inner
blast furnace are indicated in Table 3, and the residual thick-
lining materials and stave-embeddingbricks.
ness after blowout are shown in Fig.7. As shown by these
The basic concept of the inner lining material is chemi-
values silicon-nitride-bonded SiC brick showed very
favorable results.i8'8) This is the world's first example of cally similar to that of the refractory materials used in the
cooling-plate blast furnace;
SiC bricks being used in the lining of a blast furnace shaft.
A1203, graphite-silicon carbide, silicon carbide, and so
This favorable result has had a great influence on selection
on are adopted in parts which experience high thermal load.
of shaft lining material.
Nevertheless, compared with those used in the cooling
For this reason the lining material of the bosh in the lower
plate-type blast furnace, the inner lining refractory substan-
shaft of the cooling plate type blast furnace is changing from
ces used in the stave-type BF differ considerably in service
high-alumina, graphite-silicon carbide, etc. towards silicon
life.
carbide refractories.
The major cause for this variation in service life between
Apart from refractory material qualities, the cooling
refractories in stave-type BFs is the difference in inner-
plate, needless to say, plays an important part in cooling and
lining brick-sustaining ability between the two types of BFs.
holding the refractory brick. The insertion pitch of the cool-
According to examples of actual measurement, the tempera-
ing plate has a great influence on the life of the refractory
ture of the hot face of the shaft lining normally fluctuates
lining.
from 1oo to 2ooOC, but it often rises at the rate of 13 to
Figure 8 gives a comparison of the wear rate of brick
55eClmin, reaching a maximum 1200eC, and it has been

239
TAIKABUTSU OVERSEAS Vol.10No.4

observed that as often as 3 times in 20 days, there occur are all required to extend the life of blast furnace lining,
rapid changes as high as 500Clmin in the temperature of the Through a consolidated employment of the technologies
lining face8) (Table 4). Presumably these temperature fluc- that have been improved so far, it can certainly be said that
tuations are caused by rapid coming off of the substances Japan's blast furnaces have reached a level such that their
stuck on the inner lining face and also by rapid changes in life is expected to be 12 to 15 years;
gas flow. In view of this and from analyses27-30) of the Tasks for the future in BF lining technology are a further
thermal stresses on the lining, it was concluded that cracks improvement of lining damage diagnosis technology as well
can certainly be caused on presently-used refractories (ex- as improvement and development of repair technology.
cluding graphite-silicon carbide, etc.). Accordingly, unlike
in the cooling plate blast fumace, presumably cracks caused References:
in this type of blast furnace directly lead to failing of the
lining. 1) T. Ochiai, M. Ikeda, S. Fujiwara, S. Tamura and H. Imawaka, Tetsu-
Two very effective measures for reinforcing the inner to-Hagane 65,S541 (1979)
lining sustaining ability in the stave-type blast furnace have 2) T. Yamamoto, 116th & 117 Nishiyama Memorial Lectures (1987)
been attempted. One is to establish, as illustrated in Fig.9, 3) M. lkeda, M. Nagahara, T. Horio, T. Mitsuyasu, M. Nose and M.
a cooling plate between one stave and another, Nomura, Tetsu-to-Hagane 70, S740 (1984)
The other measure, as shown in Fig.10, is to hold the 4) M. lkeda, S. Fujiwara, K. Ohkawa, M. Nakai, M. Saito and Y.
brick for foreface lining with cast iron when making the Arao, Tetsu-to-Hagane 68, S675 (1982)
stave. Advantages of the latter measure are an increased 5) T. Horio, M. lkeda, T. Hagiwara, S. Fujiwara and K. Aoyama,
lining sustaining ability and a possibility of shorter blast Taikabutsu Overseas 2 [1] 3- 14 (1981)
furnace major repair work period. 6) K. Hiragushi, The 3rd Refractories Technology Course (1975)
All of these measures greatly improve the sustaining 7) K. Hiragushi, Y. Hiwatari and K. Aoyama, Tetsu-to-Hagane 62, S30
ability for the foreface brick in the conventional stave-type (1976)
blast furnace which has been the principal weakness of this 8) T. Horio, M. lkeda, K. Hiragushi, S. Fujiwara and K. Aoyama,
brick. Any of these measures will exhibit good results in Taikabutsu Overseas 2 [1] 3 -14 (1981)
furnaces where it is practically adopted. 9) S. Tamura, Tetsu-to-Hagane 68 [15] 3(1982)
When the stave was first introduced into the blast fur- 10) K. Hiragushi, Refractory Materials 119, 1 -35 (1974)
nace, chamotte brick was used for embedding the stave 11) T. Suzuki, S. Ohhara and A. Mizuguchi, Tetsu-to-Hagane 65, S542
body. Now improved materials are mainly used in the part (1979)
undergoing high therrnal load. Bricks of pure A1203, 12) T. Ochiai, M. Ikeda, S. Fujiwara and S. Tamura, Tetsu-to-Hagane
BA1203-SiC, and SiC are in use domestically and overseas. 67, S59 (1981)
With such improvement of the nature of brick mate.rial for 13) H. Ohniwa and K. Hiragushi, Seitetsu Kenkyu, 278, 32 (1974)
stave embedding and improvement of the cooling functions 14) Y. Murai and S. Mochizuki, AIME lron Making Conf. (1985)
of the stave itself, the life of staves has been greatly ex- 15) T. Hayashi, Tetsu-to-Hagane 56, 1089- 1117 (1970)
tended. 16) M. Toda, K. Ichikawa, Y. Hamazaki, E Hatakeda, H. Katayama and
A. Maki, Taikabutsu 36 [8]23-26 (1984)
17) H. Katayama, A. Maki, N. Murakami, M. Toda and Yukio Ozaki,
4. Conclusion Taikabutsu 37 [3] 33 - 37 (1985)
18) H. Hiragushi and T. Nagai, Iron and Steel Eng. 55 [6] 47-53
(1978).
ln this article, the recent technological trend of refrac- 19) T. Morimoto M. Yoshimoto, T. Matsumoto and M. Ando, AIME
tories are outlined, mainly on the nature of materials used Ironmaking Conf. (l982)
at the furnace hearth, shaft, and bosh. Needless to say, the
improvement of the nature of refractory materials employed
in blast furnace operation, as well as furnace repair, detec-
tion of damages of the furnace refractory lining, and so on,

240

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