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F
deposited overlay is used.
low-accelerated corrosion (FAC), also Temperature has a pronounced effect on the FAC
called erosion/corrosion, and cavitation are wear rate (Fig 4) and when a system is inspected,
significant and costly damage mechanisms components in the 250-400F range get a prior-
common to all types of utility and indus- ity. Flow velocity (Fig 5) has a strong effect, which
trial steam cycles. There has been an increased makes wet steam systems very susceptible to FAC.
emphasis on correcting these problems because of Reason is that the velocity of the steam usually is
recent fatal accidents and costly material damage. much higher than that of the water.
In combined-cycle (CC) plants, thinning of pipe Water chemistry effects on FAC often are not
and damage to system components made of carbon well interpreted. The pH of feedwater and steam
and low-alloy steel typically occur in the feedwater droplets must be kept above a certain threshold,
and wet-steam sections of the cycle. Experts esti- which depends on the pH agent used (Fig 6) and on
mate that more than half of all CC units have FAC temperature. For ammonia and amines, their effect
in the heat-recovery steam generator (HRSG) and diminishes with temperature. For feedwater treat-
elsewhere. Sufficient knowledge exists to predict ment with ammonia, a room-temperature pH above
and prevent these two types of damage. However, 9.5 is desirable.
designers and plant operating staffs must be proac- Oxygen actually is good for preventing FAC.
tive to avoid it. Experience indicates that 5 ppb of oxygen in feed-
FAC is a mass-transfer process in which the pro- water can practically stop FAC, while excessive
tective oxide (mostly magnetite) is removed from the concentration of oxygen scavengers accelerates it.
steel surface by flowing water. Material wear rate In most CC units that do not have copper-alloy tub-
depends on (1) steel composition, temperature, flow ing, oxygen concentrations can be as high as 20 ppb
velocity and turbulence, (2) water and water-droplet without causing any problems.
kc = 1 kc = 1 kc = 1 kc = 0.75
1. Material wear rate depends on many variables— kc = 0.15 kc = 0.15 kc = 0.16 kc = 0.04
including steel composition, oxygen concentration,
flow velocity, temperature, etc (above)
2. Component shape impacts FAC, (right) with higher
numbers in chart above signifying a stronger influence kc = 0.16 to 0.24
Ni-Cr-Mo-V steel
0.3
Ni-Cu-Mo-Nb steel
0.1
0 10 50 150 200 122 212 302 392 482
Specific material wear rate, µg/cm2-hr Temperature, F
3. Wear rate of various materials from erosion/corro- 4. Temperature effect on erosion/corrosion is great-
sion in 356F water at 580 psig moving at 65.6 ft/sec est in 266-366F range. Data are for neutral 580-psig
is shown for three typical pH/oxygen combinations water with an oxygen content of less than 40 µg/kg
flowing at 115 ft/sec. Exposure time is 200 hr
control valves. In these loca- rial loss rate exponentially with Carbon steel:
tions, FAC could be combined flow velocity. Data are for neutral 100
0 psig, 167F,
with cavitation. 580-psig/356F water with an oxy- 5.25 ft/sec
50
gen content of less than 5 µg/kg. 1Cr-½Mo
Downstream of flowmeters. (A213 Gr T12):
The piping immediately down- Exposure time is 200 hr (above) 10 580 psig,
stream of flowmeters, orifices, 5 248F, 115 ft/sec
and other restrictions has been
a source of problems because of 6. Decreasing pH increases mate- ½Mo (A161 Gr T1):
1
the increase in local velocity and rial wear, particularly below 9.2 580 psig, 248F,
0.5
local turbulence, and the suscep- (above right) 115 ft/sec
tibility to cavitation.
Downstream of control 0.1
valves. There have been a large 7. Oxygen content above 100 µg/
0 100 200 300 400 500
number of reported instances kg gives maximum steel protection Oxygen content, µg/kg
of FAC degradation, including in neutral water (right)
COMBINED CYCLE JOURNAL, Second Quarter 2004 3
FLOW-ACCELERATED CORROSION
Steam drum:
FAC, high carryover
FAC, cavitation
All: Layup corrosion,
weld corrosion cracking Stack
Internal insulation FAC
and lagging
Outlet duct
Inlet ducts
Expansion joint
Economizer:
Downcomer: FAC, pitting, corrosion
FAC, corrosion
Manway Evaporator:
Superheater: low-cycle fatigue,
stress corrosion pitting, hydrogen damage
Integral structural steel cracking, exfoliation, creep,
Expansion joint low-cycle fatigue
pvc
Flow
Inlet (p1) Outlet (p2)
T
here’s little reason for a plant manager to be fied in the adjacent text. Your evaluation should
surprised that his or her plant is experiencing consider the combined effects of component
FAC and/or cavitation damage. The majority of geometry, flow velocity, water and steam proper-
combined-cycle (CC) facilities were designed and ties, material composition, water chemistry, and
built to meet the needs of the competitive genera- operating experience.
tion market. The large number of plants ordered Consider these objectives for your evaluation:
in the 1999-2002 timeframe stretched the person- ■ Find and select components to be inspected.
nel and material resources of the entire industry. ■ Interpret NDE results.
Designs and construction work often did not get ■ Identify root causes of wall thinning.
the rigorous review and oversight that had become ■ Determine inspection interval and safety
a tradition in the generation industry. Mistakes were margin.
made. ■ Determine effects on cycle iron transport.
Also, many asset owners thought CC plants ■ Recommend engineering solutions.
so simple—typically, “just a matter of hooking up Project tasks to consider include:
modules on a slab of concrete and connecting gas ■ Preliminary assessment (drawings, flow
and electric lines”—that the detailed procedures velocities, cycle design, experience, leaks).
used for coal-fired and nuclear plants didn’t apply. ■ Component details and actual installation
Another mistake, as plant managers know well. (walkdown, steel composition, history).
One thing for certain, the industry has a wealth ■ Final system and/or component description
of knowledge of FAC and cavitation as the many and operating and inspection/maintenance
references at the end of this article attest. This history.
information offers a competitive advantage to the ■ Water-treatment history and local chemistry.
plant manger who takes the time to do the appro- ■ Computer modeling, calculation of erosion/
priate eavaluations. It helps identify areas where corrosion rates, contributions of individual
FAC and cavitation already exist and where they are effects.
likely to occur, what corrective action is warranted, ■ Monitor cavitation noises and the rate of wall-
and what type of monitoring program will enable thinning.
you to avoid forced outages and the possibility of Finally, document your conclusions and recom-
life-threatening damage. mendations in a formal report for executive review
Assessment of the propensity of individual and implement engineering solutions approved by
systems and components to FAC and cavitation the asset owner. Regular follow-up inspections of
begins with a comprehensive plant walkdown pay- susceptible systems and components are recom-
ing particular attention of areas of attack identi- mended.
flow region immediately downstream of the orifice, Cavitation, thoroughly researched in the 1960s
where velocity is highest, the static pressure drops and 1970s, is a damage mechanism well known in
below the vapor pressure and steam bubbles form. the marine industry and among pump manufactur-
The change in static pressure, Δpstat, can be mea- ers. In steam power systems, it has been mostly a
sured or calculated from the measured or estimated problem with valves and boiler feed pumps which
maximum velocity in individual components using can be damaged within a few minutes of operation
the relationship, Δpstat = 0.5 ρ V2, here ρ is the when deprived of proper suction head. Such head
water density and V is the local flow velocity. This normally is provided by the deaerator, typically
flow-velocity effect is also called dynamic pressure located more than 30 ft above the pump. Problems
or velocity head. in the 1990s at nuclear units prompted EPRI to
294 70
10. Relationship between
Change in static pressure, psi
Brass
Rate of weight loss, mg/hr
HRSG USERS
Research Institute, November 1993
9. “Guidelines for Controlling Flow-Accelerated Corrosion in Fossil
Plants,” TR-108859, Electric Power Research Institute, June
1998