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FLOW-ACCELERATED CORROSION

pH, and (3) the concentrations of both oxygen and

FAC and cavitation:


oxygen scavenger. These complex relationships are
identified in Fig 1. Fig 2 shows the impact of piping
and component geometry. Most of the above factors
Identification, have strong, exponential effects on the material
wear rate, as Figs 3 thorough 7 indicate.
assessment, The FAC problem is most pronounced in carbon
steels. In these materials, even small concentra-
monitoring, tions of chromium, molybdenum, and copper can
improve FAC resistance. A survey of 38 heats of car-

prevention bon steel found that, depending on the scrap com-


position, there could be up to 0.3% Cr, which may
improve FAC resistance by up to 100-fold. Where
FAC problems cannot be resolved by changing
By Dr Otakar Jonas, PE, Jonas Inc water chemistry, carbon steels often are replaced
by low-alloy steels, such as P11 and P22—or a weld-

F
deposited overlay is used.
low-accelerated corrosion (FAC), also Temperature has a pronounced effect on the FAC
called erosion/corrosion, and cavitation are wear rate (Fig 4) and when a system is inspected,
significant and costly damage mechanisms components in the 250-400F range get a prior-
common to all types of utility and indus- ity. Flow velocity (Fig 5) has a strong effect, which
trial steam cycles. There has been an increased makes wet steam systems very susceptible to FAC.
emphasis on correcting these problems because of Reason is that the velocity of the steam usually is
recent fatal accidents and costly material damage. much higher than that of the water.
In combined-cycle (CC) plants, thinning of pipe Water chemistry effects on FAC often are not
and damage to system components made of carbon well interpreted. The pH of feedwater and steam
and low-alloy steel typically occur in the feedwater droplets must be kept above a certain threshold,
and wet-steam sections of the cycle. Experts esti- which depends on the pH agent used (Fig 6) and on
mate that more than half of all CC units have FAC temperature. For ammonia and amines, their effect
in the heat-recovery steam generator (HRSG) and diminishes with temperature. For feedwater treat-
elsewhere. Sufficient knowledge exists to predict ment with ammonia, a room-temperature pH above
and prevent these two types of damage. However, 9.5 is desirable.
designers and plant operating staffs must be proac- Oxygen actually is good for preventing FAC.
tive to avoid it. Experience indicates that 5 ppb of oxygen in feed-
FAC is a mass-transfer process in which the pro- water can practically stop FAC, while excessive
tective oxide (mostly magnetite) is removed from the concentration of oxygen scavengers accelerates it.
steel surface by flowing water. Material wear rate In most CC units that do not have copper-alloy tub-
depends on (1) steel composition, temperature, flow ing, oxygen concentrations can be as high as 20 ppb
velocity and turbulence, (2) water and water-droplet without causing any problems.

TL = F(x), FG, FT, FC, FR

kc = 1 kc = 1 kc = 1 kc = 0.75

Steel composition factor


Water treatment factor (pH, etc)
Temperature dependence factor kc = 0.6 kc = 0.52 kc = 0.3 kc = 0.23
Geometry factor
Mass-transfer dependence function
Thickness loss rate

1. Material wear rate depends on many variables— kc = 0.15 kc = 0.15 kc = 0.16 kc = 0.04
including steel composition, oxygen concentration,
flow velocity, temperature, etc (above)
2. Component shape impacts FAC, (right) with higher
numbers in chart above signifying a stronger influence kc = 0.16 to 0.24

COMBINED CYCLE JOURNAL, Second Quarter 2004 1


FLOW-ACCELERATED CORROSION
3000
½Mo steel1 Carbon steel
1000
Carbon steel2 ½Mo

Specific material wear rate, µg/cm2-hr


(A161 Gr T1)
Carbon steel2 + 300
500 µm Metco 33
Carbon steel2 Ni-Cu-Mo-Nb
+ 500 µm nickel 100
pH O2 content
18Cr stainless steel 7 500 µg/kg
9.5 <5 µg/kg 30
1Cr-½Mo
13Cr stainless steel 7 <5 µg/kg (A213 Gr T12)
ASTM designations 10
2¼Cr-1Mo steel3 1
A161 Gr T1
2
A414 Gr B
3 2¼Cr-Mo (A213 Gr T22)
1Cr-½Mo steel4 3
A213 Gr T22
4
A213 Gr T12
Cr-Mo-Ni-V steel 1

Ni-Cr-Mo-V steel
0.3
Ni-Cu-Mo-Nb steel
0.1
0 10 50 150 200 122 212 302 392 482
Specific material wear rate, µg/cm2-hr Temperature, F
3. Wear rate of various materials from erosion/corro- 4. Temperature effect on erosion/corrosion is great-
sion in 356F water at 580 psig moving at 65.6 ft/sec est in 266-366F range. Data are for neutral 580-psig
is shown for three typical pH/oxygen combinations water with an oxygen content of less than 40 µg/kg
flowing at 115 ft/sec. Exposure time is 200 hr

high turbulence, such as in the transitions from


FAC experience vertical generating tubes to headers and drums; (2)
Though FAC control programs have been imple- economizers and l-p drum circuits which often oper-
mented in all US nuclear plants, and in many fos- ate in the peak temperature range, and (3) down-
sil-fired utility and industrial plants, major dam- comers, particularly the lower-header areas where
age still occurs, as several references listed at the FAC can be combined with cavitation.
end of this article attest. This is particularly true at Use of sodium phosphate boiler-water treatment
CC units, as noted earlier, generally for one or more can prevent FAC in HRSGs. However, in CC
of the following reasons: designs where the l-p boiler serves as a heater for
■ Limited experience in the design, construction, the intermediate-pressure (i-p) and high-pressure
and operation of CC plants by many OEMs, archi- (h-p) boilers, it cannot be used. Reason: Phosphate
tect/engineers, and owner/operators. would concentrate in the i-p and h-p boilers and
■ Imperfect technical tools—that is, software—for cause other problems.
quantifying the effects of temperature, oxygen scav- Feedwater piping. Most frequently, FAC dam-
engers, cavitation, and water chemistry on FAC. age is found in feedwater piping with the piping-
■ Misrepresentation of water-chemistry his- component geometry effect following the classifica-
tory and material compositions, leading to gross tion index shown in Fig 2. There have been at least
errors in FAC assessment. three fatal accidents caused by ruptures of thinned
Any carbon- or low-alloy-steel component or pip- pipes, none reported in combined cycles.
ing system at a CC plant is a candidate for FAC. Deaerators. FAC thinning of deaerator piping,
These include: partitions, and liners, and of the deaerating vessel
■ Single-phase systems—HRSG economizers, itself in the water outlet and steam inlet areas, are
headers, drum liners, boiler tubes, and feedwa- experienced occasionally.
ter pipes in drums; condensate/feedwater; aux- Condensers. Exhaust steam leaving the l-p
iliary feedwater, heater, and other drains; pump turbine can contain from 5 to 10% moisture and the
glands and recirculation lines. wet-steam velocity at the exit of the last row blades
■ Two-phase systems—low-pressure (l-p) tur- is hundreds of feet per second, an ideal environ-
bine wet-steam extraction sections and pipes, ment for FAC. Also, the moisture-droplet pH often
glands, blade rings, casing, rotors, and disks; is suppressed. There have been many cases of con-
flashing lines to the condenser (miscellaneous denser-support-structure FAC, and the iron oxides
drains); feedwater-heater vents, shells, and sup- produced by this process are a major impurity in
port plates; feedwater heaters; HRSG moisture condensate.
separators; condenser shell and structure. Return condensate from various processes often
is contaminated with organic and inorganic impuri-
ties and carbon dioxide, which reduces its pH and
Where to look for FAC increases the likelihood of FAC. To avoid problems,
HRSGs. Typical locations of FAC damage in make provision for automatic dumping of bad conden-
HRSGs is shown in Fig 8. It occurs in (1) areas of sate or for condensate purification by ion exchange.
2 COMBINED CYCLE JOURNAL, Second Quarter 2004
FLOW-ACCELERATED CORROSION
Feedwater heaters and other heat exchangers. some significant failures, at locations downstream of
Tubes: Carbon-steel tube bundles, particularly the control valves.
tube inlets, are among the components most vul- Thermowells, sampling nozzles, and injec-
nerable to FAC. Such tubes typically are designed tion quills. These obstacles to flow can produce
with the minimum wall thickness necessary to sup- “vortex shedding” with locally high velocities lead-
port the mechanical loads because a thinner wall ing to small areas of pipe thinning caused by FAC
promotes more efficient heat transfer. Thus even or cavitation. Pipe-wall thickness should be mea-
a small reduction in wall thickness caused by cor- sured starting from these obstacles to about three
rosion can result in failure. FAC can occur on both feet downstream.
interior and exterior tube surfaces.
On the steam side of feedwater heaters, FAC
attack depends significantly on the design and the How to control FAC
moisture content of the steam. Keep in mind that An effective FAC control program begins with an
the actual moisture content of the steam extracted assessment of the propensity of different plant
from the turbine can differ from the theoretical systems and components to FAC, and also includes
moisture level because of drainage and other condi- the use of available software with water and
tions that are specific to each turbine. steam-chemistry corrections and periodic inspec-
Vessel: Thinning of the feedwater-heater pres- tions. Monitoring of iron concentration around the
sure vessel occurs mainly at the steam and drain steam cycle also is useful; elevated concentrations
nozzles and where the flow of wet steam turns. may indicate ongoing damage in a specific subsys-
This thinning is caused by direct impingement of tem.
the jet or by the deflected jet after it has struck a Inspection and NDT. After conducting a theo-
poorly designed impingement plate. Impingement retical evaluation of your CC unit’s Rankine cycle
of steam moisture has locally eroded feedwater for its propensity to FAC and cavitation attack,
heater shells almost to perforation in several fos- select several of the most susceptible components
sil-fired units. for inspection. The nondestructive examination
Internals: Feedwater heaters often contain parti- (NDE) methods typically used include ultrasonic
tioned-off areas which serve a specialized heat-trans- wall-thickness measurement and radiography of
fer purpose. These “boxes” cool the exiting drain flow small sections of equipment and piping systems
or desuperheat the entering steam, and are subject with geometries that can cause turbulence. Inspec-
to the same damage mechanism
as the vessel. In addition, when 5000 1000
500 ½Mo (A161 Gr T1)
Specific material wear rate, µg/cm2-hr

there are leaks through a box


Specific material wear rate, µg/cm2-hr

580 psig, 1Cr-½Mo


wall, the secondary flows cre- 1000 1) (A213 Gr T12)
l G rT 356F,
ated can cause rapid damage. In 500 stee 1 61 100 128 ft/sec,
drain cooling boxes, damage can n (A 50 <5 µg O2/kg
bo Mo
ar ½
occur even without leaks if there C b
is improper control of the conden- 100 o-N
50 C u-M 10
sate level. Ni- 1 2 ) 5 Carbon steel
T
Heater drains. Major prob- M o (A213 Gr 0 psig, 167F,
1Cr-½ 5.25 ft/sec,
lem areas include the drain 10 1 20 µg O2/kg
lines below the feedwater heat- )
5 2¼Cr-Mo (A213 Gr T22 0.5
ers. They often experience prob-
lems with level control valves. 0.1
1
However, even without valve
0.5
problems, these lines frequently 32.8 65.6 98.4 131.2 6 7 8 9 10 11
experience FAC because the liq- Flow velocity, ft/sec pH
uid is near saturation conditions 1000
and it may flash across the level 5. Flowing water increases mate- 500
Specific material wear rate, µg/cm2-hr

control valves. In these loca- rial loss rate exponentially with Carbon steel:
tions, FAC could be combined flow velocity. Data are for neutral 100
0 psig, 167F,
with cavitation. 580-psig/356F water with an oxy- 5.25 ft/sec
50
gen content of less than 5 µg/kg. 1Cr-½Mo
Downstream of flowmeters. (A213 Gr T12):
The piping immediately down- Exposure time is 200 hr (above) 10 580 psig,
stream of flowmeters, orifices, 5 248F, 115 ft/sec
and other restrictions has been
a source of problems because of 6. Decreasing pH increases mate- ½Mo (A161 Gr T1):
1
the increase in local velocity and rial wear, particularly below 9.2 580 psig, 248F,
0.5
local turbulence, and the suscep- (above right) 115 ft/sec
tibility to cavitation.
Downstream of control 0.1
valves. There have been a large 7. Oxygen content above 100 µg/
0 100 200 300 400 500
number of reported instances kg gives maximum steel protection Oxygen content, µg/kg
of FAC degradation, including in neutral water (right)
COMBINED CYCLE JOURNAL, Second Quarter 2004 3
FLOW-ACCELERATED CORROSION
Steam drum:
FAC, high carryover
FAC, cavitation
All: Layup corrosion,
weld corrosion cracking Stack
Internal insulation FAC
and lagging
Outlet duct

Inlet ducts

Expansion joint

Economizer:
Downcomer: FAC, pitting, corrosion
FAC, corrosion
Manway Evaporator:
Superheater: low-cycle fatigue,
stress corrosion pitting, hydrogen damage
Integral structural steel cracking, exfoliation, creep,
Expansion joint low-cycle fatigue
pvc
Flow
Inlet (p1) Outlet (p2)

8. Typical locations of FAC and other types of damage found


in HRSGs reveal that problems generally occur in regions of
p1 Orifice Vena contracta
boiler that experience high turbulence (above)
p2

9. Sharp reduction in static pressure causes the production Static Vapor


of vapor bubbles which translates to cavitation attack in com- pressure pressure (pv)
ponents that experience a high pressure drop (right) pvc

tion grids have been developed to facilitate the


ultrasonic wall-thickness measurements of typical
Cavitation
geometrical elements. Often neglected are piping Cavitation is a repeated generation and collapse of
areas downstream of flowmeters, thermowells, and bubbles (or cavities) in a liquid because of local stat-
injection quills, where both FAC and cavitation can ic-pressure fluctuations, usually caused by changes
be active. Keep in mind that vortices generated by in flow velocity. If the pressure of a flowing liquid
the flow obstruction can travel for many feet. decreases to below its vapor pressure—for example,
Many components can be inspected during oper- because of significant increases to the local flow
ation using x-ray techniques. However, if there is velocity—then vapor bubbles are nucleated. The
an urgency for safety or other reasons to verify that bubbles are transported downstream from the flow
FAC and/or cavitation damage is not of immediate disturbance, and when they reach a region of higher
concern, and system shutdown is not possible, a pressure, they collapse suddenly and may erode any
successful hydro test of at least 50% overpressure solid material in their vicinity.
offers sufficient proof. The phenomenon is predominantly mechanical
Software solutions. At least three software in nature, but corrosive environments do accelerate
packages are available for assessment of wall thin- the damage. Shock-wave emission and jet forma-
ning caused by FAC. These have been developed by tion caused by the collapse of individual cavities are
the Electric Power Research Institute (EPRI), Palo the fundamental factors responsible for cavitation.
Alto, Calif; Electricite de France (EdF), Paris; and Tests indicate that the fatigue endurance limit of
Siemens AG, Erlangen, Germany. Results of pre- the material is the primary parameter that controls
dictions of FAC with the use of the software have cavitation. Damage occurs to the surface of the com-
been mixed, some realistic, some very wrong. The ponent, just downstream from the cavitation source.
main reasons for the wrong predictions include Cavitation bubbles are reabsorbed within five to 10
poor representation of water chemistry in the soft- pipe diameters. Barring any obstructions or changes
ware (at-temperature pH, concentration of oxygen in direction, reabsorption is accomplished causing
scavenger, concentration of oxygen, and chemistry further damage. In CC plants, cavitation damage
of water droplets), oversimplification of the water- can occur in pumps, valves, and piping.
chemistry history, and a failure to use the actual The effect of flow on pressure is illustrated in
steel composition. Fig 9 for flow through an orifice. Note that in the
4 COMBINED CYCLE JOURNAL, Second Quarter 2004
FLOW-ACCELERATED CORROSION

Checklist helps identify FAC, cavitation before they


become serious problems

T
here’s little reason for a plant manager to be fied in the adjacent text. Your evaluation should
surprised that his or her plant is experiencing consider the combined effects of component
FAC and/or cavitation damage. The majority of geometry, flow velocity, water and steam proper-
combined-cycle (CC) facilities were designed and ties, material composition, water chemistry, and
built to meet the needs of the competitive genera- operating experience.
tion market. The large number of plants ordered Consider these objectives for your evaluation:
in the 1999-2002 timeframe stretched the person- ■ Find and select components to be inspected.
nel and material resources of the entire industry. ■ Interpret NDE results.
Designs and construction work often did not get ■ Identify root causes of wall thinning.
the rigorous review and oversight that had become ■ Determine inspection interval and safety
a tradition in the generation industry. Mistakes were margin.
made. ■ Determine effects on cycle iron transport.
Also, many asset owners thought CC plants ■ Recommend engineering solutions.
so simple—typically, “just a matter of hooking up Project tasks to consider include:
modules on a slab of concrete and connecting gas ■ Preliminary assessment (drawings, flow
and electric lines”—that the detailed procedures velocities, cycle design, experience, leaks).
used for coal-fired and nuclear plants didn’t apply. ■ Component details and actual installation
Another mistake, as plant managers know well. (walkdown, steel composition, history).
One thing for certain, the industry has a wealth ■ Final system and/or component description
of knowledge of FAC and cavitation as the many and operating and inspection/maintenance
references at the end of this article attest. This history.
information offers a competitive advantage to the ■ Water-treatment history and local chemistry.
plant manger who takes the time to do the appro- ■ Computer modeling, calculation of erosion/
priate eavaluations. It helps identify areas where corrosion rates, contributions of individual
FAC and cavitation already exist and where they are effects.
likely to occur, what corrective action is warranted, ■ Monitor cavitation noises and the rate of wall-
and what type of monitoring program will enable thinning.
you to avoid forced outages and the possibility of Finally, document your conclusions and recom-
life-threatening damage. mendations in a formal report for executive review
Assessment of the propensity of individual and implement engineering solutions approved by
systems and components to FAC and cavitation the asset owner. Regular follow-up inspections of
begins with a comprehensive plant walkdown pay- susceptible systems and components are recom-
ing particular attention of areas of attack identi- mended.

flow region immediately downstream of the orifice, Cavitation, thoroughly researched in the 1960s
where velocity is highest, the static pressure drops and 1970s, is a damage mechanism well known in
below the vapor pressure and steam bubbles form. the marine industry and among pump manufactur-
The change in static pressure, Δpstat, can be mea- ers. In steam power systems, it has been mostly a
sured or calculated from the measured or estimated problem with valves and boiler feed pumps which
maximum velocity in individual components using can be damaged within a few minutes of operation
the relationship, Δpstat = 0.5 ρ V2, here ρ is the when deprived of proper suction head. Such head
water density and V is the local flow velocity. This normally is provided by the deaerator, typically
flow-velocity effect is also called dynamic pressure located more than 30 ft above the pump. Problems
or velocity head. in the 1990s at nuclear units prompted EPRI to

294 70
10. Relationship between
Change in static pressure, psi

Brass
Rate of weight loss, mg/hr

flow velocity and the 60


221 reduction of 50 Mild steel
static pressure can be
High-tensile brass
used to estimate the sus- 40
147 Gunmetal
ceptibility to cavitation (left) 30
Monel
11. Susceptibility to 20
73.5 cavitation of various Stainless steel
materials used in pow- 10
0 erplant systems illus- 0
0 65.6 131.2 196.8 trates relative resistance 0 5 10 15 20 25 30 35 40
Flow velocity, ft/sec of stainless steel (right) Test time, hr

COMBINED CYCLE JOURNAL, Second Quarter 2004 5


FLOW-ACCELERATED CORROSION
include cavitation effects in its computer. Unlike the cavitation correlates with air-fatigue or corro-
FAC, which is mostly confined to carbon-steel sion-fatigue properties.
components, cavitation can attack any material, Water chemistry probably does not play a
including stainless steels. major role in the cavitation damage found in steam
Some piping and other component damage that cycles. However, effects of concentrated impuri-
had been attributed to FAC actually was caused by ties have been measured and have confirmed that
cavitation—or possibly by an interaction of cavita- a corrosive environment can accelerate cavitation.
tion and FAC, because the flow-velocity and turbu- While cavitation is most often caused by the col-
lence effects are similar and the surface damage lapse of steam bubbles, it can also be caused by
often looks the same. gases, such as nitrogen and oxygen, and volatile
Any system handling water at near saturation chemicals coming out of solution in water and sub-
conditions is susceptible to cavitation damage. For sequently redissolving.
example, the l-p section of condensate/feedwater
systems, such as the suction of booster and boiler Recommendations
feed pumps, can be close to saturation. Saturation ■ Every CC and cogeneration plant should have
conditions can be approached by locally increasing a formal program for preventing FAC and cavi-
flow velocity around obstacles. Also, by reducing the tation, starting with an early design review that
static pressure of the water in turbulent regions, or considers all the parameters influencing FAC
by increasing water temperature. described in Fig 1.
Components that have been damaged by cavita- ■ Where organic water-treatment chemicals—
tion include pipes, valves, orifices, pumps, feedwa- such as amines, dispersants, and oxygen scav-
ter-heater drains, and other feedwater and auxil- engers—are used, evaluate their effects and the
iary water components. For example: A feedwater effects of their decomposition products.
pipe, believed to have been thinned by cavitation ■ When using any FAC software, play special atten-
after a quill, ruptured in a paper mill. Feedwater tion to the representation of pH at temperature,
approached the saturation conditions because a pH of water droplets, concentration of the oxygen
leaking feedwater heater increased the water tem- scavenger, and the concentration of oxygen.
perature and the excessive pressure drop caused ■ Inspect piping downstream of all orifices, ther-
by various piping-system components between the mowells, sampling nozzles and chemical injection
feed pump and the drum reduced the static pres- quills, and leaking valves. Also check HRSG blow-
sure. down lines, downcomers, headers, drum liners,
Management control for preventing cavitation feedwater pipes, saturated steam pipes, steam
damage is similar to that for FAC. First, conduct a separation systems, turbine extraction pipes and
preliminary evaluation of all cycle systems, making extraction valves, feedwater heater drain valves
sure to include an estimate of the component pres- and shells, feedwater piping, condensers, and
sure in relation to the saturation pressure under all boiler-feed-pump recirculation lines.
modes of operation. Next, schedule a walkdown of ■ Select a reliable and accurate method for identi-
all the systems, paying particular attention to the fying wall thinning. Your best options: ultrasonic
noises generated by cavitation. Finally, inspect for wall-thickness measurements, x-ray of piping and
thinning of selected susceptible components. other components, pulsed eddy-current technique,
Where possible, the actual pressures, tempera- and the magneto-strictive sensor technique.
tures, and flow velocities should be measured or oth- Finally, remember that cavitation can be detect-
erwise determined and used in the cavitation evalu- ed on-line by listening to the noise produced by
ation. When susceptible components are identified, the collapsing steam or gas bubbles using acoustic
consider installing acoustic emission monitoring microphones or by acoustic emission instrumenta-
instrumentation to track cavitation long-term. Typi- tion. It is important to establish critical locations for
cal areas where cavitation may occur include: HRSG periodic long-term monitoring. Continuous in-line
downcomers, particularly near the lower headers monitoring is an alternative. CCJ
and in economizer-to-drum feedwater pipes; sections
of pipe after thermowells and similar obstructions; References
control valves; condensate, booster, and feedwater Section I: Erosion/corrosion
pumps; and pump suction pipes. 1. “Low-Temperature Corrosion Problems in Fossil Power Plants—
As a guide to estimating susceptibility to cavita- State of Knowledge Report,” TR-1004924, Electric Power
Research Institute, December 2003
tion, use Fig 2, which was developed for FAC, and 2. O Jonas and L Machemer, “Tight Control of Cycle Chemistry Key
include pressure and temperature information. Fig to Successful Commissioning,” Combined Cycle Journal, First
10 presents the relationship between the reduction Quarter 2004
3. O Jonas, “Safety Issues in Fossil Utility and Industrial Steam Sys-
of static pressure and flow velocity, which also can tems,” Materials Performance, May 2001. See also http://www.
be used to estimate susceptibility to cavitation. steamcycle.com/safety_issues_pdf.htm
Material properties. Unlike FAC, all materials 4. O Jonas, “Erosion-Corrosion of PWR Feedwater Piping – Sur-
vey of Experience, Design, Water Chemistry, and Materials,”
used in steam-cycle water systems are susceptible NUREG/CR-5149, ANL-88-23, US Nuclear Regulatory Commis-
to cavitation damage (Fig 11). The material prop- sion, March 1988
5. G Cragnolino, et al, “Review of Erosion-Corrosion in Single-Phase
erty which correlates best with the susceptibility Flows,” NUREG/CR-5156, ANL-88-25, US Nuclear Regulatory
to cavitation is the fatigue limit. However, it is not Commission, April 1988
clear whether, for various aqueous environments, 6. S Bush, “The Effects of Erosion-Corrosion on Power Plant Piping,”

6 COMBINED CYCLE JOURNAL, Second Quarter 2004


FLOW-ACCELERATED CORROSION
Proceedings of the 59th General Meeting of the National Board
of Boiler & Pressure Vessel Inspectors, Volume VII, No. 1, May
1990
Panel Discussions of
Special Interest to
7. “Flow-Accelerated Corrosion in Power Plants,” TR-106611, Elec-
tric Power Research Institute, 1996
8. V K Chexal, et al, “Recommendations for an Effective Flow-
Accelerated Corrosion Program,” NSAC-2021, Electric Power

HRSG USERS
Research Institute, November 1993
9. “Guidelines for Controlling Flow-Accelerated Corrosion in Fossil
Plants,” TR-108859, Electric Power Research Institute, June
1998

Section II: Effects of water chemistry on erosion-corrosion at the upcoming


10. O Jonas, “Steam, Chemistry, and Corrosion in the Phase Tran-
sition Zone of Steam Turbines,” TR-108184, Electric Power
Research Institute, February 1999
11. O Jonas, “Use of Organic Water Treatment Chemicals,” VGB
Conference, Organische Konditionierungs-und Sauerstoffbinde-
INTERNATIONAL
mittel (Lahnstein, Germany), 1994
12. O Jonas, “Controlling Oxygen in Steam Generating Systems,”
Power, May 1990
13. O Jonas, “New Oxygen Scavengers,” Jonas Inc, 1990
WATER
14. O Jonas, “Reduction of Feedwater Iron by Minimizing Oxygen
Scavengers,” Jonas Inc, October 1997
Section III: Inspection methods and codes, erosion-corrosion
CONFERENCE
15. “NDE of Ferritic Piping for Erosion-Corrosion,” NP-5410, Elec-
tric Power Research Institute, September 1987
16. “Assessment of the Pulsed Eddy Current Technique: Detecting
Pittsburgh
Flow-Accelerated Corrosion in Feedwater Piping,” RS-109146,
Electric Power Research Institute, January 1998
October 17-21
17. “Assessment of Magnetostrictive Sensor Technique: Detecting
Flow-Accelerated Corrosion in Feedwater Piping (Revision 1),”
RS-108449-R1, Electric Power Research Institute, February
1998
Current Ideas for Chemistry Control and
18. O Jonas, “Steam Generation in Corrosion Tests and Standards,” Operation of HRSGs
ASTM MNL 20, June 1995
19. “Requirements for Examination of Class 1, 2, and 3 Systems for Participants include Dave Daniels, Irv
Detection of Pipe Wall Thinning Due to Single-Phase Flow-Accel-
erated Corrosion,” ASME Boiler & Pressure Vessel Code (Section Cotton, and Luis Carvalho
XI, Subsection IWH), to be published
20. “Examination Requirements for Pipe Wall Thinning Due to
Single-Phase Erosion and Corrosion,” ASME Boiler & Pressure
Vessel Code (Section XI), Case N-480
Pros and Cons of Amine Use in
Section IV: Other references on erosion-corrosion Industrial and Utility Power Plants
21. O Jonas, “Alert: Erosion-Corrosion of Feedwater and Wet Steam
Piping.” Power, February 1996. See also www.steamcycle.com/
Participants include Mike Rootham, Jim
plant_alert.htm
22. O Jonas, “Control Erosion-Corrosion of Steels in Wet Steam,”
Bellows, Bill Moore, and Albert Bursik
Power, March 1985. See also www.steamcycle.com/control_of_
erosion_corrosion
23. H G Heitmann and W Kastner, “Erosion-Corrosion in Water- Other Presentations of
Steam Cycles—Causes and Countermeasures,” VGB Kraftwerk-
stechnik 62, March 1982 Interest to HRSG Users
24. W Kastner, et al, “Calculation Code for Erosion-Corrosion
Induced Wall Thinning in Piping Systems,” Nuclear Engineering
❍ Monitoring and control in steam
and Design 119, 1990
25. L Goyette and G Zysk, “Material Sampling in Erosion-Corrosion
generation cycles
Programs,” Codes and Standards in a Global Environment (PVP Vol
259), American Society of Mechanical Engineers, 1993
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