Department of Chemistry

University of Gujrat
H.H. Campus, Gujrat

Course Title: Physical Chemistry-I (Practical) Course Code: CHEM-304

Credit Hrs.: 1 Semester: Spring-2021
Instructor Name: Dr. Sumaira Naeem Office Address: BS-11
Email: sumaira.usman@uog.edu.pk

Outlines:
1-
Course Title: PHYSICAL CHEMISTRY-III (Practical)
Code: CHEM-304 Credit Hours: 1

1. Determination of percentage composition of KMnO4/ K2Cr2O7 in a given

solution by spectrophotometry.

2. Spectroscopic determination of Cu percentage in the given sample.

https://youtu.be/zKkkDGwLWhg
https://youtu.be/TmHXb5CQ3RY

3. Complexometric determination of Cu (II)- EDTA mole ratio in the complex.

https://www.youtube.com/watch?v=CWGmWkF2Mh4
https://www.youtube.com/watch?v=EQxvY6a42Dw
https://www.youtube.com/watch?v=Wj4-nQmW28s
https://www.youtube.com/watch?v=7i6sGH5Me6g
https://youtu.be/gse6XFgq5R4

4. To determine the effectiveness of an extraction of I2 solution by using Solvent

Extraction method.
https://www.youtube.com/watch?v=TdU-Pw4tbyg
https://www.youtube.com/watch?v=RQ_2lN9TDZM
https://www.youtube.com/watch?v=Rl1-ulSHxl0

5. Determination of end point of a strong acid neutralize by a strong base.

https://www.youtube.com/watch?v=fv7ozqXF-5Q
https://www.youtube.com/watch?v=JoGQYSTlOKo
https://www.youtube.com/watch?v=uO8DWyRJMHo
You can watch this later, but it is explained step wise
https://www.youtube.com/watch?v=WuBPy4eur0k
This link is performance of Conductometric titrations
https://www.youtube.com/watch?v=-GS6uoFf3qQ
https://www.youtube.com/watch?v=y3Oa0L404oM

6. Determination of molecular weight of a polymer by viscosity method.

7. Evaluation of pK a value of an indicator by spectrometric method.
8. Conductometric determination of hydrolysis constant (Kh) of conjugate base of a
weak acid.
Recommended Books:
1. Silbey, R. J., Alberty, R. A. and Bawendi, M. G., Physical Chemistry, 4th ed., John-
Wiley & Sons, (2005).
2. Ball D. W., Physical Chemistry, Brooks/Cole Co. Inc., (2003).
3. Vertes, A., Nagy, S. and Klencsar, Z., Handbook of Nuclear Chemistry. Volume 1:
Basics of Nuclear Science, 1st ed., Springer, (2003).
4. Choppin, G., Liljenzin, J-. O. and Rydberg, J., Radiochemistry and Nuclear Chemistry,
3rd ed., Butterworth- Heinemann, (2002).
5. Loveland, W., Morrisey, D. J. and Seaborg, G. T., Modern Nuclear Chemistry,
John-Wiley & Sons, Inc., (2006).
6. Atkins, P. and Paula, J. D., Atkin’s Physical Chemistry, 9th ed., Oxford University
Press, (2010).
7. Somorjai, G. A. and Li, Y., Introduction to Surface Chemistry and Catalysis,
2nd ed., John-Wiley & Sons, Inc., (2010).
8. Atkins, P., Jones, L., Chemical Principles: The Quest for Insight, 5th ed., W. H. Freeman,
New York, (201
Sixteen Week Plan:

Week Topic for Study

No.
1. Introduction to important term.
2. 1-
Equilibrium constant of the KI + I2 = KI3 reaction. Instructions

3. 1-
Equilibrium constant of the KI + I2 = KI3 reaction. Discussion

4. Acid catalyzed hydrolysis of sucrose. Instructions

5. Acid catalyzed hydrolysis of sucrose. Discussion

6. Study of the adsorption isotherms of acetic acid-charcoal system.

Instructions

7. Study of the adsorption isotherms of acetic acid-charcoal system.

Discussion

8. Study of the charge transfer complex formation between iodine and

benzene. Instructions
9. Study of the charge transfer complex formation between iodine and
benzene. Discussion
10. Determination of activation energy for the acid catalyzed hydrolysis of
ethyl acetate. Instructions
11. Determination of activation energy for the acid catalyzed hydrolysis of
ethyl acetate. Discussion
12. Determination of partial molar volumes. Instructions
13. Determination of partial molar volumes. Discussion

14. Characterization of the given compound by UV-Vis spectroscopy.

Instructions

15. Characterization of the given compound by UV-Vis spectroscopy.

Discussion

16. Revision