Professional Documents
Culture Documents
Course
Module 1.1
Common Plant Hazards
This module will provide the you with an overview of common plant hazards
that you will face when you become an operator.
The key points to emphasize in this module are:
The importance of safety
The consequences of not being safe
The need to constantly look for hazards
Hardhat
Hearing Protection Safety Goggles / Glasses
Work Gloves
Hydrogen Sulfide, or H2S, is a gas that is often produced with crude oil from a
reservoir.
The amounts of H2S in the crude oil can vary.
There may be much or little. But even in small amounts H2S can be deadly.
The most serious hazard of H2S is that it can kill you at very low concentrations.
A low concentration of H2S in the air smells like rotten eggs.
Higher concentrations will affect your sense of smell, so you will not be able to
smell it at all.
H2S KILLS!!!
To start coughing, eye irritation, loss of sense of smell after 2–15 minutes 100
Lose consciousness within 30 minutes and death within one hour 500–700
If you are downwind from the source, do not move upwind until you are clear of
the gas.
How will you know IF you are clear of the gas? (Discuss)
What are the ‘golden rules’ if you suspect a colleague to be
unconscious from overexposure to H2S?
Never try to rescue him unless you are wearing breathing
apparatus.
Once the colleague is in an area clear of H2S, send for medical help
or start artificial respiration if you are qualified.
If you smell H2S on Monday morning but do not smell H2S in the
afternoon, does this mean the H2S has gone? (Discuss)
You are working at height when a high concentration of H2S is released
below you. What would you do? (Discuss)
Any place where two pipes are joined and where pipes are joined to vessels and
tanks is a source of potential leaks.
Pressure and heat inside a pipeline can create a leak in a pipe joint.
Vibration, caused by a large machine, can loosen pipe joint bolts.
Corrosive liquids and gases can eat away the gasket in a pipeline joint and
create a leak.
INTRODUCTION:
Health Hazards
The harm that chemicals can cause you depends on how you are exposed to the
chemical.
The most common chemical health hazards come from exposure to:
❏ toxic chemicals
❏ corrosive chemicals
Toxic Chemicals
Toxic chemicals are poisonous to humans.
This means they will harm you if they get into your body.
Toxic chemicals can get into your body through your skin,
your mouth, or your lungs. A toxic chemical in your
body can make you sick. Many toxic chemicals can
cause serious injury or death. Figure 1 shows the
symbol for a toxic chemical. This symbol will be on
the container of any toxic chemical.
Corrosive Chemicals
Corrosive chemicals cause chemical burns to your skin.
These burns are very similar to burns from a fir
The most common corrosive chemicals are acids and bases. Common acids are
hydrochloric acid, sulfuric acid, and nitric acid. Common bases (or alkalis) are
sodium hydroxide and sodium bicarbonate. Figure below shows the symbol for
a corrosive chemical hazard. This symbol will be on the container of a corrosive
chemical.
Flammability
Fire is a chemical reaction between a chemical (fuel) and oxygen. Figures below shows
the symbols for fire hazard. Flammable chemicals will have this label on the container.
Flammability means how easy a fuel will burn. There are several conditions of a chemical
that are related to how flammable it is.
Lower Explosive Limit (LEL)
The lowest concentration (percentage) of a gas or a vapor in air capable of producing a flash
of fire in presence of an ignition source (arc, flame, heat). The term is considered by many
safety professionals to be the same as the lower flammable limit (LFL). At a concentration in
air lower than the LEL, gas mixtures are "too lean" to burn. Methane gas has an LEL of 4.4%.
If the atmosphere has less than 4.4% methane, an explosion cannot occur even if a source of
ignition is present.
Percentage reading on combustible air monitors should not be confused with the LEL
concentrations. Explosimeters designed and calibrated to a specific gas may show the
relative concentration of the atmosphere to the LEL—the LEL being 100%. A 5% displayed
LEL reading for methane, for example, would be equivalent to 5% multiplied by 4.4%, or
approximately 0.22% methane by volume at 20 degrees C. Control of the explosion hazard is
usually achieved by sufficient natural or mechanical ventilation, to limit the concentration of
flammable gases or vapors to a maximum level of 25% of their lower explosive or flammable
© 2020 TÜV Rheinland
limit.
Dr. Amr Arafa
SCADA Operator Technician 60 days Course- Unit 1: Industrial and Process Safety Page 31
Combustible gases parameters :
The following are important parameters you must know about combustible gases
Upper Explosive Limit (UEL) or Upper Flammable Limit (UFL): The maximum
concentration of gas or vapor mixed with air that will cause the propagation of flames
when it contacts an ignition source.
In common terminology, mixtures above UEL or UFL are too rich to support
combustion.
© 2020 TÜV Rheinland
Dr. Amr Arafa
SCADA Operator Technician 60 days Course- Unit 1: Industrial and Process Safety Page 32
Chemical Hazards
Note Well, All gases and vapors have different explosive limits
Acetylene ___________LEL = 2.5%, UEL = 81% (Volumes by air)
Diesel Fuel ___________LEL = 0.6%, UEL = 7.5%
Hydrogen Sulfide (H2S)__LEL = 4.3%, UEL = 46%
Flash Point (FP) is the lowest temperature at which a chemical or gas will burn
Reactivity
A chemical reactivity hazard means that a chemical can be dangerous if it mixes
with another chemical. This is important whenever you may be using different
chemicals. Some chemicals can react violently and produce large amounts of
heat and gas if they mix with other chemicals. Some chemicals also react to
make toxic or flammable gas if they are mixed together.
Some chemicals can also react with different materials. The chemical may
dissolve or destroy the material. Be aware of the reactivity hazard when you see
the label as shown Below on a chemical container.
Chemical Safety
You must follow the correct procedures when you are working with hazardous
chemicals. Follow the chemical safety precautions to help prevent harm to
people and the environment. Before you use a chemical, you should know about
the following:
Some chemicals can be very dangerous if they are not stored correctly. The main
storage hazard is temperature. High temperature can cause high pressure. High
pressure can cause the container to break open (rupture) or explode. Some
chemicals also require special transport containers.
Chemical storage
Area
Disposal
If you do not correctly dispose of chemicals, they can become a major hazard to
you, to other workers in your area, or to the environment. Used chemicals must
be put into the appropriate container and label correctly.
Chemical
Disposal
Area
First Aid
First aid is the assistance given to any person suffering a
sudden illness or injury, with care provided to preserve life, prevent the
condition from worsening, and/or promote recovery. It includes initial
intervention in a serious condition prior to professional medical help being
available, such as performing CPR while awaiting an ambulance, as well as the
complete treatment of minor conditions, such as applying a plaster to a cut. First
aid is generally performed by the layperson, with many people trained in
providing basic levels of first aid, and others willing to do so from acquired
knowledge.
Chemical Suit
Self Contained
Breathing Apparatus
Summary
Here you learned that chemical hazards are hazards directly related to the
chemicals you will be working with every day. You learned that to be safe you
must know about the hazards associated with the chemicals you use. Read the
CHB and HAZCOM label for any chemical you are working with. These
documents give you the information you need to work safely with the chemical.
Think about the questions below to see if you feel confident about the topic.
❏ Do I know what hazards are associated with chemicals?
❏ Do I know where to find out about chemical hazards?
When you have answered “Yes” to these questions,
then you are ready to complete the module test.
Review the topic again if you need to. Ask your instructor if you still have any
questions about the content.
What information about a chemical can you get from a HAZCOM label?
_____________________________________________________
Define LEL_______________________________
Define UEL_______________________________
The maximum concentration of vapor or gas that will ignite in air at atmospheric
pressure is called: _____________________________
Solid
Examples of a solid fuel
are wood,
plastic, clothes, and coal.
Liquid
Examples of flammable liquids are gasoline, crude oil, cooking oil,
and oil paint.
Gas
Examples of gasses as fuels are liquid petroleum gas, methane
etc. (Any flammable vapor at atmospheric pressure)
© 2020 TÜV Rheinland
Dr. Amr Arafa
SCADA Operator Technician 60 days Course- Unit 1: Industrial and Process Safety Page 54
2. Requirements for Fire Prevention
Oxygen
• The oxygen present in the air
is enough for most fires to
start.
• A fuel will ignite when enough
heat is applied.
• The heat energy from the fire keeps the fire going.
• Approximately 21% of the air you breathe contains
oxygen, so there is almost always an available supply for
fire to start.
Heat
• Heat provides the energy to initiate the
combustion process.
• Heat creates flammable vapors from the
fuel.
• If the heat continues to rise, the vapors
will ignite.
Fire prevention
• Be aware of the possible dangers that can cause a fire.
• It is important that you practice fire prevention.
• Prevent fire by ensuring that the three elements of the fire
triangle are kept apart.
• Extinguish a fire by removing any one of the three
elements.
• Oxygen cannot be safely removed from the working
environment, so you must keep fuel and heat well away
from each other.
Hot Work
• Some types of work such as welding or grinding may use
equipment that can produce a source of ignition.
• The Hot Work Permit
system is used for any
hot work.
• This system ensures that
all necessary precautions
are taken before work
can begin with
equipment that may
present a risk of fire.
Fire detection
• If a fire does occur in any workplace it is important to raise the
alarm as soon as possible.
• The fire can then be dealt with before it
becomes more serious.
• Most facilities will have smoke detectors
and manual alarms.
• Smoke detectors are placed at suitable
locations around the workplace.
Manual alarms
• There are different types of manual alarm
activators.
• You should make sure that you know where the
nearest manual alarm is in case you need to
raise the alarm.
• A facility may have heat detectors or flame detectors to raise
the alarm if they overheat or catch fire.
• Once the alarm is raised, personnel can evacuate the area and,
if possible, the fire can be dealt with safely.
• If you see a fire, you should raise the alarm immediately.
• If the fire alarm is activated, you should proceed as directed by
the emergency procedures for your workplace.
© 2020 TÜV Rheinland
Dr. Amr Arafa
SCADA Operator Technician 60 days Course- Unit 1: Industrial and Process Safety Page 63
3. Equipment for fire detection and firefighting
Firefighting
• The best form of protection against fire is to prevention.
• Ensuring that heat, fuel, and oxygen are not brought together.
• Extinguish as soon as possible, prevent it getting out of control.
• Fires are classified according to the material that is burning. Fires are
classified as Class A, Class B, or Class C.
• In most workplaces, there are several methods available to extinguish
a fire. The most common are listed below.
• portable fire extinguishers fire carts
• fire blankets fire hoses
• fire monitors fire hydrants
• deluge system
Fire Monitors
• Use fire monitors to spray water onto
equipment if there is a nearby fire.
• Cools the equipment to prevent it becoming
overheated and possibly igniting.
• Fire monitors can be mobile or fixed.
• Fixed monitors are connected to the facility
firewater system.
Fire Hydrants
• Pipes connected to the facility firewater systems.
• Fire department connect hoses to hydrants when
fighting a fire.
• Only connect a hose to a fire hydrant if directed
to do so.
© 2020 TÜV Rheinland
Dr. Amr Arafa
SCADA Operator Technician 60 days Course- Unit 1: Industrial and Process Safety Page 71
3. Equipment for fire detection and firefighting
Deluge System
• If a vessel is too large for a fire
monitor to keep it cool, it may
be equipped with a deluge
system.
• In the event of fire, a series of
pipes cover the vessel with
water, or a mixture of water and
foam.
• This will extinguish the fire or
prevent the vessel from
overheating.
• Safety drills are held at all facilities to help personnel prepare for
emergencies such as a fire.
• Unless you are directed not to participate, you should use the safety
drill to think about how you would escape if the emergency was real.
• Unless you have been fully trained in firefighting procedures, you
should not attempt to fight a fire.
• See table below for your responsibilities in the event of a fire.