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Proceedings of the Combustion Institute, Volume 29, 2002/pp.

883–899

MICROPOWER GENERATION USING COMBUSTION:


ISSUES AND APPROACHES

A. CARLOS FERNANDEZ-PELLO
Department of Mechanical Engineering
University of California, Berkeley
Berkeley, CA 94720-1740, USA

The push toward the miniaturization of electromechanical devices and the resulting need for micropower
generation (milliwatts to watts) with low-weight, long-life devices has led to the recent development of the
field of microscale combustion. The concept behind this new field is that since batteries have low specific
energy and liquid hydrocarbon fuels have a very high specific energy, a miniaturized power-generating
device, even with a relatively inefficient conversion of hydrocarbon fuels to power, would result in increased
lifetime and/or reduced weight of an electronic or mechanical system that currently requires batteries for
power. In addition to the interest in miniaturization, the field is also driven by the potential fabrication of
the devices using microelectromechanical systems or rapid prototyping techniques, with their favorable
characteristics for mass production and low cost. The micro power generation field is very young and still
is, in most cases, in the feasibility stage. However, considering that it is a new frontier of technological
development, and that only a few projects have been funded, it can be said that significant progress has
been made to date. Currently, there is consensus, at least among those working in the field, that combustion
in the microscale is possible with proper thermal and chemical management. Several mesoscale and mi-
croscale combustors have been developed that appear to operate with good combustion efficiency. Some
of these combustors have been applied to energize thermoelectric systems to produce electrical power,
although with low overall efficiency. Several turbines/engines have also been, or are being, developed,
some of them currently producing positive power, also with low efficiency to date. Microrockets using solid
or liquid fuels have been built and shown to produce thrust. Hydrogen-based microsize fuel cells have
been successfully developed, and there is a need to develop reliable reformers (or direct-conversion fuel
cells) for liquid hydrocarbons so that the fuel cells become competitive with batteries. In this work, some
of the technological issues related to meso- and microscale combustion and the operation of thermochem-
ical devices for power generation will be discussed. Some of the systems currently being developed will
be presented and described.

Introduction using EDM, LBM, or FIBM were primarily related


to biomedicine and those fabricated using MEMS
The last few years have experienced a growing were sensors and actuators, other more complex me-
trend in the miniaturization of mechanical and elec- chanical devices such as pumps, motors, microrov-
tromechanical engineering devices, which follows ers, and microairplanes are now being developed.
that initiated by the areas of microelectronics, bio- The interest in producing miniaturized mechanical
mechanics, and molecular biology and that is in large devices opens exciting new opportunities for com-
part the result of the progress made in microfabri- bustion, especially in the field of micro power gen-
cation techniques. High-precision fabrication of de- eration, because of the need for power-supply de-
vices in the centimeter-scale range are being made vices with high specific energy (small size, low
using microfabrication techniques such as electro- weight, long duration).
discharge machining (EDM), laser beam machining Typical portable consumer electronics suffer from
(LBM), or focused ion beam machining (FIBM) short operation cycles between charges or replace-
[1,2]. Devices in the millimeter-scale range are being ment, and their overall weight consists largely of bat-
fabricated using microelectromechanical systems tery weight. Similarly, other more advanced MEMS-
(MEMS), rapid prototyping and batch-manufactur- based devices depend on battery systems that
ing techniques [3,4], and materials that are similar occupy significant fractions of both the mass and vol-
to those used in the integrated circuit/microchip in- ume of the entire device. A typical example of this
dustry. Although initially the microdevices produced problem is depicted in Fig. 1, that shows a MEMS
883
884 INVITED TOPICAL REVIEW

in Fig. 2. Liquid hydrocarbons have an extremely


high specific energy (typically 45 MJ/kg), are easily
transportable, and are quite safe [10]. The top bat-
teries currently available (lithium) have an energy
density of 1.2 MJ/kg (0.6 MJ/kg for an alkaline bat-
tery). Thus, a miniature combustion device with a
mere 3% system efficiency would compete with top
batteries simply from the fact that the fuel is easily
replaceable. Although higher efficiencies are needed
for combustion systems to displace batteries, the
high efficiencies obtained in large-scale power sys-
tems encourage the development of miniaturized
power-generation devices using combustion, with
the expectation that devices with competitive effi-
ciencies can be developed. Furthermore, there are
specific applications where mechanical power, or
Fig. 1. MEMS sensor/communication device and a simply heat, is desired (rovers, airplanes, Stirling en-
hearing-aid battery for power [5]. gines, etc.) and where a combustion-based device
will have the added advantage of providing this
power directly. In addition to the interest in minia-
sensing/communication network device of a few cu- turization, the field is also driven by the potential
bic millimeters volume powered by one of the small- fabrication of the devices using MEMS or rapid pro-
est batteries currently available [5]. Miniature me- totyping techniques, with their mass-production and
chanical devices such as microrovers, microrobots, low-cost characteristics. There is of course the added
and microairplanes are also limited by the weight of issue of environmental considerations related to the
the available power systems. The need to reduce sys- use of combustion. Given the small size of the de-
tem weight, increase operational lifetimes, and re- vices being considered, however, their CO2 and H2O
duce unit cost has engendered the field of micro emissions and heat release would be comparable to
power generation [6–9], high-specific-energy mi- that of the human being for the mesoscale size and
croelectromechanical power systems. significantly less for the microscale ones [11]. Since
The concept behind this new field is to utilize the it is likely that the microdevices will have combus-
high specific energy of liquid hydrocarbon fuels in tion efficiencies smaller than those of the larger de-
combustion-driven microdevices to generate power. vices, it is expected that the fractional production of
The potential advantage of using liquid hydrocarbon unburned hydrocarbons and CO will be compara-
combustion to produce power is shown graphically tively larger. On the other hand, batteries have their

14000
12340
12000
Specific Energy (Wh/kg)

10000

8000

5509
6000

4000

2000 1234
710 470
164 200 170 90 70 55
0
Li

10

Li

Zi

Li

Li

Si

Ni

Ni
lk
et
qu

th
th

th
nc

Cd
lv
%

al
ha

H
iu

er
iu

iu
-A
id

Ef

in

m
m

m
no

-Z
ir
H

fic

-Io
/S

-P

in
C

B
ie

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c
n
at
(O

at
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ym
te

te
ct

l2
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an

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ne

Fig. 2. Specific energy for iso-octane and several primary and secondary battery technolgies.
MICROPOWER GENERATION USING COMBUSTION 885

own environmental issues, and their production and there is a need to produce reliable reformers (or
disposal present an environmental hazard. direct-conversion fuel cells) so that they can be used
The power-generation devices addressed in the with liquid hydrocarbons and can become competi-
present review are those that aim to generate power tive with batteries. Still not looked at is the potential
in the range of a few watts to milliwatts. This is in complementarity of the different systems (cogener-
contrast with the so-called microturbines, which ation), such as using the exhaust heat from engines
generate power of the order of kilowatts and are not to run thermoelectric generators, fuel-cell reform-
‘‘micro’’ in the present sense, but rather in the sense ers, or Stirling engines. The combined systems could
of being smaller than their larger counterparts. result in improved overall conversion efficiencies.
Power generation in the watts range has multiple Also worth mentioning is that small-scale combus-
applications, such as electronic devices (laptops, tion has other useful applications than power gen-
phones, etc.) and miniaturized mechanical systems eration and heat production for use in power cycles.
(small robots, rovers, airplanes, etc.). The corre- Positioning of localized heat is an example of its po-
sponding combustion devices are of the order of tential applications. Another interesting example is
1 cm in size (mesoscale), and their microfabrication the use of arrays of mesoscale burners to produce
techniques are relatively conventional (EDM), in distributed combustion in large-scale gas turbine
combustors, which has the potential for interturbine
some cases with some MEMS components. Power
reheat, and for premix or highly vitiated combustion,
generation in the milliwatt range (microscale) has its
to reduce NOx [18].
application primarily in microelectronic components Some of the technological issues related to micro-
(sensors, transmitters, etc.), with the ultimate goal scale combustion and thermochemical devices for
of incorporating the power-generation device into power generation are discussed below. Many of the
the microelectronic component. These power-gen- systems currently being developed are also pre-
eration devices are constructed using primarily sented and briefly discussed.
MEMS. The ultimate goal is to have ‘‘power gen-
eration in a chip.’’ The system would then incorpo- Thermophysical Issues
rate in the same unit the power device, the micro-
processor to control the overall system, and some The characteristic length of the microcombustors
being developed to date, even in MEMS-size sys-
sort of sensor/emitter or actuator.
tems, is sufficiently larger than the molecular mean-
The micropower generation field is young (4–6
free path of the air and other gases flowing through
years) because its interest has resulted from the re- the systems that the physical-chemical behavior of
cent development of fabrication techniques to min- the fluids is fundamentally the same as in their mac-
iaturize mechanical devices and still is, in most cases, roscale counterparts. For example, the Knudsen
in the feasibility stage. However, considering that it number for air flowing through a 0.1 mm wide chan-
is a new frontier of technological development and nel is of the order of 10ⳮ3, which is much smaller
that only a few projects have been funded to date than that for free-molecule flow (Kn ⬎ 1). Conse-
(primarily by government agencies that fund ad- quently, the standard hypotheses of thermofluids
vanced conceptual projects, such as Defense Ad- such as the no-slip condition and the continuum me-
vanced Research Projects Agency (DARPA) [8,9]), dium will still apply. However, the small size of the
it can be said that significant and encouraging prog- microdevices or their components causes particular
ress has been made. Several microcombustors have characteristics of the fluid mechanics, heat transfer,
been fabricated that appear to operate with good and combustion involved in the device operation.
combustion efficiency [12–14]. Some of these com- Some of the scaling issues involved in microcom-
bustors have been applied to energize thermoelec- bustors can be understood by normalizing the con-
tric systems to produce power. The system efficiency servation equations of momentum, energy, and spe-
is currently too low, but the limitation appears to be cies in terms of the characteristic length and
in the thermoelectric component and not in the parameters of the device and analyzing their terms
combustion process itself. Several turbines/engines as the length scale is reduced. The normalized one-
have also been or are being developed, some of them dimensional form of the governing equations for the
currently producing positive power, although again gas and solid phase and their relevant boundary con-
with low efficiency [6,15,16]. Here, the problem ap- ditions can be written as (symbols are defined in the
pears to be in fabrication and thermal management Nomenclature section)
that either limit the tolerances in moving parts lc ⳵ū ⳵ū p 1 ⳵p̄
(leakage, low compression ratio) or cause reduced Ⳮ ū ⳱ ⳮ c2
tc uc ⳵t¯ ⳵x̄ qc uc q̄ ⳵x̄
efficiency of individual components (compressor,
combustion chamber). Fuel cells are also being de- 1 ⳵2ū gl
veloped [17], and although not a combustion device, Ⳮ m̄ 2 Ⳮ 2c (1)
Re ⳵x̄ uc
they have issues that are of interest to the combus-
tion community. Although hydrogen-based micro- lc ⳵T¯ ⳵T¯ 1 ⳵2T¯ Q ¯
Ⳮ ū ⳱ ␣¯ Ⳮ Da ¯ ẇ⬙ (2)
fuel cells have been successfully developed [17], tc uc ⳵t¯ ⳵x̄ Pe ⳵x̄2 CpTc
886 INVITED TOPICAL REVIEW

lc ⳵ȳi ⳵ȳ 1 ¯ ⳵2ȳi 1 ¯ number (ether based on residence or diffusion time)


Ⳮ ū i ⳱ D Ⳮ Da ẇ⬙ (3) is important to determine whether combustion will
tc uc ⳵t
¯ ⳵x̄ LePe ⳵x̄ 2 yic
be completed in the combustion chamber of the mi-
⳵T¯ s ⳵2T¯ s crodevice, since it is necessary that the chemical
⳱ Fo␣¯ s 2 (4) time be smaller than the physical time.
⳵t¯ ⳵x̄
Turning to the solid phase, the Fourier number
The relevant normalized boundary conditions for increases as the length scale is decreased, which re-
these equations are sults in a quasi-steady behavior of the solid tem-
perature. The characteristic time of heat conduction
lc uc ⳵ū
ū ⳱ 0 s̄ ⳱ l̄ through the solid is tsc ⳱ l2c /␣sc. Since the thermal
sc lc ⳵ȳ diffusivity of the microdevices’ materials (Si, SiC) is
⳵T¯ ⳵T¯ ⳵T¯ s of the same order of magnitude as that of air, the gas
T¯ ⳱ T¯ w ks s ⳱ k ⳱ Bi(T¯ s ⳮ 1) and solid diffusion times will be similar, which has
⳵x̄ ⳵x̄ ⳵x̄ implications in the heat transfer characteristics from
⳵ȳi the gas to, or from, the solid, particularly if there are
ȳi ⳱ 0 ⳱ (LePe)ȳi periodic heat fluxes at their boundary with charac-
⳵x̄ teristic times much different than the diffusion time.
The characteristic length of the components of From the relevant boundary conditions of the gas-
large power systems is large, and generally the Rey- phase conservation equations, it is deduced that as
nolds and Peclet numbers are also large. Thus, the the length scale is reduced while keeping the wall
fluid flows are mostly turbulent, and as seen from and flow variables fixed, the velocity gradients and
equations 1–3, the viscous and diffusive effects are wall frictional effects increase, as do the gas tem-
small compared to the convective effects. It is also perature and species gradients at the wall. Because
deduced that the characteristic time in these con- of the high gradients, however, it will be difficult to
vective-dominated flows is, tc ⳱ lc/uc, which is nor- keep the difference between the wall and the bulk
mally referred to as residence time. The boundary flow variables fixed, since the resulting increase in
conditions provide information about wall effects, head loss and heat and mass transfer will tend to
that usually have a small influence on the overall reduce it. This implies that in microdevices it will be
system. difficult to keep flow velocities, and temperature and
As the size of the devices is reduced, the character mass concentration differences, of the same magni-
of the governing equations and the importance of tude as in their large counterparts. In the solid, on
the different terms in the equations change. As the other hand, since the Biot number will tend to de-
characteristic length of the device is reduced, the crease (factored by the corresponding increase in the
Reynolds and Peclet numbers decrease and fluid heat transfer coefficient), the solid temperature gra-
flow tends to be less turbulent, so the viscous effects dient will also tend to decrease as indicated by the
and the diffusive transport of mass and heat become wall boundary condition. It is expected, therefore,
increasingly important. From the point of view of that microdevices will have nearly uniform solid-
combustion, an important issue is the magnitude of phase temperatures, unless the boundary heat trans-
the residence time, because it decreases as the fer coefficient is large enough for Bi ⬎ 0.1, which is
length of the combustor decreases, and it has to be unlikely. Thus, the wall effects will be very important
larger than the chemical time, tc ⳱ qc/ẇ⬙, for com- from the point of view of combustion in microcom-
plete combustion to occur. bustors. The tendency will be for the presence of
For microdevices (MEMS scale) with very small small Damkohler numbers (weak combustion) due
characteristic lengths and consequently small Rey- to heat losses through the combustor walls that re-
nolds and Peclet numbers, the flow is primarily lam- duce the reaction rate and consequently increase the
inar. Also, as can be seen from equations 1–3, the chemical time, while the small dimensions reduce
viscous and diffusive terms can become dominant the physical time.
and the convective and buoyant effects become neg- The implications of these trends on the operation
ligible. In this case, the characteristic time becomes of small-scale combustion devices are discussed with
tc ⳱ lc/ucPe ⳱ l2c /␣c (for unity Prandtl and Lewis some detail below.
numbers), normally referred to as the diffusion time.
Since turbulent mixing is small, species mixing will Fluids
be primarily by diffusion. In this regard, the diffu-
sion time is important, since it has to be smaller than The small diameter of the channels for the reac-
the residence time for complete mixing to occur. tant intake, the product exhaust, and the actual com-
Concerning combustion, the source term of equa- bustion chamber constrain the flows in microdevices
tion 2 becomes factored by Pe, which gives rise to a to relatively small Reynolds number. For example,
Damkohler number based on a diffusion time, that for a 100 W mesoscale device using a stoichiometric
is, Da ⳱ l2c ẇ⬙/qc␣c. The value of the Damkohler mixture of octane/air and with a system efficiency of
MICROPOWER GENERATION USING COMBUSTION 887

10%, the volumetric flow rate of gaseous mixture will To increase fuel evaporation or to inject the fuel
be approximately 0.4 L/s. Assuming a 5 mm diam- into the combustion chamber, it may be convenient
eter intake tube, the Reynolds number will be of the to atomize the liquid. As the devices become smaller,
order of 5000 or below, depending on the gas tem- the atomization device and the droplets must also be
perature. Similarly, for a 100 mW microscale device reduced in size. Since the surface energy of a droplet
with a 0.5 mm diameter intake, the Reynolds num- is inversely proportional to the radius of curvature,
ber will be around 50. Thus, the flow will be pri- a decrease in the system’s dimensions will increase
marily laminar for the small devices and conse- the pressure and energy requirements for atomiza-
quently the mixing of different species will be tion. Although some MEMS-based simple atomizers
primarily by diffusion. Also, as stated above, viscous (plain orifice type) have been developed [21], it ap-
effects will be important, which together with the pears that more elaborate devices or techniques to
large aspect ratios in the microchannels implies that produce micron-size droplets that will evaporate and
frictional losses will be high and that increased mix with the air in the available microscale residence
pumping will be required. On the other hand, vis- time will be needed. MEMS-based microelectro-
cous forces help in some of the problems character- spray atomizers [22,23] appear to be good potential
istic of these devices, such as leakage of gases candidates for microcombustors [24,25].
through joints or through moving surfaces. This The low Reynolds number coupled with the pla-
could be important in internal combustion (IC) en- nar nature of MEMS devices makes mixing of the
gines, since their efficiency is strongly dependent on reactants a potential problem in microsystems. Al-
the compression ratio, which will be affected by the though the small diameter of the channels helps
leakage at the piston (rotor)/housing surfaces. their diffusive mixing, the residence time of the flu-
Unexpected behavior may result in those cases ids in the channels is also small and may be insuffi-
with extremely small length scales (⬃lm), such as in cient to ensure complete mixing. For example, for a
some MEMS devices or their components. The most gaseous fuel/air mixture flowing through a 0.5 mm
obvious effect is that the flow in these cases operates channel, the diffusion time will be of the order of
in the near-Stokesian regime where the Reynolds 0.02 s, and if flow velocity is of the order of 1 m/s,
number is often less than 1. Small changes in tem- the channel length would have to be 25 mm to en-
perature, for example, can significantly change the sure diffusive mixing. This channel length may be
volumetric flow rate as can fluid-wall interactions too long for the device or result in significant pres-
that are normally ignored in macroscopic flows. Also, sure losses. Thus, in some cases where mixing of
species may need to be enhanced, different dynamic
the small length scales of the channels result in high-
mixing approaches (flow instabilities, ultrasound,
velocity gradients in the fluid. As seen from the
etc.) may have to be implemented, even though they
aforementioned boundary conditions, this results in
will introduce fabrication complexities and will con-
high wall frictional losses and high convective heat
sume valuable energy. To date, several approaches
transfer coefficients. These in turn can result in large
have been used to increase mixing rates, primarily
pressure losses, high heat transfer to or from the of liquids [26–28]. The main problems with these
fluid to the wall, and enhanced diffusive mixing. approaches are fabrication complexity, system size,
As in their large-scale counterparts, the micro- and increased pressure drops. Although these works
combustors must use the ambient air as the source are geared to mix liquids, similar concepts could be
of oxygen to both reduce volume and to maintain applied to mixing gases.
their performance edge in energy density. This im-
plies that the liquid hydrocarbon must be evaporated
and mixed with the air prior to entering the com-
bustion chamber in premixed systems or injected di- Thermal
rectly in the combustion chamber in non-premixed At the length scales of microcombustion devices,
systems. The small length scales have a large impact heat transfer by natural convection becomes small
on the dynamics and energy requirements associated because the induced buoyant flow is small (equa-
with phase change and two-phase flows. It has been tion 1). However, heat transfer by conduction
observed, for example, that the phase change from through the gas to the surrounding surfaces and by
liquid to vapor in MEMS-size channels occurs forced convection in the intake and exhaust channels
abruptly and in an unstable fashion [19], quite dif- and in the combustion chamber is significant be-
ferently from the transition observed in large tubes cause the temperature gradients are higher as the
[20]. This is partially due to the large surface area– characteristic length is decreased. Heat transfer by
to–volume ratio in microchannels that enhances the radiation also increases as the characteristic length
nucleation and wetting effects at the wall and to the decreases because of the large view factor. In addi-
behavior of bubbles that is strongly affected by the tion, as the scale of the device is reduced, the sur-
small length scales and significantly differs from face-to-volume ratio increases, which, combined
macroscopic behavior. with the enhanced heat flux, results in heat transfer
888 INVITED TOPICAL REVIEW

effects becoming very important at the surface or the incoming air would be considerably larger than
boundary of the device. This has advantages in com- the one calculated above (ka/lc in equation 5 would
ponents that use heat transfer in their operation, be replaced by a heat transfer coefficient, ha ⬎
such as evaporators or heat exchangers, since it en- 100 W/m2 K). The enhanced heat transfer to the
hances their heat-exchanging characteristics. It may incoming gas in the intake manifold of the combus-
become problematic, however, in devices where sur- tor is of particular concern in devices using premixed
face heat losses may deter their performance, as may reactants for combustion. While preheating the re-
occur with combustion chambers due to wall actants will aid in sustaining combustion to scales
quenching. smaller than the quenching distance, it may result in
It should be noted that the small buoyancy and the the autoignition of the mixture in the inlet port.
low thermal conductivity of air (ka ⬃ 0.03 W/mK) ren- Thus, insulating measures must be taken to control
der the heat losses from a combustor relatively small the amount of heat that will be transferred to the
when compared to its total heat generation. The order incoming fuel/air mixture. Furthermore, heating of
of magnitude of the heat losses from a combustor to the reactants in the intake manifold will result in a
the surrounding air can be obtained with a simple one- smaller mass charge in the combustion chamber due
dimensional, steady-state calculation. The heat flux to the reduced density, thus reducing the potential
from a flowing hot gas in the combustion chamber, net power output of the device. The lower density
through the combustor housing, to the still ambient air will also result in higher compression work per unit
surrounding the combustor can be approximately cal- mass and consequently lower overall system efficien-
culated by cies. This is particularly critical in gas turbines, since
the power requirements of the compressor deter-
q Tg ⳮ Ta mine their overall efficiency. In these cases, thermal
⳱ (5)
A 1 l 1 management becomes essential in order to reduce
Ⳮ c Ⳮ heat losses and increase the performance of the de-
hg ks ka
Ⳮ hra vices.
lc
As noted earlier, most microdevices tend to op-
where the subscript ‘‘g’’ represents the hot gases in erate at a relatively uniform temperature because of
the combustion chamber and the subscript ‘‘a’’ rep- their small size. For example, the Biot number for a
resents the air surrounding the combustor. Consid- steel or a silicon device with a length scale of 10 mm,
ering, for example, a mesosize combustor with a and subjected to moderate convection and radiation
characteristic length of lc ⳱ 20 mm capable of pro- (combined convection and radiation heat transfer
viding around 50 W of power [15], a combustion gas coefficient of 100 W/m2K), will be of the order of
and ambient air temperature of Tg ⳱ 1000 ⬚C, and 0.002, which is considerably smaller than that nor-
Ta ⳱ 20 ⬚C, respectively, a heat transfer coefficient mally considered sufficient for a lumped heat trans-
of the gases flowing through the combustion cham- fer analysis (Bi ⬍ 0.1). Thus, a uniform temperature
ber of hg ⳱ 100 W/m2K, (convection and radiation), could approximately describe the device’s internal
a SiC combustor housing (ks ⳱ 500 W/mK), and a temperature (boundary condition for equation 2).
linearized radiative heat transfer coefficient from the Reduced thermal gradients will reduce thermal ex-
housing to the ambient air of hra ⳱ 130 W/m2K, pansion stresses and subsequent misalignments in
equation 5 gives for the heat flux 0.05 W/mm2. As- moving parts. However, it introduces potential prob-
suming that the combustor’s combustion chamber lems whenever large thermal gradients are needed
has a 25 mm2 area, the heat loss from the combus- for high performance of the device, such as in ther-
tion gases would be around 1.3 W, that is ⬃3% of moelectric generators. This is also a problem for gas-
the combustor output. Several observations can also cycle-type devices (heat engines) because their effi-
be deduced from equation 5. One is that because of ciency depends on the ratio of the high- and
the large thermal conductivity of the housing (SiC, low-temperature reservoirs, and it may be difficult
steel, etc.), the solid conduction term is negligible at to attain or maintain a large temperature ratio. The
these small scales, and that heat conduction through solution of these problems again requires complex
air is also small compared with radiation. Thus, in thermal management.
order to reduce the heat losses from the combustion Regarding thermal management, complex struc-
chamber, it is important to reduce radiative heat loss tures with highly insulating materials, vacuum gaps,
from the combustor housing to the ambient air. For and/or complex thermal coatings may be needed to
this purpose, a material like silica aerogel would be insulate and reduce heat transfer from high- to low-
good to insulate the combustor since it has excellent temperature regions. However, thermal manage-
insulating properties both for conduction and radi- ment is not only restricted to spatial temperature
ation. gradients, but also to transient heat transport. Very
If, instead of still air, there is a forced flow as in different characteristic time in the gas or the solid
an intake manifold or in a gas turbine compressor, or in the periodic heat input from intermittent com-
the heat transfer from the combustion chamber to bustion may result in quasi-insulating conditions at
MICROPOWER GENERATION USING COMBUSTION 889

combustion process within the combustor. In gen-


eral, small chemical times are obtained by ensuring
high combustion temperatures, which in turn can be
achieved by reducing the heat losses in the combus-
tion chamber, preventing radical depletion at the
wall, increasing the reactants’ temperature, using
stoichiometric mixtures, and using highly energetic
fuels.
As engine size or combustion volume decreases,
the surface-to-volume ratio increases, resulting in in-
creased combustor surface heat losses and increased
potential destruction of radical species at the wall.
These mechanisms will increase the chemical time
and possibly prevent the onset of the gas-phase com-
bustion reaction or lead to quenching of an ongoing
reaction. Thermochemical management techniques
that can be used to overcome quenching are, among
others, the use of excess enthalpy combustors, gen-
erating adiabatic walls by stacking planar devices in
a symmetrical fashion (insulated temperature
boundary condition), establishing high-temperature
ceramic walls, and using surface coatings. The ear-
Fig. 3. Swiss-roll-type, excess enthalpy combustor and liest work on excess enthalpy, recirculating, burners,
recirculation combustor [10,29,30]. was conducted by Weinberg and coworkers
[10,29,30]. In these works, the combustion reaction
was optimized by using the enthalpy of the products
the boundary. For example, if the combustion time to preheat the fuel/air mixtures, in what is known as
in a compression ignition engine is much shorter a ‘‘Swiss-roll’’ combustor, shown in Fig. 3. As a result
than the heat transfer time through the engine hous- of the enthalpy exchange obtained by recirculating
ing, heat losses from the combustion reaction to the the exhaust, steady combustion has been obtained
wall could be negligible because of the lack of time with mixtures well below the normal flammability
to transfer the heat. limits. Stable combustion (described as ‘‘flameless’’
by the authors of Ref. [31]) has also been observed
Combustion at temperatures below the expected homogeneous
combustion temperatures of the fuels tested, but
Combustion in microscale systems presents prob-
lems related to the time available for the combustion above their normal catalytic temperatures [31]. The
reaction to occur and to the possible quenching of concept of recirculating the exhaust to reduce the
the combustion reaction by the wall. Near-wall heat losses from the combustion region and to pre-
chemical kinetics, related to potential low wall tem- heat the incoming reactants has been further imple-
perature and radical depletion, characterize the mented to attain combustion in thin tubes [32,33]
combustion reaction. Once again, the basic require- with diameters smaller than the quenching distances
ment for microcombustion to occur is that the physi- that are reported in the literature. It has also been
cal time available for combustion (residence time) used to develop microcombustors such as that shown
must be larger than the time required for the chem- in Fig. 4 [33]. Concerning the quenching distance,
ical reaction to occur (combustion time). For gas- it is worth mentioning that the magnitude reported
phase combustion in flow systems such as in a gas in the literature is considered often as the limiting
turbine combustor, the residence time is determined scale for microscale combustion. This is a conceptual
by the size of the combustion chamber and the flow error, because the quenching distance depends on
rate of the reactant stream through the chamber. For the reaction rate, and thus on the temperature, spe-
closed systems such as in internal combustion en- cies, and radical concentration (it is related to heat
gines, in addition to the size of the chamber, the and radicals losses to the wall). The problem of wall
revolutions per minute of the engine also determines quenching can be reduced or prevented by increas-
the residence time. For catalytic combustion, the ing the wall temperature (the quenching distance is
diffusion of species to the wall and species absorp- approximately inversely proportional to the square
tion/desorption at the wall also determine the resi- root of the temperature) or equivalently preventing
dence time. Since in general the residence time will the heat losses to the wall (adiabatic wall).
be small in microcombustors, it is important to have Elevated operating temperatures of the combus-
small chemical times to ensure completion of the tor walls not only help prevent quenching, but also
890 INVITED TOPICAL REVIEW

surface-to-volume ratio of the microcombustors. Re-


searchers have proven the concept in a miniaturized
cylindrical continuous combustor that induces a
swirling air flow that keeps the film of liquid fuel on
the wall. The device is projected to deliver power
levels varying from 10 W to kilowatts [35].
One important aspect of microscale combustion
that should be kept in mind is that although the in-
crease of the surface-to-volume ratio of the com-
bustor presents a problem for gas-phase combustion,
it favors catalytic combustion. Although the catalytic
reaction is generally slower than the gas-phase re-
action, and surface heat loss is a problem that also
affects the catalytic reaction, the relative increase of
surface area and the lower temperatures of the cat-
Fig. 4. Single pass counterflow, catalytically stabilized, alytic reaction suggest that microscale combustors
heat exchanger/microcombustor [33]. using catalytic reactions may be easier to implement
than those using gas-phase reactions. For example,
it was noted in the above-mentioned Swiss-roll com-
by reducing the chemical time help counter the ad- bustor that hydrogen/air mixtures could be ignited
verse effect of the small physical time inherent in at room temperature and other fuels (butane and
microcombustors. The physical time of the combus- propane) at less than 200 ⬚C if a catalyst were de-
tor will be given by the above-indicated residence posited on the surfaces of the combustion volume
time, diffusion time, or the revolutions per minute [31]. The role of catalytically active surfaces within
of an engine. An order of magnitude of this time is microchannels is under investigation to stabilize the
from 1 to 10 ms (a 10 mm gas turbine combustor flame structure, determine extinction limits, opti-
with 1–10 m/s flow velocity, or a rotary IC engine at mize combustion efficiencies, and reduce emissions
4000–40,000 rpm). Thus, chemical times of 1 ms or [14,31,36–38]. The device being developed in Ref.
less are necessary for the operation of the combus- [37] is a single-pass counterflow heat exchanger that
tors, which requires elevated, but not too high, tem- is designed with an incorporated catalytic surface.
peratures. Ceramic materials, such as SiO2, SiC, and The small scale greatly enhances both thermal and
Si3N4, can withstand temperatures of around 1700 K, mass transfer, which can result in volumetric heat
which are high enough to ensure short chemical generation rates of up to 10 W/mm3, and therefore
times and thus are good candidates for microcom- confirms the potential of microtechnology-based en-
bustors. The small scale of the devices and their uni- ergy conversion and chemical systems.
form temperature operation reduce the problems of Although the potential solutions to the low tem-
fracture inherent in the use of ceramic materials in peratures and short residence times seemingly in-
large-scale combustors. Coating the combustor walls herent in microscale combustors could result in
with inert materials can also reduce radical recom- competitive operating devices, further understand-
bination and chemical quenching at relatively low ing of low-temperature chemical kinetics (homoge-
temperatures [34]. neous and catalytic) and the development of highly
If the reactants are not premixed and the fuel is reactive energetic fuels is likely to be necessary to
liquid, additional time and volume will be required achieve this goal. Also needed are accurate theo-
for fuel evaporation and mixing. This time can be retical models of the physicochemical process in-
significant when compared to the gaseous premixed volved in the combustion chamber.
residence time, because the liquid evaporation and
the mixing at the low Reynolds numbers expected
in these systems are generally slow. As such, alter- Approaches to Micro Power Generation
natives to spray combustion in liquid-fueled micro- Using Combustion
combustors are currently being explored. Particu-
larly interesting is the concept of burning the liquid Although the field of microscale power generation
fuel while forming a liquid film along the wall of the using combustion is very new, there are currently
combustion chamber [35]. The advantage of this ap- several ongoing projects to develop microscale com-
proach is that the wall film reduces heat losses from bustors and power generators that are relatively well
the combustor, since it keeps the combustor walls advanced. The ultimate objective of most of these
cooled (at the liquid boiling point). It also inhibits projects is to develop a portable, autonomous power-
wall quenching because the gas-phase combustion generation system using combustion, with improve-
occurs away from the wall, while maintaining suffi- ment in energy density over batteries. A brief de-
ciently large vaporization rates because of the large scription of some of these projects is presented here.
MICROPOWER GENERATION USING COMBUSTION 891

is that they do not have moving parts, but the prob-


lem generally lies in the low efficiency of the com-
plete system. Although there are some thermoelec-
tric materials that have attractive efficiencies, they
suffer from the difficulty of maintaining a large tem-
perature drop across the thermoelectric material,
because of the small scale of the devices and because
good thermal conducting materials generally are also
good electrical conductors. Thus, good thermal man-
agement, or the possibility of decoupling the thermal
and the electrical conductivities, is key for the suc-
cess of these devices.
The Swiss-roll approach has been used to develop
thermoelectric power-generation devices using mi-
Fig. 5. Three-dimensional monolithically fabricated
croscale combustion [12,14]. The referenced re-
Swiss-roll-type combustor-thermoelectric generator [12,31].
searchers have demonstrated that their device can
produce power, although to date with low efficiency.
New designs of this type of power-generation device
have been recently proposed based on thermody-
namic analyses that promise to provide better effi-
ciencies [39]. The specific proposed design consists
of a section where heat is transferred to the incom-
ing reactants followed by another section that dis-
cards unconverted heat to the cold surroundings.
The goal of the University of Southern California
project [12,31] is to develop a highly miniaturized,
integrated, monolithically and batch-fabricated
power generator with no moving parts, capable of
powering devices down to MEMS scales. With its
three-dimensional Swiss-roll characteristics, the re-
Fig. 6. Two-dimensional stereolithography fabricated actor (shown in Fig. 5) appears to be well suited for
Swiss-roll-type catalytic microcombustor-thermoelectric MEMS-size devices because the heat losses are
generator [14]. greatly reduced. Complication presently appears in
the implementation of the thermolectric unit. To
date, macroscale and mesoscale combustors have
been fabricated and tested. Low-temperature, self-
There are a few other projects that have been re- sustained combustion has been demonstrated in
cently initiated, but that have not been referenced these larger reactors [31,36].
here for lack of sufficient information about them. The chemical energy conversion and power-gen-
The projects have been grouped into three catego- eration device at the MEMS scale developed at
ries: microcombustors, heat engines, and rockets. Al- Princeton University [14] consists of a recirculating
though combustors and rockets are not power gen- catalytic, 12.5 mm ⳯ 12.5 mm ⳯ 5.0 mm micro-
erators by themselves, they can be used in reactor (two-dimonsional Swiss roll) made of alu-
conjunction with other devices (thermoelectric, pi- mina ceramic and platinum as catalyst and a ther-
ezoelectric, inert fluid cycles, etc.) to produce elec- mopile unit, as shown in Fig. 6. A prototype device
trical power and are therefore included here because has been operated with hydrogen and with butane.
of their combustion component. Furthermore, di- Continuous operation with hydrogen has been dem-
rect mechanical power generation is also of interest, onstrated over a wide range of fuel/air mixtures and
and, as mentioned above, it is another of the assets chemical energy inputs from 2 to 12 W, at an opera-
of using combustion for power production. tion temperature of 300 ⬚C. The device generated
electrical power sufficient to power a 100 mW light
bulb. Plans to increase the efficiency of the electrical
Microcombustors/reactors generator by stacking several devices to reduce heat
losses are currently underway. These researchers ex-
Several microcombustors and chemical reactors pect that stacking two-dimensional combustors may
are currently being developed, either to use in con- be as efficient a method to reduce heat losses as a
junction with piezoelectric and thermoelectric ma- three-dimensional configuration.
terials to produce power or to use as fuel reformers A thermoelectric power generator based on cata-
in fuel cells. The obvious advantage of these devices lytic combustion in a micromachined combustion
892 INVITED TOPICAL REVIEW

ratios varying from 0.35 to 0.7. Temperatures in the


catalytic surface are reported to be in the range of
650–1000 ⬚C, depending on the equivalence ratio.
Combustion efficiencies of the order of 97% have
been reported with n-dodecane. The application of
electrospraying for liquid fuel combustion in small-
scale combustors is an important contribution of this
work, since it appears that the technique is poten-
tially applicable in MEMS-scale devices.
A chemical fuel processing microsystem for power
generation in MEMS applications is being devel-
oped at Massachusetts Institute of Technology
(MIT) [42,43]. The microsystem will consist of in-
tegrated microfabricated catalytic reactors, flow sen-
sors, heaters, microvalves, micropumps, and con-
trollers. Several alternative technologies for
microscale fuel processing are being evaluated, in-
cluding hydrogen generation for fuel cells and ther-
moelectric and thermovoltaic power generation.
Gas Turbines/IC Engines
The MIT Gas Turbine Laboratory is developing a
MEMS-based gas turbine power generator with a
total volume of approximately 300 mm3, designed to
Fig. 7. Integrated catalytic combustor-thermoelectric produce 10–20 W [6,7]. This project can be viewed
micro–power generator [40]. as the pioneering research in MEMS-based micro-
scale power generation and is for most purposes the
most advanced. A schematic of the micro–gas tur-
chamber has been developed at the University of bine is shown in Fig. 8; it includes a radial com-
Michigan [40] (Fig. 7). The combustion chamber is pressor/turbine unit, a combustion chamber, and an
2 mm ⳯ 8 mm ⳯ 0.5 mm and is covered by a di- electrical generator incorporated in the compressor.
electric diaphragm that integrates polysilicon-Pt The compressor and the turbine, 12 mm in diameter
thermopiles. Using hydrogen/air mixtures, the de- and 3 mm thick, are made of traditional comple-
vice has produced power levels of the order of 1 lW/ mentary metal oxide semiconductor (CMOS) ma-
thermocouple. The researchers expect to be able to terials and designed to rotate at more than 1 million
reach power levels of 10 lW/thermocouple with rpm. Although the gas turbine has not produced
geometrical modifications that will increase the tem- positive power yet, the development of the different
perature gradients on the diaphragm. components is well advanced, with the turbine, com-
A microscale power device that includes a com- pressor, and combustor operating independently.
bustion-driven fuel reformer and fuel cell has been Heat transfer from the combustion chamber to the
developed at Pacific Northwest National Labs [41]. compressor/intake air together with the difficulty in
The microscale fuel reformer strips hydrogen from achieving good fabrication tolerances appear to be
a hydrocarbon fuel (such as methanol), and the hy- dominant problems keeping the efficiency of the tur-
drogen-rich stream is then fed to a fuel cell to gen- bine low. Some major accomplishments include the
erate electrical power. To date, a 10–500 mW steam achievement of rotation of the turbine at 1.3 million
reformer system has been assembled and fabricated rpm by using air bearings and the continuous opera-
with a reactor volume of around 0.5 mm3. In prelim- tion of a silicon-based combustor using H2/air
inary testing, the fuel reformer, utilizing methanol mixtures [44]. More recently, a catalytic silicon mi-
or butane, was able to provide up to 100 mW of crocombustor has been developed and operated
hydrogen at an efficiency of up to 4.8%. The device with hydrocarbon mixtures [45].
was able to operate independent of any additional At the UC Berkeley Combustion Laboratories, a
external heating, even during start-up. research project is currently underway to develop a
At Yale University, a mesoscale (⬃16 ⳯ 103 mm3) liquid hydrocarbon–fueled internal combustion ro-
catalytic combustor operating with a liquid fuel elec- tary (Wankel-type) engine with sizes that are well
trosprayed into the combustor chamber has been de- below those commercially available [15,46–48]. Two
veloped [24]. The combustor is to be coupled with engines are currently being developed, a mesoscale
direct energy conversion modules for power gener- ‘‘mini–rotary engine’’ designed to deliver power on
ation. Tests have been conducted with n-dodecane the order 30 W, and a microscale ‘‘micro–rotary en-
and JP8 jet fuel at rates of 10 g/h and equivalence gine’’ designed to produce power in the milliwatt
MICROPOWER GENERATION USING COMBUSTION 893

Fig. 8. Schematic of a silicon fabricated radial inflow gas turbine and photograph of radial compressor [6] and a MEMS
catalytic silicon microcombustor for hydrocarbon fuel that could be integrated with the turbine [45].

effects of sealing, ignition, design, and thermal man-


agement on efficiency. Testing has been performed
using hydrogen/air mixtures to facilitate ignition and
a range of spark and catalytic glow plug designs as
the ignition source. Net power output of up to 3.7 W
at 9000 rpm has been obtained, although with low
efficiency (⬃0.2%). A major reason for the low ef-
ficiency of the engine is its low compression ratio,
due to leakage between the rotor apex tip seals and
the housing and over the rotor faces. The size of the
engine is at the lower scale limit of EDM fabrication,
and it is difficult to attain the required tolerances for
good sealing, even using apex seals. Work is cur-
rently underway to improve sealing and compression
ratios by implementing different rotor apex tip and
rotor face seal designs [15,46].
As for the micro–rotary engine, the project aims
at developing an engine with a rotor in the milli-
meter-range size, using MEMS techniques. The ro-
tary engine is well suited for the MEMS fabrication
techniques because of its planar construction, re-
Fig. 9. EDM steel fabricated mini–rotary engine with a duced number of parts, and self-valving operation.
10 mm rotor [15] and MEMS SiC fabricated micro–rotary
The fabrication of two MEMS-based microengines,
engine with a 3 mm rotor [47].
one made of SiC with a 2.3 mm rotor (Fig. 9) and
another of Si with a 1 mm rotor, is well advanced
range. The mini–rotary engine is EDM-fabricated (Fig. 10) [47,48]. Initial measurement of the fabri-
from steel, with an epitrochoidal-shaped housing cated engine pieces indicates that the fabrication
and a rotor approximately 10 mm in size. The sim- process has produced viable engine parts for an ini-
plest version of one of these miniengines is shown tial investigation into sealing and material character-
in Fig. 9. A test bench for the mini rotary engine has istics. The housing spur gear and rotor through-
been developed, and tests have been conducted with holes have been fabricated using a self-masking
different mini–rotary engine designs to examine the method to produce structures 150 lm in diameter
894 INVITED TOPICAL REVIEW

underway or will soon follow. Thermal management


approaches applied, or being considered for appli-
cation, for these miniaturized rotary engines include
recirculating the exhaust around the combustion
section of the housing and packaging the engine in
an aerogel/vacuum container to reduce heat losses,
using catalytic surfaces to sustain combustion at low
temperatures, and using the exhaust heat to evapo-
rate the liquid fuel.
A free-piston ‘‘knock’’ microengine based on ho-
mogeneous charge compression ignition of hydro-
carbon fuels is being developed at Honeywell [49],
with a goal of generating ⬃10 W of electrical power
in a 103 mm3 package volume. In order to achieve
reliable autoignition of the fuel and to develop these
power densities, the engine must operate at kilo-
Fig. 10. MEMS silicon fabricated micro–rotary engine
hertz frequencies, placing requirements about the
with a 1 mm rotor [48]. allowable ignition delay times. These operating fre-
quencies generate nearly adiabatic compression and
expansion, since the timescale of the compression
and 75–100 lm in height. Issues still remain with
and expansion events are much less than the char-
the fabrication process. Significant lateral etching of acteristic thermal diffusion time, leading to a higher
the spur gear profile and non-uniform etch rates overall thermal efficiency. To date, compression ig-
across the wafer reduce the number of useable parts nition has been achieved in a piston/cylinder unit
fabricated during the manufacturing process. Mod- 3 mm in diameter operating for several cycles. Seal-
ifications to the fabrication process and surface tech- ing problems in the piston/cylinder appear to have
nology system (STS) etch recipe are being imple- limited the efficiency of the engine, and material re-
mented to reduce the Si etch uncertainties. A sistance has limited its life. Attempts to resolve the
method for obtaining real-time deep-reacting ion sealing problem by using a liquid piston are being
etching (DRIE) depths using a Fourier-transform IR pursued.
spectrometer is currently being investigated and in- A free-piston/cylinder electrical power generator
stalled. The current fabrication process can produce based on a ferromagnetic piston oscillating in a mag-
acceptable engine parts, but at the expense of low netic field is under development at Georgia Tech
yield. After fabrication of micro–rotary engine hous- [16]. The piston is propelled by the alternated com-
ings and rotors with a 100:1 sidewall straightness, the bustion of a hydrocarbon fuel/air mixture at each
rotor and housing will be manually assembled. This end of the cylinder (Fig. 11). The magnetic field is
first-generation micro–rotary engine will be tested produced by permanent magnetic MEMS arrays
by compressed air to determine engine leakage and that surround the cylinder assembly. The system also
wear characteristics. The Si engine will be tested incorporates MEMS igniters. A power generator
first, followed by SiC-coated Si pieces and then sil- with a 4.3 cm stroke and 13.4 cm3 displacement has
icon nitride (Si3N4)–coated parts. The objective of been developed, and 12 W of electrical power has
these tests is to investigate the long-term wear, lu- been extracted to date, although with poor efficiency
bricity, and toughness of the materials. Initial studies due in part to sealing problems in the piston cylinder
of microfluidics, heat transfer, and combustion are unit.

Fig. 11. Free-piston power generator using permanent magnets and integrated windings [16].
MICROPOWER GENERATION USING COMBUSTION 895

containing the thrust chambers where a lead styph-


nate propellant is housed, Si3N4 burst diaphragms,
and microresistors that are used as igniters. When
the resistor is energized, the propellant ignites, rais-
ing the pressure in the chamber and rupturing the
diaphragm. Initial testing has produced 10ⳮ4 N/s of
impulse and 100 W of power. An HTPB- and am-
monium perchlorate–fueled silicon sounding micro-
rocket with a mass of 1 g has been fabricated at UC
Berkeley (Fig. 13) to propel sensors to test the at-
mosphere [54]. The microrocket generated thrust
(peak, 4 mN) for an 8 s burn.
At MIT, a high-pressure, bipropellant microrocket
engine has been manufactured and tested. The
rocket weights 1.2 g, and with a chamber pressure
Fig. 12. MEMS fabricated array of ‘‘digitalp-propulsion’’ of 12 atm has generated 1 N thrust and delivered
microthrusters [53]. 750 W of thrust [55]. A liquid propellant micro-
thruster for small-spacecraft applications is being de-
veloped at Pennsylvania State University [56]. A pro-
totype microthruster has been successfully tested
with gaseous reactants. Propellants being explored
include environmental friendly energetic oxidizers,
with alcohol as fuel and water as the liquid carrier.

Concluding Remarks
The field of micropower generation, both electri-
cal and mechanical, is basically in a feasibility stage,
and although significant progress has been made in
the last few years, there are still a number of tech-
nological problems that must be resolved before the
field establishes itself. The approach followed to date
has been that of miniaturizing currently used large-
scale devices, which introduces many problems re-
lated to fluid flow in microchannels, heat and mass
Fig. 13. MEMS silicon fabricated solid fuel microrocket, transport in the microscale, combustion in small vol-
and rocket in operation [54]. umes, design, fabrication, and diagnostics. The so-
lution of these problems requires a range of funda-
A rotationally oscillating free-piston engine that mental and applied research and manufacturing
forms four distinct combustion chambers from a sin- development that precedes the development of the
gle base structure (housing) and a swing arm is under microdevices themselves.
development at the University of Michigan [50]. The The research needs unique to the development of
device operates on a four-stroke Otto cycle. The combustion systems at the small scale include mixing
swing arm (piston) is oscillatory, making mechanical and pumping in low Reynolds number flows, simu-
torque inefficient but relatively simple for direct lation of distributed reactions, low-temperature
electrical power generation. The design goals of this chemical kinetic modeling, investigative diagnostics,
mesoscale device are the production of 20 W using materials selection, fabrication of high-aspect-ratio
a liquid hydrocarbon with a projected system mass structures and complex geometries, assembly, test-
of 54 g and a volume of 17 ⳯ 103 mm3. ing, and characterization. Materials must be able to
sustain the high temperature, harsh chemical envi-
ronment, stress, and wear due to combustion events.
Microrockets
Emissions and noise must be reduced to acceptable
Several microrocket projects are currently under- levels. High-precision, high-aspect-ratio structures
way, most of them MEMS fabricated and designed are necessary to provide adequate sealing for high
for space applications such as microsatellite posi- compression ratios. A repeatable and simple assem-
tioning [51,52]. A solid-fueled microrocket fabri- bly technique must be developed in order to mass-
cated at TRW is shown in Fig. 12 [53]. It is designed produce these devices, and lastly, the devices need
for orbit and station keeping of picosatellites or mi- to be tested and characterized to optimize their per-
crospacecraft. It consists of a three-layer sandwich formance.
896 INVITED TOPICAL REVIEW

One can speculate that some of these problems l dynamic viscosity


could be avoided if the approach to develop micro- m kinematic viscosity
power devices would be based on enlarging small
(biorelated) systems rather than miniaturizing large Subscript
ones. However, it is likely that this approach will also
have its own problems. In any case, it is important a air
to keep in mind that, because the specific energy of c characteristic value
liquid hydrocarbon fuels is around 100 times larger g gas
than that of secondary batteries, there is a lot of i species i
room for development of microdevices that use com- r radiation
bustion to produce power. Furthermore, given the s solid (device housing)
current need for power (electrical and mechanical)
in the small scale, the potential payoff is very large. Superscript
— normalized variable or property with its char-
acteristic value
Nomenclature
A surface area Acknowledgments
Bi Biot number, Bi ⳱ lc (hco Ⳮ hr)/ks
D Diffusion coefficient The author would like to acknowledge the help and con-
Da Damkohler number, Da ⳱ ẇ⬙c lc/qcuc tribution of Dr. David Walther to the preparation of this
Fo Fourier number, Fo ⳱ ␣sc tc/lc2 manuscript; his contribution was essential to the comple-
g gravity tion of the work. He would also like to thank Professors
h combined convective and linearized radiation Forman Williams, Frederick Dryer, Paul Ronney, and De-
heat transfer coefficient, h ⳱ hco Ⳮ hr rek Dunn-Rankin and Dr. Howard Ross for their com-
hco convective heat transfer coefficient ments and suggestions to improve the manuscript. Thanks
hr linearized radiation heat transfer coefficient, are due to the directors and researchers of the Berkeley
hr ⳱ erF12(Ts Ⳮ Ta)(Ts2 Ⳮ Ta2) Sensors and Actuators Center (BSAC), particularly Profes-
Kn Knudsen number, Kn ⳱ _ f/lc sors Al Pisano and Dorian Liepmann and the UC Berkeley
Le Lewis number Le ⳱ ␣c/Dc Combustion Processes Laboratory (CPL) researchers and
lc characteristic length of the device visitors, particularly Professors Kenji Miyasaka and Kaoru
Pe Peclet number, Pe ⳱ lcuc/␣c Maruta, Dr. Kelvin Fu, and Mr. Aaron Knobloch and Fa-
p pressure bian Martinez. This work was partially supported by
p̄ normalized pressure, p̄ ⳱ p/pc DARPA under contract no. DABT63-98-1-0016.
pc characteristic pressure
q heat rate
REFERENCES
Re Reynolds number, Re ⳱ uclc/tc
t time 1. Allen, D., Almond, H., and Logan., P., ‘‘Technical
t̄ normalized time, t̄ ⳱ t/tc Comparison of Micro-Electrodischarge Machining,
tc characteristic time and Copper Vapor Laser Machining for the Fabrica-
T temperature tion of Ink Jet Nozzles’’ in Proceedings of the Society
T̄ normalized temperature, T̄ ⳱ T/Tc for Optical Engineering, Vol. 4019, 2000, p. 531.
Tc characteristic temperature 2. Reyntjens, S., and Puers, R. J., Michromech. Microeng.
u velocity 11:287–300 (2001).
ū normalized velocity, ū ⳱ u/uc 3. Madou, M., Fundamentals of Microfabrication, CRC
uc characteristic velocity Press, Boca Raton, FL, 1997.
ẇ⬙ reaction rate 4. Kovacs, G. T. A., Micromachined Transducer Source-
¯
ẇ⬙ normalized reaction rate, ẇ⬙¯ ⳱ ẇ⬙/ẇ⬙c book, McGraw-Hill, New York, 1998.
ẇ⬙c characteristic reaction rate 5. Warneke, B., Last, M., Liebowitz, B., and Pister,
x spatial coordinate K. S. J., Computer Magazine 34(1):44 (2001).
x̄ normalized spatial coordinate, x̄ ⳱ x/xc 6. Epstein, A. H., Senturia, S. D., Al-Midani, U., et al.,
xc characteristic spatial coordinate ‘‘Micro-Heat Engines, Gas Turbines and Rocket En-
yi mass fraction species i gines—The MIT Microengine Project,’’ paper 97-1773,
ȳi normalized mass fraction of species i, ȳi ⳱ Twenty-Eighth AIAA Fluid Dynamics Conference,
yi/yic 1997.
yic characteristic mass fraction of species i Greek 7. Epstein, A. H., Senturia, S. D., Anathasuresh, G., et
␣ thermal diffusivity al., ‘‘Power MEMS and Microengines,’’ Proceedings of
k thermal conductivity the IEEE Transducers ’97 Conference, Chicago, IL,
kf mean free path June 1997.
MICROPOWER GENERATION USING COMBUSTION 897

8. Pisano, A., Microelectromechanical Systems (MEMS) 27. Liu, R. H., Stremler, M. A., Sharp, K. V., Olsen,
Program, DARPA/ETO, BAA 97-43, Washington, DC, M. G., Santiago, J. G., Adrian, R. J., and Beebe, D. J.,
1997. J. Microelectromechanical Systems 9(2):190–197
9. Tang, W., Micro Power Generation (MPG), DARPA (2000).
MTO Program, BAA 01-09, Washington, DC, 2001. 28. Zahn, J. D., Deshmukh, A. A., Papavasiliou, A. P., Pi-
10. Weinberg, F., Proc. Combust. Inst. 15:1 (1974). sano, A. P., and Liepmann, D., ‘‘An Integrated Micro-
11. Tortora, G. J., Introduction to the Human Body, 2nd fluidic Device for the Continuous Sampling and Anal-
ed., HarperCollins, New York, 1991. ysis of Biological Fluids,’’ Proceedings of the 2001
12. Maruta, K., Takeda, K., Sitzki, L., Borer, K., Ronney, ASME—IMECE, American Society of Mechanical En-
P. D., Wussow, S., and Deutschmann, O., ‘‘Catalytic gineers, New York, November 11–16, 2001.
Combustion in Microchannel for MEMS Power Gen- 29. Jones, A. R., Lloyd, S. A., and Weinberg, F. J., Proc.
eration,’’ Third Asia-Pacific Conference on Combus- R. Soc. London, Ser. A 360:97–115 (1978).
tion, Seoul, Korea, June 24–27, 2001. 30. Lloyd, S. A., and Weinberg, F. J., Nature 251:47–49
13. Jones, E., ‘‘Microscale Combustor/Evaporator Devel- (1974).
opment,’’ in DARPA/MEMS Project Summaries, Wash- 31. Sitzki, L., Borer, K., Wussow, S., Schuster, E., Maruta,
ington, DC, August 2001. K., Ronney, P., and Cohen, A., ‘‘Combustion in Micro-
14. Vican, J., Gajdeczko, B. F., Dryer, F. L., Milius, D. L., scale Heat-Recirculating Burners,’’ paper AIAA-2001-
Aksay, I. A., and Yetter, R. A., Proc. Combust. Inst. 1087, Thirty-Eighth AIAA Space Sciences and Exhibit,
29:909–916 (2002). Reno, NV, 2001.
15. Fu, K., Knobloch, A., Martinez, F., Walther, D., Fer- 32. Cooley, B., Walther, D., and Fernandez-Pello, A. C.,
nandez-Pello, A. C., Pisano, A., Liepmann, D., Mi- ‘‘Exploring the Limits of Microscale Combustion,’’
yaska, K., and Maruta, K., ‘‘Design and Experimental Western States Section Fall Technical Meeting of the
Results of Small-Scale Rotary Engines,’’ Proceedings Combustion Institute, Irvine, CA, October 25, 26,
of the 2001 International Mechanical Engineering 1999.
Congress and Exposition (IMECE), American Society 33. Peterson, R. B., and Hatfield, J. M., ‘‘A Catalytically
of Mechanical Engineers, New York, November 11– Sustained Microcombustor Burning Propane,’’ Pro-
16, 2001. ceedings of the 2001 International Mechanical Engi-
16. Allen, M. G., ‘‘Ceramic Micromachining Technology,’’ neering Congress and Exposition (IMECE), American
DARPA Workshop on Combustion-Based MEMS Society of Civil Engineers, New York, November 11–
Power Generation on the Microscale, for the Micro- 16, 2001.
scale, Washington, DC, 1998. 34. Masel, R., and Shannon, M., Microcombustor Having
17. Savinell, R., ‘‘A Micro Hydrogen-Air Fuel Cell’’ in Submillimeter Critical Dimensions, Patent #
DARPA/MEMS Project Summaries, Washington, DC, US06193501, 2001.
August 2001. 35. Sirignano, W. A., Pham, T. K., and Dunn-Rankin, D.,
18. Lee, S., Nelson, D., Svrcek, M., Edwards, C. F., and Proc. Combust. Inst. 29:925–931 (2002).
Bowman, C. T., ‘‘Mesoscale Burner Arrays for Gas 36. Sitzki, L., Borer, K., Schuster, E., Ronney, P. D., and
Turbine Reheat Applications,’’ 2002 Spring Meeting, Wussow, S., ‘‘Combustion in Microscale Heat-Recir-
WSS/CI, San Diego, CA, March 25–26, 2002. culating Burners,’’ Proceedings of the Third Asia-Pa-
19. Hetsroni, G., Mosyak, A., and Segal, Z., ‘‘Two Phase cific Conference on Combustion, Seoul, Korea, 2001.
Flow in Microchannels,’’ Proceedings of the 2001 37. Peterson, R. B., ‘‘Small Packages,’’ in Mechanical En-
ASME IMECE, American Society of Mechanical En- gineering, American Society of Mechanical Engineers,
gineers, New York, November 11, 2001. 2001, pp. 58–61.
20. Collier, J. C., Convective Boiling and Condensation, 38. Maruta, K., Takeda, K., Ahn, J., Borer, K., Sitzki, L.,
McGraw-Hill, New York, 1972. Ronney, P. D., and Deutschmann, O., Proc. Combust.
21. Rajan, N., Mehregany, M., Zorman, C. A., Stefanescu, Inst. 29:957–963 (2002).
S., and Kicher, T. P., J. Microelectromechanical Sys- 39. Weinberg, F. J., Rowe, D. M., Min, G., and Ronney,
tems IEEE 8:251–257 (1999). P., Proc. Combust. Inst. 29:941–947 (2002).
22. Chen, G., and Gomez, A., Combust. Sci. Technol. 40. Zhang, C., Najafi, K., Bernal, L. P., and Washabaugh,
115:177 (1996). P. D., ‘‘An Integrated Combustor-Thermoelectric Mi-
23. Ganan-Calvo, A. M., J. Fluid Mech. 335:165–188 cro Power Generator,’’ Proceedings of the Eleventh In-
(1997). ternational Conference on Solid State Sensors and Ac-
24. Kyritsis, D. C., Guerrero-Arias, I., Roychoudhury, S., tuators, Munich, Germany, June 10–14, 2001.
and Gomez, A., Proc. Combust. Inst. 29:965–972 41. Holladay, J. D., Jones, E. O., Phelps, M., and Hu, J.,
(2002). ‘‘High-Efficiency Microscale Power Using a Fuel Pro-
25. Chigier, N., et al., unpublished data, 2002. cessor and Fuel Cell,’’ paper 4559-20, SPIE Micro-
26. Lowe, H., et al., ‘‘Micromixing Technology,’’ IMRET machining and Microfabrication, San Francisco, CA,
4: Fourth International Conference on Microreaction October 21–24, 2001.
Technology, AIChE Meeting, AIChE, Atlanta, GA, 31, 42. Srinivasan, R., Hsing, I.-M., Berger, P. E., Jensen,
2000. K. F., Firebaugh, S. L., Schmidt, M. A., Harold, M. P.,
898 INVITED TOPICAL REVIEW

Lerou, J. J., and Ryley, J. F., AIChE J. 43:3059–3069, on Combustion, The Combustion Institute, Edin-
(1997). burgh, UK, July 30–August 4, 2000; “MEMS Free Pis-
43. Arana, L. R., Schaevitz, S. B., Franz, A. J., Jensen, ton Knock Engine,” poster presentation, DARPA
K. F., and Schmidt, M. A., ‘‘A Microfabricated Sus- MEMS PI Meeting, Broomfield, CO, August 29, 2001.
pended-Tube Chemical Reactor for Fuel Processing,’’ 50. Dahm, W. A., Ni, J., Mijit, K., Mayor, R., Qiao, G.,
MEMS 2001, Las Vegas, NV, January 20–25, 2002. Benjamin, A., Gu, Y., Lei, Y., and Papke, M., ‘‘Micro
44. Mehra, A., and Waitz, I. A., ‘‘Development of a Hy- Internal Combustion Swing Engine (MICSE) for Por-
drogen Combustor for a Microfabricated Gas Turbine table Power Generation Systems,’’ AIAA paper 2002-
Engine,’’ Solid State Sensor and Actuator Workshop, 0722, Fortieth Aerospace Sciences Meeting, Reno,
Hilton Head, GA, 1998. NV, January 14–17, 2002.
45. Spadaccini, C. M., Zhang, X., Cadou, C. P., Miki, N., 51. Rossi, C., Orieux, S., Larangot, B., et al., ‘‘Design Fab-
and Waitz, I. A., ‘‘Development of a Catalytic Silicon rication and Modeling of Solid Propellant Micro-
Micro-Combustor for Hydrocarbon-Fueled Power rocket—Application to Micropropulsion,” in Sensors
MEMS,’’ MEMS 2002 IEEE International Confer- and Actuators, Vol. A99, Elsevier, Amsterdam, 2002,
ence, Las Vegas, NV, January 20–25, 2002. p. 25.
46. Fu, K., Walther, D., Fernandez-Pello, A. C., Liep- 52. Micci, M. M., and Ketsdever, A. D., (eds), Progress in
mann, D., and Miyasaka, K., ‘‘Preliminary Investiga- Astronautics and Aeronautics, Vol. 187, AIAA, Reston,
tion of a Small-Scale Rotary Internal Combustion En- VA, 2000.
gine,’’ Western States Section Fall Technical Meeting 53. Lewis Jr., D. H., Janson, S. W., Cohen, R. B., and An-
of the Combustion Institute, Irvine, CA, October 25, tonsson, E. K., Sens. Actuators Physical 80(2):143–154
26, 1999.
(2000).
47. Fu, K., Knobloch, A., Cooley, B., Walther, D., Liep-
54. Lindsay, W., Teasdale, D., Milanovic, V., Pister, K., and
mann, D., Fernandez-Pello, A. C., and Miyasaka, K.,
Fernandez-Pello, A. C., ‘‘Thrust and Electrical Power
‘‘Micro-Scale Combustion Research for Applications
from Solid Propellant Microrockets,’’ Proceedings of
to MEMS Rotary IC Engines,’’ paper NHTC2001-
the IEEE Fourteenth International Conference on
11212, Proceedings of the Thirty-Fifth ASME 2001 Na-
tional Heat Transfer Conference, Anaheim, CA, 2001. MicroElectroMechanical Systems, Interlaken, Switzer-
48. Fu, K., Knobloch, A., Martinez, F., Walther, D., Fer- land, 2001, pp. 606–610.
nandez-Pello, A. C., Pisano, A., and Liepmann, D., 55. London, A. P., Ayon, A. A., Epstein, A. H., Spearing,
‘‘Design and Fabrication of a Silicon-Based MEMS S. M., Harrison, T., Peles, Y., and Kerrebrock, J. L.,
Rotary Engine,’’ Proceedings of the 2001 ASME Inter- Sens. Actuators, A 92:351–357 (2001).
national Mechanical Engineering Congress and Expo- 56. Yetter, R. A., Yang, V., Milius, D. L., Aksay, I. A., and
sition (IMECE), American Society of Mechanical En- Dryer, F. L., ‘‘Development of a Liquid Propellant Mi-
gineers, New York, November 11–16, 2001. crothruster for Small Spacecraft,’’ Eastern States Sec-
49. Yang, W., ‘‘MEMS Free Piston Knock Engine,’’ poster tion Meeting of the Combustion Institute, Hilton
presentation, Twenty-Eighth International Symposium Head Island, SC, December 2–5, 2001.

COMMENTS
William A. Sirignano, University of California, Irvine, and microscales, what parameters would be the most im-
USA. The discussion has been limited to MEMS-fabricated portant to measure for the understanding of tiny engines
designs, 100 watts or less of engine power, and laminar in terms of a list of priorities?
flows. For combustors of the desired volume, circular tubes Each of the speakers in today’s session discussed the use
rather than chips would have a smaller surface/volume ra- of liquid fuels because of the energy density advantages
tio providing heat loss. Within the range of handheld or and the need to ‘‘defeat the battery.’’ Are there any com-
pocket-fitting engine sizes, it is possible to develop engines pelling reasons to build a miniature engine that burns a
that produce several kilowatts of power and contain tur- gaseous fuel (e.g., hydrogen or natural gas)?
bulent combustor flows.

Author’s Reply. They would be the same as those for big


Author’s Reply. I agree. Actually there are multiple ap-
engines with emphasis on some specific ones related to the
plications for portable power in the kilowatt range.
issues involved in reducing the scale of the engine. Par-
ticularly important are the pressure history in the combus-
● tion chamber, development (ignition and progress) and
characteristics of the combustion process in the combus-
Gregory J. Fiechtner, Sandia National Laboratories, tion chamber, completeness of combustion and character-
USA. If diagnostics used commonly for large-scale engines istics of the exhaust gases, engine housing temperature
were to be modified for the study of combustion at meso field, and heat losses through the engine housing.
MICROPOWER GENERATION USING COMBUSTION 899

A miniature engine that uses a gaseous fuel would lose parts? You have clearly indicated that absence of moving
some of the energy density advantage of using a liquid fuel. parts is preferable, however the bulk of activity in the field
However, it still has the advantage of a continuous opera- consists of miniaturized I.C. engines. What is the funda-
tion (no need to recharge) and distributed power (no need mental merit is such an approach?
for an electrical power source), which can be essential for
Author’s Reply. The merit of miniaturized I.C. engines
some specific applications.
is that since their large counterparts have relatively large
efficiency, there is the potential for developing miniatur-
● ized engines that may also have significant efficiency. On
the other hand, since the efficiency of the large non-moving
Dimitrios Kyritsis, Yale University, USA. Could you of- parts devices is currently low, it will be necessary to not
fer an additional comment on the comparison between only develop the miniaturized device but also improve the
small-scale devices that operate with and without moving corresponding process of power generation.

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