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16.aplikasi Pembakaran Skala Micro-Meso
16.aplikasi Pembakaran Skala Micro-Meso
883–899
A. CARLOS FERNANDEZ-PELLO
Department of Mechanical Engineering
University of California, Berkeley
Berkeley, CA 94720-1740, USA
The push toward the miniaturization of electromechanical devices and the resulting need for micropower
generation (milliwatts to watts) with low-weight, long-life devices has led to the recent development of the
field of microscale combustion. The concept behind this new field is that since batteries have low specific
energy and liquid hydrocarbon fuels have a very high specific energy, a miniaturized power-generating
device, even with a relatively inefficient conversion of hydrocarbon fuels to power, would result in increased
lifetime and/or reduced weight of an electronic or mechanical system that currently requires batteries for
power. In addition to the interest in miniaturization, the field is also driven by the potential fabrication of
the devices using microelectromechanical systems or rapid prototyping techniques, with their favorable
characteristics for mass production and low cost. The micro power generation field is very young and still
is, in most cases, in the feasibility stage. However, considering that it is a new frontier of technological
development, and that only a few projects have been funded, it can be said that significant progress has
been made to date. Currently, there is consensus, at least among those working in the field, that combustion
in the microscale is possible with proper thermal and chemical management. Several mesoscale and mi-
croscale combustors have been developed that appear to operate with good combustion efficiency. Some
of these combustors have been applied to energize thermoelectric systems to produce electrical power,
although with low overall efficiency. Several turbines/engines have also been, or are being, developed,
some of them currently producing positive power, also with low efficiency to date. Microrockets using solid
or liquid fuels have been built and shown to produce thrust. Hydrogen-based microsize fuel cells have
been successfully developed, and there is a need to develop reliable reformers (or direct-conversion fuel
cells) for liquid hydrocarbons so that the fuel cells become competitive with batteries. In this work, some
of the technological issues related to meso- and microscale combustion and the operation of thermochem-
ical devices for power generation will be discussed. Some of the systems currently being developed will
be presented and described.
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Fig. 2. Specific energy for iso-octane and several primary and secondary battery technolgies.
MICROPOWER GENERATION USING COMBUSTION 885
own environmental issues, and their production and there is a need to produce reliable reformers (or
disposal present an environmental hazard. direct-conversion fuel cells) so that they can be used
The power-generation devices addressed in the with liquid hydrocarbons and can become competi-
present review are those that aim to generate power tive with batteries. Still not looked at is the potential
in the range of a few watts to milliwatts. This is in complementarity of the different systems (cogener-
contrast with the so-called microturbines, which ation), such as using the exhaust heat from engines
generate power of the order of kilowatts and are not to run thermoelectric generators, fuel-cell reform-
‘‘micro’’ in the present sense, but rather in the sense ers, or Stirling engines. The combined systems could
of being smaller than their larger counterparts. result in improved overall conversion efficiencies.
Power generation in the watts range has multiple Also worth mentioning is that small-scale combus-
applications, such as electronic devices (laptops, tion has other useful applications than power gen-
phones, etc.) and miniaturized mechanical systems eration and heat production for use in power cycles.
(small robots, rovers, airplanes, etc.). The corre- Positioning of localized heat is an example of its po-
sponding combustion devices are of the order of tential applications. Another interesting example is
1 cm in size (mesoscale), and their microfabrication the use of arrays of mesoscale burners to produce
techniques are relatively conventional (EDM), in distributed combustion in large-scale gas turbine
combustors, which has the potential for interturbine
some cases with some MEMS components. Power
reheat, and for premix or highly vitiated combustion,
generation in the milliwatt range (microscale) has its
to reduce NOx [18].
application primarily in microelectronic components Some of the technological issues related to micro-
(sensors, transmitters, etc.), with the ultimate goal scale combustion and thermochemical devices for
of incorporating the power-generation device into power generation are discussed below. Many of the
the microelectronic component. These power-gen- systems currently being developed are also pre-
eration devices are constructed using primarily sented and briefly discussed.
MEMS. The ultimate goal is to have ‘‘power gen-
eration in a chip.’’ The system would then incorpo- Thermophysical Issues
rate in the same unit the power device, the micro-
processor to control the overall system, and some The characteristic length of the microcombustors
being developed to date, even in MEMS-size sys-
sort of sensor/emitter or actuator.
tems, is sufficiently larger than the molecular mean-
The micropower generation field is young (4–6
free path of the air and other gases flowing through
years) because its interest has resulted from the re- the systems that the physical-chemical behavior of
cent development of fabrication techniques to min- the fluids is fundamentally the same as in their mac-
iaturize mechanical devices and still is, in most cases, roscale counterparts. For example, the Knudsen
in the feasibility stage. However, considering that it number for air flowing through a 0.1 mm wide chan-
is a new frontier of technological development and nel is of the order of 10ⳮ3, which is much smaller
that only a few projects have been funded to date than that for free-molecule flow (Kn ⬎ 1). Conse-
(primarily by government agencies that fund ad- quently, the standard hypotheses of thermofluids
vanced conceptual projects, such as Defense Ad- such as the no-slip condition and the continuum me-
vanced Research Projects Agency (DARPA) [8,9]), dium will still apply. However, the small size of the
it can be said that significant and encouraging prog- microdevices or their components causes particular
ress has been made. Several microcombustors have characteristics of the fluid mechanics, heat transfer,
been fabricated that appear to operate with good and combustion involved in the device operation.
combustion efficiency [12–14]. Some of these com- Some of the scaling issues involved in microcom-
bustors have been applied to energize thermoelec- bustors can be understood by normalizing the con-
tric systems to produce power. The system efficiency servation equations of momentum, energy, and spe-
is currently too low, but the limitation appears to be cies in terms of the characteristic length and
in the thermoelectric component and not in the parameters of the device and analyzing their terms
combustion process itself. Several turbines/engines as the length scale is reduced. The normalized one-
have also been or are being developed, some of them dimensional form of the governing equations for the
currently producing positive power, although again gas and solid phase and their relevant boundary con-
with low efficiency [6,15,16]. Here, the problem ap- ditions can be written as (symbols are defined in the
pears to be in fabrication and thermal management Nomenclature section)
that either limit the tolerances in moving parts lc ū ū p 1 p̄
(leakage, low compression ratio) or cause reduced Ⳮ ū ⳱ ⳮ c2
tc uc t¯ x̄ qc uc q̄ x̄
efficiency of individual components (compressor,
combustion chamber). Fuel cells are also being de- 1 2ū gl
veloped [17], and although not a combustion device, Ⳮ m̄ 2 Ⳮ 2c (1)
Re x̄ uc
they have issues that are of interest to the combus-
tion community. Although hydrogen-based micro- lc T¯ T¯ 1 2T¯ Q ¯
Ⳮ ū ⳱ ␣¯ Ⳮ Da ¯ ẇ⬙ (2)
fuel cells have been successfully developed [17], tc uc t¯ x̄ Pe x̄2 CpTc
886 INVITED TOPICAL REVIEW
10%, the volumetric flow rate of gaseous mixture will To increase fuel evaporation or to inject the fuel
be approximately 0.4 L/s. Assuming a 5 mm diam- into the combustion chamber, it may be convenient
eter intake tube, the Reynolds number will be of the to atomize the liquid. As the devices become smaller,
order of 5000 or below, depending on the gas tem- the atomization device and the droplets must also be
perature. Similarly, for a 100 mW microscale device reduced in size. Since the surface energy of a droplet
with a 0.5 mm diameter intake, the Reynolds num- is inversely proportional to the radius of curvature,
ber will be around 50. Thus, the flow will be pri- a decrease in the system’s dimensions will increase
marily laminar for the small devices and conse- the pressure and energy requirements for atomiza-
quently the mixing of different species will be tion. Although some MEMS-based simple atomizers
primarily by diffusion. Also, as stated above, viscous (plain orifice type) have been developed [21], it ap-
effects will be important, which together with the pears that more elaborate devices or techniques to
large aspect ratios in the microchannels implies that produce micron-size droplets that will evaporate and
frictional losses will be high and that increased mix with the air in the available microscale residence
pumping will be required. On the other hand, vis- time will be needed. MEMS-based microelectro-
cous forces help in some of the problems character- spray atomizers [22,23] appear to be good potential
istic of these devices, such as leakage of gases candidates for microcombustors [24,25].
through joints or through moving surfaces. This The low Reynolds number coupled with the pla-
could be important in internal combustion (IC) en- nar nature of MEMS devices makes mixing of the
gines, since their efficiency is strongly dependent on reactants a potential problem in microsystems. Al-
the compression ratio, which will be affected by the though the small diameter of the channels helps
leakage at the piston (rotor)/housing surfaces. their diffusive mixing, the residence time of the flu-
Unexpected behavior may result in those cases ids in the channels is also small and may be insuffi-
with extremely small length scales (⬃lm), such as in cient to ensure complete mixing. For example, for a
some MEMS devices or their components. The most gaseous fuel/air mixture flowing through a 0.5 mm
obvious effect is that the flow in these cases operates channel, the diffusion time will be of the order of
in the near-Stokesian regime where the Reynolds 0.02 s, and if flow velocity is of the order of 1 m/s,
number is often less than 1. Small changes in tem- the channel length would have to be 25 mm to en-
perature, for example, can significantly change the sure diffusive mixing. This channel length may be
volumetric flow rate as can fluid-wall interactions too long for the device or result in significant pres-
that are normally ignored in macroscopic flows. Also, sure losses. Thus, in some cases where mixing of
species may need to be enhanced, different dynamic
the small length scales of the channels result in high-
mixing approaches (flow instabilities, ultrasound,
velocity gradients in the fluid. As seen from the
etc.) may have to be implemented, even though they
aforementioned boundary conditions, this results in
will introduce fabrication complexities and will con-
high wall frictional losses and high convective heat
sume valuable energy. To date, several approaches
transfer coefficients. These in turn can result in large
have been used to increase mixing rates, primarily
pressure losses, high heat transfer to or from the of liquids [26–28]. The main problems with these
fluid to the wall, and enhanced diffusive mixing. approaches are fabrication complexity, system size,
As in their large-scale counterparts, the micro- and increased pressure drops. Although these works
combustors must use the ambient air as the source are geared to mix liquids, similar concepts could be
of oxygen to both reduce volume and to maintain applied to mixing gases.
their performance edge in energy density. This im-
plies that the liquid hydrocarbon must be evaporated
and mixed with the air prior to entering the com-
bustion chamber in premixed systems or injected di- Thermal
rectly in the combustion chamber in non-premixed At the length scales of microcombustion devices,
systems. The small length scales have a large impact heat transfer by natural convection becomes small
on the dynamics and energy requirements associated because the induced buoyant flow is small (equa-
with phase change and two-phase flows. It has been tion 1). However, heat transfer by conduction
observed, for example, that the phase change from through the gas to the surrounding surfaces and by
liquid to vapor in MEMS-size channels occurs forced convection in the intake and exhaust channels
abruptly and in an unstable fashion [19], quite dif- and in the combustion chamber is significant be-
ferently from the transition observed in large tubes cause the temperature gradients are higher as the
[20]. This is partially due to the large surface area– characteristic length is decreased. Heat transfer by
to–volume ratio in microchannels that enhances the radiation also increases as the characteristic length
nucleation and wetting effects at the wall and to the decreases because of the large view factor. In addi-
behavior of bubbles that is strongly affected by the tion, as the scale of the device is reduced, the sur-
small length scales and significantly differs from face-to-volume ratio increases, which, combined
macroscopic behavior. with the enhanced heat flux, results in heat transfer
888 INVITED TOPICAL REVIEW
effects becoming very important at the surface or the incoming air would be considerably larger than
boundary of the device. This has advantages in com- the one calculated above (ka/lc in equation 5 would
ponents that use heat transfer in their operation, be replaced by a heat transfer coefficient, ha ⬎
such as evaporators or heat exchangers, since it en- 100 W/m2 K). The enhanced heat transfer to the
hances their heat-exchanging characteristics. It may incoming gas in the intake manifold of the combus-
become problematic, however, in devices where sur- tor is of particular concern in devices using premixed
face heat losses may deter their performance, as may reactants for combustion. While preheating the re-
occur with combustion chambers due to wall actants will aid in sustaining combustion to scales
quenching. smaller than the quenching distance, it may result in
It should be noted that the small buoyancy and the the autoignition of the mixture in the inlet port.
low thermal conductivity of air (ka ⬃ 0.03 W/mK) ren- Thus, insulating measures must be taken to control
der the heat losses from a combustor relatively small the amount of heat that will be transferred to the
when compared to its total heat generation. The order incoming fuel/air mixture. Furthermore, heating of
of magnitude of the heat losses from a combustor to the reactants in the intake manifold will result in a
the surrounding air can be obtained with a simple one- smaller mass charge in the combustion chamber due
dimensional, steady-state calculation. The heat flux to the reduced density, thus reducing the potential
from a flowing hot gas in the combustion chamber, net power output of the device. The lower density
through the combustor housing, to the still ambient air will also result in higher compression work per unit
surrounding the combustor can be approximately cal- mass and consequently lower overall system efficien-
culated by cies. This is particularly critical in gas turbines, since
the power requirements of the compressor deter-
q Tg ⳮ Ta mine their overall efficiency. In these cases, thermal
⳱ (5)
A 1 l 1 management becomes essential in order to reduce
Ⳮ c Ⳮ heat losses and increase the performance of the de-
hg ks ka
Ⳮ hra vices.
lc
As noted earlier, most microdevices tend to op-
where the subscript ‘‘g’’ represents the hot gases in erate at a relatively uniform temperature because of
the combustion chamber and the subscript ‘‘a’’ rep- their small size. For example, the Biot number for a
resents the air surrounding the combustor. Consid- steel or a silicon device with a length scale of 10 mm,
ering, for example, a mesosize combustor with a and subjected to moderate convection and radiation
characteristic length of lc ⳱ 20 mm capable of pro- (combined convection and radiation heat transfer
viding around 50 W of power [15], a combustion gas coefficient of 100 W/m2K), will be of the order of
and ambient air temperature of Tg ⳱ 1000 ⬚C, and 0.002, which is considerably smaller than that nor-
Ta ⳱ 20 ⬚C, respectively, a heat transfer coefficient mally considered sufficient for a lumped heat trans-
of the gases flowing through the combustion cham- fer analysis (Bi ⬍ 0.1). Thus, a uniform temperature
ber of hg ⳱ 100 W/m2K, (convection and radiation), could approximately describe the device’s internal
a SiC combustor housing (ks ⳱ 500 W/mK), and a temperature (boundary condition for equation 2).
linearized radiative heat transfer coefficient from the Reduced thermal gradients will reduce thermal ex-
housing to the ambient air of hra ⳱ 130 W/m2K, pansion stresses and subsequent misalignments in
equation 5 gives for the heat flux 0.05 W/mm2. As- moving parts. However, it introduces potential prob-
suming that the combustor’s combustion chamber lems whenever large thermal gradients are needed
has a 25 mm2 area, the heat loss from the combus- for high performance of the device, such as in ther-
tion gases would be around 1.3 W, that is ⬃3% of moelectric generators. This is also a problem for gas-
the combustor output. Several observations can also cycle-type devices (heat engines) because their effi-
be deduced from equation 5. One is that because of ciency depends on the ratio of the high- and
the large thermal conductivity of the housing (SiC, low-temperature reservoirs, and it may be difficult
steel, etc.), the solid conduction term is negligible at to attain or maintain a large temperature ratio. The
these small scales, and that heat conduction through solution of these problems again requires complex
air is also small compared with radiation. Thus, in thermal management.
order to reduce the heat losses from the combustion Regarding thermal management, complex struc-
chamber, it is important to reduce radiative heat loss tures with highly insulating materials, vacuum gaps,
from the combustor housing to the ambient air. For and/or complex thermal coatings may be needed to
this purpose, a material like silica aerogel would be insulate and reduce heat transfer from high- to low-
good to insulate the combustor since it has excellent temperature regions. However, thermal manage-
insulating properties both for conduction and radi- ment is not only restricted to spatial temperature
ation. gradients, but also to transient heat transport. Very
If, instead of still air, there is a forced flow as in different characteristic time in the gas or the solid
an intake manifold or in a gas turbine compressor, or in the periodic heat input from intermittent com-
the heat transfer from the combustion chamber to bustion may result in quasi-insulating conditions at
MICROPOWER GENERATION USING COMBUSTION 889
Fig. 8. Schematic of a silicon fabricated radial inflow gas turbine and photograph of radial compressor [6] and a MEMS
catalytic silicon microcombustor for hydrocarbon fuel that could be integrated with the turbine [45].
Fig. 11. Free-piston power generator using permanent magnets and integrated windings [16].
MICROPOWER GENERATION USING COMBUSTION 895
Concluding Remarks
The field of micropower generation, both electri-
cal and mechanical, is basically in a feasibility stage,
and although significant progress has been made in
the last few years, there are still a number of tech-
nological problems that must be resolved before the
field establishes itself. The approach followed to date
has been that of miniaturizing currently used large-
scale devices, which introduces many problems re-
lated to fluid flow in microchannels, heat and mass
Fig. 13. MEMS silicon fabricated solid fuel microrocket, transport in the microscale, combustion in small vol-
and rocket in operation [54]. umes, design, fabrication, and diagnostics. The so-
lution of these problems requires a range of funda-
A rotationally oscillating free-piston engine that mental and applied research and manufacturing
forms four distinct combustion chambers from a sin- development that precedes the development of the
gle base structure (housing) and a swing arm is under microdevices themselves.
development at the University of Michigan [50]. The The research needs unique to the development of
device operates on a four-stroke Otto cycle. The combustion systems at the small scale include mixing
swing arm (piston) is oscillatory, making mechanical and pumping in low Reynolds number flows, simu-
torque inefficient but relatively simple for direct lation of distributed reactions, low-temperature
electrical power generation. The design goals of this chemical kinetic modeling, investigative diagnostics,
mesoscale device are the production of 20 W using materials selection, fabrication of high-aspect-ratio
a liquid hydrocarbon with a projected system mass structures and complex geometries, assembly, test-
of 54 g and a volume of 17 ⳯ 103 mm3. ing, and characterization. Materials must be able to
sustain the high temperature, harsh chemical envi-
ronment, stress, and wear due to combustion events.
Microrockets
Emissions and noise must be reduced to acceptable
Several microrocket projects are currently under- levels. High-precision, high-aspect-ratio structures
way, most of them MEMS fabricated and designed are necessary to provide adequate sealing for high
for space applications such as microsatellite posi- compression ratios. A repeatable and simple assem-
tioning [51,52]. A solid-fueled microrocket fabri- bly technique must be developed in order to mass-
cated at TRW is shown in Fig. 12 [53]. It is designed produce these devices, and lastly, the devices need
for orbit and station keeping of picosatellites or mi- to be tested and characterized to optimize their per-
crospacecraft. It consists of a three-layer sandwich formance.
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COMMENTS
William A. Sirignano, University of California, Irvine, and microscales, what parameters would be the most im-
USA. The discussion has been limited to MEMS-fabricated portant to measure for the understanding of tiny engines
designs, 100 watts or less of engine power, and laminar in terms of a list of priorities?
flows. For combustors of the desired volume, circular tubes Each of the speakers in today’s session discussed the use
rather than chips would have a smaller surface/volume ra- of liquid fuels because of the energy density advantages
tio providing heat loss. Within the range of handheld or and the need to ‘‘defeat the battery.’’ Are there any com-
pocket-fitting engine sizes, it is possible to develop engines pelling reasons to build a miniature engine that burns a
that produce several kilowatts of power and contain tur- gaseous fuel (e.g., hydrogen or natural gas)?
bulent combustor flows.
A miniature engine that uses a gaseous fuel would lose parts? You have clearly indicated that absence of moving
some of the energy density advantage of using a liquid fuel. parts is preferable, however the bulk of activity in the field
However, it still has the advantage of a continuous opera- consists of miniaturized I.C. engines. What is the funda-
tion (no need to recharge) and distributed power (no need mental merit is such an approach?
for an electrical power source), which can be essential for
Author’s Reply. The merit of miniaturized I.C. engines
some specific applications.
is that since their large counterparts have relatively large
efficiency, there is the potential for developing miniatur-
● ized engines that may also have significant efficiency. On
the other hand, since the efficiency of the large non-moving
Dimitrios Kyritsis, Yale University, USA. Could you of- parts devices is currently low, it will be necessary to not
fer an additional comment on the comparison between only develop the miniaturized device but also improve the
small-scale devices that operate with and without moving corresponding process of power generation.