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Energy Conversion and Management 48 (2007) 1238–1244

www.elsevier.com/locate/enconman

Experimental study of micro-thermophotovoltaic systems


with different combustor configurations
W.M. Yang a, S.K. Chou a,*
, C. Shu a, Z.W. Li a, H. Xue b

a
MSTI, Department of Mechanical Engineering, National University of Singapore, 10 Kent Ridge Crescent, S119260, Singapore
b
Department of Mechanical Engineering, California State Polytechnic University, 3801 West Temple Avenue, Pomona, CA 91768, USA

Received 15 March 2005; accepted 8 October 2006


Available online 27 November 2006

Abstract

The effects of combustor configuration on the performance of micro-thermophotovoltaic (micro-TPV) power generators are described
in this paper. The micro-TPV system is made of a silicon carbide (SiC) emitter, a simple nine layer dielectric filter and a gallium antimony
(GaSb) photovoltaic (PV) cell array. Properly increasing the backward facing step height of the micro-combustor can increase the short
circuit current and the maximum output power of the system. Combustion chamber diameter is a very important factor affecting the
performance of micro-TPV systems. Properly decreasing the combustion chamber diameter can significantly increase the short circuit
current and maximum output power of the system. Both the short circuit current and the maximum electrical power output increase
with increases of the flow rate and the H2/air ratio. When the flow rate of H2 is 1.17 · 10 3 g/s and the H2/air ratio is 0.9, the micro-
TPV system with a micro-combustor of 3.0 mm diameter is able to deliver an electrical power output of 0.92 W.
 2006 Elsevier Ltd. All rights reserved.

Keywords: Micro-TPV power generator; Filter; SiC emitter; GaSb PV cells

1. Introduction energy conversion devices. Solid propellant micro-rockets


and bi-propellant micro-rockets are typical micro-rockets
Interest in micro-power generators is fueled by both a being developed [1,2]. Micro-rockets do not produce electri-
technology push and a user pull. The technology push is cal power, only thrust. They are mainly used in micro-space-
the development of micro-machining capability based on craft for station keeping, attitude control, gravitation
semiconductor manufacturing techniques. This enables compensation and orbit adjustment. Micro-turbine engines,
the fabrication of complex small parts and assemblies – micro-rotary engines, micro-free piston ‘‘knock’’ engines
devices with submicron precision. User pull is the prolifera- and P3 micro-heat engines are typical indirect energy con-
tion of small, portable electronics such as laptop computers, version devices [3–6]. The basic principle of these kinds of
micro-rovers, micro-aircrafts and micro-robots, which micro-devices is: the conversion of thermal power to
require compact energy supplies whose energy and power mechanical power through a proper thermodynamic cycle
density exceed that of the best batteries available today. followed by conversion of the mechanical power to electrical
To utilize the high specific energy of hydrocarbon fuels in power by an electrical generator. These micro-power devices
combustion driven micro-devices to generate power is feature a high speed moving part and are able to produce
behind the development of micro-power generators. higher power density. However, the existence of the high
Generally, micro-devices can be grouped into three cate- speed moving parts significantly increases the difficulty of
gories: rockets, direct energy conversion devices and indirect fabrication and assembly.
Micro-thermoelectric power generators and micro-TPV
*
Corresponding author. Tel.: +6568742215. systems are typical direct energy conversion devices [7–
E-mail address: mpecsk@nus.edu.sg (S.K. Chou). 10]. They do not have any moving parts, and they convert

0196-8904/$ - see front matter  2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.enconman.2006.10.002
W.M. Yang et al. / Energy Conversion and Management 48 (2007) 1238–1244 1239

the thermal power to electrical power directly. There are array, they generate free electrons and produce an electrical
very limited reports on the study of small TPV systems power output under the function of the p/n junction. SiC is
and micro-TPV systems. In 2001, Bitnar et al. [11] reported selected as the emitter (combustor) material because of its
a small grid connected TPV system consisting of an ytter- good emissivity and high temperature reliability. A GaSb
bia mantle emitter and silicon solar cells with a 15 W elec- PV cell array is employed because it is the only available
trical power output at an efficiency of 1.1%. In a later paper commercial low band gap PV cells responding up to
by Durisch et al. [12], a system efficiency of 2.8% was 1.8 lm. Fig. 2 shows the quantum efficiency of the GaSb
reported by using preheated air for combustion. However, PV cells. The process being used to fabricate GaSb PV cells
the volume of the system is still on the order of 100 cm3 or replicates the silicon solar cell fabrication process, using
more. At the micro-scale, the system will experience more inexpensive diffusion steps with no toxic gases [13]. SiC is
challenges in combustion management, heat recirculation a typical broadband emitter. The spectra of broadband
and assembly. In 2003, Neilsen et al. [10] reported a MEMS emitters operating at temperatures 1000–1600 K contain
based flat structure micro-TPV system with an efficiency of significant proportions of sub-band gap photons with ener-
0.08%. In 2001, we initiated study on a micro-cylindrical gies not sufficient to generate charge carriers in the PV
TPV power generator on the order of a few cubic centime- cells. This portion of energy will be absorbed by the PV
ters in volume [8,9]. A prototype micro-TPV power gener- cells and will result in a destructive heat load on the gener-
ator has been assembled and tested, and an efficiency of ator components, subsequently lowering the conversion
0.72% has been achieved. In this paper, we further disclose efficiency of the system. So, a filter should be employed
the effects of the diameter of the micro-cylindrical combus- in the micro-TPV system. Ideally, the filter should be able
tor and the height of the backward facing step on the per- to reflect all non-convertible photons back to the emitter
formance of micro-TPV power generators. and transmit all convertible photons to the PV cell array.
However, in practice, it is very hard to achieve this. In
2. Structure of micro-thermophotovoltaic systems our study, a nine layer dielectric filter is employed in the

Micro-TPV power generators use PV cells to convert


heat radiation, e.g. from the combustion of fossil fuels into
electricity. Therefore, for micro-TPV applications, the
desired output of the micro-combustor is a high and uni-
form temperature along its wall. Compared to macro-
TPV systems, the micro-TPV systems feature a much
higher power density per unit volume due to the high sur-
face to volume ratio, which makes the study of micro-TPV
systems particularly attractive.
A micro-TPV system has been assembled in the
National University of singapore (NUS). Fig. 1 shows
the schematic of the micro-TPV system. The system con-
sists mainly of a micro-cylindrical SiC combustor, a nine
layer dielectric filter and a GaSb photovoltaic cell array.
A H2/air mixture is combusted in the micro-cylindrical
SiC combustor. As the wall of the micro-combustor (i.e.
the SiC emitter) is heated to a high enough temperature,
it emits many photons. When they impinge on the PV cell Fig. 2. The quantum efficiency of GaSb PV cells.

Cooling fins

Micro PV cells covered


mixer with filters

SiC emitter

Combustion chamber

Fig. 1. The schematic of the micro-TPV system.


1240 W.M. Yang et al. / Energy Conversion and Management 48 (2007) 1238–1244

micro-TPV system to recycle this portion of energy. The fil- MA2SCCF, with an accuracy of 1%. Fig. 4 shows the mea-
ter is fabricated with alternating layers of silicon and sili- suring point.
con dioxide and is deposited on a glass slide and bonded Another micro-combustor with a different combustion
on top of the GaSb PV cells with silicone. The filter is able chamber diameter is also designed to study the effect of
to recycle the photons emitted in the 1.8–3.5 lm mid-wave- the diameter on the performance of micro-TPV system.
length band [14], a large part of the unusable photons with Fig. 5 shows the specifications of the micro-combustor
energy lower than the band gap of GaSb PV cells. Fig. 3 and wall temperature measuring position. The diameter
shows the reflectance of the filter. of the combustion chamber is changed to 3.0 mm, but
The micro-combustor is one of the most important com- the length of the combustion chamber and the wall thick-
ponents of the micro-TPV system. The desired output is a ness are the same as that of the other combustors.
high and uniform temperature along the wall of the micro- The experimental rig is shown in Fig. 6. It includes: (i) a
combustor. Early studies indicated that a micro-cylindrical micro-TPV system, (ii) a connection tube with four 0.2 mm
combustor with a backward facing step is one of the sim- diameter orifices, distributed equally around the perimeter,
plest but effective structures for micro-TPV applications through which high pressure hydrogen and air are mixed
[15]. Here, we will study further the effects of configura- evenly, (iii) a plenum filled with high pressure and uniform
tions of the micro-combustor on the performance of hydrogen, (iv) two sets of electronic mass flow controllers
micro-TPV power generators. (Brooks, 5850E), one for hydrogen with a capacity of
To study the effect of the backward facing step of a 1000 SCCM and the other for air with a capacity of 5000
micro-combustor on the performance of the micro-TPV SCCM. The two controllers are capable of controlling flow
system, three kinds of micro-combustors with different rates accurately to 1% of full scale, through which the H2/
backward facing steps are designed, see Fig. 4. The inner air ratio can be accurately controlled. Two electronic mul-
diameters at the entrance, i.e. d1, are 2.3 mm, 2.5 mm timeters with an accuracy of 0.5% are employed to measure
and 2.7 mm, forming three step heights of 0.6 mm, the open circuit voltage and short circuit current of the
0.5 mm and 0.4 mm, respectively. The temperature along micro-TPV system under different flow rates and H2/air
the wall of the micro-combustor is measured by an inte- ratios.
grated high performance infrared thermometer, Marathon
3. Experimental results and discussion

The experiments are first conducted in a micro-TPV


power generator with a combustor of 3.5 mm diameter to
study the effect of backward facing step height on the per-
formance of the system. It was found that flame flows back
upstream of the backward facing step when the step height
is 0.4 mm, while combustion only takes place in the com-
bustion chamber when the step heights are 0.5 mm and
0.6 mm. The results indicate that the backward facing step
should be high enough to avoid back flow of the flame.
Fig. 7 shows the performance curve of the micro-TPV sys-
tem with different backward facing steps when the flow rate
at the inlet is 0.0476 l/s. From the figure, we can see that
Fig. 3. The reflectance of a simple nine layer dielectric filter. the open circuit voltage of the system is almost identical

Fig. 4. Micro-combustor with different backward facing steps.


W.M. Yang et al. / Energy Conversion and Management 48 (2007) 1238–1244 1241

Fig. 5. Micro-combustor with a combustion chamber diameter of 3 mm.

2.5 0.7

0.6

Current (A) / Power (W)


2
0.5

Voltage (V)
1.5 0.4

1 0.3

0.2
0.5
0.1

0 0
0.5 0.6 0.7 0.8 0.9 1
H2/air ratio
Open-circuit voltage, step height 0.5 mm
Short-circuit current, step height 0.5 mm
Maximum output power, step height 0.5 mm
Open-circuit voltage, step height 0.6 mm
Short-circuit current, step height 0.6 mm
Maximum output power, step height 0.6 mm

Fig. 7. The performance of the micro-TPV system under different


backward facing step at flow rate of 0.0476 l/s.

0.6
Maximum power output (W)

0.4
Fig. 6. Schematic of experimental set-up.

0.2
for the two step heights of 0.5 mm and 0.6 mm. However,
there is a slight increase for the short circuit current and
the maximum output power when the step height increases 0
from 0.5 mm to 0.6 mm, especially at high H2/air ratios. 0.035 0.04 0.045 0.05
When the H2/air ratio is 1.0, the increases are 6.2% and Flow rate at the inlet (l/s)
6.7% for short circuit current and maximum power output,
Fig. 8. The performance of the micro-TPV system with different steps
respectively. Fig. 8 shows the maximum output power of under different flow rates, H2/air ratio is 0.9. The solid line presents the
the micro-TPV system with different step heights as the step height of 0.5 mm, the dash line presents the step height of 0.6 mm.
flow rate changes from 0.0366 l/s to 0.047 6 l/s. From this
figure, we can observe the same effect of step height on
the performance of the micro-TPV system under other flow energy density and the electrical power output of the
rates. It is noted that an appropriate increase of the step micro-TPV system. A 5–10 K increase has been obtained
height can facilitate recirculation of combustion mixture for the wall temperature when the step height increases
near the wall, enhancing the mixing process of combustion from 0.5 mm to 0.6 mm. It should be noted that the step
around the rim of the tube and ensuring a complete and height cannot be increased too much, or a dead zone of
stable combustion. So, a higher temperature can be combustion will be created, which will decrease the perfor-
achieved along the wall, thereby increasing the radiation mance of the micro-TPV power generator.
1242 W.M. Yang et al. / Energy Conversion and Management 48 (2007) 1238–1244

Furthermore, from Fig. 7, we can also see that for the combustion chamber diameter increases from 3.0 mm to
two step heights, with an increase in the H2/air ratio, both 3.5 mm, the mean flow speed decreases from 6.21 m/s
the short circuit current and the maximum electrical power to 4.56 m/s, respectively. This represents a decrease of
output increase drastically. This is because more fuel takes 26.6%, which decreases the heat exchange rate between
part in the combustion, subsequently increasing the tem- the high temperature gas and the combustor wall drasti-
perature along the wall of the micro-cylindrical combustor, cally, thus decreasing the temperature of the wall.
improving the spectral distribution and radiation energy According to Planck’s rule, the radiation power density
density and thereby generating higher current and electrical is proportional to T4, and therefore, the decrease in wall
power output. The open circuit voltage also increases temperature will significantly decrease the performance of
slightly due to higher energy density, which is consistent the micro-TPV system.
with the results of James [16]. For the two step heights, Fig. 10 shows the temperature distribution along the
Fig. 8 shows that the maximum output power increases wall of the above two micro-combustors. The mean wall
fairly linearly with the increase of flow rate. temperature decreases about 80 K when the combustion
When the flow rate is kept at 0.0439 l/s, the perfor- chamber increases from 3.0 mm to 3.5 mm in diameter
mance curves of the micro-TPV power generator with and the H2/air ratio is 0.9, which not only decreases the
different combustion chamber diameters are shown in radiation power density but also worsens the spectral dis-
Fig. 9. The volumes of the two combustion chambers tribution, thus decreasing the percentage of useful radia-
are 0.154 cm3 and 0.113 cm3. It can be observed that tion photons. Fig. 11 shows the spectral distribution of
there is a significant increase both for the short circuit the above two kinds of micro-combustors. We can see
current and the maximum output power of the micro- from this figure that the emissive power from the combus-
TPV system as the combustion chamber decreases from tor with a diameter of 3 mm is much higher than that
3.5 mm to 3.0 mm in diameter. When the H2/air ratio
is 1.0, the increases are 52% and 57% for the short circuit
current and the maximum output power, respectively. It
is believed that increasing combustion chamber volume 1400
Temperature along the wall (K)

will increase the retention time of the fuel in the combus-


tor, thus improving the completeness of combustion. At
the same time, the surface of the combustor is also 1100
increased from 1.91 cm2 to 2.16 cm2, representing an
increase of 13%. Therefore, an increase in electrical
power output is initially expected. However, increasing 800
the combustion chamber volume also brings another
problem, that is, a decrease in the flow speed. As the
500
0 5 10 15 20

Distance from the step (mm)


2.5 1
Combustion chamber diameter is 3.0 mm
Current (A) / Power (W)

2 0.8 Combustion chamber diameter is 3.5 mm

Fig. 10. Temperature distribution along the wall of micro-combustor at


Voltage (V)

1.5 0.6
flow rate of 0.0439 l/s and H2/air ratio of 0.9.

1 0.4

0.5 0.2 4.00E+04


Emissive power (W/m2/μ m)

0 0 3.00E+04 d=3.5 mm
0.5 0.6 0.7 0.8 0.9 1
d=3.0 mm
H2/air ratio
2.00E+04
Open-circuit voltage, d=3.5 mm
Short-circuit current, d=3.5 mm 1.00E+04
Maximum output power, d=3.5 mm
Open-circuit voltage, d=3.0 mm 0.00E+00
Short-circuit current, d=3.0 mm 0 3 6 9 12
Maximum output power, d=3.0 mm Wavelength λ(μm)

Fig. 9. The performance of the micro-TPV system with different Fig. 11. Spectral distribution of above two kinds of micro-combustors at
combustion chamber diameters at flow rate of 0.0439 l/s. flow rate of 0.0439 l/s and H2/air ratio of 0.9.
W.M. Yang et al. / Energy Conversion and Management 48 (2007) 1238–1244 1243

2.5 1 ture along the wall of the micro-combustor. For the


micro-TPV power generator with a combustion chamber

Current (A) / Power (W)


2 0.8 diameter of 3.0 mm, when the flow rate is 0.0476 l/s at
the H2/air ratio of 0.9 (corresponding to a H2 flow rate
Voltage (V)

1.5 0.6
of 1.17 · 10 3 g/s), the system is able to deliver an electri-
1 0.4 cal power output of 0.92 W, the open circuit voltage and
short circuit current are 2.32 V and 0.52 A, respectively.
0.5 0.2 Since the active area of the PV cells is 4.0 cm2, a power
density of 0.23 W/cm2 has been achieved, which is much
0 0
higher than that obtained by Nielson (0.032 mW/cm2)
0.035 0.04 0.045 0.05
[10].
FLow rate (l/s)
However, just like the other micro-power generators
Open-circuit voltage, d=3.0 mm being developed around the world, the development of
Short-circuit current, d=3.0 mm the micro-TPV power generator is still at an early stage.
Short-circuit current, d=3.5 mm For example, to further increase the output electrical
Open-circuit voltage, d=3.5 mm power density and improve the efficiency of the micro-
Maximum output power, d=3.0 mm TPV system, it is necessary to employ a selective emitter
Maximum output power, d=3.5 mm instead of a SiC broadband emitter. This can improve the
emissive spectral distribution drastically. Selective emitting
Fig. 12. Performance of the micro-TPV power generator with different
combustion chamber diameters under different flow rates, H2/air ratio is materials include oxides of rare earth materials such as
0.9. erbia (Er2O3) and ytterbia (Yb2O3) [17], surface micro-
structuring tungsten [18] and Co/Ni doped MgO [19].
The clearance between the PV cells and the micro-combus-
from the combustor with a diameter of 3.5 mm. Further- tor is too big in the present design. A vacuum package can
more, because only radiation photons with energy greater be employed in a future design to reduce the heat loss by
than the bandgap of the PV cells can evoke free electrons natural convection considerably, thus minimizing the heat
and generate electricity (for the GaSb PV cells employed load on the PV cells.
here, the wavelength should be less than 1.8 lm), with a
decrease in radiation temperature, the peak of the spectral 4. Conclusion
distribution curve shifts to the longer wavelength region,
thus decreasing the percentage of useful radiation The results from an experimental study of a prototype
photons. micro-TPV power generator with different combustor
The decrease in open circuit voltage is relatively small configurations are described in this paper. The micro-
when the combustion chamber diameter increases from TPV system is made of a SiC emitter, a simple 9 layer
3.0 mm to 3.5 mm. This is because the open circuit voltage dielectric filter and a GaSb photovoltaic cell array. By
is mainly determined by materials characteristics and the increasing the backward facing step height of the micro-
operating temperature of the PV cells. combustor, the short circuit current and the maximum
Fig. 12 shows the performance of the micro-TPV output power of the system can be raised. Combustion
power generator with different combustion chamber chamber diameter is a very important factor affecting
diameters when the flow rate changes from 0.0366 l/s the performance of a micro-TPV system. By decreasing
to 0.0476 l/s, and the H2/air ratio is 0.9. We can see the combustion chamber diameter, we can significantly
from Fig. 12 that under different flow rates, there are sig- increase the short circuit current and maximum output
nificant increases both for short circuit current and for power of the system, while the increase in the open circuit
maximum output power of the micro-TPV system as voltage is less significant. Both the short circuit current
the combustion chamber diameter decreases from and the maximum electrical power output increase with
3.5 mm to 3.0 mm, while the increase in open circuit an increase in the flow rate and the H2/air ratio. When
voltage is less significant. Similar increases can be the flow rate of H2 is 1.17 · 10 3 g/s and the H2/air ratio
observed under other H2/air ratios. The results indicate is 0.9, the micro-TPV system with a micro-combustor of
that there exists an optimal value for the diameter of 3.0 mm in diameter is able to deliver an electrical power
the micro-combustor. output of 0.92 W; and the open circuit electrical voltage
Furthermore, from Fig. 12, we can also see the same and short circuit current are 2.32 V and 0.52 A,
behaviour as is shown in Fig. 8. For the above two differ- respectively.
ent micro-combustors, both the short circuit current and
the maximum output power of the micro-TPV system Acknowledgement
increase almost linearly with the increase of flow rate.
This is because an increase in flow rate means more fuel This work was supported by a National University of
is combusted in the same period, increasing the tempera- Singapore Grant No. R-265-000-114-112.
1244 W.M. Yang et al. / Energy Conversion and Management 48 (2007) 1238–1244

References [11] Bitnar B, Durisch W, Mayor J-C, Sigg H, Tschudi HR, Palfinger G.
Development of a small TPV prototype system with an efficiency
[1] Orieux S, Rossi C, Esteve D. Compact model based on a lumped >2%. In: Proceedings of the 17th Photovoltaic Solar Energy
parameter approach for the prediction of solid propellant micro- Conference and Exhibition, Munich, 22–26 October 2001.
rocket performance. Sens Actuator A 2002;101:383–91. [12] Durisch W, Bitnar B, Mayor J-C, Roth Fritz von, Sigg H, Tschudi
[2] London AP, Ayon AA, Epstein AH, Spearing SM, Harrison T, Peles HR, et al. Small self-powered grid-connected thermophotovoltaic
Y, et al. Microfabrication of a high pressure bipropellant rocket prototype system. Appl Energy 2003;74:149–57.
engine. Sens Actuator A 2001;92:351–7. [13] Ferguson LG, Frass LM. Theoretical study of GaSb PV cells
[3] Waitz IA, Gauba G, Yang ST. Combustors for micro-gas turbine efficiency as a function of temperature. Sol Energy Mater Sol C
engines. J Fluid Eng 1998;120:109–17. 1995;39:11–8.
[4] Fu K, Knobloch AJ, Cooley BA, Walther DC, Fernandez-Pello C, [14] Fraas LM, Samaras JE, Huang HX, Minkin LM, Avery JE, Daniels
Liepmann D, et al. Microscale combustion research for applications WE, et al. TPV generators using the radiant tube burner configura-
to MEMS rotary IC engine. In: Proceedings of NHTC, 2001 National tion. 17th European Photovoltaic Solar Energy Conference and
Heat Transfer Conference, Anaheim, CA, 10–12 June 2001. p. 1–4. Exhibition, Munich, 22–26, October 2001. p. 1–4.
[5] Yang W. MEMS Free-piston knock engine 28th International [15] Yang WM, Chou SK, Shu C, Xue H, Li ZW, Li DT, et al.
Symposium on Combustion, Edinburgh, UK, 30 July-4 August, Microscale combustion research for application to micro ther-
2000, p.1–4. mophotovoltaic systems. Energy Convers Manage 2003;44:
[6] Whalen S, Thompson M, Bahr D, Richards C, Richards R. Design, 2625–34.
fabrication and testing of the P3 micro heat engine. Sens Actuator A [16] James JL, Burger DR. TPV cell IV curve testing with varying black
2003;104:290–8. body emission temperatures, intensities, and cell temperatures. Sol
[7] Sitzki L, Borer K, Schuster E, Ronney PD, Wussow S. Combustion in Energy Mater Sol C 1996;40:177–81.
microscale heat-recirculating burners, The Third Asia-Pacific Con- [17] Krishna MG, Rajendran M, Pyke DR, Bhattacharya AK. Spectral
ference on Combustion, Seoul, 24–27 June, 2001.p. 1–4. emissivity of ytterbium oxide-based materials for application as
[8] Yang WM, Chou SK, Shu C, Li ZW, Xue H. Development of selective emitters in thermophotovoltaic devices. Sol Energy Mater
microthermophotovoltaic system. Appl Phys Lett 2002;81:5255–7. Sol C 1999;59:337–48.
[9] Yang WM, Chou SK, Shu C, Li ZW, Xue H. A prototype [18] Heinzel A, Boerner V, Gombert V, Wittwer V, Luther J. In:
microthermophotovoltaic power generator. Appl Phys Lett Proceedings Thermophotovoltaic Generation of Electricity, 4th
2004;84:3864–6. NREL Conference, Denver, USA, 11–14 October 1998. p. 191–
[10] Nielsen OM, Arana LR, Baertsch CD, Jensen KF, Schmidt MA. A 194.
thermophotovoltaic micro-generator for portable power applications. [19] Furguson LG, Dogan F. A highly efficient NiO-doped MgO matched
The 12th International Conference on Solid State Sens, Actuator emitter for thermophotovoltaic energy conversion. Mater Sci Eng
Micro Sys, Boston, 8–12 June 2003. p. 714–717. 2002;B83:35–41.

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