A kind of method of producing liquid boron fertilizer

Technical field
The present invention relates to a kind of method of making fertilizer, particularly relate to a
kind of method of producing liquid boron fertilizer.
Background technology
As everyone knows, fertilizer is the indispensable nutrient of agriculture production and plant
absorbing, and plant need absorb various nutrients, and wherein, boron fertilizer is exactly one of
nutrient of plant needs.Boron fertilizer in the market mainly is borax, boric acid and boron mud,
is solid state, solvability and unsatisfactory by the plant absorbing ability, and peasant Hua
Liaoqian, it is little to produce effects; In addition, in state-owned soil more than 95% lack
solubility boron, illegal individual of minority or unit usually flood market with boron fertilizer
of poor quality in order to obtain illegal profit in the society, lead the peasant into a trap.How to
solve imbalance between supply and demand on the market, the protection peasant benefit do not
encroached on, the service agriculture, rural areas and farmers, build a harmonious society, must
develop suitable best boron fertilizer as soon as possible, this be we be engaged in agriculture the
fertilizer research worker responsibility with the obligation.
Summary of the invention
The purpose of this invention is to provide a kind of easy and simple to handlely, pollution-free,
can form the method for producing liquid boron fertilizer of industrialized mass, to remedy the
deficiencies in the prior art.
To achieve these goals, the alleged method of producing liquid boron fertilizer is such:
The present invention is solvent with water, concentration is not auxiliary agent of 95% ethylene
glycol, humic acid solution and boric acid are raw material, extract respectively by weight
percentage: water is 22.78%, the ethylene glycol of concentration 95% is 19.398%, humic acid
solution be 0.012% and boric acid be 57.81%, total amount is 100%, and unit is gram; To sum up
state water, 95% ethylene glycol, humic acid solution, boric acid is inserted in the reactor
together, is under 30 ° to 70 ℃ the condition in temperature, continuously stirring 3 to 4 hours,
leave standstill cooling delivery normal temperature state, take out in the reactor again and be
stirred material, be the liquid boron fertilizer of producing.
The method of producing liquid boron fertilizer involved in the present invention is characterized
in that, temperature is 48 ℃, and churning time is 3.5 hours.
The method of producing liquid boron fertilizer that the present invention is alleged has novel,
scientific and reasonable, technological specification, easy and simple to handle, non-
environmental-pollution, is suitable for advantage such as modern industrialization batch
process; The liquid boron fertilizer that utilization the present invention produces, cheap, easy to
use, need not the soil conversion energy and directly absorbed by plant, be used for the demand
of plant to boron, control plant boron deficiency disease plays and shortly grow, takes root,
strong sprout, urgees the effect that flower, fruit retention, diseases prevention are degeneration-
resistant, raise productivity and improve the quality.The alleged boron fertilizer of the present
invention is liquid, is faint yellow, and substantially tasteless can be widely used in fields such as
agricultural, forestry, can convert water in 1: 500 ratio and be used for plant leaf surface and
spray, and also can be used for seed dressing and drip irrigation.Produce liquid boron fertilizer
with the present invention, its every technical indicator all reaches or is better than specialized
standard, for example the accurate value of the content of boron is g/L 〉=100, and the boron
content of liquid boron fertilizer of the present invention is g/L＞110, and harmful element
arsenic (As), cadmium (Cd), chromium (Cr), plumbous (Pb) (all in element) percentage
composition are far below the technological standard value.
Technical solution of the present invention is described in detail as follows in conjunction with
the embodiments:
Embodiment
Water intaking (water quality should reach drinking water standard) is 22.78% respectively by
weight percentage, the ethylene glycol of concentration 95% is 19.398, humic acid solution be
0.012% and boric acid be that 57.81% total amount is 100%, unit is gram; With total amount is
10 kilograms of (10,000 gram) preparations, and 2.278 grams of then fetching water, 95%
ethylene glycol, 1939.8 grams, humic acid solution are 1.2 grams, boric acid 5781 grams;
Aforementioned water, ethylene glycol, humic acid solution and boric acid are inserted in the
reactor together, are under 48 ℃ the condition in temperature, and continuously stirring left
standstill cooling delivery normal temperature state after 3.5 hours, take out in the reactor and
are stirred material, are the liquid boron fertilizer of producing.If want practical application, can
be in 1: the 500=liquid boron fertilizer: the ratio of water be converted water, can be directly
used in plant leaf surface and spray, and also can be used for seed dressing and drip irrigation.

No.2
The method of preparing liquid boron fertilizer with surface activity includes the following steps: 1. mixing
borax, boric acid and/or boron trioxide in 2-8 molar portions, organic compound A in 1-2 molar portions
and water in 2-5 molar portions, heating to 90-120 deg.c to dissolve and reflux reaction for 2-3 hr; and 2.
cooling to 80-100 deg.c, adding organic compound B in 0.5-1 molar portions, further reflux reaction for 1-
1.5 hr, cooling to room temperature to obtain the liquid boron fertilizer. The compound A is at least one of
ethylene diamine, diethanolamine, diethylidene triamine, etc; and the compound B is at least one of
glycerin, fatty acid, fatty acid acyl halide, etc. The liquid boron fertilizer has high content, quick acting and
no pollution.
CN1944349A
China
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Chinese
Inventor
夏中梅
侯勇
曾显斌
王兰英
魏敏
敬华英
严庆海
邓建华
曾芸

Worldwide applications
2006  CN
Application CN 200610022116 events 

2006-10-25

Application filed by 四川省兰月农化科技开发有限责任公司

2006-10-25

Priority to CNB2006100221160A

2007-04-11

Publication of CN1944349A

2008-05-07

Application granted

2008-05-07

Publication of CN100386293C

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Patent citations (2)
 
Cited by (9)
 
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Description

Preparation method with liquid boron fertilizer of surface active function

Technical field:
The present invention relates to a kind of liquid boron fertilizer, especially relate to a kind of preparation
method with liquid boron fertilizer of surface active function.Be particularly related to the water soluble liq
boron fertilizer preparation method that a kind of pure boron content can reach 150 grams per liters
specifically.
Background technology:
Boron is the necessary micronutrient element of crop, boron is in process of crop growth, single-minded
physiological function and effect are arranged, be that other nutritive element can't be displaced, there is
the arable soil boron deficiency more than 95% in China, need use the boron fertilizer crop could normal
growth, is industrial borax or boric acid and use maximum as boron fertilizer at present in the agriculture
production, and industrial borax is used as fertilizer has following problem in agriculture production:
1, solvability is very little at normal temperatures for industrial borax, and temperature influence is bigger,
must use with redilution behind the hot water dissolving earlier;
2, often use after the industrial borax in plant leaf surface or soil crystallization again or by soil fixing and
can not be by plant utilization, a large amount of nonactive boron attainment branch that caused in the
soil local accumulation, when the temperature of waiting for the coming year gos up, discharged once
more by crystallization or the plain dissolving again of fixed boron, local boron concentration can exceed
standard greatly in the soil, is easy to cause the crop boron poisoning;
3, industrial borax can not be taken into account the physiological property of crop absorption nutrient in
the agriculture production, its spread at blade surface, tack, resistance of rainwater washing against all
can not obtain considering, therefore the boron attainment divides utilization ratio lower, a large amount of
boron is plain to run off, and is especially to the pollution of environment to the waste of resource;
4, used boric fertilizer is solid or adds part trace B attainment branch in compound/mixed fertilizer in the
agriculture production at present, and its aqueous solution effective boron content is very limited.
Summary of the invention:
The objective of the invention is to overcome the defective of above-mentioned boron fertilizer, propose a
kind of high-content, quick-acting, pollution-free, effectively solve the boron deficiency problem of crop,
and make things convenient for the preparation method of the liquid boron fertilizer that the peasant uses
safely with surface active function.
The objective of the invention is to take following technical scheme to realize:
The preparation method of liquid boron fertilizer of the present invention comprises the steps:
1) get at least a molfraction by 2-8 in borax, boric acid, the boron trioxide, with 1-2 molfraction organic
coordination compound A, 2-5 molfraction water mixes, and heats to dissolve back flow reaction 2-3 hour
to 90-120 ℃ of condition;
2) after the reaction, be cooled under the 80-100 ℃ of condition, add 0.5-1 molfraction organic
coordination compound B, stir, keep temperature to continue back flow reaction 1-1.5 hour, be cooled to
room temperature, obtain liquid product of the present invention,
Above-mentioned organic coordination compound A is at least a in quadrol, diethanolamine,
diethylenetriamine, single methylamine, dimethylaminopropylamine, hydroxy-ethylenediamine three acetic
acid, the glycine etc.; Organic coordination compound B is at least a in glycerine, lipid acid (as: dodecyl
sodium sulfonate and salt thereof), fatty acid acyl halogen compound, oxyethane, epoxy chloropropane,
ethylene glycol, the propylene glycol etc.
The high concentration liquid boron fertilizer that the present invention is prepared has very low interfacial
tension, and measuring its interfacial tension in micelle-forming concentration (CMC) is 42.4-45.5 * 10 -
3
N/m, hydrophilic and oleophilic value (HLB) is 14, has good surface active function, as fertilizer sources
uses, its aqueous solution has good spread and resistance of rainwater washing against on the plant leaf
surface, can improve fertilizer utilization efficiency and absorption rate greatly, reduces fertilizer amount.
The high concentration liquid boron fertilizer that the present invention is prepared, its pure boron content
100-150 grams per liter.
The high concentration liquid boron fertilizer that the present invention is prepared, because of having
surface active function, improve fertilizer utilization efficiency and absorption rate greatly, therefore
consumption is more economized, extension rate is higher, and working concentration is lower, and the
mu consumption only is the 50-60 milliliter, clear water extension rate 1000-1200 doubly mainly adopts
foliage-spray to carry out the land for growing field crops and uses during use.Its fertilizer efficiency sees
Table 1.
The present invention compared with prior art has following advantage:
1, liquid boron fertilizer technology of preparing provided by the present invention, raw material is cheap
and easy to get, and preparation cycle is short, and the reaction conditions gentleness is easy to operate
and safe, 100% output capacity, production cost is low, is suitable for suitability for industrialized
production.
2, easy to use, the pure boron content of the prepared liquid boron fertilizer of the present invention is up
to the 100-150 grams per liter.Can mix with arbitrary proportion with water, dissolve not temperature
influence, it is neutral that the aqueous solution is, and can mix with any agricultural chemicals, chemical
fertilizer and use, use and convenient.
3, rapidly and efficiently, because the prepared liquid boron fertilizer of the present invention has surface
active function, have good spread and tack on the plant leaf surface, and resistance of rainwater washing
against, fully take into account the characteristics of plant leaf surface absorption nutrient, so the boron
attainment is divided and can be absorbed by plant 100%, additional fast plant boron attainment branch,
fertility is lasting, and the fertility utilization ratio reaches 100%.Effect of increasing production is obvious,
significantly improves crop quality (its fertilizer efficiency sees Table 1).
4, the prepared liquid boron fertilizer safety and environmental protection of the present invention makes
things convenient for the peasant to use safely, and the aqueous solution is neutral colourless transparent
liquid, and the absorption rate height is safe in utilization to crop, to no any pollutions such as soil, air,
water bodys.
Embodiment:
Embodiment 1:
Get boric acid, quadrol, water with 4: 1: 2 mixed of mol ratio, stir, heat and to 100 ± 5 ℃ of conditions,
dissolve, back flow reaction 2 hours is cooled under 90 ± 5 ℃ of conditions, adds 0.5 mole of glycerin
while stirring, keep temperature, back flow reaction 1 hour stops heating, is cooled to room temperature
and gets the object of the invention product.Its fertilizer efficiency sees Table 1.
Embodiment 2:
Get boric acid, boron trioxide, diethylenetriamine, quadrol, water with mol ratio 3: 2: 2: 0.1: 5 mixed, stir,
heat and to 110 ± 5 ℃ of conditions, dissolve, back flow reaction 2 hours is cooled under 90 ± 5 ℃ of
conditions, adds 0.5 mole of sodium laurylsulfonate while stirring, keep temperature, back flow reaction
1.5 hours stops heating, is cooled to room temperature and gets the object of the invention product.Its
fertilizer efficiency sees Table 1.
Embodiment 3:
Get boric acid, borax, boron trioxide, diethanolamine, glycerol, water with mol ratio 2: 2: 2: 1: 0.5: 4 mixed,
stir, heat and to 110 ± 5 ℃ of conditions, dissolve, back flow reaction 3 hours is cooled under 90 ± 5 ℃ of
conditions, adds 0.5 mole of Witco 1298 Soft Acid amine while stirring, keep temperature, back flow
reaction 1.5 hours stops heating, is cooled to room temperature and gets the object of the invention
product.Its fertilizer efficiency sees Table 1.
Table 1 the present invention mainly needing to be used for the test situation of boron crop such as rape
(this test in the Shuangliu County, Sichuan Province, Shifang county carry out)

Do not Do not
The Shuangliu The Shifang The The
use use
County county present present
Borax boron Borax boron
inventi inventi
fertiliz fertiliz
on on
er er
Mu
50 200 0 50 200 0
boron
millilit gra gra millilit gram gra Per mu
fertilizer ?? ?? ?? ?? ?? ??
ers ms m ers s m yield
amount 205.5 184.7 171.3 201.1 180.6 169.8
(kg)
Average
stimulati ?? ?? ?? ?? Mu ?? ?? ??-- ??93.9 ?? ??--
??-- ??--
on ratio 19.96 7.8 18.43 6.36 volume 102.6 40.2 30.24
(%) increas
e value
(unit,
the
rape
bank
up the
roots of
seedlin
gs
calculat
es with
 The Shuangliu The Shifang
County county
3.0
yuan/k
The foregoing description is that foregoing of the present invention is further described, but this should be
interpreted as that the scope of the above-mentioned theme of the present invention only limits to the
foregoing description.All technology that realizes based on foregoing all belong to scope of the present
invention.