Chandna Coaching Classes

IRDE Raipur(1), Karanpur (2) , Dehradun

Mob: 9997506700, 9536092109
Max Marks : 20
Time = 1hr
(ELECTROCHEMISTRY)

1. The cell reaction is spontaneous or feasible when emf of the cell is:
(a) negative (b) positive (c) zero (d) either positive or negative [1]
2. A current liberates 050g of hydrogen in 2 hours. The weight of copper
(at.wt.= 635) deposited at the same time by the same current through copper
sulphate solution is:
(a) 635 g (b) 318 g (c) 159 g (d) 155 g [1]
3. The more___ ( positive / negative) the standard reduction potential of a metal,
the ____(lesser / greater) is its ability to displace hydrogen from acids. [1]
4. 005 M NaOH solution offered a resistance of 316 ohm in a conductivity cell
at 298 K. If the cell constant of the cell is 0367 cm-1 , calculate the molar
conductivity of the NaOH solution. [2]
5. For the following reaction : 2Fe3+ + 2I- →2Fe2+ + I2 , has E0cell =0.236V at
298 K. Calculate the standard Gibbs energy of the cell reaction. [2]
6. State Faraday's first law of electrolysis. How much charge in terms of Faraday
is required for the reduction of 1mol of Cu2+ to Cu. [2]
7. The resistance of a conductivity cell containing 0.001M KCl solution at 298 K
is 1500 Ω. What is the cell constant if conductivity of 0.001M KCl solution at
298 K is 0.146 × 10-3 S cm-1. [2]
8. Calculate emf of the cell at 298K
Mg(s)| Mg2+ (0.1 M) || Cu2+ (0.01 M)|Cu(s) , Given Eocell = 2.71 [3]
9. 03605 g of a metal is deposited on the electrode by passing 12 amperes of
current for 15 min through its salt solution. The atomic weight of the metal is
96. What is the valency of the metal? [3]
10. A 0·05 M NH4OH solution offers the resistance of 50 ohms to a conductivity
cell at 298K. If the cell constant is 0·50 cm-1 and molar conductance of
NH4OH at infinite dilution is 471·4 ohm-1 cm2 mol-1 , calculate: (i) Specific
conductance (ii) Molar conductance (iii) Degree of dissociation [3]

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