Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur

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30062020 Assignment # 1018 Combo Batch

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(Topic : ELECTROCHEMISTRY )
(for JEE-Mains & Advanced 2020)
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Subjective Type :

Q1. Calculate the dissociation constant of water at 25°C from the following data.

Specific conductance of H2O = 5.8 × 10–8 mho cm–1

 H∞ + = 350.0 and  OH
∞
- = 198 mho cm
2

Q2. Calculate Ka of acetic acid if its 0.05 N solution has equivalent conductance of 7.36
∞
mho cm2 at 25°C  CH3COOH = 390.7 mho cm2

Q3. Calculate the equilibrium concentration of all ions in an ideal solutions prepared by
mixing 25 ml of 0.1 M Tl+ with 25 ml 0.2 M Co3+ .

E° (Tl+ / Tl3+) = – 1.25 volt, E° (Co3+ / Co2+) = 1.84 volt.

Q4. Calculate the cell potential of a cell having reaction Ag2S + 2e  2Ag + S2– in a
solution buffered at pH = 3 and which is also saturated with 0.1 M H2S .

For H2S K1 = 10–8 and K2 = 1.1 × 10–13 , Ksp (Ag2S = 2 × 10–49) , E° (Ag+/Ag) = 0.8

Q5. Hydrogen peroxide can be prepared by successive reaction

2NH4HSO4  H2 + (NH4)2S2O8

(NH4)2S2O8 + 2H2O  2NH4HSO4 + H2O2

The first reaction is an electrolytic reaction. The second is steam distillation. What
amount of current would have to be used in the first reaction to produce enough
intermediate to yield 100 g pure H2O2 per hour, assume 50 % anode current effi-
ciency.

Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
Contact Number : 9889655556 , 7458910091 page no # 2
 Q6. Determine at 298 K for cell Pt / H2 (g) |H+ (aq)|| KCl (1 M)| Hg2Cl2 , Hg () / Pt

(a) Find its emf at ph = 5

(b) The pH when Ecell = 0

(c) The positive electrode when pH = 7.5

Given E°RP(RHS) = 0.28 , E°RP(LHS) = 0.699

Q7. Estimate the cell potential of a Deniel cell having 1 M Zn2+ and originally having 1 M
Cu2+ after sufficient NH3 has been added to the cathode compartment to make NH3
concentration 2 M. Given Kf for [Cu(NH3)4]2+ = 1 × 1012.

E° for the reaction Zn + Cu2+  Zn2+ + Cu is 1.1 volt.

Q8. The over all formation constant for the reaction of 6 mole of CN– with Co2+ is 1 ×
1019. The standard reduction potential for the reaction [Co(CN)6]3– + e  [Co(CN)6]4–

is – 0.83 V. Calculate the formation constant [Co(CN)6]3–

Given Co3+ + e  Co2+ ; E° = 1.82 volt

Q9. For the Galvanic cell Ag/AgCl (s) |KCl (0.2 M)|| KBr (0.001 M) / AgBr (s) / Ag.

calculate the emf generated and assign correct polarity to each electrode for spon-
taneous process after taking the cell reaction at 25°C.

Ksp(AgCl) = 2.8 × 10–10 , Ksp (AgBr) = 3.3 × 10–13

Q10. At 25° C , H f (H 2 O , ) = – 567 00 J /mo le and energy of ioni sation of

H2O () = 19050 J/mole. What will be the reversible emf at 25°C of the cell

Pt |H2 (g) (1 atm) / H+ || H2O , O2 (1 atm) / OH– | Pt ,

If at 26°C the emf increase by 0.001158 volt.

Q11. In the refining of Silver by electrolytic method what will be the weight of 100 gm Ag
anode if 5 Amp. current is passed for 2 hr. Purity of Silver is 95% by weight.

Q12.

Value of E° will be ?

Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
Contact Number : 9889655556 , 7458910091 page no # 3
 Q13. In the Acid Base titration [H3PO4 (0.1 M) + NaOH (0.1 M)] emf of the solution is
measured by couplling this electrode with suitable reffrence electrode. When alkali
is add pH of solution is accordance with equation, Ecell = E°Cell + 0.059 pH.

For H3PO4 K a1 = 10–3 , K a2 = 10–8 , K a3 = 10–13.

What is the cell emf at the second end point of the titration if E°Cell at this stage is
1.3805 volt.
Comprehension #
The molar conductance of NaCl varies with the concentration as shown in the follow-
ing table

λ Cm  λ m  b C Where λ Cm = molar specific conductance

λ m = molar specific conductance at infinite dilution

C = molar concentration

Molar Concentration Molar Conductance

of NaCl In ohm-1 cm2 mole-1

4  10-4 107
9  10-4 97
16  10-4 87

When a certain conductivity cell (C) was filled with 25 × 10-4(M) NaCl solution.
The resistance of the cell was found to be 1000 ohm. At infinite dilution, conduc-
tance of Cl- and SO4- 2 are 80 ohm-1cm2mole-1 and 160 ohm-1cm2mole-1 respectively.

Q15. What is the molar conductance of NaCl at infinite dilution?

(a) 147 ohm-1cm2mole-1 (b) 107 ohm-1cm2mole-1
(c) 127 ohm-1cm2mole-1 (d) 157 ohm-1cm2mole-1

Q16. What is the cell constant of the conductivity cell (C)

(a) 0.3895 cm-1 (b) 3.85 cm-1 (c) 38.5 cm-1 (d) 0.1925 cm-1

Q17. If the cell (C) is filled with 5 × 10-3 (N) Na2SO4 the observed resistance was 400
ohm. What is the molar conductance of Na2SO4.
(a) 19.25 ohm-1cm2mole-1 (b) 96.25 ohm-1cm2mole-1
(c) 385 ohm-1cm2mole-1 (d) 192.5 ohm-1cm2mole-1

Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
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