Jiz Z0882 2011

Copyrighted material licensed to Fernando, Jr. Hipolito on 2021-02-23 for licensee's use only.
No further reproduction or networking is permitted. Distributed by Techstreet LLC, www.techstreet.com.

JAPANESE
INDUSTRIAL
STANDARD
Translated and Published by
Japanese Standards Association
JIS Z 8802: 2011
(SICE/JSA)
Methods for determination of pH of
aqueous solutions
ICS 71.040.40
Reference number: JIS Z 8802:2011 (E)
PROTECTED BY COPYRIGHT 9S
z 8802: 2011
Date of Establishment: 1958-03-03

Date of Revision: 2011-05-20
Date of Public Notice in Official Gazette: 2011-05-20
Investigated by: Japanese Industrial Standards Committee
Standards Board
Technical Committee on Basic Engineering
JIS Z 8802: 2011, First English edition published in 2012-02
Translated and published by: Japanese Standards Association

4-1-24, Akasaka, Minato-ku, Tokyo, 107-8440 JAPAN
In the event of any doubts arising as to the contents,

the original JIS is to be the final authority.
© JSA 2012
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or
utilized in any form or by any means, electronic or mechanical, including photocopying and
microfilm, without permission in writing from the publisher.
Printed in Japan
NH/AT
PROTECTED BY COPYRIGHT
z 8802:2011
Contents
Page
1 Scope····························································································································1
2 Normative references ................................................................................................ 1
3 Terms and definitions············· ............................ ·..... ···· .. ·············· ............................ 1

4 General matters ........................................................................................ ·.............. ·· 2
5 Classification and type of pH meter ...................................................................... · 2
5.1 Classification .............................................................................................................. 2
5.2 Type ............................................................................................................................. 2
6 Construction of pH meter ......................................................................................... 3
7 pH standard solution ................................................................................................ 3
7.1 Classification of pH standard solutions and quality and composition .............. 3
7.2 pH value of pH standard solution at each temperature ..................................... 4
7.3 Preparing method of prepared pH standard solution .......................................... 6
7.4 Storing method of pH standard solution ............................................................... 8
8 Operating method .............................................................................................. · ... · ... 8
8.1 Test of pH meter · ··.................................. ·... ·... ·... ·..................................................... 8
8.2 Measuring method ...... ·... ·................................................. · ... · ... ·... ·... ·........................ 9
9 Record of measured results .. ·· .. ···· .............. ·... ·........... ·.... · ...................................... 11
(i)
z 8802:2011
Foreword
This translation has been made based on the original Japanese Industrial Standard
revised by the Minister of Economy, Trade and Industry through deliberations at
the Japanese Industrial Standards Committee as the result of proposal for revision
of Japanese Industrial Standard submitted by the Society of Instrument and Control
Engineers (SICE)/Japanese Standards Association (JSA) with the draft being attached,
based on the provision of Article 12 Clause 1 of the Industrial Standardization Law
applicable to the case of revision by the provision of Article 14.
Consequently JIS Z 8802: 1984 is replaced with this Standard.
This JIS document is protected by the Copyright Law.
Attention is drawn to the possibility that some parts of this Standard may conflict
with a patent right, application for a patent after opening to the public or utility
model right which have technical properties. The relevant Minister and the Japanese
Industrial Standards Committee are not responsible for identifying the patent right,
application for a patent after opening to the public or utility model right which have
the said technical properties.
(ii)
JAPANESE INDUSTRIAL STANDARD JIS Z 8802 : 2011
Methods for determination of pH of

aqueous solutions
1 Scope
This Japanese Industrial Standard specifies the methods for determination of pH
of aqueous solutions of 0 oc to 95 oc with the pH meter using glass electrode.
2 Normative references
The following standards contain provisions which, through reference in this text,
constitute provisions of this Standard. The most recent editions of the standards
(including amendments) indicated below shall be applied.
JIS K 0050 General rules for chemical analysis
JIS K 0211 Technical terrns for analytical chemistry (General part)
JIS K 0213 Technical terms for analytical chemistry (Electrochemistry part)
JIS K 84 7 4 Potassium trihydrogen dioxalate dihydrate (Reagent)
JIS K 8514 Sodium bromide (Reagent)
JIS K 8622 Sodium hydrogen carbonate (Reagent)
JIS K 8625 Sodium carbonate (Reagent)
JIS K 8809 Potassium hydrogen phthalate (Reagent)
JIS K 8866 Sodium tetraborate decahydrate (Reagent)
JIS K 9007 Potassium dihydrogen phosphate (Reagent)
JIS K 9020 Disodium hydrogenphosphate (Reagent)
JIS Z 8805 Glass electrodes for measurement of pH
3 Terms and definitions

For the purposes of this Standard, the terms and definitions given in JIS K 0211,
JIS K 0213 and JIS Z 8805, and the following apply.
3.1 pH
the value obtained from the electromotive force measured with a glass electrode pH
meter utilizing the pH value of pH standard solution specified in this Standard as
reference
NOTE : It is read as PIETTI or PIEITI.
3.2 certified pH standard solution

the pH standard solution of which the pH value is measured according to the primary
method determined by CCQM of CIPM, or the pH standard solution being traceable
to it in which the expanded uncertainty to give 95% of confidence interval is approxi-
mately within 0.015
2
z 8802:2011
NOTE: For example, oxalate pH standard solution, phthalate pH standard

solution, neutral phosphate pH standard solution, phosphate pH stan-
dard solution, borate pH standard solution and carbonate pH standard
solution of JCSS are included.
3.3 prepared pH standard solution

the pH standard solution of the composition in table 2 prepared in accordance with 7.3
3.4 pH standard solution

generic term for certified pH standard solution specified and prepared pH standard
solution
3.5 zero calibration

that in which potential is adjusted by using the standard solution of the composition
similar to the internal solution of glass electrode and the pH of the standard solution
at that temperature is made to indicate
NOTE : It is also called zero point adjustment.
3.6 span calibration

that in which, after zero calibration, the inclination of potential to pH is adjusted by
using the standard solution of different pH from that used for zero calibration and the
pH at that temperature is made to indicate
NOTE : It is also called sensitivity adjustment.
4 General matters
General conditions as to general matters shall be in accordance with JIS K 0050.
5 Classification and type of pH meter
5.1 Classification
The pH meters shall be classified into the following three models according to the
purpose of use.
a) Portable pH meter
b) Table pH meter
c) Stationary pH meter
5.2 Type
The pH meters shall be classified into four types given in table 1 according to the
performance. The performance shall be in accordance with the test results in 8.1.
3
z 8802:2011
Table 1 Types of pH meter
Type Repeatability Linearity

0 +0.005
j 0.03
I ±0.02
II ±0.05 :1::0.06
III ±0.1 ±0.1
6 Construction of pH meter
The pH meter consists of detection part, amplification part and indication part, and
examples of its construction are given in figure 1.
~---•t
I. Depteacrttion
. ..
Amplification and
indication part
a) In the case of portable pH meter and table pH meter
Detection ~---•.. , Amplification Indication

part . part part
b) In the case of stationary pH meter
Figure 1 Example of construction of pH meter
a) Detection part The detection part consists of glass electrode, comparison elec-
trode, temperature compensation temperature sensitive element and holders re-
taining them.
Further, in some cases it does not contain temperature compensation tempera-
ture sensitive element.
b) Amplification part The amplification part has the capability of amplifying the
electromotive force of detection part, further of carrying out operation for tempera-
ture compensation, and or converting it to the electric signal of the level neces-
sary for indication part.
c) Indication part The indication part is either of indicator or recorder indicat-
ing measured results, or the using both instruments. The indication system is
either of analogue type or digital one, or that using both types.
7 pH standard solution
7.1 Classification of pH standard solutions and quality and composition

The classification of pH standard solutions and the quality and composition shall
be as given in table 2.
4
z 8802:2011
Table 2 Classification of pH standard solutions and quality and

composition
Classification Quality Composition of pH standard

solution
Certified pH standard Prepared pH
solution specified standard solution
Oxalate pH For example, the pH Potassium trihydrogen dioxalate
standard solution standard solution of aqueous solution of 0.05 mol/kg
JCSS
Phthalate pH For example, the pH Potassium biphthalate aqueous
standard solution standard solution of solution of 0.05 mol/kg
JCSS
Neutral phosphate For example, the pH Potassium dihydrogen phosphate of
pH standard standard solution of 0.025 mol/kg
solution .rcss Disodium hydrogenphosphate
aqueous solution of 0.025 mol/kg
That prepared by
Phosphate pH For example, the pH 7.3 Potassium dihydrogen phosphate of
standard solution standard solution of 0.008 695 mol/kg
JCSS Disodi urn hydrogenphosphate
aqueous solution of 0.030 43 mol/kg
Borate pH For example, the pH Sodium tetraborate (borax) aqueous
standard solution standard solution of solution of 0.01 mol/kg
JCSS
Carbonate pH For example, the pH Sodium hydrogen carbonate of
standard solution standard solution of 0.025 mol/kg
JCSS Sodium carbonate aqueous solution
of 0.025 mol/kg
NOTE: mol/kg is mass molar concentration which shows the amount of substance of solute in
1 kg of solvent.
7.2 pH value of pH standard solution at each temperature

The typical value of pH value at each temperature of prepared pH standard solu-
tion is given in table 3, and the typical value of pH value of certified pH standard
solution specified at each temperature is given in table 4. The pH value at tempera-
ture not given in table 3 or table 4 shall be obtained by smooth interpolation.
5
z 8802:2011
Table 3 Typical value of pH value at each temperature of prepared

pH standard solutions
Temperature pH value
oc Oxalate Phthalate Neutral Borate Carbonate al
phosphate
0 1.67 4.01 6.98 9.46 10.32
5 1.67 4.01 6.95 9.39 (10.25)
10 1.67 4.00 6.92 9.33 10.18
15 1.67 4.00 6.90 9.27 (10.12)
20 1.68 4.00 6.88 9.22 (10.07)
25 1.68 4.01 6.86 9.18 10.02
30 1.69 4.01 6.85 9.14 (9.97)
35 1.69 4.02 6.84 9.10 (9.93)
38 - - - - 9.91
40 1.70 4.03 6.84 9.07 -
45 1.70 4.04 6.83 9.04 -

50 1.71 4.06 6.83 9.01 -
55 1.72 4.08 6.84 8.99 -
60 1.73 4.10 6.84 8.96 -

70 1.74 4.12 6.85 8.93 -
80 1.77 4.16 6.86 8.89 -
90 1.80 4.20 6.88 8.85 -
95 1.81 4.23 6.89 8.83 -
Note a) The values in parentheses mean secondary interpolated values.
6
z 8802:2011
Table 4 Typical value of pH value at each temperature of certified pH

standard solution (informative)
Tempera- pH value
ture
Oxalate Phthalate Neutral Phosphate Borate Carbo-
phosphate nate
oc Class 1 Class 2 Class 1 Class 2 Class 1 Class 2 Class 1 Class 2 Class 1 Class 2 Class 2
0 1.666 1.67 4.003 4.00 6.984 6.98 7.534 7.53 9.464 9.46 10.32
5 1.668 1.67 3.999 4.00 6.951 6.95 7.500 7.50 9.395 9.40 10.24
10 1.670 1.67 3.998 4.00 6.923 6.92 7.472 7.47 9.332 9.33 10.18
15 1.672 1.67 3.999 4.00 6.900 6.90 7.448 7.45 9.276 9.28 10.12
20 1.675 1.68 4.002 4.00 6.881 6.88 7.429 7.43 9.225 9.22 10.06
25 1.679 1.68 4.008 4.01 6.865 6.86 7.413 7.41 9.180 9.18 10.01
30 1.683 1.68 4.015 4.02 6.853 6.85 7.400 7.40 9.139 9.14 9.97
35 1.688 1.69 4.024 4.02 6.844 6.84 7.389 7.39 9.102 9.10 9.92
38 1.691 1.69 4.030 4.03 6.840 6.84 7.384 7.38 9.081 9.08 -
40 1.694 1.69 4.035 4.04 6.838 6.84 7.380 7.38 9.068 9.07 9.89
45 1.700 1.70 4.047 4.05 6.834 6.83 7.373 7.37 9.038 9.04 9.86
50 1.707 1.71 4.060 4.06 6.833 6.83 7.367 7.37 9.011 9.01 9.83
55 1.715 1.72 4.075 4.08 6.834 6.83 - - 8.985 8.98 -
60 1.723 1.72 4.091 4.09 6.836 6.84 - - 8.962 8.96 -
70 1.743 1.74 4.126 4.13 6.845 6.84 - - 8.921 8.92 -

80 1.766 1.77 4.164 4.16 6.859 6.86 - - 8.885 8.88 -
90 1.792 1.79 4.205 4.20 6.877 6.88 - - 8.850 8.85 -
95 1.806 1.81 4.227 4.23 6.886 6.89 - - 8.833 8.83 -
NOTE: Values for Class 1 are mentioned in OIML recommendation (R054-e81) and values for
Class 2 are those rounded off to two decimal places.
7.3 Preparing method of prepared pH standard solution
7.3.1 Materials
The water and reagents used for preparation of prepared pH standard solution shall
be as follows:
a) Water The water of not more than 2 x lQ-6 S/cm (25 °C) in electric conductivity.
For borate-prepared pH standard solution and carbonate-prepared pH standard
solution, water especially removed of carbon dioxide shall be used.
b) Potassium trihydrogen dioxalate dihydrate, specified in JIS K 8474.
c) Potassium biphthalate, being pH standard solution used specified in JIS K 8809.
d) Potassium dihydrogen phosphate, being pH standard solution used specified
in JIS K 9007.
e) Disodium hydrogenphosphate, being pH standard solution used specified in JIS
K 9020.
7
z 8802:2011
f) Sodium tetraborate decahydrate, being pH standard solution used specified

in JIS K 8866.
g) Sodium hydrogen carbonate, being pH standard solution used specified in JIS
K 8622.
h) Sodium carbonate, being pH standard solution used specified in JIS K 8625.
7 .3.2 Preparing method

The preparing method for each prepared pH standard solution shall be as follows.
The volume shall be that at 25 oc. The amount of reagent weighed out shall be the
indicated value of the balance (calibrated by a weight of 8 g/cma in density) in which
the buoyancy of air at the time of weighing at the height near to sea level is not cor-
rected.
a) Oxalate-prepared pH standard solution Grind down potassium trihydrogen
dioxalate dihydrate in an agate mortar and preserve it in a desiccator containing
silica gel for 18 h or longer. Take 12.606 g of it, dissolve it with a small amount of
water, transfer it into a 1 L volumetric flask and add water up to the marked line.
b) Phthalate-prepared pH standard solution Heat potassium biphthalate at
120 oc for about 1 h beforehand and leave it cool in a desiccator containing silica
gel as it is. Take 10.119 g of it, dissolve it with a small amount of water, transfer
it into a 1 L volumetric flask and add water up to the marked line.
c) Neutral phosphate-prepared pH standard solution Heat potassium
dihydrogen phosphate at 105 oc ± 2 oc for 2 h and disodium hydrogen phosphate
at 110 oc for 2 h beforehand respectively and leave them cool in a desiccator con-
taining silica gel as they are. Take 3.390 g of potassium dihydrogen phosphate
and 3.536 g of disodium hydrogenphosphate, dissolve them with a small amount
of water, transfer them into a 1 L volumetric flask and add water up to the marked
line.
d) Phosphate-prepared pH standard solution Heat potassium dihydrogen phos-
phate at 105 oc ± 2 oc for 2 h and disodium hydrogenphosphate at 110 oc for 2 h
beforehand respectively and leave them cool in a desiccator containing silica gel
as they are. Take 1.179 g of potassium dihydrogen phosphate and 4.302 g of di-
sodium hydrogenphosphate, dissolve them with a small amount of water, trans-
fer them into a 1 L volumetric flask and add water up to the marked line.
e) Borate-prepared pH standard solution Grind down sodium tetraborate
decahydrate in an agate mortar, leave it in a desiccator containing (saturated)
sodium bromide solution to which sodium bromide specified in JIS K 8514 is fur-
ther added as it is to make it a constant weight. Take 3.804 g of it, dissolve it a
small amount of water without carbon dioxide, transfer it into a 1 L volumetric
flask and add the water without carbon dioxide up to the marked line.
D Carbonate-prepared pH standard solution Leave sodium hydrogen carbon-
ate in a desiccator containing silica gel for about 3 h as it is and take 2.92 g of it.
Separately, put sodium carbonate in a platinum crucible, heat it at 600 oc to make
it a constant weight and take 2.640 g of it. Dissolve the both with a small amount
of water without carbon dioxide, transfer it into a 1 L volumetric flask and add
the water without carbon dioxide up to the marked line.
8
z 8802:2011
7.4 Storing method of pH standard solution

Prepared pH standard solution shall be stored in a hermetically-sealed high-quality
hard glass or polyethylene bottle. Because the pH valued of prepared pH standard
solution is occasionally changed 1 ! due to long period storage, the prepared pH stan-
dard solution for which long time has elapsed after preparation shall be used after its
pH value is confirmed to be same by comparing it with that freshly prepared. And
the certified pH standard solution shall be in accordance with the respectively indi-
vidual certificate of attestation or certificate of calibration. The pH standard solution,
which is once used or left opened in the atmosphere as it is, shall not be used again.
Note 1J For example, the pH values of borate-prepared pH standard solution and
carbonate-prepared pH standard solution are decreased due to the ab-
sorption of carbon dioxide or the like.
8 Operating method
8.1 Test of pH meter

The pH meter accepted by the following test shall be used:
a) Repeatability test The detection part of pH meter prepared according to 8.2.1
and 8.2.2 is dipped into one optional kind of pH standard solution and the indica-
tion of pH meter is read after 10 min. Then, the detection part is sufficiently
washed with water, water content being wiped and it is again dipped in the same
pH standard solution. After 10 min, the indicated value of pH meter is read. The
pH standard solution is measured 3 times by operation in this way and all those
indicated values shall conform to the specifications of table 1 to each type of pH
meter.
b) Linearity test After calibrating the detection part of pH meter prepared accord-
ing to 8.2.1 using neutral phosphate pH standard solution and phthalate pH stan-
dard solution and phthalate pH standard solution according to 8.2.2, the detection
part is sufficiently washed with water and water content is wiped. Then, it is
dipped into borate pH standard solution and its value is read. Thereafter, the
detection part is again sufficiently washed with water and water content is wiped.
It is again dipped in the same borate standard solution and the indicated value
is read. It is measured 3 times as to borate pH standard solution by operation in
this way and the results are averaged. The difference between this average value
and the pH value of used borate pH standard solution shall conform to the require-
ments specified in table 1 for each type of pH meter.
Moreover, the pH standard solution to be used for linearity test shall be in ac-
cordance with table 5.
9
z 8802:2011
Table 5 pH standard solution to be used for linearity test
Type pH standard solution to be used

Certified pH standard solution marked with three decimal
0
places. For example, Class 1 of JCSS
I
Certified pH standard solution or prepared pH standard
II
solution
III
c) The tests of a) and b) shall be carried out at 10 octo 40 oc in temperature of pH

standard solution and for the stability of temperature of each pH standard solu-
tion, there shall not be variation exceeding the values given in table 6.
8.2 Measuring method
8.2.1 Preparation
The power source of pH meter is preliminarily applied before use, and the detec-
tion part is repeatedly washed with water not less than 3 times and wiped with clean
filter paper, absorbent cotton, etc. However, when especially soiled, it is washed with
detergent hydrochloric acid of 0.1 mol!L, etc. for a short time as required and further
sufficiently washed with running water. The glass electrode being under dry condi-
tion for a long time shall be used after preliminarily dipping it into water for one night
(e.g., 12 h).
8.2.2 Calibration of pH meter

The calibration of pH meter shall be carried out by zero calibration and span cali-
bration. By alternately carrying out zero calibration and span calibration, it shall be
calibrated until these pH values agree with values given in table 3 in the case of using
the prepared pH standard solution, and the values given in the certificate of attesta-
tion or the certificate of calibration in the case of using the certified pH standard so-
lution at respective ± 0.005, ± 0.02, ± 0.05 and ± 0.1 on pH meters of 0, I, II and III in
type.
When it is calibrated, the pH standard solution shall be selected from table 2 and
the measuring precision of temperature of pH standard solution and the stability of
temperature of pH standard solution during calibration shall conform to table 6. How-
ever, either of the certified pH standard solution or the prepared pH standard solu-
tion shall be selected according to purpose of measurement or designation of individual
standard, however when traceability is required, the certified pH standard solution shall
be used.
10
z 8802:2011
Table 6 Measuring precision of temperature of pH standard solution

and stability of temperature of pH standard solution during
calibration
Type Measuring precision of temperature of Stability of temperature of pH standard

pH standard solution solution during calibration
0 ± 0.1 oc ::'::0.2oc
I c:::0.5 oc
II _t 0.5 oc
±2 oc
III
a) Zero calibration For zero calibration, the pH meter shall be calibration by dip-
ping the detection part into neutral phosphate pH standard solution, and by regu-
lating the value corresponding to the temperature of pH standard solution. In this
case, it shall be calibrated by the value of table 3 in the case of using the prepared
pH standard solution, and by the value of certificate of attestation or certificate
of calibration in the case of using the certified pH standard solution.
Further, the pH meter with the temperature compensating dial or digital switch,
the scale value shall be set at the temperature of pH standard solution.
b) Span calibration The span calibration shall be as follows.
1) When pH value of sample solution is not more than 7 The pH meter shall
be calibrated by dipping the detection part into phthalate pH standard solution
or oxalate pH standard solution, and by regulating the value corresponding to
the temperature of pH standard solution. In this case, it shall be calibrated by
the value of table 3 in the case of using the prepared pH standard solution, and
by the value of certificate of attestation or certificate of calibration in the case
of using the certified pH standard solution.
2) When pH value of sample solution exceeds 7 The detection part is dipped
into phosphate pH standard solution, borate pH standard solution or carbonate
pH standard solution and the following operation shall be carried out in the same
way as that of 1).
NOTE: When pH value of sample solution is not less than 11 As the
solution equivalent to prepared pH standard solution for pH value
of not less than 11, sodium hydroxide solution of 0.1 mol/L not con-
taining carbonate and saturated (at 25 °C) calcium hydroxide solu-
tion may be used. pH value of this aqueous solution at each
temperature is given in table 7.
11
z 8802:2011
Table 7 pH value at each temperature of sodium hydroxide solution of

0.1 mol/Land saturated calcium hydroxide solution (informative)
Tempera- Sodium hydroxide Saturated calcium Tempera- Sodium hydroxide Saturated calcium
ture solution of 0.1 mol!L hydroxide solution ture solution of0.1 mol/L hydroxide solution
oc oc
0 13.8 13.43 35 12.6 12.14
5 13.6 13.21 40 12.4 11.99
10 13.4 13.00 45 12.3 11.84
15 13.2 12.81 50 12.2 11.70
20 13.1 12.63 55 12.0 11.58
25 12.9 12.45 60 11.9 11.45
30 12.7 12.30
8.2.3 Measurement
After calibrating pH meter, the electrode is washed and immediately pH of sample
solution shall be measured. The amount of sample solution shall be necessarily suf-
ficiently taken to the degree so that the measured value is not changed.
Further, the pH meter with the temperature compensating dial or digital switch
shall not have the variation of liquid temperature exceeding the value given in table 6
during measurement.
NOTE : For the measurement of pH value of not less than 11, there is a fear of
generating alkali error by ordinary glass electrode and lowering its
measured value. Especially, when the ionic concentration of alkali metal
is high, its error becomes larger. Therefore, it should be preferable that
the electrode having little alkali error is used and further necessary
correction is carried out.
9 Record of measured results

In the record of measurement results, the items in a) to h) and if necessary those
in i) and j) shall be mentioned.
a) Temperature of sample solution
b) Type of pH meter (including electrode)
c) N arne of sample
d) Quality of pH standard solution (classification, supplier and characteristic value)
e) Measured value
f) Designation of apparatus (name of manufacturer and name of type)
g) Date of measurement
h) N arne of person in charge of measurement
i) Measurement uncertainty
j) Other necessary items
OIML recommendation (R054-e81), pH SCALE for AQUEOUS SOLUTIONS
Bibliography
z 8802:2011
12.
Errata for JIS (English edition) are printed in Standardization and Qualit;v Control, published
monthly by the Japanese Standards Association, and also provided to subscribers of JIS
(English edition) in li!Iontllly Information.
Errata will be provided upon request, please contact:
Standards Publishing Department, Japanese Standards Association
4-I-24, Akasaka, Minato-ku, Tokyo, 107-8440 JAPAN
TEL. 0.'3-3583-8002 FAX. 0.'3-358.'3-0462

Jiz Z0882 2011

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Jiz Z0882 2011

Uploaded by

Copyright:

Available Formats

Copyrighted material licensed to Fernando, Jr. Hipolito on 2021-02-23 for licensee's use only.

No further reproduction or networking is permitted. Distributed by Techstreet LLC, www.techstreet.com.

JIS Z 8802: 2011

Date of Establishment: 1958-03-03

JIS Z 8802: 2011, First English edition published in 2012-02

Translated and published by: Japanese Standards Association

In the event of any doubts arising as to the contents,

3 Terms and definitions············· ............................ ·..... ···· .. ·············· ............................ 1

Methods for determination of pH of

3 Terms and definitions

3.2 certified pH standard solution

NOTE: For example, oxalate pH standard solution, phthalate pH standard

3.3 prepared pH standard solution

3.4 pH standard solution

3.5 zero calibration

3.6 span calibration

5 Classification and type of pH meter

Table 1 Types of pH meter

Type Repeatability Linearity

a) In the case of portable pH meter and table pH meter

Detection ~---•.. , Amplification Indication

b) In the case of stationary pH meter

Figure 1 Example of construction of pH meter

7.1 Classification of pH standard solutions and quality and composition

Table 2 Classification of pH standard solutions and quality and

Classification Quality Composition of pH standard

7.2 pH value of pH standard solution at each temperature

Table 3 Typical value of pH value at each temperature of prepared

45 1.70 4.04 6.83 9.04 -

55 1.72 4.08 6.84 8.99 -

60 1.73 4.10 6.84 8.96 -

Table 4 Typical value of pH value at each temperature of certified pH

70 1.743 1.74 4.126 4.13 6.845 6.84 - - 8.921 8.92 -

95 1.806 1.81 4.227 4.23 6.886 6.89 - - 8.833 8.83 -

7.3 Preparing method of prepared pH standard solution

f) Sodium tetraborate decahydrate, being pH standard solution used specified

7 .3.2 Preparing method

7.4 Storing method of pH standard solution

8.1 Test of pH meter

Table 5 pH standard solution to be used for linearity test

Type pH standard solution to be used

c) The tests of a) and b) shall be carried out at 10 octo 40 oc in temperature of pH

8.2 Measuring method

8.2.2 Calibration of pH meter

Table 6 Measuring precision of temperature of pH standard solution

Type Measuring precision of temperature of Stability of temperature of pH standard

Table 7 pH value at each temperature of sodium hydroxide solution of

9 Record of measured results

OIML recommendation (R054-e81), pH SCALE for AQUEOUS SOLUTIONS

You might also like