01403117: Fundamentals of General Chemistry

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Q1. (%) ÉÑ4%14 84 .ÇÄ? Ö Ü
Ä +' ('"-á+82à+/.10'äâ 0ã+ A !*ÅÜ'+('"/Üäà+/.10'äâ
0ã+ B åã.<3.?>çã?çã+çÜä/.10'äâ 0ã+Ç'äâ /Üä>,4? â /Üä>Çé. )Å>%4(ÜÅè1ç$+
Ö ç$+ â 0éÜ
Ü'01.%.1>%4(ÉÑ4%14 84 .?
(ç) )Å>%4(ÜÅè1ç$+ â 0éÜÜ'01.%.1>%4(ÉÑ4%14 84 . åã./.10'äâ 0ã+çã.ä0ã+?Ä
Ü'+('"&+$ÖäÇ'äâ à+ A !*Å B?

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Q2. %ÑÜ'01./ê.&1'"ÉÑ4%14 84 .&+$Öä<ëÜ
rate = k[A]2[B2].

&.%à+1Å&3é.äÉÑ4%14 84 . <3.?>çã?çã+Ç'äâ A !*Å B2 *(*ä<1$äÖ &+$ÖäÇ'+ÇÄ Ü'01.

%.1>%4(ÉÑ4%14 84 .)Å ______ <4(>Éí +______>Çé.
A + B2 Æ products

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Q3. %ÑÜ'01./ê.&1'"ÉÑ4%14 84 .çÜä sucrose à+ water
C12H22O11 + H2O Æ 2C6H12O6

>Éí + rate = k[C12H22O11] &*'ä).%ÉÑ4%14 84 .(ê.>+4+èÉ 3 ='Ö3;?ä ÇÄÖ 25oC

6.00 g/L çÜä C12H22O11 *(*ä>Éí + 5.40 g/L )ä<ê.+37<é.<äÇÄÜ Ö '01. k
/ê.&1'"ÉÑ4%14 84 .+ÄÇÜ
ÄÖ 7
ì &9á?4 25oC
[A]
µ +
=
-

kt
[A ] อ

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Q4. <é.<äÇÄÜ
Ö '01./ê.&1'"%.1/*.80'3çÜä!%î/ nitrogen dioxide
2NO2 Æ 2NO + O2

%'"*ê.!/ä>*>ïÜ12?Ä<.é 2.00 M-1 s-1 )ä<ê.+37>3*.à+&+é 3834+.ÇÄÇÇ

ÄÖ .ê à&ã<3.?
>çã?çã+ NO2 *(*ä).% 2.00 mol/L >Éí +1.50 mol/L

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Q5. ).%9.,!/(äÉÑ4%14 84 .%.1/*.80'3çÜä/.1 A ÇÄÜ
Ö 7
ì &9á?4 27oC
%) <3.?>çã?çã+>14? Ö 0ã+ A = ……………….M
ç) Ü'+('"ÉÑ4%14 84 . = ……………………..
<) <é.<äÇÄÜ Ö '01. (k) = ………… &+é 38…………
ä) <é.<1$äÖ =Ä304 = ………………………. s
(!/(ä!0é3ó4 <
Ä (
4 )
time (s)
)) <3.?>çã?çã+çÜä A >?ëÜ
Ö t = 1 +.ÇÄ
(!/(ä34ó<
Ä .ê +37)

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Q6. /ê.&1'"ÉÑ4%14 84 . NO2 Æ NO + 1/2O2
>çÄ8+%ÑÜ'01.è(ã rate = 1.4x10-10[NO2]2 ÇÄÜ Ö 7
ì &9á?4 25oC
åã. 3 mol çÜä NO2 >14? Ö 0ã+à+9.=+ÅÉ4 (É14?.01 2 L )ä<ê.+37&.
<é.<1$äÖ =Ä30
4 çÜäÉÑ4%14 84 .+Äâ

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Q7.E (kJ)

Reaction progress

%) ?Ä%*è%8éÜ8%Äç
Ö +
â ' à+%1.ò+Äâ………………….
ç) /.1ÜÅè1>Éí +/.1?'ó8'+02………………….
<) &.,*'ää.+%éÜ%'??'+02çÜäç'+ â %ê.&+(Ü'01.ÉÑ4%14 84 .………………….
<é. ôH çÜäÉÑ4%14 84 .+Äâ?<
Ä .é …………………..kJ
ä) )ä>çÄ8+%ÑÜ'01./ê.&1'"ÉÑ4%14 84 .+Äâ…………………. ………………….

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Q8. /ê.&1'"ÉÑ4%14 84 .à+/9.3Å!%î/ ?Ä<.é Ea = 103 kJ/mol !*Å<é.<äÇÄÜ Ö 0' 1.
>Éí + 0.085 min-1 ÇÄÜ Ö 7
ì &9á?4 273 K )ä&.<é.<äÇÄÜ
Ö '01.ÇÄÜ
Ö 7
ì &9á?4 323 K

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Q9. )ä&.<é.,*'ää.+%éÜ%'??'+02 (activation energy) çÜäÉÑ4%14 84 . åã.<é.<äÇÄÖ
Ü'01.?Ä<.é >Éí + 3 >Çé.>?ëÜ
Ö Üì7&9á?>4 ,4? â ).% 300 K >Éí + 310 K
Ö ç$+

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Q10. %.113?%'+çÜäÜÅ0Ü? Cl >1éä(ã38!%î/ N2 %*è%åá%+ê.>/+Ü>Éí +

N2 +Cl N2Cl (fast, equilibrium)

N2Cl + Cl Æ Cl2 + N2 (slow)
(a) )ä1Å"ì/.1?'ó8'+02à+%*è%('ä%*é.3
Ö ê.>/+Ü à&ã%ÑÜ'01.>Éí + rate = k[N2][Cl]2
(b) )ä!/(äà&ã>&í+3é.%*è%ÇÄ+

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Q11. ÉÑ4%14 84 . 2NH3(g) Æ N2(g) + 3H2(g) ?Ä<.é <äÇÄÜ
Ö '01. 1.0x10-3 s-1
ÇÄÖ 327oC åã.<3.?>çã?çã+>14?
Ö 0ã+çÜä!%í/ NH3 >Çé.%'" 2 M )ä!/(ä
34óÄ%.1<ê.+37&.
%) Ü'01.>14? Ö 0ã+çÜäÉÑ4%14 84 .
ç) <3.?>çã?çã+çÜä!%í/ NH3 >?ëÜ Ö >3*.öé.+èÉ 2 ='Ö3;?ä
Ö 0ã+>Éí + 1 M <1$äÖ =Ä30
<) ÉÑ4%14 84 .+Äâå.ã <3.?>çã?çã+>14? 4 çÜäÉÑ4%14 84 .)Å?Ä<.é
>Çé.%'" >?ëÜÖ <3.?>çã?çã+>14? Ö 0ã+>Éí + 2 M &1ëÜè?é >,1.ÅÜÅè1

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Q12. 12,%+, 3, 4 2H2 + 2NO Æ N2 + 2H2O 6H = -300 kJ -7%898(':;7<
K1
2NO N 2 O2 )+=>
N2O2 + H2 kÆ
2
N2O + H2O ?@4
k3
N2O + H2 Æ N2 + H2O )+=>

%) *4+-'Ä3';Å+ÇÉÖ Ñ *4+Ü(
á) %89%á'; < .7à 2 )+73%>â4Ö09+
É) %89%á';< .7à 1 )+73%>â4%+0">;%4+Ö09+
:) !*(:>,Ä7%4+)á73;%äÖ'Å+4Ü&@*Ö(É8@Ö:%'"%89%áÖ:12,%+, 3, 4
ã) ã:)á73;%+4å!*(:+0('"ç8'::4;ç+@Ö-+0"éÅ4è !&;â :áÖ:*4+Å':< Å@;
*4+-'Ä3';Å+Ç *4+)?,:ê@Ö;%'--';ÅÇ !80ë8,Åí'ìîÇÜ;%+4åÜ&@?(' )ã;
!80+0"é?>â : Ea1 !80 6H áÖ:12,%+, 3, 4(@>3
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Q13.
12,%+, 3, 4 X + Y Æ Z !*(:(':
ïÉ+:+â4:ç8'::4;(@4;á>4
ã:Ü?@áÖ
@ -ñ8ã4%%+4åÅÖ"Éè4ó4-ÅâÖ91;7<

%). ã4%!ë;ë':ç8'::4; 12,%+, 3, 4;7<-ã7 4è ;>; ........á';

< ÅÖ; !80-7á;
< ' %è4&;(
Ö'Å+4 )1= ;á'; < .7à …….
á). *4+)?,:ê@Ö;%'--';ÅÇÜ( *843Å'>9(@:4â 3.7* à (
é ………………
É). ç8'::4;%+0Åé; @ (Ea) áÖ:12,%+, 3, 4 B2 Æ Z ).â4%'" …………………..kJ/mol
:). 12,%+, 3, 4 X + Y Æ Z )1= ;12,%+, 3, 4!""Ü( !80 H -7)É+ÑÖ à :&-43
ã). 12,%+, 3, 4Ü()%,(9(@?4@ .7*
à (
é

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Q14. ã4%ë8%4+.(8Ö: 2A + 2B Æ C + 2D .7à 25oC Ü&@áÖ
@ -ñ8(':Å4+4:

%4+.(8Ö: à Å@; (M)

É>4-)á@-á@;)+,- Ö'Å+4)+,-
à Å@;
.7à [A], M [B], M (M/s)
1 0.10 0.20 2
2 0.20 0.40 32
3 0.20 0.20 8
4 0.40 0.40 X

ã:&4*,:à ÅâÖ91;7<
1) %2Ö'Å+4áÖ:12,%+, 3, 4
2) Ö';('"+>-áÖ:12,%+, 3, 4
3) Éâ4 X Ü;Å4+4:-7É4â ).â4%'"á@ÖÜ(
4) Éâ4É:.7Ö à 'Å+4ç+@Ö-&;â >3
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Q15. ã:ÅÖ"Éè4ó4-ÅâÖ91;7<
%) ó@4Å@Ö:%4+&4Éâ4ç8'::4;%+0Åé;@ (Ea) áÖ:12,%+, 3, 4 ã0.è4%4+.(8Ö:9(@
Ö3â4:9+ 3%Å'>Ö3â4:ç+@Ö-Éè4ÖÄ,"43Ü&@?(' )ã;)ç73: 1 >,Ä7

á) ó@4Å@Ö:%4+8(Éâ4 Ea ã0Å@Ö:.è4Ö3â4:9+ !80)ç+40)&ÅéÜ( Ea ã$:8(8:

É) ã4%.ô/ä7%4+?; áÖ:12,%+, 3, 4
4HBr(g) + O2(g) Æ 2H2O(g) + 2Br2(g)
9-âÉ>+)%,(á';
< )(73> (one step mechanism) )ç+40)&ÅéÜ( ã:ÖÄ,"43

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 Next Chapter

*-(é8)É-7
(Chemical Equilibrium)

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