JEE Main 2019 Mock Test Solutions

IT2019JEE Main 2019 Mock Test (100379.
1)-PCM21
HINTS AND SOLUTIONS

PHYSICS (PART-I)
1 50 Hz for half-wave, 100 Hz for full-wave
2. we know
ne2 

m
Cu Cu Cu 50
  1.4  = 10/7
 Au Au  Au 49
3. Without charged plate, frequency is given by

1 g
f=
2 
When charged plate is placed under simple pendulum, due to opposite charge, the attraction between
charged block and metal ball will be there. So effective force will increase. Hence frequency (new) will
increases.
longitudinal stress 15  107
4. Y=   3  1011 N m2
longitudinal strain 5  104
3
5. v =  A 2  x2 , x = A
2
6. As there will be no loss in internal energy of the gas
n1CV T1  n2CV T2 = (n1 + n2)CVT
P1V1 PV PV P V 
 T1  2 2 T2   1 1  2 1  T
RT1 RT2  RT1 RT2 
P V  P2 V2  T1T2
 T 1 1
P1V1T2  P2 V2 T1
As number of moles of the gas will be constant
n1 + n2 = n
 P1V1 P2 V2   PV1 PV2 
    
 RT1 RT2   RT RT 
P1V1T2  P2 V2 T1 (P1V1  P2 V2 )T1T2 P1V1  P2 V2
 P  
T1T2  V1  V2  P1V1T2  P2 V2 T1 V1  V2

7. q
R
  = qR = ItR = 103  5  0.5T = 25 mWb
8. Q = nCT = 600
U = nCVT = 450
C 4 4 4 3R
   C  CV    2R
CV 3 3 3 2
9. 1
P0   2  v2  P0  2gh  2gh
2
So, v  2 gh
g T 
10.  100  2 
g T 
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IT2019JEE Main 2019 Mock Test (100379.1)-PCM22
11. Large surface area helps in releasing most of the heat from transistor and only collector is the region
which can be compensated in its width.
12. Let the block is in translational equilibrium and ready to N

topple. F
=F
N = mg
Taking torque about C.O.M. = 0
a a a mg
F   f    N 
2  2  2 = F
2F = N
N
F
2
N
f 
2
but f  N
N
 N
2
1

2
1012  2  104  25 4
13. Number of emitted electrons  = 5 × 10 electrons
105
–15
q = + ne = 8 × 10 C.
14. Successive frequencies will differ by an amount v/2L
Q+x x
1  2 
15. Electric field between the capacitor plates = 
20 2 0 C
Qx x 1
E=   Q  2x 
2A0 2A0 2A0 
d
 Potential different Ed = Q  2x   
2A0
Q  2x
 
2C
Q
 x =  C
2
3 2
16. = B
4
d 3 2 dB
=  
dt 4 dt
 32
i= 
R 4R
E
17. = E – ir
2
E
 i= . . . (i)
2r
2E = i(3 + r) . . . (ii)
r=1
18. dQ = dU + dW
PdV
C = Cv + …(i)
ndT
Differentiating TV 2  cons tan t
dV V
 …(ii)
dT 2T
PV = nRT …(iii)
solving eq. (i), (ii) and (iii)
C=R
19. Z= R 2  X 2 = 9  X2
R 3
but cos  = 
Z 5
X = 4 .
20. For adiabatic process, TV1 = constant

 1
m
T   = constant

T
= constant
  1
1
  T1  1   3  = 4/3
 1
2 2
f=  6
 1  4 
 3  1
 
21. V = V = 3 V

 = 2  105/C
22. VA  VB  6V for current in 4  resistor to be zero. Potential difference 2 resistor = 10  6 = 4V

Current through 2 resistor = 2A
net emf (10  4)
So, 2  
net resis tance (2  R)
On solving, R = 1 
0 A 4 0 A
23. 
 d d  3 d
d  2  2K 
1 4
Or 
d 1 3d
1
2  K 
On solving, we get K = 2
24. q1 + q2 = 3Q, q3 + q4 = Q, q5 + q6 = Q
the field inside the metal plates must be zero
q1 q2 Q Q
   0 …..(i)
20 20 20 20
3Q q3 q Q
  4  0 ...…(ii)
20 20 20 20
3Q Q q q
  5  6 0 …..(iii)
20 20 20 20
from (i), (ii) and (iii) we get
Q 3Q
q3   ; q5  
2 3
25. In a rigid system angular velocity of a point with respect to any other point is same.
d D dy y x
26.   d ; x    2
d  D  
Y 0.1 10 20 4
  2  2  (2)  
 0.25 25 25 5
 = 0.25 y = 0.1
2
I  Imax cos2
5
2S 2S 2S 8S
27. PB  ,PA   
3R 3R R 3R
PB 1

PB 4
28. VP  Vpindued  VPq  V0 P r1

kq kq O 
Vpinduced   O
r r1 R
r
29. When pure rolling starts friction reduces to zero. So plank does not have any acceleration so
surface is horizontal.
30. Initial activity = ANA + BNB = Ai

final activity = ANA + BNB = Af
N N
A = 2 B and NA = NB NA = A6 ,NB  B3
2 2
Ai 5

A f 96
CHEMISTRY (SECTION-II)
1. D
[Cr(en)3]3+ ; Hyb. : d2sp3 ; does not exhibit geometrical isomerism but exhibits optical isomerism
2 3
[IrF3 (H2O)2 (NH3 )] ; Hyb. : d sp ; exhibits geometrical isomerism but does not exhibit optical
isomerism.
[NiCl4 ]2 ; Hyb. : sp3
2 3
[Co(CN)2 (ox)2 ]3  ; Hyb. : d sp ; exhibits both geometrical isomerism and optical isomerism.
2. C
Ni(CO)4 and [Co(CO)4 ] - both are tetrahedral and diamagnetic
3. C
50 C 230C
(I) Ni  4CO   [Ni(CO 4 )]   Ni  4CO 
(impure) (volatile) (pure)
1 
(II) Cu2S  O2  Cu2O  SO2
2
high
Cu2S  2Cu2 O 
temp.
6Cu  SO2
electrolysis
(III) MgCl2 (s)   Mg2  ( )  2Cl ( )
At cathode : Mg2   2e  Mg(s)
At anode : 2Cl ()  Cl2 (g)  2e
4. C
In I group only Li form nitride and all II group metals form nitride.
H O (moist)
Mg  N2  Mg3N2 
2
 Mg(OH)2  NH3
H O (moist)
Ca  N2  Ca3N2 
2
 Ca(OH)2  NH3
H O (moist)
Li  N2  Li3N 
2
 LiOH  NH3
K + N2  no reaction
5. A
Thermal stability order top to bottom increases
6. A
Thermal stability order NH3 > PH3 > AsH3
7. A
PCl3  H2O  H3PO3  HCl
8. C
Let the hydrocarbon Cx Hy, then it undergoes combustion in the following manner
 y y
CxHy   x   O2  xCO2  H2O C
 4  2
30 mol 90 mol 60 mol
1ml 3 ml 2 ml
or 1 mol 3 mol 2 mol
Equal volumes of all gases contain equal number of molecules at the same conditions of temperature
and pressure.
Therefore, we have
y y
x  2 and x   3   3  2  1  y  4
4 4
Thus, the molecular formula = C2H4
9. B
The number of electrons in each species is
NO  7  8  1  14, C22   6  6  2  14
CN  6  7  1  14, N2  7  2  14
10. B
Using de Broglie relationship
h 6.63  10 34
   0.40 nm
m  1.67  10 27  103
11. D
Higher is the charge/size ratio, higher is the polarizing power
12. A
–
CN and NO has 14e each, hence same bond order = 3
13. A
We will find out the equilibrium temperature at which
G = 0. We know that
G = H – TS
0 = H – TS
Therefore, h = TS. Hence,
179.1 1000
T  1118 K
160.2
14. D
For an ideal gas, isothermal reversible process,
v 
S  2.303 nRlog  2 
 v1 
 100 
 2.303  2  8.314  log  
 10 
–1 –1
= 38.3 J mol K
15. C
O OH
(i) CH MgBr
 3
(ii) H O2
16. A
The expression for Tf is
Tf = i  Kf  m
For the reaction Na2 SO4  2Na  SO24 , i  2  1  3
Hence, Tf = 3  1.86  (0.01/1) = 0.0558 K
17. A
Given that
Ag  NH3  [Ag(NH3 )]
[Ag(NH3 )]
K1   3.5  10 3
[Ag ][NH3 ]
and [Ag(NH3 )]  NH3  [Ag(NH3 )2 ]
Therefore, for the overall reaction
Ag  2NH3  [Ag(NH3 )2 ]
[Ag(NH3 )2 ] [Ag(NH3 )] [Ag(NH3 )2 ]
K  
[Ag ][NH3 ]2 [Ag ][NH3 ] [Ag(NH3 )] [NH3 ]
–3 –3 –6
= K1 . K2 = 3.5  10  1.73  10 = 6.08  10 .
18. D
The reaction is
Ba(NO3 )2  CaCO3  BaCO3  2NaNO3
Here [CO23  ]  [Na2CO3 ]  104 M.
Therefore, the solubility product is
K sp  [Ba2  ][CO 32 ]
or 5.1 109  [Ba2 ]  104
2+ –5
We get [Ba ] = 5.1  10 . At this value, precipitation just starts.
19. D
The reaction are
H2CO3  H  HCO3 K1  4.2  107 …(1)
HCO3 H  
CO32  K 2  4.8  10 11
…(2)
+
As K2 << K1. All the H ions (in total) are due to equation (1) only
From the first equation,
[H ]A  [HCO3 ]  [H ]total

2– 2– + + –
[CO3 ] is negligible as compared to [HCO3 ] of [H ]total. So, the concentrations of H and HCO3 are
approximately equal.
20. A
For the given cell reaction
Eocell  0.14  0.13  0.01 V
According to Nernst equation
0.0591 [Pb 2 ]
Ecell  Eocell  log But as
2 [Sn2 ]
0.0591 [Pb 2 ]
Ecell  0  0.01  log
2 [Sn2 ]
[Pb2 ] 0.01
 log   0.3
[Sn2 ] 0.0296
[Pb2 ]
i.e.,  0.5
[Sn2 ]
21. A
The rate expression is Rate = k[P]x [Q]y.
Substituting values for (I) and (II) from the given table and evaluating (I)/(II), we get
y y
0.0012  1 10 2  1  1
        y 1
0.024  2  102  2 2
Substituting values for (I) and (III) and evaluating (I)/(III) we get
x x
0.0012  6  102  1  1
      x 1
0.024  12  10 2  2  2 
So, the overall order of the reaction is 1 + 1 = 2. Substituting values of x and y in the expression for
(I), we get
0.012 = k  (6  10–2)  (1  10–2)  k = 2 min–1.
22. C
The protective power of lypophilic solution is expressed in terms of gold number, Lesser the gold
number greater its protective power.
23. B
For the molecule C2(Cl)(Br)(F)I six geometrical isomers are possible
24. C
For the given molecule two geometrical and two optical isomers are possible
25. D
+
Cl
CH3 CH CH 2 CH2 CH2 CH CH 2
OH
CH 2 Cl
H3C
26. B
O O O
CH3 CH 2 C H  OH CH3 CH C H CH3 CH2 C H
OH O

CH 3 CH2 CH CH3 CH2 CH CH C H
C C H CH3
CH3 O
27. C
Cl
Na

dry. Ether

Br
28. A
CH3–CH2–OH will give haloform test
29. B
Will give the tollen’s test

O OH
30. D
Cl
H
is optically active isomer
C C C
H H
MATHEMATICS (PART-III)
1. 1 + a1  2 a1 , 1  a2  2 a2 , 1  an  2 an
n
Hence, (1 + a1)(1 + a2) ..... (1 + an)  2
ze  1
2. Let ze = 2z + 1  z 
2
4 3
 z  1   ze  1
 Equation whose roots are ‘2z + 1’ is  e    20
 2   2 
4 3
 (ze – 1) + 2(ze – 1) + 32 = 0
3. Let xp(x) – 1 = A(x – 1)(x – 2) ..... (x – 9)

1
Put x = 0  A 
9
1
 10p 10   1  9
9
1
 p 10  
5
4. x1 + x2 = 6, x1·x2 = 4 and x12  6x1  4  0

8
Now,
 x12  4x1  4     x1 8 
28  x18  x18
 257
x18 x18
1 3
5. p , q
4 4
Mean = np, standard deviation = variance  3  npq = 9
1 3
 n    9  n = 48  mean = 12
4 4
3 5  2 3 5  2 41
6. r1  r2   
2 2 4
7. Let y = mx be the chord

2 2 3  4m 4
Hence, x (1 + m ) – x(3 + 4m) – 4 = 0  x1  x 2   x1  x 2 
1  m2 1  m2
2 24
But x2 = –4x1  7m + 24m = 0  m = 0, 
7
13 sin 
8. Equation of normal at (13 cos , 5 sin ) is  y  5 sin     x  13cos  
5 cos 
5  5 5
 cos  = 0, sin       , 2  sin1 ,   sin 1
24 2 24 24
4 sin t  t cos t  t 5 1
9. Let x = t, lim  , now expand it
t0 t  e  1  2t 
2t 6
5
3
x2 2 3
10. g  x   x2  g x    c  1  c  c 
5 5 5
2
5
x2 3 67
g x     g4  
5 5 5
2
11. f(x) < 2 for x < 1 and f(x) > 3 for x > 1
   [2, 3]
10

12. Put 1  x

1
2  t  I  2  t

13
3 dt
3 

 1 x 2
1
 3
c
5
1  1  4x
13. y  xy  y  ,y 1
2
19
 I
6
1
x
14. Let  f  t  dt  k  f(x) = e (1 + k)
0
1
t
  e 1  k  dt  k
0
1
 k
2e
1 2
1 3 41 3
15. A    a 2 x 2  ax  1 dx  a     a
0
3 4 48 4
 1  cos 2x   1  cos 2x 
16. y  c1 cos x  c 2    c3    c4
 2   2 
2 2
17.  + 2 = 3a and 2 = f(a) = 2a
1 a 1 b 1 c 1 d
18.  a,  b,  c,  d
2 2 2 2
120 119 119
19. 3 = 3·3 = 3(4 – 1) = 3(4k – 1) = 12k – 3 = 12(k – 1) + 9
100
20. Number of ways of selecting ‘r’ person from 60 men and 40 women is Cr
100
 Maximum = C50
21. Number of ways of selecting atleast zero things from ‘p’ alike things is (p + 1)
9
 10  1  1  119  1
6
22. AAA BBB can be arranged at ‘6’ places in  20
33
‘6’ places can be selected 3 c1  3c1  3 c 2  3  81
 20  81 = 1620
6
c3 5
23. 3

6 54
2
24. AB = A  ABA = A = AB = A
2 2
 A = A and B = B
2 2 2
(A + B) = A + B + AB + BA = 2(A + B)
3 2 2
(A + B) = (A + B) (A + B) = 2 (A + B)
7 6
(A + B) = 2 (A + B)
 
 bc ˆi  ˆj  kˆ
25. a     
a b c  2
x 1 y  2 z  3
26.    k1  x = 1 + 3k1, y = 2 + k1 and z = 3 + 2k1
3 1 2
x  3 y 1 z  2
   k 2  x = 3 + k2, y = 1 + 2k2 and z = 2 + 3k2
1 2 3
 P(4, 3, 5) only (B) and (C) satisfy
1 3
27. sin A cosB and cos A sinB 
4 4
 2 1 2
A  B   sin A   cot A = 3
2 4
A B C 7  A B C R 3
28. 1  4 sin sin sin   R  4r sin sin sin   
2 2 2 4  2 2 2 r 4
   1 
29. sin1 x  cos 1 x   cos 1 x  cos1 x  cos1 x   x   0, 
2 4  2
2
30.  tan1 x  cot 1 x 2  2tan1 x    tan1 x   5  tan 1 x 
2 
,   x = –1
2  8 3 4

JEE Main 2019 Mock Test Solutions

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JEE Main 2019 Mock Test Solutions

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IT2019JEE Main 2019 Mock Test (100379.

HINTS AND SOLUTIONS

3. Without charged plate, frequency is given by

12. Let the block is in translational equilibrium and ready to N

14. Successive frequencies will differ by an amount v/2L

20. For adiabatic process, TV1 = constant

21. V = V = 3 V

22. VA  VB  6V for current in 4  resistor to be zero. Potential difference 2 resistor = 10  6 = 4V

28. VP  Vpindued  VPq  V0 P r1

30. Initial activity = ANA + BNB = Ai

At cathode : Mg2   2e  Mg(s)

At anode : 2Cl ()  Cl2 (g)  2e

[H ]A  [HCO3 ]  [H ]total

Will give the tollen’s test

3. Let xp(x) – 1 = A(x – 1)(x – 2) ..... (x – 9)

4. x1 + x2 = 6, x1·x2 = 4 and x12  6x1  4  0

7. Let y = mx be the chord

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