PHYSICS

(SECTION-A)
   
1. (a) F  q[E  v  B]
 ˆi kˆ 
ˆj
 
= q 3iˆ  ˆj  kˆ  3 4 1 
 1 1 3 
 
= q [3iˆ  ˆj  2kˆ  ˆi)  12  1)  ˆj( 9  1)  k(3
ˆ  4)]

= q [3iˆ  ˆj  2kˆ  13iˆ  10ˆj  k]

ˆ

= q [10iˆ  11 ˆj  k]
ˆ

= Fy = 11q ĵ .

2. (d) For solenoid

B
H
0
B = 0n
 H = nI
100
 3 × 103 = ×I
0.2
  = 6A

3. (c)


R

Magnetic field at centre of circle

0  
BA = = 0 [Also pqafd  = 2R]
2R 
a

45°

4 0 
Magnetic field at centre ; {ks=k = (2 sin 45)
a
4
2
16 0 
= [Also pqafd 4a = ]
2

BA 2
Now vc 
BB 8 2

4. (a)
5. (a) qE = qVB ........(a)
mV
&r= ........(b)
qB
from (a) & (b) :
qB 2r
m=
E
1.6  10 19  0.25  0.5  10 2
m=  2 × 10–24 kg
10 2

6. (a)

7. (c)

Net charge,
∆𝜙 1 1 𝜋
𝑄= = 𝐴 𝐵 −𝐵 = × 3.5 × 10 0.4 sin − 0
𝑅 10 10 2
1
= (3.5 × 10 )(0.4 − 0)
10
= 1.4 × 10
8. (b)
According to faraday’s law of electromagnetic induction, 𝑒 = −
𝑑𝑖 15
𝐿× = 25 ⇒ 𝐿 × = 25
𝑑𝑡 1
Or, 𝐿 = 𝐻
Change in the energy of the inductance,
1 1 5
∆𝐸 = 𝐿(𝑖 − 𝑖 ) = × × (25 − 10 )
2 2 3
5
= × 525 = 437.5 𝐽
6

9. (c)
Power input (𝑉 𝐼 ) = 2.2 kW
2.2kW
∴𝑉 = = 220 volts
(10𝐴)
∴input voltage for step –down transformer
𝑉 𝑁
= =2
𝑉 𝑁
V =2×V = 2 × 220
= 440𝑉
Also, = ∴ 𝐼 = × 10 = 5𝐴

10. (d)
𝐼=𝐼 1−𝑒 Here 𝑅 = 𝑅 + 𝑟 = 1Ω

0.8𝐼 = 𝐼 1−𝑒 .

⇒ 0.8 = 1 − 𝑒
1
⇒𝑒 = 0.2 =
5
1
⇒ 100𝑡 = ln 5 ⇒ 𝑡 = ln 5 = 0.016 𝑠
100
11. (d)
Impedance of coil = 100Ω
𝜙 = 45∘
⇒ R = X = 50√2
⇒ 50√2 = 𝜔 × L
50√2
⇒L= = 1.1 × 10 H
2𝜋 × 1000
Nearest value given is 1.1 × 10 H.

12. (c)
In steady state, inductor behaves as a conducting wire.
So, equivalent circuit becomes

1 1 1 1
   1
Req 3 3 3
 Req  1
 Circuit becomes

0
i  10 A
3

13. (c)
Assuming current I in outer loop magnetic field at
0i 2 2 0i
centre  4    2sin 450  
4 
L L
2

Flux through inner loop

M
i
2 2 0 l 2
M
L

14. (c)
1
f 
2 LC
To increase the resonating frequency product of L and C should decrease.
By joining capacitor in series, capacitor will decrease
15. (c)
2
E  440sin100 t , L  H

2
X L   L  100  100 2

E0 440
Peak current I 0    2.2 2 A
X L 100 2
AC ammeter reads RMS value therefore reading will Irms
I0
I rms   2.2 A
2

16. (a)

220
I rms   5.5 A
40

XL is not equal to Xc. So rms current in (b) can never be larger than (a).

17. (b)
R R R
P  P1    as X L  R 
Z R 2  X L2 R 2
1
P1 
2
R
p2   P2  1
R2   X L  X L 
2

18. (a)
z  1002   200  100 
2

 100 2
V 200 2
irms  rms 
z 100 2
=2A

19. (c)
20. (a)
XL=10-2x3000 = 30 
1 40
XC  6
 
3000  25  10 3
X  X L  XC
40 50
 30  
3 3
X 50 1
tan    
R 3  100 6
1
  tan 1    tan 1  0.17 
6
(SECTION-B)
1. (60)
Maximum emf   N AB
N  20,   50, B  3 102 T
  20  50     0.08  3  102  60.28  102
2

Rounded off to nearest integer=60

2. (60)
d
  20t  20mV
dt

i   10t  10mA
R
at t=5
|i|=60mA

3. (667)
f = 3GHz, ε = 2.25
𝑣
𝑉 =⋋ 𝑓 ⇒=
𝑓
1
𝐶=
𝜇 𝜀
1 C
𝑉= ⇒⋋=
𝜇 𝜀 𝜀 f∙ μ ε ∙ √μ ε ∙ f
3 × 10 1
⇒⋋= ⇒⋋=
f ∙ √μ ∙ √ε 3 × 10 × √1 × √2.25
⇒⋋= 667 × 10 cm

4. (250)
  8t 2  9t  5
d
emf     16t  9 
dt
At t = 0.25 s
Emf = -[(16 x 0.25)-9] = 5V
Emf 5V
Current =  
Resistance 20
1 1000
 A mA  250mA
4 4
5. (1)
mv
Sol. R =
qB
1
q × 12 × 103 = m × (106)2
2
24  10 3 m
12

10 q
24  10 3  10 6
R=
1012  0.2
R = 12 × 10–2 m
R = 12 cm

6. (3.5)
Let r be the radius of the circular loop.
 A   r2
A
r 

Magnetic field at the centre of the loop is
I
B 0
2
B
I 2B A
 0 I 
A  
2

Now, magnetic moment of the loop is
M = IA
2B A
 .A
0 
3
2B A 2

0 
 n=2 and m=1.5
 n  m  3.5

7. (4)
0 i 8
Given,  T
2R 2
In 2nd case,
 2
 0 i    0 i 
2
0i
B        4T
 4R   4R  2 2R
8. (40)
 p- 2400 V, NP= 5000
 s= 240 V, Ip = 5 A
 = 80% = 0.8
P I
  cut  s s
Pin  p I p
 p I p 0.8  2400  5
 Is    40 A
s 240
9. (22)
X L   L  2  50  101  10
1 1 100
XX    10 4 
 C 2  50 
R  10 
100
𝑍= 10𝜋 − + 10 ≃ 10𝛺
𝜋
𝐸 220
𝑖= ≃ ≃ 22𝐴𝑚𝑝
2 10

10. (10)
Energy stored in capacitor
1 1
 CV 2  500  106  104
2 5
5
 J
2
Current will be maximum when whole energy of capacitor becomes energy of inductor.
1 2 5
LI 
2 2
5 5
I   10 A
L 50  103
 CHEMISTRY
(SECTION-A)
21. (d)
W(VI) is more stable than Cr (VI)
- Permanganate titrations in presence of HCl are unsatisfactory as HClis oxidised to 𝐶𝑙
Lanthanoid oxides are used as phosphors.

22. (b)
𝐺𝑑 (𝑍 = 64) = [𝑋𝑒]4𝑓
𝜇= 𝑛(𝑛 + 2) = 7(7 + 2) = 7.9𝐵. 𝑀

23. (c)
(a) CrO3 (d) V2 O5 (c) MnO2 (b) Fe2O3 (e) Cu 2O
So order of oxidation state a > d > c > b > e

24. (b)
Cerium exists in two different oxidation state
+3, +4
Ce+4 + 3e-  Ce3+ E° = + 1.61 V
Ce+3 + 3e-  Ce E° = -2.336 V
It shows Ce+4 acts as a strong oxidising agent & accepts electron
25. (c)
Eu Yb
EM0 3 / M 2 
0.35 1.05
Hence, due to more reduction potential in Eu as compared to Yb, it can concluded that Eu2+ is more stable
than Yb2+.

26. (a)
Magnetic moment, 𝜇 = 𝑛(𝑛 + 2)BM (where, n = no. of unpaired electrons) As transition metal
atom/ion in a complex may have unpaired electrons ranging from zero to 5 . So, maximum
number of unpaired electrons that may be present in a complex is 5 .
∴ Maximum value of magnetic moment among all the transition metal complexes is

27. (d)
Wavelength of the energy absorbed by the coordination compound is inversely proportional
to ligand field strength of the given co-ordination compound. The strong field ligand causes
higher splitting of the d -orbitals. The decreasing order of ligand field strength is NH > H O >
Cl. Therefore decreasing order of absorbed wavelength is (I) > (II) > (III)

28. (d)
EDTA is used in the treatment of lead poisoning. DeferrioximeB is used in treatment of iron
poisoning and D-penicillamine is used in treatment of heavy metal poisoning, while cis-platin
is used for treating cancer

29. (d)
If Δ > P then for d ⇒ t e
If Δ > P then for d ⇒ t e
30. (d)
[Fe(CO)4 (C2O4)]+

One unpaired electron

Spin only magnetic moment
= 3 B ⋅M.= 1.73BM

31. (b)
Ring is formed due to formation of nitrosoferrous sulphate

32. (a)
When metal is in low oxidation state then it forms complexes when ligands have good  -accepting character

33. (b)
Ni(CO)4Hybridisation sp3
[Ni(CN)4]2-Hybridisation dsp2
[Co(CN)6]3- Hybridisation d2sp3
[Co(F)6]3-Hybridisation sp3d2

34. (c)

35. (b)
The rate of S 1 is decided by the stability of carbocation formed in the rate determining step.
 Carbocation(𝐷) is most stable due to +𝑅 effect of CH O group, (C) isstabilised by +I and +𝐻
effects of the CH group; (B) is least stable due to −I effect of 𝑀𝑒𝑂 group. So increasing order
of rate of S 1 is
(𝐵) < (𝐴) < (𝐶) < (𝐷)

36. (c)

37. (a)

38. (d)
39. (a)

, 𝑠𝑝 𝑑 no. of lone pair= 1

40. (d)
Radon is radioactive element and not present in atmosphere.

(SECTION-B)
1. (3)
The structure of perchloric acid is

The number Cl = O bonds in 𝐻𝐶𝑙𝑂

𝑂 is 3.

2. (5)
Mohr's salt :(NH4)2Fe(SO4)2⋅ 6H2O
The number of water molecules in Mohr's salt = 6
Potash alum :KAl(SO4)2⋅ 12H2O
The number of water molecules in potash alum = 12
6
So ratio of number of water molecules in Mohr's salt and potash alum 
12
1

2
= 0.5
= 5x10-1

3. (l)

The electrophile


E is singlet carbene so it has on lone pair.
4. (2)
Number of  electron = 2

5. (2)
The number of optical isomers for [Cr(C2O4)3]3−is two.

6. (2)
MCl3.2 L octahedral

MCl3 .2l 

Ex . AgNO3
1 mole of AgCl
1 mole
Its means that one Cl−ion present in ionization sphere.
∴formula = [MCl2 L2]Cl
For octahedral complex coordination no. is 6.
∴ L act as bidentate ligand

7. (1)
Co  NH 3 6  Cl2

Co 2  :  Ar  3d 7 4s 0 4 p 0
For this complex  0  P.E., so pairing of electron does not take place. sp 3 d 2 hydbridisation
Total 3 unpaired electrons are present.
Co  NH 3 6  Cl3

Co3 :  Ar  3d 6 4s 0 4 p 0
d 2 sp3 hybridisation
NH 3 acts as SFL because  0  P.E .
So here all electrons becomes paired
8. (19)
K Cr O
2 + 2𝑥 − 14 = 0 ⇒ 𝑥 = +6
K M nO
1 + 𝑦 − 8 = 0 ⇒ 𝑦 = +7
K Fe O
2 + 𝑧 − 8 = 0 ⇒ 𝑧 = +6
𝑥 + 𝑦 + 𝑧 = 6 + 7 + 6 = 19

9. (0)
6 6
Cr O42  , Cr2 O72 difference is zero
10. (6)
2KMnO4 + 5H2C2O4 + 3H2SO4  K2SO4 + 2MnSO4+10CO2 + 8H2O
Mn2+ has 5 unpaired electrons therefore the magnetic moment is 35 BM
MATHEMATICS

SECTION-A
41 D
42 B
43 B
44 C
45 B
46 C
47 B
48 A
49 C
50 A
51 B
52 D
53 B
54 D
55 D
56 B
57 C
58 C
59 C
60 A
SECTION-B
1 1
2 4096
3 3
4 1
5 0
6 42
7 968
8 99
9 18
10 1440