SAFETY DATA SHEET

AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : AVITERA® BLACK SE

Manufacturer or supplier's details

Company : Huntsman Singapore Pte Ltd
Address : Resident Representative Office in Ho Chi Minh City
Unit 2704, Saigon Trade Center, 37 Ton Duc Thang Street, Ben
Nghe Ward, District 1
Ho Chi Minh City,
Vietnam
Telephone : +84 8 39103745
Telefax : +84 8 39103746

Company : Huntsman Textile Effects

Address : 150 Beach Road, #37-00 Gateway West
189720
Singapore
Telephone : +65 63906448

E-mail address : pehs_te@huntsman.com

Emergency telephone : Europe: +32 35751234

Americas: +1 703 527 3887
Africa: +32 35751234
Asia & Pacific: +65 6336 6011
China: +86 20 39377888
+86 532 83889090
India: + 91 22 42 87 5333
USA & Canada: 800 424 9300

Recommended use of the chemical and restrictions on use

Recommended use : Textile dyes, finishing and impregnating products; including
bleaches and other processing aids

2. HAZARDS IDENTIFICATION

GHS Classification
Skin sensitization : Category 1

GHS Label element

Hazard pictograms :

Signal Word : Warning

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

Hazard Statements : H317 May cause an allergic skin reaction.

Precautionary Statements : Prevention:

P280 Wear protective gloves.
P261 Avoid breathing dust.
P272 Contaminated work clothing must not be allowed out of
the workplace.
Response:
P302 IF ON SKIN:
P352 Wash with plenty of soap and water.
P363 Wash contaminated clothing before reuse.
P333 If skin irritation or rash occurs:
P313 Get medical advice/ attention.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

Cases of respiratory sensitization have been observed with reactive dyes.
Should an individual become sensitized a physician should be consulted and all contact with
reactive dyes must cease immediately.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Mixture

Hazardous ingredients
Chemical Name CAS-No. Concentration (%)
2-Naphthalenesulfonic acid, polymer with 36290-04-7 >= 1 - <= 3
formaldehyde, sodium salt
citric acid 77-92-9 >= 1 - <= 3
White mineral oil (petroleum) 8042-47-5 >= 1 - <= 3
REACTIVE ORANGE TZ 5719 – >= 13 - <= 30

4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Show this material safety data sheet to the doctor in
attendance.
Do not leave the victim unattended.

If inhaled : If unconscious place in recovery position and seek medical

advice.
If symptoms persist, call a physician.

In case of skin contact : If on skin, rinse well with water.

In case of eye contact : Flush eyes with water as a precaution.

Remove contact lenses.
Protect unharmed eye.

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

Keep eye wide open while rinsing.

If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear.

Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

Most important symptoms : None known.

and effects, both acute and
delayed

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet

media

Specific extinguishing : Standard procedure for chemical fires.

methods Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment : Wear self-contained breathing apparatus for firefighting if

for fire-fighters necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Use personal protective equipment.

protective equipment and Avoid dust formation.
emergency procedures Avoid breathing dust.

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.

Methods and materials for : Keep in suitable, closed containers for disposal.
containment and cleaning up

7. HANDLING AND STORAGE

Advice on protection against : Avoid dust formation. Provide appropriate exhaust ventilation
fire and explosion at places where dust is formed.

Advice on safe handling : Avoid formation of respirable particles.

Do not breathe vapors/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Dispose of rinse water in accordance with local and national

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

regulations.
Persons susceptible to skin sensitization problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Electrical installations / working materials must comply with
the technological safety standards.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Ingredients CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
White mineral oil (petroleum) 8042-47-5 TWA (Mist) 5 mg/m3 VN OEL
STEL (Mist) 10 mg/m3 VN OEL
Personal protective equipment
Respiratory protection : P3 filter.

Hand protection
Material : Neoprene gloves
Break through time : 1-4h

Remarks : The suitability for a specific workplace should be discussed

with the producers of the protective gloves.

Eye protection : Eye wash bottle with pure water

Tightly fitting safety goggles.

Skin and body protection : Dust impervious protective suit

Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures : Wash hands before breaks and at the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : powder

Color : black

Odor : No data is available on the product itself.

Odor Threshold : No data is available on the product itself.

pH : 5 - 5,5, 2 % (20 °C)

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

Flash point : Not applicable

Evaporation rate : No data is available on the product itself.

Flammability (solid, gas) : No data is available on the product itself.

Upper explosion limit : No data is available on the product itself.

Lower explosion limit : No data is available on the product itself.

Vapor pressure : No data is available on the product itself.

Relative vapor density : No data is available on the product itself.

Relative density : No data is available on the product itself.

Density : 1 g/cm3

Solubility(ies)
Water solubility : 100 g/l (23 °C)

Solubility in other solvents : No data is available on the product itself.

Partition coefficient: n- : No data is available on the product itself.

octanol/water
Autoignition temperature : No data is available on the product itself.

Thermal decomposition : No data is available on the product itself.

Viscosity : No data is available on the product itself.

Self-Accelerating : No data is available on the product itself.

decomposition temperature
(SADT)

10. STABILITY AND REACTIVITY

Reactivity : No decomposition if stored and applied as directed.

Chemical stability : No decomposition if stored and applied as directed.
Possibility of hazardous : Stable under normal conditions.
reactions
No decomposition if stored and applied as directed.

Dust may form explosive mixture in air.

Conditions to avoid : No data available

11. TOXICOLOGICAL INFORMATION

Routes of exposure : No data is available on the product itself.

Acute toxicity

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

Acute oral toxicity - Product : LD50 (Rat): > 2.000 mg/kg

Ingredients:
White mineral oil (petroleum):
Acute inhalation toxicity
: LC50 (Rat, male and female): > 5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Assessment: The substance or mixture has no acute
inhalation toxicity

Ingredients:
citric acid:
Acute dermal toxicity : LD50 (Rat, male and female): > 2.000 mg/kg
Method: OECD Test Guideline 402

REACTIVE ORANGE TZ 5719:

Acute dermal toxicity : LD50 (Rat, male and female): > 2.000 mg/kg
Method: OECD Test Guideline 402
Assessment: The substance or mixture has no acute dermal
toxicity

Acute toxicity (other routes of : No data available

administration)

Skin corrosion/irritation
Product:
Result: No skin irritation
Remarks: Information given is based on data on the ingredients and the toxicology of similar
products.

Serious eye damage/eye irritation

Product:
Result: Stains the eyes

Respiratory or skin sensitization

Product:
Remarks: Causes sensitization.

Assessment: No data available

Germ cell mutagenicity

Ingredients:
citric acid:
Genotoxicity in vitro : Metabolic activation: with and without metabolic activation

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

Method: OECD Test Guideline 471

Result: negative

Metabolic activation: negative

Result: positive

White mineral oil (petroleum):

Genotoxicity in vitro : Concentration: 12 - 60 ug/plate
Metabolic activation: Metabolic activation
Method: OECD Test Guideline 471
Result: negative

Concentration: 1000 ug/plate

Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative

REACTIVE ORANGE TZ 5719:

Genotoxicity in vitro : Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: positive

Method: OECD Test Guideline 473

Result: negative

Metabolic activation: with and without metabolic activation

Method: OECD Test Guideline 476
Result: positive

Ingredients:
citric acid:
Genotoxicity in vivo : Application Route: Oral
Method: Directive 67/548/EEC, Annex V, B.22.
Result: negative

Application Route: Oral

Method: OECD Test Guideline 475
Result: negative

White mineral oil (petroleum):

Genotoxicity in vivo
: Cell type: Somatic
Application Route: Intraperitoneal injection
Exposure time: 72 h
Dose: 1 - 5 g/kg
Method: OECD Test Guideline 474
Result: negative

REACTIVE ORANGE TZ 5719:

Genotoxicity in vivo : Cell type: Somatic
Application Route: Oral
Dose: 2000 mg/kg
Method: OECD Test Guideline 474
Result: negative

Cell type: Somatic

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
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Application Route: Oral

Method: OECD Test Guideline 486
Result: negative

Carcinogenicity
Ingredients:
White mineral oil (petroleum):
Species: Rat, (male and female)
Application Route: Oral
Exposure time: 24 month(s)
Dose: 1200 mg/kg
Frequency of Treatment: 7 daily
Method: OECD Test Guideline 453
Result: negative

Carcinogenicity - : No data available

Assessment

Reproductive toxicity
Ingredients:
White mineral oil (petroleum):
Effects on fertility
: Species: Rat, male and female
Application Route: Dermal
Method: OECD Test Guideline 415
Result: No effects on fertility and early embryonic
development were detected.

REACTIVE ORANGE TZ 5719:

Species: Rat, female
Application Route: Oral
Method: OECD Test Guideline 421

Ingredients:
citric acid:
Effects on fetal development : Species: Mouse
Application Route: Oral
Result: No teratogenic effects.

Species: Rabbit
Application Route: Oral
Result: No teratogenic effects.

Species: Rat
Application Route: Oral
Result: No teratogenic effects.

Species: Mouse
Application Route: Oral
Result: No teratogenic effects.

White mineral oil (petroleum):

Species: Rat, female
Application Route: Oral

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SAFETY DATA SHEET

AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

General Toxicity Maternal: NOAEL (No observed adverse

effect level): >= 5.000 mg/kg body weight
Method: OECD Test Guideline 414
Result: No teratogenic effects.

Reproductive toxicity - : No data available

Assessment

STOT-single exposure
No data available

STOT-repeated exposure
No data available

Repeated dose toxicity

Ingredients:
White mineral oil (petroleum):
Species: Rat, male and female
NOEC: 2 mg/kg, 50 mg/m3
Application Route: Ingestion
Test atmosphere: dust/mist
Exposure time: 4 Weeks
Number of exposures: 7 d
Method: OECD Test Guideline 412

Species: Rat, male and female

NOAEL (No observed adverse effect level): >= 2000 mg/kg
Application Route: Skin contact
Exposure time: 13 Weeks
Number of exposures: 7 d
Method: Subchronic toxicity

REACTIVE ORANGE TZ 5719:

Species: Rat, male and female
NOAEL (No observed adverse effect level): 1000 mg/kg
Application Route: Ingestion
Exposure time: 672 h
Number of exposures: 1 d
Method: Subacute toxicity

Repeated dose toxicity - : No data available

Assessment

Aspiration toxicity
Ingredients:
White mineral oil (petroleum):
May be fatal if swallowed and enters airways.

Experience with human exposure

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

General Information: No data available

Inhalation: No data available

Skin contact: No data available

Eye contact: No data available

Ingestion: No data available

Toxicology, Metabolism, Distribution

No data available

Neurological effects
No data available

Further information
Product:
Remarks: No data available

12. ECOLOGICAL INFORMATION

Ecotoxicity
Toxicity to fish - Product : LC50 (Brachydanio rerio (zebrafish)): > 100 mg/l
Exposure time: 96 h

Ingredients:
2-Naphthalenesulfonic acid, polymer with formaldehyde, sodium salt:
Toxicity to daphnia and other : EC50: 9,9 - 15 mg/l
aquatic invertebrates Exposure time: 48 h

EC50 (Daphnia magna (Water flea)): 37 mg/l

Exposure time: 48 h

EC50 (Daphnia magna (Water flea)): 39 mg/l

Exposure time: 48 h
Method: OECD Test Guideline 202

citric acid:
Toxicity to daphnia and other
aquatic invertebrates
: LC50 (Daphnia magna (Water flea)): 1.535 mg/l
Exposure time: 24 h
Test Type: static test
Test substance: Fresh water

EC50 (Daphnia): > 50 mg/l

Exposure time: 48 h
Test Type: static test

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Version Revision Date: SDS Number: Date of last issue: -
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Test substance: Fresh water

White mineral oil (petroleum):

Toxicity to daphnia and other
aquatic invertebrates
: LL50 (Daphnia magna (Water flea)): >= 100 mg/l
Exposure time: 48 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 202

REACTIVE ORANGE TZ 5719:

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 202

Ingredients:
REACTIVE ORANGE TZ 5719:
Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): > 100 mg/l
Exposure time: 72 h
Test substance: Fresh water
Method: OECD Test Guideline 201

M-Factor (Acute aquatic : No data available

toxicity)

Toxicity to fish (Chronic : No data available

toxicity)

Ingredients:
White mineral oil (petroleum):
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
: NOEC (Daphnia magna (Water flea)): >= 1.000 mg/l
Exposure time: 21 d
Test Type: semi-static test
Test substance: Fresh water
Method: OECD Test Guideline 211

M-Factor (Chronic aquatic : No data available

toxicity)

Toxicity to bacteria - Product : IC50: > 100 mg/l

Exposure time: 3 h

Toxicity to soil dwelling : No data available

organisms

Plant toxicity : No data available

Sediment toxicity : No data available

Toxicity to terrestrial : No data available

organisms

Ecotoxicology Assessment

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
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Ingredients:
2-Naphthalenesulfonic acid, polymer with formaldehyde, sodium salt:
Acute aquatic toxicity : Harmful to aquatic life.

White mineral oil (petroleum):

Acute aquatic toxicity : This product has no known ecotoxicological effects.

Ingredients:
2-Naphthalenesulfonic acid, polymer with formaldehyde, sodium salt:
Chronic aquatic toxicity : This product has no known ecotoxicological effects.

White mineral oil (petroleum):

Chronic aquatic toxicity : This product has no known ecotoxicological effects.

Toxicity Data on Soil : No data available

Other organisms relevant to : No data available

the environment

Further information:
No data available

Persistence and degradability

Biodegradability - Product : Biodegradation: 10 - 20 %
Exposure time: 28 d
Method: Simulation Test - Aerobic Sewage Treatment. B.
Biofilms

Biochemical Oxygen : 0 mgO2/g

Demand (BOD) - Product

Chemical Oxygen Demand : 850 mgO2/g

(COD) - Product
BOD/COD : No data available

ThOD : No data available

BOD/ThOD : No data available

Dissolved organic carbon : No data available

(DOC)

Physico-chemical : No data available

removability

Stability in water : No data available

Photodegradation : No data available

Impact on Sewage : No data available

Treatment

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

Bioaccumulative potential
Ingredients:
citric acid:
Bioaccumulation : Bioconcentration factor (BCF): 3,2

Ingredients:
citric acid:
Partition coefficient: n- : log Pow: -0,76 - -0,12
octanol/water GLP: no

REACTIVE ORANGE TZ 5719:

Partition coefficient: n- : log Pow: < -1,8 (20 °C)
octanol/water pH: 7
Method: Partition coefficient
GLP: yes

Mobility in soil
Mobility : No data available

Distribution among : No data available

environmental compartments

Stability in soil : No data available

Other adverse effects

Environmental fate and : No data available
pathways

Results of PBT and vPvB : No data available

assessment

Endocrine disrupting : No data available

potential

Adsorbed organic bound : 0%

halogens (AOX) - Product
Hazardous to the ozone layer
Ozone-Depletion Potential Not applicable

Additional ecological : No data available

information - Product
Global warming potential : No data available
(GWP)

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Do not re-use empty containers.

14. TRANSPORT INFORMATION

International Regulation

IATA
Not regulated as a dangerous good

IMDG
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture
Other international regulations
The ingredients of this product are reported in the following inventories:
CH INV : The mixture contains substances listed on the Swiss Inventory

TSCA : Low volume exemption

DSL : This product contains the following components that are not on
the Canadian DSL nor NDSL.
AICS : Not in compliance with the inventory

NZIoC : Not in compliance with the inventory

ENCS : Low volume exemption

KECI : Not in compliance with the inventory

PICCS : Not in compliance with the inventory

IECSC : Low volume exemption

Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)

16. OTHER INFORMATION

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AVITERA® BLACK SE
Version Revision Date: SDS Number: Date of last issue: -
1.0 2016/03/15 400001019495 Date of first issue: 2016/03/15

Date format : yyyy/mm/dd

While the information and recommendations in this publication are to the best of our
knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS
TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE

APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE
SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE. THE PRODUCT
MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN
HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT
THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and
are dependent upon the manufacturing circumstances or other processes. Such hazards,
toxicity and behaviour should be determined by the user and made known to handlers,
processors and end users.

The trademarks above are the property of Huntsman Corporation or an affiliate thereof.

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN

EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR
HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY
CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART
OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR
BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL
REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET
SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT THE
ABOVE ADDRESS.

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