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Ceramics International
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Keywords: The efficiency of the Bryton cycle strongly depends on the maximum temperature of the cycle. However, re-
Gas turbine strictions on metallurgical problems deprive engineers from the benefit of high temperatures. Ultrahigh tem-
Ultrahigh temperature ceramics perature ceramics can be considered in such cases, instead of traditional materials like M152 superalloy. In this
Heat transfer study, SiC reinforced HfB2 and ZrB2 ultrahigh temperature ceramics were proposed as gas turbine stator blades.
Thermal stress
The heat transfer and stress-strain equations were solved numerically by the finite element method to obtain
Stator blade
temperature and stress distributions. The results showed that the maximum thermal stress occurs in vicinity of
Numerical simulation
the cooling ducts where the temperature gradient is maximum. The maximum displacements of 1.2 mm (for
HfB2–SiC) and 1.14 mm (for ZrB2–SiC) occur in the upper wall. It can be noticed that the ZrB2–SiC made blade
showed lower maximum stress and displacement than those for the HfB2–SiC made one, as a result of lower
expansion coefficient of ZrB2–SiC system. The addition of SiC to monolithic HfB2 and ZrB2 ceramics decreases
their thermal conductivity and following that, the temperature uniformity in blades reduces. Although the
thermal stresses and the probability of failure in these stator blades enhance, the ZrB2–SiC material presented the
best performance among the other investigated samples. Both Coulomb-Mohr and Von Mises failure analyses
were employed. It was understood that both blades made of HfB2–SiC and ZrB2–SiC composites simply withstand
the applied stresses with the safety factors of about 1.5.
∗
Corresponding author.
∗∗
Corresponding author.
E-mail addresses: vajdi@uma.ac.ir (M. Vajdi), Mehdi.Shahedi.Asl@unb.ca (M. Shahedi Asl).
https://doi.org/10.1016/j.ceramint.2020.08.164
Received 18 July 2020; Received in revised form 17 August 2020; Accepted 18 August 2020
Available online 20 August 2020
0272-8842/ © 2020 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
K. Vaferi, et al. Ceramics International 47 (2021) 567–580
results indicated that the maximum stress in the blade is on the top fir with conventional superalloys such as M152.
tree of the trailing corner. They also concluded that thermal expansion Despite the remarkable thermo-mechanical properties of the
and centrifugal load do not remarkably affect crack initiation at the top monolithic TiB2, ZrB2, and HfB2, they have limitations like weak flex-
fir tree. Graham et al. [24] studied the thermal characteristics of the gas ural strength and poor sinterability. The high amounts of oxide im-
flows and recommended several basic methods to promote the heat purities on the powder particles of these ceramics decrease their sin-
transfer estimation of turbine blades. Han and Goldstein [25] examined terability. In general, these ceramics are combined with other refractory
the effect of several parameters on heat transfer and flow characteristics phases such as SiC to promote the bending strength, fracture toughness
of impinging-jets in gas turbines. They understood that nozzle geo- and oxidation resistance [26–28]. The SiC reinforced boride matrix
metry, curved surfaces and turbulence could affect the heat transfer rate composites are promising alternatives for applications involving high
of impinging jets. temperatures (e.g. cutting tools, heat exchangers, aerospace industry,
Different methods have been proposed to increase the blade's life, gas turbine blades, etc.) [65,132]. Sadegh Moghanlou et al. [65] nu-
which can be categorized into three major groups including blade merically investigated the heat transfer behavior and temperature dis-
cooling methods such as active and passive methods [26–28], thermal tribution in the cutting tool made of SiC reinforced TiB2, HfB2 and ZrB2
barrier coating methods, and using proper material for producing ceramics. They pointed out that the addition of SiC to monolithic
blades. Utilizing cooling lines is the most common method to reduce the ceramics leads to a better thermal performance of cutting tools made of
temperature of blades and retain it below the allowable temperature these composites.
[29,30]. However, it should be noted that the cooling of blades results Up to now, to the best of our knowledge, ZrB2–SiC or HfB2–SiC
in a considerable decrease in thermal efficiency [20,31–33]. Thermal composites have not been considered in the gas turbine blade's manu-
barrier coatings (TBCs) can protect the turbine components against facturing. On the other hand, numerical methods are a powerful tool in
excessive temperatures by providing thermal insulation. TBCs are ad- investigating the heat transfer and stress distribution or optimizing the
vanced ceramic coatings, which consist of oxidation- and corrosion- engineering problems [133–139]. So in the present work, the influence
resistant layers. Because of lower thermal conductivity of these coat- of exploiting SiC doped ZrB2 and HfB2 composites on heat transfer rate
ings, they can act as a thermal barrier to reduce the blade surface and thermal stresses in stator blades have not been examined. In the
temperature [34,35]. Moreover, TBCs are transparent to radiations of present study, HfB2–SiC and ZrB2–SiC composites are selected as al-
hot gases and can decrease the thermal stresses [36,37]. The third ternative materials in the manufacturing of gas turbine stator blades.
method for increasing the blade's life is using materials with high re- The deformations, thermal stresses, and temperature distributions in
sistance against heat and hot-corrosion. Superalloys and ceramics are the blades made of these materials are investigated. Heat transfer in the
two groups of promising alternative materials utilized in the hottest HfB2–SiC and ZrB2–SiC made turbine blades is investigated numerically
parts of turbines. They retain their durability, structural stability, and using finite element method analysis.
mechanical properties at high temperatures better than the other ma-
terials. Predominantly turbine blades are made of stainless steel, tita- 2. Stator blade geometry
nium, nickel alloys, etc. [38]. Since the turbine is directly located after
the combustion section, the hot combustion gases pass into the first The selected geometry for investigating thermal characteristics of
stage of turbine blades. Thus, the blades need to withstand tempera- the gas turbine stator blade is same as the applied geometry in Refs.
tures over 2000 °C, while steel and nickel possess the melting points of [71,131]. Fig. 1 depicts an overview of the chosen geometry for the
about 1480 °C and 1455 °C [39,40]. investigated turbine blade. As mentioned in the introduction part, the
Ceramics, in particular the ultrahigh temperature ceramics blades are exposed to very high temperatures and faced metallurgical
(UHTCs), have much higher melting points (over 3000 °C) [41–49]. problems. Therefore, it is needed to cool the blades using the com-
UHTCs are a specific type of ceramics, which can be utilized in harsh pressor's outlet air. The bleed-air flow from the compressor (T = 600 K
environments containing extreme temperatures and chemical re- and P = 30 bar) directed to the blade through internal cooling ducts.
activity. Considering the melting temperature as a criterion, a handful For a better understanding of the cooling process, the cooling ducts and
of carbides [50–59], borides [60–103], and nitrides [104] of transition some mounting details are indicated in Fig. 2. The detailed information
metals can be considered as UHTCs [66,105–107]. High strength, long about the geometry of ribs is neglected to simplify the calculation, and
fatigue life, good resistance to oxidation and corrosion at high tem- the average Nusselt number correlation is utilized to predict the heat
peratures are some of the most important features of UHTCs [108–125]. transfer coefficient accurately.
Borides such as TiB2, ZrB2, and HfB2 offer high thermal and electrical
conductivities, good elastic modulus and excellent hardness [99–101]. 3. Governing equations
They have widely used in oxidizing environments because of their su-
perior oxidation resistance in comparison with the other materials The gas turbine components are exposed to high-temperature flue
[126–129]. gases. The high-temperature combustion gases transfer heat to the
The mentioned features and the high thermal conductivity of UHTCs blade surfaces by convection mechanism. Computational Fluid
have encouraged researchers to utilize these ceramics to enhance the Dynamic (CFD) principles can predict the temperature distribution in
heat transfer performance of turbines. Vaferi et al. [130] examined the turbine blades. In the present study, conjugate heat transfer is carried
temperature distribution and deformations of a gas turbine stator blade out to acquire thermal and mechanical performance data on the stator
made of monolithic TiB2. They reported a reduction in thermal stresses, blade. The heat diffusion and linear elastic equations are considered as
as well as an enhancement in maximum displacement using TiB2 the governing equations to cover thermo-mechanical characteristics of
ceramic instead of ZrB2. Nekahi et al. [131] numerically investigated blades. The heat diffusion equation in the stator blade is as follow
the heat transfer behavior and thermal stresses in a turbine blade made [71,131]:
of HfB2 ceramic. They achieved a safety factor of 1.28 (based on Cou-
lomb-Mohr theory) and reported that HfB2 made blades can simply T
C = . (k T )
withstand the applied compressive stresses. Sadegh Moghanlou et al. t (1)
[71] offered a solution to decrease the gas turbine's defects at higher
temperatures by utilizing UHTCs such as ZrB2. They used Comsol
where t (s ) and T (K ) are allocated to time and temperature. ( ), C
kg
m3
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
Fig. 1. (a) An overview of selected geometry of the blades, and (b) the blade with cooling ducts shown.
any point, and the reference temperature at points with no strain, re- where v represents the Von Mises stress. Moreover, x , y and z are
spectively. The initial strains and stresses are not taken into account in allocated to the normal stresses, and xy , zx and zy show the shear
these equations, and the properties of the applied material are regarded stresses in three directions. In Eq. (8) n exhibits the safety factor, Sut (Pa)
to be isotropic. In Eq. (4), D(Pa) states the sixth order elasticity tensor. and Suc (Pa) display the ultimate tensile strength and ultimate com-
It demonstrates the stiffness matrix of the material and because of the pressive strength, respectively. It should be mentioned that A and B
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
Fig. 3. The comparison between the safe areas in (a) Von Mises, and (b) Coulomb-Mohr criteria.
are the principle stresses of the blade in different directions. The gen- The turbine engine works at the local temperature of 900 K, and the
erated temperature gradient together with no movement feasibility in heat transfer coefficient is about 25 m2.K . The average Nusselt number of
W
the fixed supports of the stator blade lead to thermal stresses. When the 400 is regarded for the cooling passages to simplify the calculations of
blades made of composites such as ZrB2–SiC, or HfB2–SiC are heated flow inside the ducts. The heat flux in cooling ducts is calculated by Eq.
and expanded, they are exposed to compressive stresses. Hence, the (10) [71].
third case of Eq. (8) is suitable to estimate the failure possibility in the
1
blades made of such UHTCs. k 1 0.332 Re x2 Rex 5 × 105
h= Pr 3 × 4 Re 5
x x 5 × 10
0.0296 Re x5 (9)
4. Boundary conditions
Nucool µcool Ccool
q = (Tcool T)
Fig. 4 demonstrates the different surfaces of the turbine blade, 2Prcool Hcool (10)
which are exposed to thermal boundary conditions. The hot flow of
combustion gases with the temperature around 1100 K and pressure of in which C ( ), µ( ), and H(m) indicate the heat capacity, visc-
J
kg . K
kg
m.s
30 bar passes over the blade surfaces. The related heat flux is specified osity, and the characteristic length of cooling air, respectively. Fig. 5
utilizing the convective heat transfer coefficient which is presented by displays the surfaces with the thermally insulated boundary condition.
Eq. (9) [141]. In this equation, x (m) shows the distance from the be- Moreover, it is needed to apply solid mechanics boundary condi-
ginning of the plate. The sound speed is considered 650 m/s, and the tions to solve the linear elastic equations. Spring foundations and roller
subsequent Mach number is about 0.7 for the pressure side and 0.45 for are the boundary conditions used to control the movement of the blade.
The rest of the boundaries are free to move as a result of thermal ex-
( )
the suction side [71,130]. The parameter U s in Reynolds number
m
Fig. 4. The different surfaces of the blade with the convective cooling boundary condition.
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
Fig. 6. The (a) top and (b) bottom views of the spring foundation.
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
Fig. 8. The thermal conductivity variations of the studied materials vs. temperature [143].
Fig. 9. The coefficients of thermal expansion (CTE) for the studied materials as a function of temperature [143].
Table 1
The Young's modulus values for the used materials.
Material Young's modulus (GPa) Reference
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
Fig. 11. The temperature distribution in the blade made of ZrB2–SiC composite.
Fig. 12. The temperature distribution in the blade made of HfB2–SiC composite.
Fig. 13. The temperature contours in the blades made of (a) HfB2, (b) ZrB2, (c) HfB2–SiC, and (d) ZrB2–SiC UHTCs.
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
Fig. 14. The principal stresses in the blade made of ZrB2–SiC composite.
Fig. 15. The principal stresses in the blade made of HfB2–SiC composite.
Fig. 16. The stress distribution in the blades made of (a) HfB2, (b) ZrB2, (c) HfB2–SiC and (d) ZrB2–SiC UHTCs based on the Coulomb-Mohr criterion.
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
Fig. 17. The stress distribution in the blades made of (a) HfB2, (b) ZrB2, (c) HfB2–SiC and (d) ZrB2–SiC UHTCs based on the Von Mises criterion.
Table 2 efficiency. The addition of SiC to monolithic HfB2 and ZrB2 ceramics
The safety factor values for the ZrB2–SiC and HfB2–SiC materials. reduces their thermal conductivity (Fig. 8), and following that, the
Material Safety factor
temperature uniformity in blades decreases. As a result, the thermal
stresses and the probability of failure in the stator blades increase.
Coulomb-Mohr Von Mises However, it seems that the other properties of the material such as
coefficient of thermal expansion and Young's modulus have better im-
ZrB2–SiC 1.32 1.6
HfB2–SiC 1.4 1.7
pacts on the exposed stresses.
ZrB2 [153,154] 1.02 1.27 Figs. 14 and 15 illustrate the principal stresses of the stator blade
HfB2 [131] 1.28 1.56 made of ZrB2–SiC and HfB2–SiC composites, respectively. As can be
seen, the utilization of ZrB2–SiC composite caused to produce less
maximum principal stress in the stator blades compared to using
and subsequent thermal stresses [131,150]. Fig. 3 provides a compar- HfB2–SiC one. As mentioned earlier, the thermal characteristics of
ison between the temperature contours of the four proposed materials. materials such as thermal conductivity and thermal expansion have
According to Fig. 13a–b, at temperatures above 500 K, ZrB2 has higher significant effects on the thermal stresses, which are appeared in the
thermal conductivity than HfB2 (as shown in Fig. 8), which causes more blades. By decreasing the temperature gradient in the stator blade, the
uniform temperature distribution in the blade made of ZrB2. Therefore, applied thermal stresses are reduced. In order to diminish the tem-
it can be concluded that the high thermal conductivity of materials perature gradients, it is required to use a material with higher thermal
results in temperature gradients reduction, which subsequently de- conductivity. According to Fig. 8, it can be seen that because of the
creases the related thermal stresses. The lower thermal stresses in the higher thermal conductivity of ZrB2–SiC in comparison with HfB2–SiC,
turbine components, the longer life span of them. It should be noted the utilization of ZrB2–SiC reduces the stresses in the blade through
that the high thermal conductivity of materials causes more dissipation providing a better temperature distribution. On the other hand,
in the heat and energy of the inlet gases, which reduces turbine
Fig. 18. The force distribution plots for blades made of (a) HfB2–SiC and (b) ZrB2–SiC composites.
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
Fig. 19. The displacement plots for blades made of (a) HfB2–SiC and (b) ZrB2–SiC composites.
Fig. 20. The displacement plots for the blades made of (a) HfB2, (b) ZrB2, (c) HfB2–SiC and (d) ZrB2–SiC UHTCs.
ZrB2–SiC has a lower thermal expansion coefficient than HfB2–SiC withstand the applied stresses. The calculated safety factors for the
(Fig. 9), which is another reason for the lower stresses in the blade proposed materials based on both Coulomb-Mohr and Von Mises cri-
made of ZrB2–SiC. In the present study, two criteria of Coulomb-Mohr teria are presented in Table 2. Based on these results, Coulomb-Mohr is
and Von Mises are used to measure the safety factor of the stator blade. more accurate criterion than Von Mises for investigating the probability
Figs. 16 and 17 show the stress distribution plots based on Coulomb- of failure in brittle materials.
Mohr and Von Mises criteria, respectively. Among the investigated Fig. 18 shows the force distribution plots on the blade surfaces in
UHTCs, the utilization of ZrB2 causes the highest stress; whereas ap- contact with the turbine walls. As can be expected, lower force is ap-
plying ZrB2–SiC in the manufacturing of blades provides the best per- plied on the blade made of ZrB2–SiC composite. Displacements and
formance for turbines by inducing less stresses. In the Coulomb-Mohr deformations of the stator blades made of HfB2–SiC and ZrB2–SiC ma-
criterion, the compressive principal stresses are used to calculate the terials are indicated in Fig. 19. The minimum displacement occurs at
safety factor, while in the Von Mises theory, the factor of safety is the thermal insulation wall and increases to the leading edge of the
computed by normal and shear stresses. The values of 0.9 and 0.75 GPa blade. The maximum displacements of blades made of these composites
were reported for the compressive strength of HfB2–SiC and ZrB2–SiC are approximately same (with a difference of 0.06 mm). Spring foun-
composites, respectively [145,151,152]. By comparing the obtained dations and rollers are the main reasons to decrease the displacement
maximum principle stresses and values of the compressive strength for values from the upper surface to the thermal insulation wall. Fig. 20
each material, it can be understood that both composites simply compares the displacement and deformation plots of stator blades made
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K. Vaferi, et al. Ceramics International 47 (2021) 567–580
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Declaration of competing interest
[20] M. Rezazadeh Reyhani, M. Alizadeh, A. Fathi, H. Khaledi, Turbine blade tem-
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[21] K.M. Kim, Y.H. Jeon, N. Yun, D.H. Lee, H.H. Cho, Thermo-mechanical life pre-
interests or personal relationships that could have appeared to influ- diction for material lifetime improvement of an internal cooling system in a
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Acknowledgements transfer, stress and failure in a gas turbine blade with circular cooling passages,
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Mohsen Mohammadi acknowledges the funding received from 2011.03.002.
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Natural Sciences and Engineering Research Council of Canada (NSERC) blades in a gas turbine engine by mechanical analysis, Eng. Fail. Anal. 9 (2002)
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