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Aldehydes & Ketones 11/4/2020

Nomenclature

• common name derived from the corresponding acid


name
Aldehydes & Ketones
replaced with
Dr. T. Geetha
St. Mary's College Thrissur

Nomenclature IUPAC Nomenclature

H
Cl

O
Cl
Cl

Trichloroacetaldehyde/ Chloral ɑ- Bromo-ɑ-methyl propionaldehyde Methyl Phenyl Ketone Methanal 2- Bromo-3-methylheptanal Hept-3-enal

Dimethylketone Ethyl methyl ketone Propanone 1-Phenylpropan-1-one


DiPhenyl Ketone/Benzophenone 2-Methylcyclohexanone

Preperation
Structural isomerism
Metamerism
• By oxidation of 1o alcohol
Chain isomerism Functional isomerism

Pentanal

3-Pentanone 2-Pentanone

Position isomerism

2-Methylbutanal
Tetrahydropyran
Pent-2-en-1-ol Pent-3-en-1-ol
/Oxane

St. Marys College, Thrissur 1


Aldehydes & Ketones 11/4/2020

Preperation Oxidation of 2o alcohol to ketone


By oxidation of 1o alcohol

Oppenauer Oxidation Dehydrogenation of alcohol

Reverse of MPV reduction Double bond remains undisturbed

Dehydrogenation of alcohol

St. Marys College, Thrissur 2

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