Scribd Logo
Upload

Welcome to Scribd!

  • Aldehydes & Ketones Notes 2

    Uploaded by

    geethamukundant652
    6 views5 pages
    The document discusses the synthesis of aldehydes and ketones. It describes several methods for synthesizing them including reduction with DIBAL-H, Rosenmund reduction using acid chlorides and Grignard's reagents, and the distillation of calcium carboxylates. It also discusses the chemical properties of aldehydes and ketones such as their planar, trigonal geometry and ability to undergo nucleophilic addition reactions.

    Original Description:

    Aldehydes & Ketones 2

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document discusses the synthesis of aldehydes and ketones. It describes several methods for synthesizing them including reduction with DIBAL-H, Rosenmund reduction using acid chlorides and Grignard's reagents, and the distillation of calcium carboxylates. It also discusses the chemical properties of aldehydes and ketones such as their planar, trigonal geometry and ability to undergo nucleophilic addition reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    6 views5 pages

    Aldehydes & Ketones Notes 2

    Uploaded by

    geethamukundant652
    The document discusses the synthesis of aldehydes and ketones. It describes several methods for synthesizing them including reduction with DIBAL-H, Rosenmund reduction using acid chlorides and Grignard's reagents, and the distillation of calcium carboxylates. It also discusses the chemical properties of aldehydes and ketones such as their planar, trigonal geometry and ability to undergo nucleophilic addition reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 5

    Aldehydes & Ketones 11/4/2020

    Stephen reaction

    Synthesis of Aldehydes & Ketones

    Dr. T. Geetha
    St. Mary's College Thrissur

    Reduction with DIBAL-H Alkyl Cyanide & Grignards reagent

    If excess of grignards reagent is used, reaction continues to form tertiary alcohol

    Rosenmund reduction Acid chloride & Grignards reagent

    St. Mary's College, Thrissur 1


    Aldehydes & Ketones 11/4/2020

    Acid chloride & Dialkylcadmium Acid chloride & Dialkylcadmium

    Acid chloride & Dialkylcadmium Calcium carboxylate


    Dry distillatrion of calcium formate yields formaldehyde
    Synthesis of Dialkylcadmium

    Dry distillatrion of calcium carboxylate other than calcium formate yields ketones

    Calcium carboxylate Aromatic aldehyde

    Etards Reaction

    • Dry distillatrion of a mixture of calcium formate & calcium carboxylate yield


    aldehyde along with formaldehyde and a symmetrical ketone

    • Dry distillatrion of a mixture of two different calcium carboxylate will yield a


    mixture of an unsymmetrical ketone & two symmetrical ketone

    • Mixture is seperated by fractional distillation

    St. Mary's College, Thrissur 2


    Aldehydes & Ketones 11/4/2020

    Aromatic aldehyde Rosenmund reduction

    Etards Reaction

    Stephen reaction

    Reduction with DIBAL-H Fridedel Crafts acylation

    Alkanenitriles

    St. Mary's College, Thrissur 3


    Aldehydes & Ketones 11/4/2020

    Alkanenitriles chemical properties

    sp2 hybridised carbon Planar Trigonal planar geometry

    Nucleophilic addition reaction Comparison aldehydes & Ketones

    Planar

    Comparison aldehydes & Ketones Comparison aldehydes & Ketones

    St. Mary's College, Thrissur 4


    Aldehydes & Ketones 11/4/2020

    Aromatic & Aliphatic aldehyde

    St. Mary's College, Thrissur 5

    You might also like