You are on page 1of 7

This article was downloaded by: [University of Colorado at Boulder Libraries]

On: 02 January 2015, At: 07:15


Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered office: Mortimer
House, 37-41 Mortimer Street, London W1T 3JH, UK

Welding International
Publication details, including instructions for authors and subscription information:
http://www.tandfonline.com/loi/twld20

Methods for reducing weld porosity in argon-shielded


arc welding of aluminium alloys
a a b b b
M.M. Shtrikman , A.V. Pinskii , A.A. Filatov , V.V. Koshkin , E.A. Mezentseva &
b
N.V. Guk
a
Scientific Research Institute of Aviation Technology , Moscow, Russia
b
Sukhoi Design Bureau , Moscow, Russia
Published online: 04 May 2011.

To cite this article: M.M. Shtrikman , A.V. Pinskii , A.A. Filatov , V.V. Koshkin , E.A. Mezentseva & N.V. Guk (2011) Methods
for reducing weld porosity in argon-shielded arc welding of aluminium alloys, Welding International, 25:06, 457-462, DOI:
10.1080/09507116.2011.554241

To link to this article: http://dx.doi.org/10.1080/09507116.2011.554241

PLEASE SCROLL DOWN FOR ARTICLE

Taylor & Francis makes every effort to ensure the accuracy of all the information (the “Content”) contained
in the publications on our platform. However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness, or suitability for any purpose of
the Content. Any opinions and views expressed in this publication are the opinions and views of the authors,
and are not the views of or endorsed by Taylor & Francis. The accuracy of the Content should not be relied
upon and should be independently verified with primary sources of information. Taylor and Francis shall
not be liable for any losses, actions, claims, proceedings, demands, costs, expenses, damages, and other
liabilities whatsoever or howsoever caused arising directly or indirectly in connection with, in relation to or
arising out of the use of the Content.

This article may be used for research, teaching, and private study purposes. Any substantial or systematic
reproduction, redistribution, reselling, loan, sub-licensing, systematic supply, or distribution in any
form to anyone is expressly forbidden. Terms & Conditions of access and use can be found at http://
www.tandfonline.com/page/terms-and-conditions
Welding International
Vol. 25, No. 6, June 2011, 457–462
Selected from Svarochnoe Proizvodstvo 2009 62(12) 16 – 22

Methods for reducing weld porosity in argon-shielded arc welding of aluminium alloys
M.M. Shtrikmana, A.V. Pinskiia, A.A. Filatovb, V.V. Koshkinb, E.A. Mezentsevab and N.V. Gukb
a
Scientific Research Institute of Aviation Technology, Moscow, Russia; bSukhoi Design Bureau, Moscow, Russia

Cause analysis of porosity in aluminium argon-arc welded joints is carried out, particularly that of aluminium– lithium alloy
1424. Feasible production methods of reducing the quantity of voids in the joints are considered.
Keywords: aluminium; aluminium –lithium alloys; weld pool; voids; nucleation/initiation; degassing

The aluminium alloys, used widely as the structural alloy in metallurgical production is restricted. In proces-
Downloaded by [University of Colorado at Boulder Libraries] at 07:15 02 January 2015

material for aircraft, are continuously improved by sing components made of aluminium –lithium alloys, a
increasing their corrosion resistance and specific strength surface layer with the thickness of up to 0.3 mm is removed
characteristics. The most important requirement is to before welding from the welded edges by machining or
ensure high technological properties, including weldability chemical treatment. In some cases, it is recommended3 to
of the alloy. One of the special features of aluminium and carry out thermal vacuum treatment of the welded
its alloys, which greatly complicates welding, is the elements in order to dissociate hydrides and other unstable
formation of a surface oxide film characterized by high gas compounds, reduce the lithium content of the surface
adsorption capacity. The moisture adsorbed on the porous layer, and remove the volatile breakdown products.
oxide film in the form of aluminium hydroxide with Furthermore, even if all the requirements imposed by
variable composition (Al2O3·n H2O) and other contami- the currently valid instructions on the preparation of
nants interacts with the liquid weld pool metal and produces components for welding and welding materials are
hydrogen bubbles in the melt1,2. satisfied, in some cases, it is not possible to produce
The surface of aluminium –magnesium alloys with welded joints without pores. Some of the pores remain
lithium contains a thicker (up to 0.3 mm) and porous layer between the crystals during solidification of the weld pool.
with oxides and the layer absorbs a large amount of The rising and escape of the bubbles in welding of more
moisture3,4. In metallurgical production of semi-finished complicated (in comparison with butt) types of joint
products to be welded, the surface layers of the products (T-joints) become far more difficult. Therefore, it is very
show the formation of chemical compounds of the type of important to intensify the second stage of the pore
hydrides and hydrocarbonates which generate hydrogen in formation process in welding – rising and escape of the
the form of bubbles in the liquid metal of the weld pool and bubbles from the melt.
in the solid – liquid metal of the weld zone. The pore Many authors, investigating the kinetics of pore
nuclei2,4,5 form mostly on the refractory oxide inclusions formation in the welded joints, note that the effect on the
with low wetting which penetrate into the weld pool from weld pool causing mixing or oscillations of the melt leads
the boundary oxide layer on the surface of the welded to rising and removal of the gas bubbles from the melt.
components and the filler wire. This process is intensified by different procedures –
The formation of pores in the metal of the welded mechanical oscillations of the arc7, intermittent supply of
joint and the weld zone may also be caused by metal- the filler wire8, superposition of short-term powerful
lurgical hydrogen present in the semi-finished products1. current pulses on the main welding current9, low-
A significant role in the formation of pores is played1,6 by frequency modulation of rectangular current of different
the process of diffusion of hydrogen from the parent metal polarity10, electromagnetic stirring11, etc.
observed at the hydrogen content in the metal higher than In this work, investigations were carried out on
1.4 cm3/100 g. methods of reducing weld porosity in argon-shielded arc
One of the reasons for the formation of pores1,6 is the welding of an alloy of the Al –Mg –Li system, i.e. 1424
jump-like change of the solubility of hydrogen with the alloy, used as the structural materials for aircraft
variation of the temperature of the weld pool and the weld containers, including fuel tanks. The 1424 aluminium
zone with the solid –liquid metal (Table 1). alloy is recommended12 as the material with high specific
The pore formation process usually takes place in two strength (r ¼ 2.54 g/cm3) and high corrosion resistance.
stages: nucleation and growth of a pore, floating upwards, The chemical composition and mechanical properties of
and escape of the pore from the melt. the alloy are presented in Table 2.
In the first stage, to reduce the number of nuclei of gas The fuel tank is assembled from rigid panels joined
bubbles, it is necessary, if possible, to block the source that together by automatic argon-shielded arc welding. The
generates of hydrogen into the weld pool. Therefore, the main types of welded joint in the structure of the fuel tank
amount of impurities in the semi-finished products of the are simple butt and T-joints. Since the tank is filled with
ISSN 0950-7116 print/ISSN 1754-2138 online
q 2011 Taylor & Francis
DOI: 10.1080/09507116.2011.554241
http://www.informaworld.com
458 M.M. Shtrikman et al.

Table 1.

TU 1-804-397-
Solubility of hydrogen

Source

2002
3
cm /100 g Mass Volume
T (oC) of metal fraction (%) fraction (%)
300 0.01 9.44 £ 1028 0.0024
660 (solid) 0.0036 3.4 £ 1026 0.0862

Kamensk-Uralsky Metallurgical Plant (KUMP)


6.52 £ 1025

Zn
660 (liquid) 0.69 1.65


700 0.92 8.7 £ 1025 2.2

, 0.0015
800 1.67 4.0

Na
Impurities (%)
fuel, the welded joints are subject to stringent leak

,0.08
tightness requirements and, consequently, more stringent

Si
standards of acceptable porosity.
Downloaded by [University of Colorado at Boulder Libraries] at 07:15 02 January 2015

The specimens of 1424 alloy with a thickness of

, 0.1
Fe
2.5 mm and the dimensions for welding butt joint of
300 £ 90 mm and T-joints 250 £ 90 mm (the flange of the
T-joints), and 250 £ 35 mm (the web of the T-joints) were

0.07– 0.1

Supplier
Zr
prepared for welding in accordance with the currently
valid instructions. The surface layer was removed by
mechanical or chemical milling and scraping (immedi-

d (%)
Co
ately prior to welding) to a depth of 0.25 mm from both

10


sides of each butt-welded edge at a distance of 15 mm from
the end of the edges, and also from the surface of the

Transverse
elements joined by T-joints (Figure 1(c)). The specimens

s0.2

290
(MPa)
V


were assembled and secured for welding in a special

Mechanical properties, minimum


experimental stand: for butt welding on a replaceable
backing plate without any holes and with small holes

430
(MPa)
with a diameter 1.5 mm, the distance between the holes

sB
Ti


was 15 –20 mm for supplying argon to the surface of the
melt of the welded joint during welding.
The sheet components for welding T-joints were d (%)
Cu

8
assembled by placing the web between two angular
Composition (%)

backing plates (Figure 1(b)), preventing movement of the


0.1– 0.25

Longitudinal

web so that the end of the edge of the flange was situated
s0.2

290

380
Mn

(MPa)

approximately on the level of the upper surface of the


backing plate (not lower). Subsequently, the flange of the
T-joints was placed on the end of the edge of the web and
0.02 –0.2

the surface of the backing plate and pressed to them.


430

460
(MPa)
Be

sB

Welding was carried out using ADSV 6 automatic


welding equipment with AMg63 filler wire with an arc
Type of semi-finished products according to

Sheet, d ¼ 1.5 – 6.0 mm, TU 1-804-397-

power source – Magic Wave 2600 CrL inverter welding


0.05 – 0.08

equipment, manufactured by Fronius (Austria). The


Sc

conditions for automatic argon-shielded arc welding of


Pressed profile, TU 1-804-395-2002

the specimens are presented in Table 3.


X-ray examination of the welded joints showed small
0.4 – 0.7
Zn

pores mainly in the zones with accelerated cooling and


TU

solidification of the weld metal – at the interface and in the


root of the welded joint (Figure 2(a)). Larger pores were
1.5– 1.8

found in the central and upper part of the welded joints


Li

(Figure 2(b)). Evidently, these pores did not manage to


move to the surface of the weld pool during solidification.
4.7– 5.2

In the welded T-joints, the oxide inclusions and pores of


Mg

2002

different sizes were concentrated mostly in the root of the


welded joint (Figure 2(c)). This may be due to the fact that
1424TG1

the surface of the edges in the T-joints is placed in a less


Table 2.

Alloy

favourable position in comparison with the butt-welded


1424

joint for treatment with the arc discharge and also for
Welding International 459

(a) (b)
≥ 30 P P

1
Treatment zones 2
≥ 15

8
R

4 S 3

Figure 1. Preparation of the surface of the edges (a) and assembling diagram (b) for welding T-joints: (1) the flange, (2) the clamping
inserts (two), (3) angular backing sheet and (4) the web.

rising and the removal of the defects from the root of the centres of initiation of gas bubbles and become
Downloaded by [University of Colorado at Boulder Libraries] at 07:15 02 January 2015

welded joint. zones of fracture.


The defect characteristics of the welded joints in the
aluminium alloys – the small pores and oxide inclusions – The removal of the oxide figure from the surface of the
could not be always detected by X-ray and ultrasonic welded edges and the welding wire results in a large
examination, especially in the T-joints. These defects were reduction in the number of pores of the welded joint, but
detected in fractographic examination of the fracture this is not the only condition for producing the welded
surface of the full-size welded specimens with a working joints without pores. The hydrogen, forming the pores,
cross section of 50 £ 2.5 mm (flange) and 20 £ 2.5 mm may penetrate into the weld pool from other sources –
(web), tested in low-cycle fatigue (LCF) by tensile loading from the welded and welding materials, especially from
along the joint. The typical defects (Figure 3) acted as the shielding gas.
areas of failure of the specimens in the test. Table 4 shows It is well known that even high-quality argon contains
welding defects detected on the fracture surface of the small amounts of impurities – oxygen, hydrogen, and
fatigue specimens tested by pulsed tensile loading of the nitrogen. In most cases, the metal is protected against the
T-joints in the welded specimens of the sheets of 1424 effect of air in the welding zone on the front side by
alloy (flange thickness 2 mm, web thickness 2.5 mm), blowing in argon, and on the weld root side it is shielded
produced by automatic argon-shielded arc welding with using a backing strip. In the production, the melt is
AMg63 filler. protected against air using a temporary backing sheet with
Analysis of the fracture zones in an electron scanning an internal channel with small holes (diameter approxi-
microscope shows the following. mately 1 mm) spaced at a small distance (15 – 25 mm)
along the entire channel. Argon is supplied through the
. The LCF testing of the welded specimens with channel and the holes on the surface of the melt heated
pulsed tensile loading results in multiple area during welding to a high temperature. Argon has the
fatigue fracture. positive thermodynamic potential DGT0 , so that according
. The fine pores and oxide inclusions open up in the to the DGT0 – T equilibrium diagram and the equilibrium
path of propagation of the fatigue crack and change constant ln KP –T, the surface of the melt is oxidized with
the direction of crack propagation, accelerating the formation of Al2O313. A spot with different degrees of
crack propagation and reducing the endurance of the oxidation (depending on the temperature of the metal and
welded joint. Therefore, care must be taken when the rate of discharge of the argon jets) remains opposite
considering recommendations made by certain every hole of the backing strip on the surface of the melt.
authors who propose different methods of complete As the consumption of argon increases, the diameter of
fracture of the oxide film and assume that this could the hole in the backing sheet becomes smaller, the rate
result in changes in the requirements in production of discharge of the argon jet and the amount of discharge
on the removal of the oxide film from the surface of of argon increase, and, consequently, the impurities in
the edges. However, the particles of the fracture argon manage to interact with the hot metal in the high-
film, penetrating into the weld pool, may act as the temperature stage of the weld cycle. Thus, suitable

Table 3.

Welding wire diameter Welding current Welding speed Wire feed rate Argon flow rate
Joint (mm) (mA) (m/h) (m/h) (l/min)
Butt 1.6 120 16 – 18 60 – 70 10
T 2.0 200– 220 12 – 14 60 – 80 12

Note: Automatic argon-shielded arc welding, thickness of specimens 2.5 mm, alloy 1424.
460 M.M. Shtrikman et al.

Figure 2. (a) Pores and oxide inclusions in a butt-welded joint at the weld boundary (b) and the upper part of the welded joint (c) and
also in the root of the T-welded joint.
Downloaded by [University of Colorado at Boulder Libraries] at 07:15 02 January 2015

Figure 3. Areas of fracture of the welded specimens in testing to determine sB and LCF: (a) a chain of pores, excess metal on the web,
and the flange of the T-joints, coarse traces of dressing the welded joint; (b) oxidized pores and cracks on the surface of the fillet and
(c) internal pores.

thermodynamic conditions are created for the reaction of impurities in the composition of argon at the hot surface of
the gas impurities present in argon with the metal of the the melt.
melt and for the formation of the oxide skin on the melt14. It was also established that the effective shielding of
The experimental results show that the degree of the melt in welding can be achieved by using a temporary
oxidation of the melt in the area of discharge of the jet backing sheet tightly pressed to the welded edges and to
from the hole and the number of pores in the welded joint the penetration area without additional blowing of argon
decrease (Table 5) with the decrease of the consumption of (Table 5, II-3). If there is no tight contact between the
argon in blowing into the backing sheet from 5 to welded edges and the penetration area with the backing
0.3 l/min. This is explained by the reduction of the rate of sheet, the backing sheet should be purged with argon at a
discharge of argon from the holes and of the amount of gas rate of 4– 5 l/min prior to welding. The argon flow rate

Table 4.

Number of cycles to fracturea at smax (MPa)


Fractographic features of zones with fatigue
Loading direction sB (MPa) 160 250 fracture areas

Along the joint 550– 580 14; 150 2 177; 849 15; 520 2 22; 970 Chains of pores carried
100; 780 21; 598 on and below the surface of
the fillet; oxide films on the
surface of the fillet and below
the surface
Across the joint 415– 425 110; 740 2 261; 550 1290 2 25; 000 Pores and geometrical stress concentrators on
160; 155 17; 324 the fillet in the form of
excess metal on the web and
flange of the specimen
a
v ¼ 5 Hz. The lowest, highest, and mean values of endurance determined on the basis of the results of tests on five specimens are presented.
Welding International 461

Table 5.

Number of pores
Experiment Variant in 100 mm of
no. The varied technologicalparameter no. Variants of the technologicalparameter welded joint
I Heat removal into the equipment 1 A backing sheet and support played 22 – 25
through the backing below the clamping keys – copper
sheet and clamping keys
2 The same, steel 10 – 12
II Blowing argon through the 1 With blowing argon 22 – 25
holes in the copper backing sheet fluoride 4 – 5 l/min
3 Without blowing (no holes) 8 – 10
4 Blowing into the backing sheet 3–5
prior to welding, 4 – 5 l/min
Blowing in welding, 0.3 – 0.5 l/min
III Stirring of the weld pool 1 Without rotation of the arc 22 – 25
5 With rotation of the arc and axial 6–8
feed of welding wire
Downloaded by [University of Colorado at Boulder Libraries] at 07:15 02 January 2015

6 The same, with the welding wire 1–3


preheated during welding
IV Heat and mass transfer of the 1 The axes of the electrode and of 22 – 25
metal to the interface in the the nozzle of the welding torch
tail part of the weld pool were perpendicular to the weld axis
7 The same, with tilting by 20 – 258from 10 – 13
the vertical in the welding direction

Notes: (1) Automatic argon-shielded arc welding, AMg63 filler wire, alloy 1423, d ¼ 2.5 mm, the type of joint - butt. (2) The central part of the welded joint 250 mm long into
specimens for each variant was examined. (3) The results of approximate calculations of the number of pores (the projection of the pores on radiographs and within the limits of
the resolution power of the method) reflect the tendency for the reduction of porosity using the proposed method.

should then be gradually reduced to 0.2– 0.3 l/min and the pores decreases by a factor of 1.5– 2. Additional gas jet
welding should be carried out at this flow rate (Table 5, flows can also be used for this purpose15.
II-4). At the same time, the flow of new volumes of argon As mentioned previously, stirring of the weld pool
to the heated metal is reduced, and, consequently, the supports degassing of the pool. An efficient method of
amount of the impurities in argon is lower. intensifying degassing of the pool is welding with a
The time during which the weld pool is molten and, rotating electrode with vertical feed of the filler wire
consequently, the rising time of the gas bubbles is through an insulating channel in the axial part of the
increased are by reducing the intensity of heat removal welding head16. As shown in Figure 4, continuous
from the welding zone into the clamping device. preheating of the filler wire1 increases the heat content
Two groups of specimens were welded (three speci- of the weld pool and also the duration of the existence of
mens in each group). The specimens were assembled for the weld pool which together with the stirring of the pool
welding on a copper plate with an insert made of a copper with the forces of rotation of the rotating arc has a
sheet between the welded edges and the clamping keys of
welding equipment (the first group, Table 5, I-1) and on
the backing sheet of 1Cr18Ni9Ti steel with an insert below
the clamping keys also made of stainless steel (second
group, Table 5, I-2). According to radiographs, the number
of the pores in the welded joints of the specimens of the
second group is 2 – 3 times smaller than in the welded joint
of the specimens of the first group (Table 5). 1
The solidification rate of the metal which delays I0
the exit of the pores from the weld pool is linked with the
temperature gradient at the interface in the tail part of
Iw
the weld pool. Investigations were carried out into the 2
possibilities of increasing the heat content of the zone and Ar Ia
the degassing time of the weld pool metal by the transfer of
mass of hot metal from the central part of the pool into the
tail part and, consequently, displacing the solidification
front. This was carried out by affecting the liquid metal of
the weld pool by the pressure of the arc and the argon jet
which displaces the liquid metal into the tail part of the Figure 4. Diagram of argon-shielded arc welding with a
pool when the torch tilted (the axis of the electrode and the rotating electrode and vertical feed of preheated filler wire: (1)
gas jet) by 20– 308by the ‘angle forward’. The number of filler wire and (2) tungsten electrode.
462 M.M. Shtrikman et al.

beneficial effect on the degassing conditions of the weld References


pool (Table 5, III-5, III-6). 1. Nikiforov GD. The metallurgy of fusion welding of
Advantages of the process of welding with a rotating aluminium alloys. Moscow: Metallurgiya; 1972.
arc with vertical feed include the increase of cleaning of 2. Obaturov VN, Erozin AA. The role of surface contamination
the surface of cathodic of the welded edges to remove the in the formation of pores in welding of aluminium alloys.
oxide film and also the protection of the surface of the Svar Proiz. 1971;8:21 –33.
3. Bokshtein SZ, et al. Effect of he treatment in vacuum on the
heating section of the filler wire against oxidation and
susceptibility of the 1420 alloy to the formation of pores in
contamination by passing the filler wire through an welding. Avt Svarka. 1975;9:52– 54.
insulating pipe just prior to introduction into the weld 4. Ishchenk AY, et al. Weldability and technology of arc
pool. welding of high strength alloy of the aluminium-magnesium-
lithium system. Avt Svarka. 1985;10:47– 49.
5. Patskevich IR, Deev GF. Effect of the properties of the
Conclusions interface on the nucleation of gas pores in welding. Svar
In argon-shielded arc welding of aluminium alloys, it is Proiz. 1973;9:53– 54.
necessary to use various methods to reduce the number of 6. Rabkin DM. Metallurgy of fusion welding of aluminium and
its alloys. Kiev: Naukova Dumka; 1986.
Downloaded by [University of Colorado at Boulder Libraries] at 07:15 02 January 2015

pores in the weld metal in the first and second stages of the
pore formation process. 7. Boldyrev AM. The mechanism of formation of the structure
In the first stage, the number of gas formation sources of the weld metal with the introduction of low-frequency
oscillations of the weld pool. Svar Proiz. 1976;2:52– 54.
falling into the weld pool can be reduced (in addition to
8. Zubrienko GL, et al. Argon-shielded arc welding of
fulfilling the requirements of the currently available aluminium alloys with intermittent filler wire feed. Svar
instructions on the preparation of the surface of the edges Proiz. 1980;6:46– 47.
of components for welding) using a backing plate for 9. Slavin GA. The formation of the misoriented structure of the
protection against air, with the plate tightly pressed to the weld metal in application of low-frequency oscillations on
edges and the penetration area, without additional blowing the weld pool. Svar Proiz. 1980;6:3– 5.
of argon during welding through holes in the backing plate 10. Ishchenko AY, et al. The effect of the parameters of low-
or with blowing argon prior to welding and with blowing frequency modulation of current with different polarity and
rectangular shape on the structure of the weld in welding of
during welding with the low consumption of argon (0.2 –
aluminium alloys. Avt Svarka. 1990;9:23– 27.
0.3 l/min).
11. Cheyun AG, et al. Arc welding of 014020 aluminium alloy
In the second stage of degassing, it is essential to using electromagnetic stirring. Avt Svarka. 1981;6:19– 21.
take technological measures directed at increasing the 12. Fridlyander IN, et al. Development of thermally stable Al –
duration of existence of the weld pool, reducing the Li alloy 1424 for application in the welded fuselage.
temperature gradient at the interface of the tail part of MiTOM. 2002;31:3– 7.
the pool, and ensuring highly efficient stirring of the 13. Shmykov AA. Relationship of the interaction of controlled
weld pool. atmospheres with metals. MiTOM. 1967;5.
These conditions are guaranteed during welding with a 14. Shtrikman MM. Protection of the reverse side of the welded
joint during welding. Svar Proiz. 1979;6:21– 25.
rotating tungsten electrode with the axial feed of preheated
15. Shtrikman MM, et al. Arc welding with the effect of
filler wire.
directional gas jet flows on the weld pool. Svar Proiz.
1999;12:3– 6.
16. Shtrikman MM. Argon-shielded arc welding of rotating
Note electrodes with a filler wire feed. Avt Svarka. 1983;1:
1. Author’s certificate 1166942 (USSR). 46 –47, 53.

You might also like