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ABSTRACT
T h e f r e q u e n c y d i s t r i b u t i o n or r e l a t i v e a b u n d a n c e o f m i n e r a l s in soils varies w i t h t h e
five p r i n c i p a l classes of factors t h a t g o v e r n soil f o r m a t i o n . T h e c h a r a c t e r i s t i c s of t h e
m i n e r a l s of t h e p a r e n t m a t e r i a l , t h e t i m e factor, c l i m a t i c factors, relief factors a n d
biotic factors e a c h c a n be s h o w n to h a v e i m p o r t a n t i n d e p e n d e n t effects on clay m i n e r a l -
ogy of soils u n d e r proper c i r c u m s t a n c e s . T h e soil p a r e n t m a t e r i a l e x e r t s a control o v e r
t h e f r e q u e n c y d i s t r i b u t i o n of m i n e r a l s in soils b y i n t r o d u c t i o n of t h e c l a y m i n e r a l s into
t h e soil directly, b y controlling t h e ecru'so of chemical w e a t h e r i n g i n t h e soil t h r o u g h
t h e relative susceptibility of its m i n e r a l s to w e a t h e r i n g , b y f u r n i s h i n g a b u n d a n t d i v a l e n t
metallic cations, b y i m p e d i m e n t of d r a i n a g e , or b y acceleration of l e a c h i n g w h e n h i g h l y
p e r m e a b l e . T h e t i m e f a c t o r is c o n s p i c u o u s as long t i m e s give a n a d v a n c e d degree of
w e a t h e r i n g e v e n in t e m p e r a t e climates. C l i m a t e is i m p o r t a n t , s i n c e h i g h l y w e a t h e r e d
m a t e r i a l s i n e v i t a b l y occur as a r e s u l t of i n t e n s e leaching in w a r m t r o p i c a l a n d e q u a t o r i a l
climates. R e l i e f is i m p o r t a n t in c o n c e n t r a t i n g leaching w a t e r a n d m e t a l l i c cations, in
affecting o x i d a t i o n or r e d u c t i o n . T h e biotic factor affects m i n e r a l s c o n s p i c u o u s l y w h e r e
a n A 0 horizon develops a n d r e s u l t i n g c h e l u v i a t i o n m o v e s R~Oa o u t of t h e A 2 horizon.
I n h e r i t e d m i n e r a l s s u c h as illite, q u a r t z , feldspars, f e r r o - m a g n e s i a n m i n e r a l s , car-
b o n a t e s a n d g y p s u m a r e m o s t a b u n d a n t in Clays of l i t t l e - w e a t h e r e d p a r e n t m a t e r i a l s
a n d soils of t h e zonal D e s e r t , B r o w n , C h e s t n u t a n d T u n d r a soils as well as i n t r a z o n a l
M o u n t a i n g r o u p s a n d a z o n a l Regosols a n d Lithosols. S e c o n d a r y l a y e r silicate m i n e r a l s
s u c h as vermiculite, s e c o n d a r y chlorite, m o n t m o r i l l o n i t e , kaolinite a n d halloysite are
most abundant in clays of nloderately weathered parent materials and soils of the
zonal Chernozem, Prairie, Gray-Brown Podzelic, Podzol, Red-Yellow Podzolic, and
Low l-Iumic Latosol groups as well as intrazonal Planosol, Rendzina, Dark Magnesium
soil, and ~'iesenboden groups. Secondary sesquioxide minerals such as hematite,
goethite, allophane, gibbsita and anatase and residual resistant primary minerals such
as ilmenite and magnetite predominate in the more highly weathered parent materials
and soils of the zonal Ferruglnous l-[umic Latosols, I~ydrol IKumic Latosols, Lat0solie
Brown, and Ando soils and Latorites, as well as the intrazonal Tropical Savannah and
Ground Water Podzol ortstein soils.
INTRODUCTION
An extremely wide variety of minerals occurs in the clay fraction in the major
great soil groups of the world. It is the purpose of the present article to
examine the frequency distribution or relative amounts or percentages of
minerals that occur in the clay fractions of different great soil groups as
related to the major factors of soil formation. Occasional reference is made to
133
134 SIXTI~ NATIONAL COI~FERENOE ON ~LAYS AND CLAY ~[IIq]]I%ALS
the minerals of the silt fraction where they are related to the minerals in the
clays. The term " layer silicates " is employed for the layer structured group
of silicates, which makes up the largest portion of the clay fraction of many
softs of intermediate degree of weathering, but also makes up important
constituents of silts, sands, and consolidated rocks and thus cannot as
accurately be termed " clay minerals." " Great soil groups " is used in the
sense employed in the soil classification field (Thorp and Smith, 1949), falling
in the categorical listing : soil phase, soil type, soil series, soil family, great
soil group, soil suborder and soil order. " Factors of soil formation " refers
specifically to the five principal classes of soil genetic factors : parent material,
time, climate, relief and living organisms (lV[uckenhirn and others, 1949).
Since m a n y analytical data on this subject have been published in various
journals, the main objective centers on clarification of the way the soil genetic
factors control clay distribution.
The criteria used in soil classification encompass m a n y characteristics other
than soft mineralogy, such as the number and thickness of various horizons,
and the organic content, structure, color, texture (amount of clay, silt and
sand, as distinct from its mineralogy), acidity, and mottling of each horizon.
These characteristics are important to soil classification as to use-suitabftity
and to interpretations of soil genesis. Many of these factors are controlled b y
t h e soft-forming factors more or less independently of the mineral species of
the softs, and thus significant soil groupings often do not follow soil minerMogy
in close detail.
Broad differences in soil mineralogy do, on the other hand, cause differences
in important soil characteristics, and this gives rise to a rough, broad correla-
tion between soil groupings and soil mineralogy. The fact t h a t geochemical
weathering of rocks reflects wide differences in climatic factors leads to " a
broad g e n e r a l . . , association of chemical weathering processes and products
with soil formations distributed over the earth " (Jackson and Sherman~
1953, p. 242).
Secondary
7 ' chlorite (8).~ (f)
TIME FACTORS
Time is a necessary component of all of the other soft-forming factors
affecting soil clay mineralogy. But time is not unique in this overlapping ;
for example, climatic factors require parent material to operate on. Thus to
assess the time factor, one must observe its effect with the other factors held
more or less constant. The present day trend in soft genesis interpretation
has been to recognize changes in soils and soil mineralogy as a function of
time, with de-emphasis on the earlier steady state (" equilibrium ") concept,
because older landscapes inevitably have minerals of greater stability index
than younger landscapes (as reviewed by Jackson and Sherman, 1953, pp. 257
and 281-290). For example, older limestone-derived softs of central Pennsyl-
vania are rich in kaolinite (Alexander, IIendricks and Nelson, 1939) ; nearby
the younger Hagerstown soils are rich in illite and beidellite (Jackson and
others, 1954). The great soft group may be Gray-Brown Podzolic in both
140 SIXTlt NATIONAL CONFEICENCE ON CI~YS AND CLAY MINEJ~ALS
CLIMATIC FACTORS
Climatic factors are traditionally the prime " active " factors of soil
formation. The clay mineralogy of soil, in time, responds sensitively to
climatic factors, as reviewed elsewhere (Jenny, 1941, pp. 118-191 ; Jackson
and Sherman, 1953). Thus for example, rainfall and temperature are climatic
intensity factors that interact with permeability of parent rock (a capacity
factor) reviewed above. Long times of course invariably introduce possible
changes in climatic intensity factors. Yet broad geographic ranges in present
climate tend to give corresponding mineral sequences in different hemis-
pheres (I-Iseung and Jackson, 1952 ; Jackson and others, 1948 ; Fie!des and
Swindale, 1954), progressing from primary minerals in cool dry climates
through layer silicates, to abundant AI(OH)a, Fe2Oa and TiO 2 in warm moist
climates. Authigenic kaolinite and halloysite make up 80 percent of clay in
soils from granite and basalt in western Australia (Hosking, Neilson and
Carthew, 1957). High temperatures of warm temperate and l~ropical climates
bring out the red and brown colors indicative of the accumulation of free
iron oxides, hematite and goethite, sometimes in large amounts (15-60
percent). Ten to 15 percent hematite occurs in the Red-Yellow Podzolic soils
of Southeastern United States, in soils such as the Cecil (Coleman and
Jackson, 1946). Rainfall need be only a moderate 40 in. (not unlike
temperate regions)to give 20-30 percent free iron oxide in the Humic
Latosols of Hawaii under tropical temperatures (Tamura, Jackson and
Sherman, 1953). Accumulation of much iron and titanium oxide is favored
by a w e t - d r y seasonal distribution of rainfall, as in the Ferruginous Humic
Latosol and the Latosolic Brown soil of Hawaii which have 35-50 percent
hematite, goethite and magnetite, and 20 or more percent of anatase and
ilmenite (Tamura, Jackson and Sherman, 1955). Gibbsite or kaolinite occurs
in the C horizons, in amounts up to 30-50 percent.
RELIEF FACTORS
Relief or topography affects soil clay mineralogy through concentrating
water (causing hydrolysis and leaching), seepage (bringing in cations in
solution), and b y affecting oxidation or reduction (through water and air
supply). Leaching is more severe when the waters are acid or neutrM than
when high in metallic cations. Leaching is greatly affected by the permeability
of the parent material, making relief interact with the parent materiM
factors (discussed above).
FREQUENCY DISTRIBUTIONOF CLAY MINEICALS. 141
Abundance of divalent cations, in seepage or runoff water has been
reported by many workers to favor montmorillonite formation, as in the Dark
IV[agnesinm Clays of Hawaii, and in Wiesenboden and Planosol soils (reviewed
by Jackson and Sherman, 1953). Iron is accumulated by seepage on to
Ferruginous Humic Latosol areas (Tamura, Jackson and Sherman, 1953,
1955). Poor drainage and its associated oxidation or reduction concentrated
70 percent goethite in Ortstein concretions of a Ground Water Podzol of
Wisconsin (Whittig and Jackson, unpublished), and 85 percent hematite in
concretions of Tropical Savannah Podzol of Haiti (Tamura and Jackson,
unpublished).
Relief also acts by supplying alluvial soil parent material, as noted from
montmorillonite sediments (above), but once a soil material is moved, clarity
of nomenclature requires its mineralogy to be a parent material factor rather
than a relief factor.
BIOTIC FACTORS
Plant residues return large amounts of metallic cations and silica to soils
and the literatnre suggests that these substances may contribute greatly to
clay formation. A most conspicuous biotic effect on soil mineralogy is under
mor-forming type of vegetation. For example, Kauri trees of New Zealand
give a thick A~ horizon consisting of more than 90 percent free SiO 2 (quartz
and cristobalite) (Swindale and Jackson, 1956), while nearby soils under grass
and other type of trees show little podzolization. The silica is residual from
the parent material, while the other minerals have weathered ont. Layer
silicates and gibbsite are retold in still deeper horizons. The organic A 0
horizon supplies organic compounds to leaching waters which are able to
chelate Fe and A1, and this accelerates the dissolution of primary and
secondary silicates and oxides and their subsequent eluviation, the combined
process being termed cheluviation (Swindale and Jackson, 1956). Similar
but less extreme effects operate in forming zonal Podzol and Gray Wooded
A 2 horizons of North America, so that illite, vermiculite, chlorite and
montmorillonite and other layer silicate clays are left after cheluviation of
the iron oxides.
ACKNOWLEDGMENTS
This contribution from the Department of Soils, University of Wisconsin,
an invited paper for the Conference session oll Genesis of clays, was supported
in part by the University I~eseareh Committee through a grant of funds
from the Wisconsin Alumni Research Foundation, for equipment, materials,
and graduate student assistantships which made possible many of the
mineralogical analyses referred to.
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