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Solutions Chemistry: Alo Mgo Nao Ko
Solutions Chemistry: Alo Mgo Nao Ko
guru
Sri Chaitanya IIT Academy 16-09-17_Jr.Super60-1_JEE-ADV_2011_P2_WAT-18_Key &Sol’s
SOLUTIONS
CHEMISTRY
1. D.
Due to the larger size of hydrated Li ion conductivity decreases.
2. A
As metallic character of element attached to oxygen atom increases, the difference
between the electronegativity values of element and oxygen increases and thus basic
character of oxides increases and vice versa, Hence, the increasing correct order of
basic nature is Al2O3 MgO Na2O K2O
3. C
0
350 C
2 Na O2 Na2O2 ; 2 Na2O2 2CO2 2 Na2 CO3 O2
4. D
BeO C Cl2 BeCl2 CO
(y)
BeCl2 2 H 2O Be OH 2 2 HCl
(z)
5. C
BaC2 N 2 Ba CN 2
CaC2 N 2 CaCN 2
6. A)
Al2 O3 6HCl 2AlCl3 3H 2 O
AlCl3 6NaOH Na 3 Al OH3 Na 3AlO3 3H 2 O
B)
Al2 O3 6HCl 2AlCl3 3H 2 O
AlCl3 3NaOH Al OH3 Al2 O3 3H 2O
C)
Al2 O3 6HCl 2AlCl3 3H 2 O(Not AlO2 )
AlCl3 3NaOH Al OH3
D)
7. C
H 3 BO3 3C2 H 5OH C2 H 5 BO3 3H 2O
Methyl borate
(green flame)
8. C
2
B4O5 OH 4 5 H 2 O 2 B OH 3 2 B OH 4
or B4O7 2 7 H 2O 2 B OH 3 2 B OH 4
9. ABD
The solubility of the alkali metal carbonates increases down the group from Li to Cs.
This is because of the fact that down the group with increasing size of cation the
lattice energy as well as hydration energy also decrease but the change in lattice
energy is more as compare to that of hydration energy. lithium hydrogen carbonate is
not obtained in the solid form while all other elements form solid hydrogen
carbonates.
b) K2CO3 cannot be prepared by solvary process because intermediate formed, KHCO3 is
appreciable soluble in water.
c) Li2CO3 and MgCO3 both are not thermally stable.
d) Fact ref. NCERT
10. ABD
K 2 SO4 CaSO4
13. 2
Out of s-black elements Be and Mg do not impart any colour to flame.
14. 7
8 moles of a mixture of Li 2 CO3 and KHCO3 contain 3:1 ratio means it contain 6 moles
of Li 2CO3 and 2 moles KHCO3 .
On heating, Li2CO3 Li2O CO2
2KHCO3 K 2 CO3 H 2 O CO 2
6 moles of CO2 will be evolved on heating 6 moles of Li2CO3 and 1 mol. of CO2 is
evolved from 2 moles of KHCO3
15. 3
2Cr OH 3 3 Na2O2 2 Na2CrO4 2 NaOH 2 H 2O
16. 7
OH
B O
O OH
O B
HO-B
O O
B
OH
17. 6
B2 H 6 6 H 2O 2H 3 BO3 6 H 2
18. 8
O O
HO OH
B B
HO OH
O O
Peroxoborate
19. a r , s ; b r ; c pqrs ; d q
d) Na2O2 CO2 Na2CO3 ; 2 Na2O2 2CO 2 Na2CO3 O2 ,Hence, it absorbs CO and CO2
and liberates oxygen.
20. a pq ; b p, s ; c p, r ; d p
Reactions are
Re d
B2 H 6
heat
2 B 3H 2
B2 H 6 6 H 2O 2 H 3 BO3 aq 6 H 2
AlCl3
B2 H 6 HCl B2 H 5Cl H 2
0
200 C
B2 H 6 NH 3 B3 N 3 H 6
(Borazole)
(Inorganic benzene borazine)
PHYSICS
21. Compare the standard moment of inertias of the bodies
22. IA
8 r t r
2 2
t 16r 2 / e
, I B 8 16r 2 , I B 64I A
2 4 2
F x
x
N
mg
For equilibrium, f mg
And normal reaction ,N=F
Sec: Jr.Super60-I Page 5
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Sri Chaitanya IIT Academy 16-09-17_Jr.Super60-1_JEE-ADV_2011_P2_WAT-18_Key &Sol’s
Torque due to F 0 (F passes through centre)
As the body is in equilibrium and hence, torque due to friction about centre of mass is
equal to torque due to normal reaction about centre of mass.
24. From figure shown
a
T2
T1
a2
a1
40N
50N
50 T1 5 2
T2 40 4
T1 2 T2 1 4
100 20 40 4 4
28 60
60
2.1m / s 2
28
25. For equilibrium of rod considering limiting friction we use
f1 N 2
N1 N 2
w N1 f 2 0
N1 N2 w
N1 2 N1 W
w
A O
f1
2 3 2 4 3 3 2
6 2 8 3 3 2
3 2 8 3 0
3 2 9 3 0
3 3 1 3 0
1
As 3
3
26. As
M
2 1
1
I I full square
4
1
M full l 2 full /12
4
2
1
I 4m
2l
4 12
I AA1 I CC1 Ma 2
A B
C1
A1 B1
a b
Ml 2
28. I 24M R 2 24
3
24Ml 2 8Ml 2
I 32Ml 2
29. Applying net torque= ri Fi
30. B,C
From figure we have
1 3
IY mR 2 & I X I Z mR 2
2 4
31. Case 1:
FR I
40 0.25 4
5
rad / s 2
2
1 2
l
2
r
5 5
2
2 0.25
40
2 rad / s
17
32. As the sphere is rotating uniformly the tangential acceleration of any particle on
sphere will be zero and all particles will only have normal acceleration.
33. N 2 L block
T 50 10 50 2 T 600 N
2
&1 F 0.10 0.25 600
0.25
0.10 F 8 150
12
2 0.01 5.6
12
5.6 12
2 1.12
5.6 12
Applying = N 2 L 6 20 N 2 0.10
2 1.12
N 20
N 2 L block
mg T mr1
36. A rod of length l is pivoted about an end. Find the moment of inertia of the rod about
this axis if the linear mass density of rod varies as ax 2 b kg / m
As mass of the rod varies with its length, here we cannot use the expression
Ml 2
.which is only used for uniformly distributed mass along the length of rod pivoted
3
at an end. In this case we consider an elemental length dx from the axis at a distance
x.Let its mass be dm ,where
dm dx
ax 2 b dx
During rotation of rod this dm revolves in a circle of radius x, hence its moment of
inertia dl is given as
dl dmx 2
ax 2 b x 2 dx
The moment of inertia of the whole rod is given by integrating the above expression
1
within limits from O to l as I ax 2 b x 2 dx
0
l
ax 5 bx3
Or
5 3 0
al 5 bl 3
Or
5 3
Ml 2 l
37. i) 1 mg cos530
3 2
Ml 2 l l
ii) 1 mg cos530 mao sin 530
3 2 2
a0 sin 530 2 g cos 530
3 3
a0 2 g g
4 2
dI z R 2 sin 2 dm I x R 2 sin 2 dm
dI y R 2 cos 2 dm I y R 2 cos 2 dm
dI z R 2 dm I z R 2 dm
40. Applying rotational equation and then applying torque equation about the respective
pivots
MATHS
4 4 4
41. Given L 1 2 1 2 1 2 .........
3 4 5
2 2 2 2 2 2 2
1 1 1 1 ..... 1 1 1 ....
3 4 5 6 3 4 5
1 2 3 4 5 6 7
..... ......
3 4 5 6 3 4 5
1 2 1
3 4 6
x3 1 x 1 x x 1
2
Now 3
x 1 x 1 x 2 x 1
2 1 3 1 4 1 5 1
M , , , ....
2 1 3 1 4 1 5 1
22 2 1 32 3 1 42 4 1
2 2 2
2 2 1 3 3 1 4 4 1
n r 1 r 1
Lt .
n
r 1 r r 2
2 3 4 n 1 2 3 n 1
Lt .... ...
n 1
2 3 n 3 4 n2
2 n 1
Lt 2
n
n2
1 3 1
L1 M N 1 6 8
2 2
1
n
4
42. lim 4 r 1 r 2 r 3 n
n
r0
1
4 n 1 n 2 n 3 n 4 4
lim
n
n
4
1
lim n 1 n 2 n 3 n 4 4 n
n
1
1 2 3 4 4
lim n 1 1 1 1 n
n
n n n n
1 2 3 4 1/ 4
1 1 1 1 1
n n n n
lim
n 1
n
43. 2 f x f y f x f y f xy ; y x
2
2 f x 2 f x f x 2
put x 1;
2
2 f 1 3 f 1
2
f 1 3 f 1 2 0
f 1 1 f 1 2 0
1
f 1 1 or f 1 2, Re placing y by
x
1 1
2 f x . f f x f f 1
x x
1 1
2 f x . f f x f f 1
x x
If f 1 2
1 1
f x f f x . f
x x
f x 1 x 2 but f 2 5
n
1 2
n 2 and f x 1 x 2
f x 1x R
But f 2 5
f 1 1
lim f 5 1 52 26
x5
1
44. lim a x e x x a, a 0
x
ln a x e x
ln a lim
x x
This gives as / format.
a x ln a e x
Hence L.H rule, we get lim Lna x x
x
a e
a x ln a e x
lim Lna x x
x
a e
a e,
n n n
r r
45. t 1 3r
r 1
r
r 1
2
r 4
r 1 r 1 2 r 2
2
1 r r 1 r r 1
n 2 2
r 1 2 r r 1 r r 1
2 2
1 n 1 1 1 1
2 r 1 r 2 r 1 r 2 r 1 2
1
n 2
n 1
1 n 2 n 1 1 1 n2 n n
1
2 2
2 n n 1 2 n n 1
; lim
n
r 1
tr
2
3
46. Here tan 1 2 x 1
tan 1 2 x 2x 3
3
3
For 2 x 3, tan 1 2 x 1
2
3
tan 1 2x as n
1
lim 2
0
n
3 1
tan 2 x 5
f x 0 for 2 x 3
1
47. lim f x ln 1 f x ln f x
x 0
e
e f x 1
lim ln e f x 1 ln f x lim ln
x 0 x 0 f x
0 if f x 0 as x 0
As f x is defined x R
f 0 0
sec2
2 bx
48. lim sin 2
x 0
2 ax
sec 2
2 bx
Let k lim sin 2
x 0
2 ax
2
ln sin 2 ax
ln k lim
x 0
2
cos 1 bx
a2
By L.H rule, we get ln k
b2
a2
b2
k e
49. a,d
f 1 0 lim 1 h 1 1 h lim h 1 1
h 0 h 0
f 1 0 lim 1 h 1 1 h lim h 0 0
h 0 h 0
50. b.c
Since the greatest integer function is discontinuous (sensitive) at integral values of x,
for a given limit to exist both left0and right-hand must be equal.
L.H .L lim 2 x a x 1 b 1 x
x 1
2 1 a 1 b 1 1 a b
2 1 a 0 b 2 1 2b
x 0, x 1 x x 1 x 1
2
Also, cot 1 lim f x
x 0
cot 1
cot1 1
52. a,b,c
x3
cos 2 x cos x e x cos x e x
53. Given that lim 2
x 0 xn
x3
cos x 1 cos x e x
lim 2
x 0 xn
x5 x4 x6 x2 x4 x2 x3 x3
1 ..... 1 1 ......
1 x ....
2! 4! 6! 2! 4! 2! 3! 2
lim n
x 0 x
= n=4
54. Conceptual
n
2 x
n k sin x 1
lim
x
55. lim k 1
3
lim sin x
x0
n 3 x 0
L=1/3
2n tan
56. f n, 2n
tan
lim f n,
n tan
3lim f x 1
or lim f x x 3
x
x
2
lim f x
3y 1
or y 2 3
y
or y 2 3 y 2 3 y 1 0
3
or y 1 0
or y 1
58. m=0,n=2
tan x tan x
59. p) 1 and 1 for x 0
x x
tan x
1 h; h 0
x
tan x
200 200 200h; h 0
x
tan
200 200
x
sin x sin x
Also 1 and 1 for x 0
x x
sin x
1 h; h 0
x
sin x
200 200 200 h; h 0
x
sin x
200 199
x
tan x sin x
lim 200 200 399
x 0
x x
tan x
q) 100 100 1 h 100 100h; h 0
x
tan x
100 100 h 0 as h 0
x
sin x
r) 1 h; h 0 as x 0
x
sin x x
1 h 0 and 1 for x 0
x tan 1 x
x
1 h; h 0
tan 1 x
x
1 1
tan x
sin x x
lim 100 200 1 0 200 200
x 0
x tan x
sin x sin 1 x
s)As x 0, 1and 1 as x 0
x x
sin 1 x
1 h; h 0
x
sin 1 x
h 0 as h 0
x
tan 1 x tan 1 x
Also 1 and 1 as x 0
x x
tan 1 x
200 200 1 h ; h 0
x
tan 1 x
200 200 200h 199
x
60. p d ; q c; r a ; s b
ao x m a1 x m1 ....ak x m k
x
b0 x n .... bl xl e
a a x ......ak a k m n
x 0 1 l .x
bo b1 x ......bl x
p) m n
a0 m n
0 0 m n
b0
p d
ao
q) m n lim x
x 0 bo
q c
r) m n
a0 1 a
lim x if 0 0, n m even
x 0 bo 0 n m
b0
r a
a0
s)By the similar logic lim x , 0 and n-m is even
x 0
b0
s b
2014_PAPER-I
IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS.
Darken the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as:
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
23-09-17_Jr.Super60-I_Jee Adv_WAT-19_Weekend Syllabus
MATHS: SYLLABUS COVERED FROM 18-09-17 TO 21-09-17
PHYSICS: SYLLABUS COVERD FROM 18-09-17 TO 22-09-2017
CHEMISTRY: GROUP 13: Preparation, properties and uses and aluminium, alumina,
aluminium chloride and alums, Group 14, Water, heavy water, H2O2
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PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Multiple Correct Choice 3 0 10 30
Total 20 60
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 30) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 31 – 40) Questions with Integer Answer Type 3 0 10 30
Total 20 60
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 50) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 51 – 60) Questions with Integer Answer Type 3 0 10 30
Total 20 60
a
B
v
A
‘A’ is point of wheel.
A) A is vertically upwards
B) B may be vertically downwards
C) C cannot be horizontal
D) some point on the rim may be horizontal in forward direction.
2. A sphere is thrown along a rough surface as shown. Mass of the sphere is M and
radius is R. If t is total time taken to start pure rolling after thrown, then:
5v0
A) speed of the sphere when it starts pure rolling is
7
t
B) work done by friction is greater in first half i.e. 0 to compare to later half
2
t
i.e., to t
2
C) work done by friction is zero after time t
1
D) the net work done on the sphere is Mv02
4
3. An uniform solid cylinder is placed on a horizontal board. The coefficient of friction
horizontal direction at right angles of the cylindrical axis. Then (take g 10m / s 2 )
3R
x
O B
4R
5 7
A) mR 2 about O B) mR 2 about O
2 2
1
C) mR 2 about A D) 4mR 2 about A
2
Sec: Jr. Super60-I space for rough work 5
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C) Acceleration of rod is 1 m / s 2
170
D) Tension in right string is N
3
6. A small mass m is attached to a massless string whose other end is fixed at P as shown
in the figure. The mass is undergoing circular motion in the x-y plane with centre at O
m
O
A) V1 V2 r
B) Total mechanical energy of sphere and wedge system is conserved during the
process
C) The ratio of total kinetic energy of the sphere and to the wedge at the instant the
sphere leaves the wedge is 19:5
5 gh
D) V1
6
8. A uniform rod AB of length ‘L’ mass M is suspended by two massless identical
threads. Initially the rod AB is in equilibrium in the horizontal position and the
system is in vertical plane as shown in fig. Immediately after the thread (1) breaks,
(take g is acceleration due to gravity)
Mg sin
A) Tension in thread (2) is
1 3sin 2
6 g sin 2
B) Angular acceleration of the rod about it’s centre of mass is
L 1 3sin 2
C) The end A of the rod has acceleration component in vertically upward direction
D) Centre of mass of the rod has horizontal acceleration component towards leftward
9. A solid sphere is given an angular velocity about a horizontal axis and kept on a
rough fixed incline plane. Then choose the correct statement.
M
B) If tan , the wedge will topple for m .
3sin sin cos
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9 (both
inclusive).
11. A rectangular rigid fixed block has a long horizontal edge. A solid homogeneous
cylinder of radius R is placed horizontally at rest with its length parallel to the edge
such that the axis of the cylinder and the horizontal edge are in same vertical plane
shown in the figure. There is sufficient friction present at the edge, so that a very small
12. An ideal string is wrapped several times on a solid cylinder of mass 4 kg and radius 1
m. The pulleys are ideal and the surface between block and ground is smooth.
Cylinder rolls without slipping on the block. If the torque acting on the cylinder is
10x
N-m, then find the value of x.
9
just before and just after cutting the string then find the ratio of N 1 / N 2 .
H
rm
M F
15. The solid semi-cylinder of mass m and radius R is rolled slowly through an angle by
the horizontal force P. If the coefficient of static friction is s, the angle at which
1 3
sin s
.Find ‘n’.
n 3 s
16. A solid cylinder of mass m = 4 kg and radius R = 10 cm has two ropes wrapped
around it, one near each end. The cylinder is held horizontally by fixing the two free
ends of the cords to the hooks on the ceiling and both the cords are exactly vertical.
The cylinder is released to fall under gravity. The linear acceleration of the cylinder is
n
g then n = ?.
n 1
of 6 m/s. It then ascends a smooth continuous track as shown in figure. The height up
x
to which it will ascend is m . Value of x is? (g =10m/s2)
5
6m/s
18. A constant power is supplied to a rotating disc. Angular velocity ( ) of disc varies
with its lower edge resting on a horizontal surface. The minimum coefficient of static
x
friction s which is necessary to prevent any initial slipping of the ring is . Value of
10
x is
20. A binary star consists of two starts A (mass 2.2Ms) and B (mass 11Ms), where Ms is
the mass of the sun. They are separated by distance r and are rotating about their
centre of mass, which is stationary. What is the ratio of the total angular momentum of
the binary star to the angular momentum of star B about the centre of mass?
conductivity
C) As the temperature is increased from absolute zero some of the para form gradually
B) On an average over all 2½ oxygen atoms per tetrahedron unit are shared in double
chain silicate
2n
C) Si2O5 n
is the repeating unit or basic unit of double chain silicate
D) SiO44 units polymerise to form silicate because Si atom has less tendency to form
Hence
A) A Na2 SiO3 B) B SiF4
D) Interstitial carbides are less denser and harder than pure metals
Sec: Jr. Super60-I space for rough work 20
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The total number of sigma and Pi bonds present in the compound A are: ........
12
32. In cyclic silicate ion Si6O18 the number of oxygen atoms shared are: .........
33. The number of oxygen atoms not acting as bridges (Si-O-Si) in the mineral kinoite
Ca2Cu2 Si3O10 .2 H 2 O .
They y x is:
40. How many of the following reactions lead to the formation of CO as one of the
products?
COOH 2 ; HCOOH ;
Conc. H 2 SO4 Conc. H 2 SO4
dilute
Al2O3 C Cl2 K 4 Fe CN 6 ;
H 2 SO4
Ni CO 4 B2O3 C
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B) (C) and (D) out of which
ONE or MORE are correct.
1 1
x x
e e
41. Let f x g x 1 1
where g x is a continuous function, then lim f x exits, if
x x x 0
e e
A) g x is any polynomial B) g x x2
C) g x sin x D) g x 2 3x 4 x3
5x if x Q
f x 2
where Q is set of rational numbers then
x 6 if x R Q
A) f x is continuous for x R
C) f x is continuous at x 2
D) f x is continuous at x 0
C) xf | x 3 f x 1
D) f | 1 3
A) f x is continuous at x
2
3
B) f x is not differentiable at x
2
C) f x is continuous at x
D) f x is not differentiable at x
2
is not true.
A) f x is continuous for all real x 0, 2
B) f x is not differentiable at x
4
C) Number of points where f x is not differentiable is 2
sin x x
2 x 5
46. If f x 5 b 1 x 5 is continuous at x 5 , a, b R , then ( denotes
x 2 11x 24 x 5
ab 2
x 3
G.I.F)
773 523 a 125
A) a b B) a b C) a b D)
540 540 b 648
B) f x has discontinuity at x 1
C) f x has discontinuity at x 2
x n sin 1 x 0 n 2
48. The set of points of differentiability of the function f x x
0 x 0
contains (Where R is set of real numbers)
A) ,0 B) R 0 C) 0, D) R
all real x . Let f 1000 999 , then which of the following is/are true
1 1
A) f 500 B) f 199
500 199
1 1
C) f x x R 0 D) f 1999
x 1999
Sec: Jr. Super60-I space for rough work 27
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C) f x 2 tan 1 x x R
D) f x is differentiable x R
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9 (both
inclusive).
x
51. The number of points where f x in x 0, 30 is discontinuous is ( is G.I.F)
3
1 1
2sin x 2tan x
if x 0
52. Let f be a function defined on 1,1 as f x 2 tan x 2sin x then the value
K if x 0
the interval , is
x 2 x 0
2
56. If f x x 2 0 x 1 then the number of points of discontinuity of f x is
x x 1
x 3
57. f x a sin x be c x (a, b, c R). If f x is differentiable at x 0 , then the value
of a b is equal to
n
x 1
58. Let g x ;0 x 2 where m 0, n 0 are integer. Let P be the left hand
loge cos m x 1
value of f 3 is
KEY SHEET
2014-P1
PHYSICS
1 ABCD 2 ABC 3 BD 4 AC 5 AB
6 C 7 ABCD 8 ABD 9 AD 10 AB
11 6 12 8 13 1 14 4 15 4
16 2 17 9 18 3 19 4 20 6
CHEMISTRY
21 AC 22 BCD 23 ABCD 24 ABCD 25 BCD
31 8 32 6 33 8 34 7 35 5
36 0 37 9 38 3 39 2 40 5
MATHS
41 BC 42 BC 43 ABCD 44 ABD 45 BD
51 9 52 1 53 1 54 6 55 4
56 1 57 0 58 4 59 4 60 4
SOLUTIONS
PHYSICS
1. At A :
2
V
R
a
R A
V B
a
R
R
V2
If a then aB may be vertically downwards
R
(B) is correct.
At C :
C R
a
V
R
(C) is correct.
Consider this
V
R
a
(D) is correct.
2
2. mgR mR 2
5
5 g
2 R
t; v v0 gt
2 V0
t
7 g
2 5
V V0 V0 V0
7 7
3. mac Ffr
I rF fr rmac
rmac
a ac r r
I
mr 2 ac
or, a ac 2ac
mr 2
2
a 6
or, 3ac a, ac 2m / s 2
3 3
ma
So, f FR so maximum value of this force is equal mg
3
malim
Hence mg or, alim 3 g 3 0.3 10 9m / s 2
3
MR 2
4. (a) m (R ) (3R)
2
5
mR 2
2
(c) Conceptual
5.
6. L m r rO v
LO m r rO v mre r mre t m r2 z
L m r rP v m rer hz mret mh re r m r2 z
1 1 12 2 2
mgh mV12 2mV22 mr w
2 2 25
5 gh
V1
6
Non-conducing of mass M and radius R
8. T cos macm x
Mg T sin macm y
T sin L I cm
2
And apply thread constrained along length of the thread acceleration is zero.
mg sin
1 3sin 2
6 g sin 2
L 1 3sin 2
9. Due to torque of friction about CM, eventually, decreases to zero, initially there is
no translation. Friction is sufficient for pure rolling therefore after sometime pure
rolling begin. There is no external force in x direction therefore momentum is
conserved along x direction.
10.
m
=mgcos
M
Mg
M
m
3sin sin cos
2
4
11. from C.O.M.E, g (1 cos )
R 3
m 2
From dynamics of circular motion mg cos
R
1 4
On solving above eqs. cos
7
mgR
KR
7
When the cylinder loses its constant i.e., the frictional force vanishes, also torque due
to gravitational force is zero. Hence its angular velocity is constant and rotational
kinetic energy becomes constant, while its translational kinetic energy increases.
Applying conservation of energy at position (1) and position (3)
Decrease in gravitational P.E. = Gain in rotational K.E. + translational K.E.
mgR 6
KT mgR mgR
7 7
From (3) and (4), we have
6
mgR K
KT 7 or T 6
KR mgR KR
7
1 2 1 2
mgR 0 mgR cos I mv
2 2
v
But
R
1
And I mR 2
2
1 1 1 2
Therefore, mgR mgR cos mR 2 v2 / R2 mv
2 2 2
mv 2
mg cos c
R
v2
Or g cos c ............... (2)
R
From eqns. (1) and (2),
4
g 1 cos c g cos c
3
4
Or cos c
7
1 4
Or c cos
7
4
Therefore, speed of CM of cylinder just before it leaves the constant is gR .
7
T = (40 – 6a)/3
Also, by = I , we get
3a
T R + fs R= I
2R
T + fs = 3Ia/2R2
(40 – 6a)/3 + (40 – 12a)/3 = 3Ia/2R2 a = 80/(18 + 9I/2R2)
As = I = I (3a/2R)
=I =I (3a/2R)
3I 80 3 80 80
N m
2R 9I 18 9 9
18
2R 2
By constraint that lower end will have acceleration only in horizontal direction.
14.
about O=0
H
ma mgr
4
F H
. gr
M m 4
F 4N
P s
N
15.
N mg
4R
P (R Rsin ) mg sin 0
3
3
Also sin s
4 3 s
mr 2 a
2TR IX
2 R
Ma 2a
T And a
4 3
17. Let m be the mass of the disc. Then translational energy of the disc is
1
KT mv 2 When it ascends on a smooth track its rotational kinetic energy will
2
remain same while translational kinetic energy will go on decreasing. At highest point.
1 v2 (6)2
KT = mgh or mv 2 mgh or h 1.8 m .
2 2g 2 19
2 P 1/3
or d d on integration, we find that
or (n) 1/3.
2r
19. Centre of mass of semicircular ring lies at a distance of from the center.
2r
OC , OP r
or CP = 1.185r.
If there is no slipping, then the instantaneous axis of rotation passes through P.
C
O I =2mr
mg N
f= N P
a C x
O
a y
a
P From Newton’s law,
Fy ma y
or mg - N = may
or mg - N = ma sin
1.185 2r 1
or mg N m g
1.185r
2
2
mg 0.2 mg
or N = mg - 0.2mg
or N = 0.8 mg …(iii)
Fx = max
or sN= (m) (a cos )
1.185g r
or s (0.8mg) (m)
1.185r
or s = 0.398
Therefore, minimum value of static friction is 0.398.
20. I system mA rA2 mB rB2 mA mB / mA mB r2
Lsystem I system m A mB / m A mB r2
2
IB mB rB2 mB m2A / mA mB r2
2
LB IB mB mA2 / mA mB r2
SS
Sec: Jr. Super60-I Page 10
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Since O-D bond is polar while D-D bond is non-polar. So, exchange reactions with
D2O is eaiser. Atomic sizes of H 2 , D2 and T2 are same.
H 2 F2 H 2O
29. SiO2 NaOH Na2 SiO3 SiF4 H 2 SiO3 H 2 SiF6
30. Interstitial carbides are more denser and harder than pure metals.
31. A is C3O2 O C C C O
12
32. In cyclic silicate ion Si6O18 the number of oxygen atoms shared is 6.
33. The number of monovalent oxygen atoms are present in the mineral kinoite
Ca2Cu2 Si3O10 .2H 2O is 8.
36. AlH 3 3 H 2O Al OH 3 3H 2
AlN 3H 2O Al OH 3 NH 3
Fe2O3 3C 2 Fe 3CO
P4O10
CH 2 COOH 2
H 2O
Conc. H 2 SO4
HCOOH CO
H 2O
180o C
Ni CO 4 Ni 4CO
MATHS
1 1 1 1
x x x x
e e e e
41. lim 1 1
1 and lim 1 1
1 , lim f x exists, if lim g x 0
x 0 x x x 0 x x x 0 x 0
e e e e
42. f x is continuous at ' x ' satisfying 5 x x 2 6 i ,e x 2, 3
43. Given f x . f y f x f y f xy 2 x, y R
Put x y 1 then f 1 2 3 f 1 2 0
f 1 1 or f 1 2
If f 1 1 then f x 1 x R.
f 1 1 , hence f 1 2
1 1 1
Replace ' y ' with then f x . f f x f f 1 2
x x x
f 4 65, f x x3 1 f1 x 3x 2
3
44. Plotting the graph we get points of discontinuity at x , , 0, and is continuous
2 2
3
at x , f x is not differentiable at x ,
2 2 2
cos x 0 x cos 1 3 4
45. f x 34 cos 1 3 4 x sin 1 3 4
sin x sin 1 3 4 x 2
25 6
1 5 b 1 3ab2 a ,b
108 5
1
47. f 1 lim x x x
x 1 x
lim x 0 x 1
x 1
1
1
f 1 lim x x x
x 1 x
lim x 1 x 0
x 1
1
1
f 2 lim x x x
x 2 x
lim x 0 x 2
x 2
4
1
f 2 lim x x x
x 2 x
lim x 0 x 1
x 2
2
48. Clearly for x 0 f x is differentiable.
At the point x 0 ,
f 1000 f 999 1
999 f 999 1
1
f 999
999
1
The numbers 999 and are in the range of f .
999
Hence, by intermediate value property of continuous function, function takes all
1
values between 999 and , then there exists
999
1
,999 such that f 500
999
1
Then f f f 1 f 500
500
1 1
Similarly, 199 ,999 , thus f 199
999 999
But there is nothing to show that 1999 lies in the range of f . Thus (D) is not correct
and (C) is also incorrect.
2 tan 1 x if x 1
1 2x
50. sin 2 tan 1 x if 1 x 1
1 x2
2 tan 1 x if x 1
x
51. f x is not continuous at x 3, 6,9,12,15,18, 21, 24, 27
3
1 1
2sin x 2 tan x
52. K lim f x lim
0 2 tan x
x 0 x 2sin x
ab 2 x2 3x
lim sin cos 1 3
x 0 x2 a b
2 9
ab 3
a 2b 2
4b 2 6b 9a 0
b is real, D 0 a 14
54. (i) f x 1 x 0
1 x 0
(ii) f x 1 x 0
1 x 0
(iii) f x 1 x 0
1 x 0
(iv) f x 1 x 0
1 x 0
(v) f x 1 x 0
1 x 0
(vi) f x 1 x 0
1 x 0
55. Draw the graph, we get the function is not differentiable and continuous at two points
between x 2 and x 2 also function is not continuous at x 2 and x 2
x 2 x 0
2
56. f x x 2 0 x 1
x x 1
x 2 if x 2
f x x 2 if -2<x 0
x2 2 if 0 x<1
x if x 1
Clearly f x is discontinuous at x 1
Clearly f x is continuous at x 0
a cos x be x 3cx 2 if x 0
f1 x
a cos x be x 3cx 2 if x 0
L.H.D=R.H.D
a b a b a b 0
n
x 1
58. lim 1
x 1 log e cos m x 1
n 1
n x 1
lim 1
x 1 sin x 1
m.
cos x 1
n 1
n x 1
lim 1
x 1 m tan x 1
n
1, n 2, m n 4
m
59. f 2x f x x
x x
f x f
2 2
x x x
f f
2 4 4
:
:
:
x x x
f n 1
f
2 2n 2n
x x x x
lim f 2 x f lim x .... n
n 2n n 2 4 2
x
f 2x 1
1
1
2
f 2x 2x 1
f x x 1
60. Conceptual
2012_PAPER-II
IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS.
Darken the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as:
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
07-10-17_Jr.Super60-I_Jee Adv_WAT-20_Weekend Syllabus
MATHS: SYLLABUS COVERED FROM 03-10-17 TO 06-10-17
PHYSICS: SYLLABUS COVERD FROM 03-10-17 TO 06-10-2017
CHEMISTRY: Detection of nitrogen, sulphur, phosphorus and halogens, Estimation of
carbon, hydrogen, nitrogen, halogens, sulphur, phosphorus, Hybridisation of carbon; Sigma
and pi-bonds; Shapes of simple organic molecules
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
JEE-ADVANCE-2012-P2-Model
Time: 07:30 AM to 10:30 AM IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : 9 – 14) 3 -1 6 18
(3 Comprehensions : 2+2+2 = 6Q)
Sec – III(Q.N : 15 – 20) Questions with Multiple Correct Choice 4 0 6 24
Total 20 66
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 28) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : 29 – 34) 3 -1 6 18
(3 Comprehensions : 3+3 = 6Q)
Sec – III(Q.N : 35 – 40) Questions with Multiple Correct Choice 4 0 6 24
Total 20 66
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : (41 – 48) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : (49 – 54) 3 -1 6 18
(3 Comprehensions : 2+2+2 = 6Q)
Sec – III(Q.N : 55 – 60) Questions with Multiple Correct Choice 4 0 6 24
Total 20 66
Sec: Jr. Super60-I space for rough work 2
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
PHYSICS Max. Marks: 66
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. What is direction of gravitational field at a point P . P is on a plane containing biggest
circle of uniform hollow hemisphere as shown.
A) a B) b C) c D) d
2. Let magnitude of gravitational field at a distance r from centre of uniform
hemisphere of mass m at point p shown in figure be E . ( R is radius of hemisphere)
Gm Gm Gm Gm
A) E B) E C) E D) E 2
r2 2r 2 r2 r R
Sec: Jr. Super60-I space for rough work 3
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
3. Gravitational field at a point p in a small hole made in uniform thin spherical shell of
mass m and radius R is approximately
Gm Gm Gm
A) B) C) 0 D)
R2 2 R2 3R 2
4. Gravitational field at point P due to rod of mass m is
2
Gm Gm Gm 1 1
A) B) 2
C) 2
D) Gm
r1r2 r1 r2 r1 r2 r1 r2
2
5. A wire of uniform cross sectional area ' a ' length l is having density which varies
linearly from p1 at one end to p2 at other end. Both ends of wire are connected and
Sec: Jr. Super60-I space for rough work 4
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
wire is transformed into a circular loop. Length of wire doesn’t change. The
component of gravitational field along the axis of circular loop made of given wire at
a distance x from the centre of loop is
G p1 p2 al G p1 p2 lax
A) 2
B) 3
2x 2 2
l
x2
2
G p1 p2 lax G p1 p2 lax
C) 3
D) 3
2 2 2 2
l l
2 x2 2 x2
2 2
6. Gravitational field due to very long hollow cylinder of mass m, length l , and radius R
at a point on the axis of cylinder just outside cylinder is l R
2Gm Gm Gm 3Gm
A) B) C) D)
Rl Rl R2 Rl
7. Two uniform rods A and B of length 0.6 m each of masses 0.01 kg and 0.02 kg
respectively are rigidly joined end to end. The combination is pivoted at the lighter
end, P as show in figure. Such that it can freely rotate about point P in a vertical
plane. A small object of mass 0.05 kg moving horizontally, hits the lower end of the
11. The angular velocity of the pole after the skaters are connected is
22 1 20 1 17 1 14 1
A) rads B) rads C) rads D) rads
3 3 3 3
12. By pulling on the pole, the skaters reduce their distance apart to 1 m. The angular
velocity now is
A) 45rads 1 B) 50 rads 1
C) 55 rads 1
D) 60 rads 1
M and the other has mass m such that M = 2m. The distance between the centres of
13. The period of rotation of the stars about their common centre of mass
4 2 3 8 2 3 2 2 3 4 2 3
A) d B) d C) d D) d
Gm Gm 3Gm 3Gm
14. The ratio of the angular momentum of the two stars about their common centre of
mass (Lm/ LM) and the ratio of kinetic energies of the two stars (Km/KM.) is
touching rod but not sticking to it. Ball D collides with one end of rod
perpendicularly. Which of the following is correct statement about direction of motion
of small balls A, B, C , D & rod shown just after collision of ball D with rod?
3v v 3 2
A) vc 0 B) C) D) E mv
5a 5a 5
Sec: Jr. Super60-I space for rough work 12
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
19. Two identical uniform rods connected end to end by a frictionless pin joint are placed
along x axis on a frictionless horizontal surface. These are free to rotate with respect
to each other about vertical axis z axis passing through pin joint. A particle of mass
m moving with velocity v along y axis strikes rod at one end as shown. The direction
of velocities of different points on rod just after collision will be
mass 30kg is hinged at the line AB joining the two heavy metallic plates. The hinges
are frictionless. The moment of inertia of the laminar sheet about an axis parallel to
AB and passing through its centre of mass is 1.2 kg – m2. Two rubber obstacles P and
Q are fixed, one on each metallic plate at a distance 0.5 m from the line AB. This
Sec: Jr. Super60-I space for rough work 13
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
distance is chosen, so that the reaction due to the hinges on the laminar sheet is zero
during the impact. Initially the laminar sheet hits one of the obstacles with an angular
velocity 1 rad/s and turns back. If the impulse on the sheet due to each obstacles is 6
N – s. The location of centre of mass of laminar sheet from AB is x & angular velocity
C) Fe2 Fe CN 6
D) Fe3 Fe CN 6 4
CH3
H
CHO
A) NO3 B) C N C) S CN D) S 2
Sec: Jr. Super60-I space for rough work 18
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
35. Which of the following compounds may give blood red coloration while performing
Lassaigne’s test for nitrogen?
A) (NH2)2CO B) (NH2)2C = S
SO3H
SO3H
NH2
C) D)
36. Kjeldahl’s method cannot be used for estimation of nitrogen in
A) C6H 5NO2 B) Pyridine
C) C6H5 – N = N – C6H 5 D) C6H 5NHCOCH3
37. Which of the following compounds will give white precipitate with AgNO3?
A) C6 H 5 N H 3 I B) NaCl
C) NH 2 N H 3Cl D) C6 H 5 N H 3Cl
A) CH 2 C H B) H C C
C) H 2C C CH 2 D) O C C C O
39. Which of the following is the correct statement regarding ethene?
A) All the atoms are in the same plane
B) Bond provides the most reactive centre in the molecule.
C) SP 2 Hybridized carbon atoms are present
D) One C C bond is present
40. Which of the following is correct?
A) Oxidation state of Fe in sodium Nitro prusside is 2+
B) AgI is in yellow color due to polarization effect
C) AgBr is a yellow ppt. and is sparingly soluble in excess NH 4OH
D) Yellow ppt is the detection of phosphorus when an organic compound is heated
with Na2O2 and then boiled with con. HNO3 , followed by the addition of Ammonium
A) 1 B) -1 C) 2 D) 0
42. If be a repeated root of a quadratic equation f x 0 and A x , B x , C x be
x100 x99 x2
45. If f ( x) ... x 1 then
100 99 2
A) f 1 (1) f 1 (0) B) 100 f 1 (1) f 1 (0)
a /2 2 /2 a /2
A) e B) ae /2
C) e D) e
2 a 2
SECTION - II
(COMPREHENSION TYPE)
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
Paragraph for Questions 49 and 50
(1) The graph of f 1 x is made of line segments joined such that left end point is
(3) The derivatives of f x , where defined, agrees with the step pattern as shown here.
information.
dy
53. If x 3cos cos3 , y 3sin sin 3 then = ------------ at
dx 4
2 1
A) B) – 1 C) D) 1
3 2
2
dy x2 4
54. x sec cos ,y sec6 cos 6 ; 2k 1 / 2, k Z , then dx y2 4
A) 36 B) 6 C) 30 D) None of these
Sec: Jr. Super60-I space for rough work 25
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
55. A twice differentiable function f(x) is defined for all real numbers and satisfies the
following conditions:
'
f (0)=2; and f "(0) 3.
f 4 65 . Then
A) f 1 x Is a polynomial of degree 2
B) Roots of f 1 x 2 x 1 are real
C) xf 1 x 3 f x 1
D) f 1 1 3
Sec: Jr. Super60-I space for rough work 26
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_JEE-ADV_2012_P2_WAT-20_Q’P
d
57. If f x g x where g x e x. f x ex. f x then
dx
given f 0 0 .
A) g x Is an even function
B) f x is an odd function
C) g 1 0 f1 0 g 0
D) g1 0 f 0
x sin x3 x dy
58. If y e tan x then may be equal to:
dx
x sin x3 x
A) e 3x3 cos x3 sin x3 tan x ln tan x 2 x cos ec 2 x
x sin x3 x
B) e x3 cos x3 sin x3 tan x ln tan x 2 x cos ec2 x
x sin x3 x
C) e cos x3 x3 sin x3 tan x ln tan x 2 x cos ec2 x
x sin x3 x x s ec 2 x
D) e 3 x3 cos x 3 sin x 3 tan x ln tan x
tan x
1 1 1
A) 41 ....... 2
9 25 2N 1
1 1 1
B) 4 1 ....... 2
9 25 2N 1
1 1 1
C) 41 ....... 2
9 25 2N 1
1 1 1
D) 4 1 ....... 2
9 25 2N 1
A) f 4 f 4
B) f 2 f 2 0
C) f 4 f 4 0
D) f 2 f 2
KEY SHEET
2012-P2
PHYSICS
1 C 2 C 3 B 4 A 5 C
6 B 7 A 8 A 9 B 10 A
11 B 12 D 13 D 14 D 15 A
16 CD 17 AC 18 ACD 19 BD 20 BC
CHEMISTRY
21 D 22 A 23 A 24 A 25 D
26 C 27 C 28 B 29 C 30 B
31 C 32 D 33 B 34 A 35 BC
MATHS
41 A 42 D 43 B 44 D 45 D
46 A 47 C 48 C 49 C 50 C
51 A 52 B 53 B 54 A 55 AD
56 ABCD 57 AB 58 AD 59 A 60 AC
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_Jee-Adv_2012-P2_WAT-20_Key Sol’s
SOLUTIONS
PHYSICS
1. Conceptual
2. Conceptual
3. Net Gravitational field
4.
Gdm G dr
E
r2 r2
1 1 G r2 r1 Gm
G E
r r2 r1r2 r1r2
p1 p2 al l
5. m R
2 2
Gm
E 3
R2 x2 2
6. Conceptual
2 gl 4m mA 3mB
or
I
1
a 1 v
3
3v
4a
9. Conservation of angular momentum during collision of m1 & m2
m1V0 2 R m1V1 2 R m2V2 2 R
V0 V1 V2 1
V0
V2 V1 2
2
3V0 3V0
2V2 V2
2 4
By conservation of angular momentum when the masses will have same
3V0
m R 5mR 2
2
3V0
R
10
max imum speed of m3
2
1 2 1 1 3V0
10. kx 5mR 2 2
m
2 2 2 4
mV02
x
80 k
11. Conceptual
12. Conceptual
Sec: Jr. Super60-I Page 4
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Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_Jee-Adv_2012-P2_WAT-20_Key Sol’s
13. Let the angular speed of revolution of both stars be w about the common centre ,
that is, centre of mass of system.
2 2d Gm 2m 4 2 3
m . Solving we get T d
3 d2 3Gm
14. The ratio of angular momentum is simply the ratio of moment of inertia about
center of mass of system.
2
2d
m
Lm Im 3
2
2
LM IM d
2m
3
Similarly, The ratio of kinetic energy is simply the ratio of moment of inertia about
center of mass of system.
2
1 2
2d
Im m
Km 2 3
2
2
KM 1 2 d
IM 2m
2 3
15. Conceptual
16. Conceptual
17. The data is incomplete. Let us assume that friction form ground on ring is not
impulsive during impact. From linear momentum conservation in horizontal direction.
We have
2 1 0.1 20 = 0.1 0 2 v
Here, v is the velocity of CM of ring after impact. Solving the above equation, we
have v = 0 Thus CM becomes stationary.
Correct option is (a).
3 1 1 2 1
1 2 0.5 2 0.5
2 2 2 0.5
or 6 m v f vi 30 r r
1
or r 1 ………….(i)
5
Similarly, angular impulse about AB = change in angular momentum about AB
Angular impulse = Linear impulse
Perpendicular distance of impulse from AB
Hence, 6 0.5 m I AB 1
(Initial angular velocity = 1 rad/s)
or 3 I CM Mr 2 1
23. VN 2 38ml
P 732 32 700
700 38 273
VN2 at STP ml
350 760
Sec: Jr. Super60-I Page 7
Downloaded from jeemain.guru
Sri Chaitanya IIT Academy 07-10-17_Jr.Super60-I_Jee-Adv_2012-P2_WAT-20_Key Sol’s
22400ml 28 gm N 2
2 38 273 28 2 38 273
gm
760 22400 760
28 2 38 273 100
% Nitrogen = 6.25%
22400 760 0.546
24. SP SP 2 SP3
25. CH 2 CH CH 2 N C:
26. NH 2 NH 2 .HCL
27. 6
28. Fe4 Fe CN 6 3
29. / 30. The residual acid requires, 60 0.5 meq of NaOH = 30meq NaOH
The no.of meq of H 2 SO4 that reacts with NH 3 = (50 1 30) 20meq
no.of meq of NH 3 is 20 meq
Weight of NH 3 = 20 10 3 17g
= 0.34g
Weight of Nitrogen in 0.34g NH 3 is 0.28g
0.28
% by weight of N 100 56%
0.5
31. Conceptual
32. Conceptual
33. Na2 Fe CN 5
NO Na2 S Na4 Fe CN 5
NOS
34. CN , CNS , S 2
2
35. Fe3 SCN Fe SCN
42. F1 0 F x is divisible f x
44. f g x x f 1 g x g1 x 1
1 4
g1 x 1
1 g x
f g x
45. Conceptual
f' x
46. Observe f 0 0 and Lt 100 f' 0 100
x 0 1
Now using first principle
f x h f x f x f h x 2 h2 f x
f' x Lt Lt
h 0 h h 0 h
f h
Lt 0
h 0 h
f' 0 100
47. Conceptual
48. Take ‘log’ and differentiate twice and use y ' 0 1
49. f x 2x a : 1 x 0
b:0 x 1
x c :1 x 4
x d :4 x 6
50. a b 1 x, 4 c d 4
f 0 0 a 0 b, c 1, d 7
f x 2x : 1 x 0
0:0 x 1
x 1:1 x 4
7 x:4 x 6
dy
d dy
53 cot 2
dx dx
d
dx
54. Tan sec cos Tan x2 4
d
dy
6Tan sec 6 cos 6 6Tan y2 4
dx
dy 6 y2 4 dy
2
x2 4
36
dx x2 4 dx y2 4
x sin x3 x
58. e 3 x3 cos x3 sin x 3 tan x ln tan x 2 x cos ec 2 x
x sin x3 x x s ec 2 x
e 3x3 cos x3 sin x3 tan x ln tan x
tan x
Since f 0 0
2016_PAPER-I
IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS.
Darken the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as:
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
14-10-17_Jr.Super60-I_Jee Adv_WAT-21_Weekend Syllabus
MATHS: SYLLABUS COVERED FROM 09-10-17 TO 13-10-17
PHYSICS: SYLLABUS COVERD FROM 09-10-17 TO 13-10-2017
CHEMISTRY: ORGANICCHEMISTRY-Nomenclature of Hydrocarbons, Nomenclature of
mono and bi-functional organic compounds including common names, Nomenclature of
Aromatic compounds (Benzene), Structural isomerism (excluding Tautomerism)
Downloaded from jeemain.guru
Total 18 62
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 23) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 24 – 31) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 32 – 36) Questions with Integer Answer Type 3 0 5 15
Total 18 62
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 41) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 42 – 49) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 50 – 54) Questions with Integer Answer Type 3 0 5 15
Total 18 62
Sec: Jr. Super60-I space for rough work 2
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6Gm 2 1 1 2Gm 2 1 1
C) 1 D) 1
a 3 4 a 3 4
2. An un powered spacecraft has to hit a far off planet of mass M, radius R. Maximum
entrance area h 2 from which ‘the spacecraft can be projected so as to hit the planet.
GM 2GM
A) R2 1 2
B) R2 1 2
RV0 RV0
2GM 2GM
C) 4 R 2 1 2
D) 4 R 2 1 2
RV0 RV0
2 1 2 1
C) V 2 GM D) V 2 G
r3 a2 r a
4. A shell of mass M and radius R has a point mass m placed at a distance r from the
centre. The gravitational potential energy U (r) vs r will be [assume potential energy at
infinity to be zero]
Sec: Jr. Super60-I space for rough work 4
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A) B)
C) D)
5. A uniform hollow sphere has internal radius a and external radius b. The ratio of
gravitational potential at a point on its outer surface to that of a point on its inner
surface is
2 b3 a 3 2 b3 a 3 a a 2 b2
A) B) C) D) 1
3b b2 a 2 3b b2 a2 3b a 2 b 2
7. A double star system consists of two stars having masses M and 2M. The distance
between their centres is equal to r. They revolve under their mutual gravitational
interaction. Then, which of the following statements are not correct.
A) Heavier star revolves in circular orbit of radius 2r/3
B) Both the stars revolve with same angular speed, period of which is equal
2
to r 3/ 2
3GM
C) Kinetic energy of the heavier star is twice that of the other star.
GM 2
D) Kinetic energy of the heavier star is
3r
R
d
2
3GMm
A) The work done by the friction on the block is
8R
3
B)
2
1
C)
2
D) The gravity does +ve work on block
11. Assuming Earth, an uniform sphere of mass M and radius R. At a point P inside Earth
at a distance r measured from centre of Earth (r < R)
3 r 2 Gm
A) Pressure (p) caused by gravitational compression is 1
8 R 2 R3
3 r 2 GM 2
B) Pressure (p) caused by gravitational compression is 1
8 R2 R4
3 GM
C) Gravitational field Intensity at the centre is
2 R2
D) Gravitational field Intensity at the centre is zero.
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases.
14. Assuming V as the gravitational potential at the centre of earth, the potential at a
11V
distance half the radius from its centre will be . The value of x is
10 x
16. A particle is projected vertically upwards from the surface of the earth (radius Re)
with a speed equal to one fourth of escape velocity. The maximum height attained by
Re
it from the surface of the earth is . Then 'N' is
5N
17. Two uniform solid spheres of equal radii R, but mass M and 4M have a centre to
centre separation. 6R, as shown in the figure.
18. A bullet is fired vertically upwards with velocity v from the surface of a spherical
planet. When it reaches its maximum height, its acceleration due to the planet’s
gravity is 1/4th of its value at the surface of the planet. If the escape velocity from the
planet is vesc = v N , then the value of N is (ignore energy loss due to atmosphere)
H3C CH3
A) 2,6-dimethylhepta-2,5-dienoicacid.
B) 3,7-dimethylhepta-2,5-dienoicacid.
C) 1-Hydroxy-2,6-dimethylhepta-2,5-dienone
D) 3-Hydroxy -2,6-dimethylhepta-2,5-dienone.
20. Some statements about structural isomers of C5 H11 Br are given below.
i) It has four primary bromides
ii) It has three secondary bromides
iii) It has two tertiary bromides.
A) :Formylethylbezene
CH 2 CH CH
B) CHO CHO :Propene-1,3-dicarbaldehyde
D) :1-methyl-3-ethylcyclohexene
27. Metamerism can be shown by
A) Ketones B) Esters C) Ethers D) tertiary amines
28. The correct names of functional isomers of butanoicacid is/ are
A) Ethylethanoate B) Methylpropanoate
C) Propylmethanoate D) Isopropylmethanoate
29. Identify the correct statement/s among the following is/are
A) N,N-dimethylaniline and Phenylmethyl amine are functional isomers.
B) N-methylaniline and phenylethanamine are functional isomers.
C) iso-butylamine and tertiarybutyl amine are chain isomers.
D) n-butylamine and iso-butylamine are chain isomers.
30. Which of the following names are correct for the compound containing molecular
formula is C7 H 8 O ?
A) Phenylmethanol B) 2-methylphenol
C) 3-methylphenol D) methoxybenzene.
Sec: Jr. Super60-I space for rough work 16
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vii) : benzeneacetaldehyde.
35. The number of structural isomers possible for C6 H 6 O3 containing benzene ring
(Do not consider peroxybond containing isomers) is X.
The number of structural isomers possible for C7 H 9 N containing benzene ring is Y.
Then X + Y is....
36. The number of cyclic isomers for C5 H10 is ‘X’ and the number of open chain structural
isomers for C5 H10 is ‘Y’. Then X Y is..
x x 1
p lim 2x 2x
then, pr _______
x 0 e e r 1
f f
2 2
39. A sphere of radius 10cm shrinks to radius 9.8cm. The approximate decrease in volume
is ____ cu.cm
A) 80 B) 80 C) 16 D) 16
A) B) C) D)
2 6 3 4
41. A horse runs along a circle with a speed of 20km/h. A lantern is at the centre of the
circle. A fence is there along the tangent to the circle at the point at which the horse
starts. The speed with which the shadow of the horse moves along the fence at the
moment when it covers 1/8 of the circle in km/h is
A) 20 B) 40 C) 30 D) 60
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases
42. Which of the following curves are orthogonal
x2 y 2 x2 y2 x2 y2 x2 y2
A) 1, 1 B) 1, 1
21 17 3 1 47 4 21 23
x2 y2 x2 y2 x2 y2 x2 y2
C) 1, 1 D) 1, 1
49 4 23 22 21 9 42 30
Sec: Jr. Super60-I space for rough work 20
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axis are
3 2 3
A) 0, 0 B) 3, C) 2, D) 3,
2 3 2
‘b’ km from the junction of two roads inclined at 900 and travel towards the junction
and after 2 hours, they are nearing each other at the rate of
4v 2 a b v 2v 2 a b v
A) 2 2 2
km / hour B) 2 2
km / hour
a b 4 a b v 8v a b 2 a b v 8v 2
6v 2 a b v 8v 2 a b v
C) 2 2 2
km / hour D) 2 2
km / hour
a b 6 a b v 8v a b 8 a b v 8v 2
Sec: Jr. Super60-I space for rough work 21
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48. A point on the parabola y 2 18x at which the ordinate increases at twice the rate of
the abscissa is
9 9 9 9
A) (2, 6) B) (2, – 6) C) , D) ,
8 2 8 2
49. An error of 0.01cm is made while measuring the radius 5cm of a circle.
A) The error in circumference will be 0.02 cm
B) The error in area will be 0.1 sq.cm
C) The relative error in circumference will be 0.002
D) The percentage error in area will be 0.004
50. Water is dripping out from a conical funnel of semi vertical angle at the uniform
4
rate of 2cm3 / s .Through a tiny hole at the vertex at the bottom when the slant height
of the water is 4cm. If cm / s be the rate of decreases of the slant height of the water,
then the value of 4 2 must be
51. The rate of change of the volume of a sphere with respect to its surface area, when the
radius is 2 cm, is
52. If y 4 x 5 is tangent to the curve y 2 px3 q at the point (2, 3) then p q =
1 1
the value of lim x2 f x 2 5 f 4 x2 4 f 7x2 is then k=
x o k
54. A man 1.6m high walks at the rate of 30m per minute away from a lamp which is 4m
above ground. If k is the rate at which the man‘s shadow is lengthening, then the value
of k/4 is _____________
KEY SHEET
2016-P1
PHYSICS
1 C 2 B 3 A 4 D 5 A
11 BD 12 ABCD 13 BC 14 2 15 8
16 3 17 3 18 2
CHEMISTRY
19 A 20 B 21 C 22 C 23 C
29 D 30 ABCD 31 AD 32 6 33 9
34 4 35 8 36 0
MATHS
37 A 38 D 39 A 40 C 41 B
42 AC 43 AD 44 ABCD 45 ABC 46 A
47 D 48 CD 49 ABCD 50 2 51 1
52 9 53 3 54 5
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SOLUTIONS
PHYSICS
1. Total potential energy is V Uij
Gm 2 1 1 1 6Gm 2 1 1
6 6 3 1
a a 3a 2a a 3 4
2.
r B
R V
v02 GM 1 v02 r 2
2 R 2 R2
v02 R 2GM R
r2
v02
R2 2 2GM
Area = r 2 v0
v02 R
1 2 GmM 1
6. Kinetic energy mv or KE . Thus choice (A) is correct.
2 2r r
GM
Angular momentum = mvr = mx xr m GMr , which is proportional to r .
r
1 1 GM 1
correct. The freuqeuncy of revolution is v 3
.i.e. v 3/ 2 .
T 2 r r
Hence, the heavier star revolves in a circle of radius r/3 while the lighter star in a
circle of radius 2r/3. Hence option(a) is wrong.
r 2
B) (2M) 2GM 2
3
1/ 2 1/ 2
r 2 2GM 2 3GM 3GM r 3/ 2
(2M) T 2
3 r2 r3 T r3 3GM
1/2
0 3mur
8. A) L m u cos30 r 2
M
G
GM 27 9
Vremaing
R 5R
3
GM GM 44GM
VR
R 45R 45R
For escape velocity
1 44GMm
mv 2
2 45R
88 GM
V
45 R
GMm 3R GMm
3
2 R2 2 4R
GM 3M
df .r (4 r 2 p.dr ), P
R3 4 r3
df R 3 r 2 GM 2
dp ,P dp 1
4 r2 r 8 R2 R4
12. (A) If it is projected radially it will go up and than move down in a straight line
B) If it is projected will a small velocity near the earth`s sarface, g will be almost
constant So its path will be almost parabolic. (Projectile Motion)
GM
(C) If the body is projected tangentially with orbital speed V0 then it will
r
R 11GM 11 2V 11V
at r
2 8R 8 3 12
dv
15. E here dx drSin
dx
1
18. At height R from the surface of planet acceleration due to planet’s is th in
4
comparison to the value at the surface
GMm 1 2 GMm GMm 1 2
So, mv and mvesc 0
R 2 R R R 2
vesc v 2
A) B) C) CH 3 D)
OH OH
CH 3 OH
Resorcinol: OH : Hydroquinone- OH
32. ii, x are not isomers for the given compound and iii and v are aldehydes:
33. X= 7 and Y= 2
34. i, ii, iii, vi are correct.
OH
OH OH
OH
OH
OH , OH OH
35. X is 3( , OH )
NH 2
CH 2 NH 2 NH CH 3 NH 2 NH 2
CH 3
CH 3 CH3 )
Y is 5( , , , ,
36. X=5( , , , , )
Y = 5( , , , , )
MATHS
3
37. Sol. slope of 3x 2y 1 is
2
1 3
f1
2 2
x x 1 0 1 1
p lim 2x 2x
x 0 e e 0 1 1 3
f f f1 f1
2 2 2 2
1 1 1/ 3 1/ 3 1
pr .....
r 1 3 32 1 1/ 3 2/ 3 2
2013_PAPER-II
IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS.
Darken the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as:
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
21-10-17_Jr.Super60-I_Jee Adv_WAT-22_Weekend Syllabus
MATHS: SYLLABUS COVERED FROM 16-10-17 TO 20-10-2017
PHYSICS: SYLLABUS COVERD FROM 16-10-17 TO 20-10-2017
CHEMISTRY: Geometrical isomerism, Conformational isomerism of ethane, butane, derivatives of
ethane and cyclohexane
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1 x
B) the unit of sin 1 is radian
b
C) the dimensions of x are same as those of b
D) the unit of a is metre
1
4. The speeds of two particles are measured to be v1 10.20 0.02 ms and
B) may be infinity
D) must be zero
K2
B) T 2 here K radius of gyration
g
C) T1 2
g
1 T0
D) f here linear density , T0 =tension in string
8. If the dimension of the length are expressed as G x c y h z , where G, c and h are the
universal gravitational constant, speed of light and Planck’s constant respectively, then
A) x 1/ 2, y 1/ 2 B) x 1/ 2, z 1/ 2
C) y 1/ 2,z 3/ 2 D) y 3/ 2, z 1/ 2
SEC: Jr. Super60-I space for rough work Page 6
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C
Here, L = Distance between suspension point O and centre C of the ball,
g = Acceleration due to gravity.
In the determination of value of acceleration due to gravity g by simple pendulum, the
time period is measured by a stopwatch whose least count is 0.5 s and the length of
string is measured with a meter scale, having least count of 1 mm. The diameter of the
SEC: Jr. Super60-I space for rough work Page 7
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A) M 1L0T 0 B) M0 L 1T 0 C) M 0 L0T 1
D) M 0 L0T 0
SECTION – III
(MATRIX MATCH TYPE)
This section contains 4 multiple choice questions. Each question has matching lists. The codes for the lists
have choices (A), (B), (C), and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
17. Considering Force (F), Velocity (V) and Energy (E) as fundamental quantities, match
the correct dimensions of following quantities
Column I Column II
I. Mass P. [F–1 V° E1]
F time is (-2)
C 2
A) P B) S C) Q D) R
A) Z azobenzene E azobenzene
OH
H3C H3C
C=N C=N
H OH H
B) E acetaldoxime Z acetaldoxime
H COOH H H
C=C C=C
H COOH
NH2 NH2
D) Z-isomer E-isomer
A) B)
C) D)
B)
Me
F
A)
CI Me
CH3
H
CH3 CI
C) D)
H CH3
H H
A) H 3C CH 2 CH CH CH 3 B)
H3C OH
H3C OH
C = N
C) H D) H3C CH3
H H
Y
In substituted cyclohexane, groups larger than hydrogen are more stable in the
equatorial position. The cis isomers has two groups on the same side of the ring, either
both up or both down. The trans isomer has two groups on opposite side of the ring,
one up and one down.
A) B)
C) D)
30. Find out most stable conformer of cis-3-fluorocyclohexanol
A) B)
C) D)
SEC: Jr. Super60-I space for rough work Page 21
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Stereoisomers, which can be interconverted simply by rotation about sigma bonds, are
conformational isomers. While those, which can be converted only by breaking and
remaking of bonds and not simply by rotation, are called configurational isomers.
The angle between C – C and C – H bonds on adjacent carbon atoms in any
conformation is called dihedral angle. The cyclic compounds most commonly found in
nature containing six membered rings can exist in a conformation that is almost
completely free of strain. The most stable conformation of cyclohexane is chair form.
According to Bayer strain theory, the greater is the deviation from the normal
tetrahedral angle, greater is the angle strain or torsional strain and hence lesser is the
stability of the cycloalkane.
33. Dihedral angle between two methyl groups of n-butane in the gauche and anti forms
respectively are:
A) 600, 00 B) 600 and 1800 C) 00, 600 D) 1800, 600
34. Which among the following conformation of cyclohexane is the most stable form?
A) Chair form B) Half chair form
C) Twist boat form D) Boat form
SEC: Jr. Super60-I space for rough work Page 23
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A) Br Br B) CH3
H 3C CH3
CH = C H 3C
CH3 CH3
CH3 H
C) H3C D) H3C
36. The number of G.I. of the compound
C2 H 5 CH CH CH CH CH CH CH 3 is
A) 4 B) 3 C) 8 D) 6
SEC: Jr. Super60-I space for rough work Page 24
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CH3
H
CH3
H CH3
IV. S. Zero
H H
H
I II III IV
A) P Q S R
B) Q R P S
C) S Q P R
D) P Q R S
from Column II
Column I Column II
I. CH 3 CH C CH CH 3 P. 4
II. CH 3 CH CH CH N OH Q. 8
III. CH 3 CH C C CH CH 3 R. 0
IV. CH 3 CH CH CH CH CH CH C2 H 5 S. 2
I II III IV
A) S P R Q
B) R P S Q
C) Q R S P
D) P Q R S
I Ethane P Gauche
3-Fluoropropanal about
III R Staggered
C 2 C3
I II III IV
A) R S P Q
B) Q R P S
C) R P P Q
D) P Q R S
SEC: Jr. Super60-I space for rough work Page 28
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Column I Column II
R R
HO H H R
I.
H OH
< H OH
P. Torsional strain
R OH
I II III IV I II III IV
A) P Q R S B) Q P R S
C) S Q P R D) R S P Q
SEC: Jr. Super60-I space for rough work Page 29
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f x
A) f is strictly increasing B) lim 1
x x
C) f is strictly decreasing D) f is non-monotonic
42. Let f : R R be defined as f x sin x ax b a, b, R . Then the equation
f x 0 has :
A) only one real root which is positive if a 1, b 0
B) only one real root which is negative if a 1, b 0
C) only one real root which is negative if a 1, b 0
D) only one real root which is positive if a 1, b 0
C) f x is an even function
2
D) Monotonic increasing in 0, 1,
3
44. For which of the following functions Rolle’s theorem is applicable ?
x 2
A) f x ,x 1, 4
2 x
B) f x x 1 x 3/ 2 , x 0,1
3
C) f x x 1 ,x 2,0
5 1
D) f x sgn x sgn x ,x , (sgn (x) denotes signum functions) of x)
2 2
SEC: Jr. Super60-I space for rough work Page 31
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B) f 0 f 2 2f 1
C) f 0 f 2 2f 1
2
D) 2 f 0 f 2 3f
3
2 3
46. Let h x f x f x f x for every real number x. Then
sin x
,x 0
A) f x sin x B) f x x
1, x 0
C) f x cos2 x D) f x sin 2 x sin x
SECTION - II
(COMPREHENSION TYPE)
This section contains 4 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Questions 49 and 50
4 2
Consider, f x 2 x 3cos x, R.
49. The least positive integral value of for which f x is monotonically increasing for
all x R.
A) 2 B) 3 C) 4 D) 5
50. For 2, if f x x2 f sin x , then the sum of all integral values of x, is:
A) 3 B) 5 C) 6 D) 10
10,10 :
A) 3 B) 5 C) 16 D) 18
A) g (x) is decreasing in ,
4 2
B) g (x) increasing in 0,
4
C) g x is monotonically increasing
D) None of these
SEC: Jr. Super60-I space for rough work Page 35
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A. f x x 2 2 x 5 is increasing in P.
x
B. f x e is increasing in Q. ,1 2,
C. f x log e x increasing in R. 1,
x3 3x 2
D. f x 2 x 5 is increasing in S. 0,
3 2
T. R
A B C D
A) R P S Q
B) P R Q S
C) Q R S P
D) S Q P R
SEC: Jr. Super60-I space for rough work Page 37
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1
A. f x x is decreasing in P. R
x
1
B. f x 1 x 3 is decreasing in Q. 0,
e
D. f x x x is decreasing in S. 1,
A B C D
A) R S Q P
B) Q R P S
C) R P S Q
D) Q R S P
Column I Column II
A. f increases on P. log2 3/ 2 ,
B. f decreases on Q. ,log 2 3/ 2
0,
C. g decreases on R. 6
5
D. g increases on S. ,
6
A B C D
A) R P Q S
B) Q S R P
C) P Q S R
D) S R Q P
SEC: Jr. Super60-I space for rough work Page 39
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6 AC 7 ACD 8 BD 9 B 10 A
11 C 12 B 13 D 14 A 15 A
16 B 17 B 18 A 19 A 20 A
CHEMISTRY
21 CD 22 ABC 23 ABC 24 BCD 25 ABD
26 AB 27 ABC 28 BD 29 C 30 A
31 A 32 D 33 B 34 A 35 B
36 C 37 C 38 B 39 C 40 D
MATHS
41 AB 42 ABC 43 AD 44 ABCD 45 BD
46 AC 47 ACD 48 B 49 A 50 C
51 B 52 D 53 A 54 A 55 A
56 D 57 B 58 A 59 C 60 C
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Vrel sin i
2. e , , A / r2
urel sin r
2
5 Nm 2
kg
m5G 2 kg 2
2
UL2 N m kg m / sec m
kg 5 N 2 m 4 sec2
4
kg N m kg 2 m 2 m2
kg kg m / sec 2
dimensionless
kg 2 m 2
1 x
3. a) Here, sin 1 is dimensionless
b
1 x
b) Let sin 1
b
x
sin 1
b
Here, should be in radian.
1 x
So, the unit of sin 1 is radian
b
x
c) Dimensions of Deminsions of 1 = deimensionless
b
Dimension of x= Dimension ob b
Sec:Jr.Super60-I Page 2
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dy
5. y sin or cos
d
Or dy cos d
Or y cos
y cos cos
Or
y y sin
y
Fractional error in y
y tan
But tan has any value from zero to infinity. Hence, fractional error will have any
value from infinity to zero. Hence, options (a) , (b), (c). are correct.
40 s
6. T 2s
20
Further, t = nT = 20T or t 20 T
t T
t T
T 2
Or T t 1 0.05s
t 40
l 1/ 2
Further, T 2 orT g
g
T 1 g
100 100
T 2 g
Percentage error in determination of g is
T 200 0.05
100 200 5%
g T 2
Correct options are (a) and (c).
Sec:Jr.Super60-I Page 3
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x z 0,3x y 2 x 1, 2 x y z 0
x 1/ 2, y 3/ 2, z 1/ 2
L 4 2L
9. T 2 g
g T2
2.45
105.3 106.5 25cm
2
T 2.07s
2 L
g 4
T2
g L 0.1 0.005 2 0.5
2
g L 106.525 2.07 10
0.00098 0.048 0.04898 0.049
g
Percentage error in g 100 0.049 100 4.9%
g
g 2 0.5
10. 0.00098 0.026
g 2 20.07
g
percentage error in calculation of g is 100 0.026 100 2.6%
g
11. and g are the length pendulum and the acceleration due to gravity. Hence, their
respective dimensions are L and LT-2
12. We have,
T k1x g y .... I
Writing dimensions on both sides of eq. (I), we get
Sec:Jr.Super60-I Page 4
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Or M 0 L0T M 0 Lx y T 2y
x y 0 x 2y z 1 2x 2 y z 0
x y 2 y 2y z 2 y 2 y2z
1
y 2y 0 1 L 10 0.11 1000 10 2
2 x 2 y 1 z
14. M MLT MLT LT
x y 1 x 2y z 0 2x 2 y z 0 x 0
1
M 100 0.1 100 2
17. Conceptual
2
mgl MLT L 2
18. (i) B 2
T
l ML
Thus, i q, r
2
F MLT 1
(ii) C T
l2 ML 1
L 2
Thus, ii r
M 1 L3T 2
(iv) R ML º T º
1 2
LT
Thus, iv p, s
1
19. a) i 0.333 0.3
3
Thus, i q
1.00
ii 0.333 0.3
3.00
Thus, ii r
iii 2 0.3 2 0 2
Thus, iii s
iv 2 0.6 2 1 1
Thus, iv p
g1 g 2 g3 g4 g5
20. i
g 5
9.85 9.76 9.91 9.79 9.78 2
9.82ms
5
Thus, i q
2
ii g1 g1 g 0.032ms
2
g2 g2 g 0.060ms
2
g3 g3 g 0.090ms
2
g4 g4 g 0.030ms
2
g5 g5 g 0.040ms
g1 g2 g3 g4 g5 2
g 0.05ms
5
Thus, ii p
g 0.05
iii Re lativeerror 0.0051
g 9.82
Thus, iii s
g
iv Percentage error 100 0.51
g
Thus, iv r
Sec:Jr.Super60-I Page 6
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I) HO H II) HO H
24. Me H
25. As per CIP same priority groups on opposite gives E-isomer and same side Z-isomers
26. 1) Stable due to H- bonding 2) P is most stable due to H-bonding in it’s gauche
conformations.
27. CONCEPTUAL
28. Structural formula 2,2-dimethylbutane is
CH3
4 3
CH3 C CH2-4CH3
CH3
H H
CH3
Sec:Jr.Super60-I Page 7
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But f ' x f x
f x 1
f' x 1 0
1 f x 1 f x
f is strictly increasing
f x f' x f x
Lt Lt dt 1
x x x 1 x 1 f x
As Lt f x
x
If a b, f 0 b and b o f 0 0
If a 1, b 0 then f is decreasing
2
43. f x ,x 1 x
f' x 2 x 3 x 1 3x 2
f" x 2 x 2 15 x 2 2ox b
f 1 f 0
By LMVT, f ' c1
1 0
f 2 f 1
f ' c2
2 1
f ' x is increasing and c1 c2
f ' c1 f ' c2
f 1 f 0 f 2 f 1
f 0 f 2 2f 1
f'1 f' 2
f 2/3 f 0 f 2 f 2/3
2 2 23
0
3
2f 0 f 2 3 f 2/3
Sec:Jr.Super60-I Page 9
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2
3 f x 2f x 1 0, x R
h' x 0 if f ' x 0
h is increasing whenever f is increasing
h' x 0 if f ' x 0
h is decreasing whenever f is decreasing
47. CONCEPTUAL
48. CONCEPTUAL
4 2
PASSAGE I f x 2 x 3 is x, R
4 2
49. f' x 2 3sin x 0
4 2
1 sin x 1 2 3 0
x 3 or 3
Least positive integer 2
f' x 16 8 3sin x 8 3sin x 0
f is increasing
50. f x x2 f sin x
x x2 sin x
x 1,2,3 respectively
sin x 1 2 3 6
PASSAGE II
f x ax 3 bx 2 cx 4
2
f' 2/3 5 / 3, f " 0
3
Degree of f ' x is two f " x is are
2
f' x k x 2/3 c
Sec:Jr.Super60-I Page 10
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d d
g x g x g x .x
dx dx
x. g ' x g x
atx 4, the derivative
4. g ' x g x
1
4. 0
3
1 1
Hence f 4 0 g x and g ' x 1
f 0
PASSAGE III
2
f x cos2 x 2 x 2 1 1 x2, R
53. 1 f x cos2 x 2 x
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3x 2 2 x 1 x 2 2 x 9
2 x 2
x 1,0,1
2
54. f is increasing x R f' x 2sin 2 x 2 2 1 1 / 2x 0
1
at ,f' x 0
2
this is valid only at 1
55. f ' sin x 0 and f " sin x 0 x 0, / 2
g x f sin x f cos x
g is increasing in ,
4 2
g is decreasing in 0,
4
57. CONCEPTUAL
58. CONCEPTUAL
59. CONCEPTUAL
60. CONCEPTUAL
Sec:Jr.Super60-I Page 12
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2015_PAPER-I
IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS.
Darken the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as:
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
28-10-17_Jr.Super60-I_Jee Adv_WAT-23_Weekend Syllabus
MATHS: SYLLABUS COVERED FROM 23-10-17 TO 27-10-2017
PHYSICS: SYLLABUS COVERD FROM 23-10-17 TO 27-10-2017
CHEMISTRY: Optical isomerism, Inductive effect
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Sri Chaitanya IIT Academy 28-10-17_Jr.Super60-I_JEE-Adv_2015_P1_WAT-23_Q'P
JEE-ADVANCE-2015-P1-Model
Time: 3:00 Hours IMPORTANT INSTRUCTIONS Max Marks: 264
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 9 – 18) Questions with Multiple Correct Choice 4 -2 10 40
Matrix Matching
Sec – III(Q.N : 19 – 20) 8 -4 2 16
(+2/-1 for every match)
Total 20 88
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 28) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 29 – 38) Questions with Multiple Correct Choice 4 -2 10 40
Matrix Matching
Sec – III(Q.N : 39 – 40) 8 -4 2 16
(+2/-1 for every match)
Total 20 88
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 41 – 48) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 49 – 58) Questions with Multiple Correct Choice 4 -2 10 40
Matrix Matching
Sec – III(Q.N : 59 – 60) 8 -4 2 16
(+2/-1 for every match)
Total 20 88
Sec: Jr. Super60-I space for rough work Page 2
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Sri Chaitanya IIT Academy 28-10-17_Jr.Super60-I_JEE-Adv_2015_P1_WAT-23_Q'P
PHYSICS Max Marks: 88
SECTION – I
(SINGLE INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer, 0 if not attempted and 0 in all other cases.
1. A circular tube of uniform cross-section is filled with two liquids of densities 1 and
2 such that half of each liquid occupies a quarter of volume of the tube. If the line
joining the free surface of the liquids makes an angle with horizontal, then
1 k12
tan , where K1 and K2 is integer. Find the numerical value K1 / K2?
K 21 2
2. A wooden stick of length L, radius R and density has a small metal piece of mass m
(of negligible volume) attached to its one end. The minimum value for the mass m (in
terms of given parameters) that would make the stick float vertically in equilibrium in
a liquid of density is KR2L 1 . Find the value of K.
Sec: Jr. Super60-I space for rough work Page 3
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Sri Chaitanya IIT Academy 28-10-17_Jr.Super60-I_JEE-Adv_2015_P1_WAT-23_Q'P
3. A cylinder of uniform cross-section is immersed into two liquids as shown in Fig.
Equal volume of cylinder is submerged in both the liquids and density of cylinder is .
The magnitude of acceleration of the cylinder at the shown instant is g/K. Where
equal volume of cylinder in two liquids. Find the value of K.
4. A liquid is kept in a cylindrical vessel which is rotated about its axis. The liquid rises
at the side. If the radius of the vessel is 0.05m and the speed of rotation is 2 rev/sec.
Find the difference in the height of the liquid at the centre of the vessel and its sides
(in cm). g 9.86m / s 2
A
B) the pressure P at the base of the vessel is 2hgg
a
C) the weight of the liquid W is greater than the force exerted by the liquid on the base
D) the walls of the vessel exert a downward force (FW) on the liquid
A) The pressure inside the bottle at the base will remain unaltered
B) The normal reaction on the bottle form the ground will remain unaltered
C) The pressure inside the bottle at the base will increase by an amount (1/2) gH
D) The pressure inside the bottle at the base will decrease by an amount (1/4) gH